ITPI20090027A1 - PHYSIOLOGICALLY AND BIOLOGICALLY ACTIVE SALTS OF CIS-AND TRANS-TRAUMATIC ACID FOR THE TREATMENT OF MONOCOTILEDON AND DICOTILEDON PLANTS - Google Patents

PHYSIOLOGICALLY AND BIOLOGICALLY ACTIVE SALTS OF CIS-AND TRANS-TRAUMATIC ACID FOR THE TREATMENT OF MONOCOTILEDON AND DICOTILEDON PLANTS Download PDF

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Publication number
ITPI20090027A1
ITPI20090027A1 IT000027A ITPI20090027A ITPI20090027A1 IT PI20090027 A1 ITPI20090027 A1 IT PI20090027A1 IT 000027 A IT000027 A IT 000027A IT PI20090027 A ITPI20090027 A IT PI20090027A IT PI20090027 A1 ITPI20090027 A1 IT PI20090027A1
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Prior art keywords
treatment
monocotyledonous
nutrition
dicotyledonous plants
trans
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IT000027A
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Italian (it)
Inventor
Filippo Lulli
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Filippo Lulli
Turf Europ Srl
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Priority to IT000027A priority Critical patent/ITPI20090027A1/en
Publication of ITPI20090027A1 publication Critical patent/ITPI20090027A1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof

Description

DESCRIZIONE DESCRIPTION

E’ stato riscontrato dell’ inventore che i sali dell’acido traumatico (cis- e trans-) e dei cationi agronomicamente e botanicamente attivi manifestano azioni benefiche sui tessuti piante soggette a danni e ferite di varia causa e natura: The inventor found that the traumatic acid salts (cis- and trans-) and agronomically and botanically active cations manifest beneficial actions on plant tissues subject to damage and wounds of various causes and nature:

a) boro a) boron

b) calcio b) football

c) rame c) copper

d) ferro ferrico o ferroso d) ferric or ferrous iron

e) manganese e) manganese

f) magnesio f) magnesium

g) molibdeno g) molybdenum

h) potassio h) potassium

i) zinco i) zinc

j) ammonio quaternario in forma libera o come parte di: j) Quaternary ammonium in free form or as part of:

i. urea the. urea

ii. urea formaldeide (UF) ii. urea formaldehyde (UF)

iii. isobutilidendiurea (IBDU) iii. isobutylideneurea (IBDU)

iv. metilen urea (MU) iv. methylene urea (MU)

I sopraccitati sali abbinano le peculiari capacità rigeneratrici dei tessuti vegetali dell’acido traumatico, inducendo inoltre effetti benefici tipici dei micro- e macronutrienti agrari, in modo sinergico ed amplificato. The aforementioned salts combine the peculiar regenerative abilities of the plant tissues of traumatic acid, also inducing beneficial effects typical of agricultural micro- and macronutrients, in a synergistic and amplified way.

La presente invenzione riguarda l’uso dei sali sopraccitati per la preparazione di formulati fitosanitari ed agronomici somministrabili in soluzione acquosa, sospensione o paste\pomate\gel, per il trattamento terapeutico di danni, ferite e alterazioni istologiche su piante Monocotiledoni o Dicotiledoni causate da stress biotici o abiotici, calpestio, usura e/o pratiche agronomiche, laddove l’azione cicatrizzante e rigenerante dell’acido traumatico sia abbinata all’azione nutritiva e fitoregolativa di cationi agronomicamente e botanicamente attivi. The present invention relates to the use of the aforementioned salts for the preparation of phytosanitary and agronomic formulations that can be administered in aqueous solution, suspension or pastes \ ointments \ gels, for the therapeutic treatment of damage, wounds and histological alterations on Monocotyledonous or Dicotyledonous plants caused by stress. biotic or abiotic, trampling, wear and / or agronomic practices, where the healing and regenerating action of the traumatic acid is combined with the nutritional and phyto-regulating action of agronomically and botanically active cations.

L’inventore desidera fornire una più accurata descrizione dei Sali di acido traumatico e dei cationi agronomicamente e botanicamente attivi oggetto della presente invenzione. I sali di seguito descritti sono stati preparati a base di acido trans-traumatico C12H2o04, peso molecolare Mw = 228.63, punto di fusione 160-162°C, come prodotto dalla Cayman Chemical anche se qualsiasi tipo di acido traumatico (cis- o trans-) prodotto da qualsiasi azienda chimica è utilizzabile per la preparazione dei sali. The inventor wishes to provide a more accurate description of the traumatic acid salts and the agronomically and botanically active cations object of the present invention. The salts described below have been prepared based on trans-traumatic acid C12H2o04, molecular weight Mw = 228.63, melting point 160-162 ° C, as produced by Cayman Chemical even if any type of traumatic acid (cis- or trans- ) produced by any chemical company can be used for the preparation of salts.

o or

a) Traumatato di boro: a) Boron trauma:

Formula: C36H54Oi2B2, Formula: C36H54Oi2B2,

Peso molecolare = 699.62 Molecular weight = 699.62

Analisi elementare calcolata: C 61.74%, H 7.72%, O 27.44%, B 3.10% Calculated elemental analysis: C 61.74%, H 7.72%, O 27.44%, B 3.10%

Analisi elementare sperimentale: C 61.23%, H 8.13%, O 27.30%, B 3.34% Experimental elemental analysis: C 61.23%, H 8.13%, O 27.30%, B 3.34%

Solubilità in acqua > 5 mg/ml, Solubility in water> 5 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

b) Traumatato di calcio: OÌ Formula: Ci2Hi804Ca b) Calcium trauma: OÌ Formula: Ci2Hi804Ca

Peso molecolare = 266.07 Molecular weight = 266.07

Analisi elementare calcolata: C 54.12%, H 6.76%, O 24.06%, Ca 15.06% Calculated elemental analysis: C 54.12%, H 6.76%, O 24.06%, Ca 15.06%

Analisi elementare sperimentale: C 53.87%, H6.35%, O 24.32%, Ca 15.46% Experimental elemental analysis: C 53.87%, H6.35%, O 24.32%, Ca 15.46%

Solubilità in acqua > 2 mg/ml, Solubility in water> 2 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

c) Traumatato di rame c) Trauma of copper

Formula: C12Hi804Cu Formula: C12Hi804Cu

Peso molecolare = 289.55 Molecular weight = 289.55

Analisi elementare calcolata: C 49.73%, H 6.22%, O 22.10%, Cu 21.95% Calculated elemental analysis: C 49.73%, H 6.22%, O 22.10%, Cu 21.95%

Analisi elementare sperimentale: C 49.20%, H 5.88%, O 22.47%, Cu 22.45% Experimental elemental analysis: C 49.20%, H 5.88%, O 22.47%, Cu 22.45%

Solubilità in acqua > 10 mg/ml, Solubility in water> 10 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

d) Traumatato ferrico o ferroso d) Ferric or ferrous injuries

Traumatato ferroso Ferrous injury

Formula: C12H1804Fe Formula: C12H1804Fe

Peso molecolare = 507.84 Molecular weight = 507.84

Analisi elementare calcolata: C 28.35%, H 3.54%, O 12.60%, Fe 55.51% Analisi elementare sperimentale: C 28.77%, 3.03%, O 13.09%, Mg 55.11% Solubilità in acqua > 10 mg/ml, Calculated elemental analysis: C 28.35%, H 3.54%, O 12.60%, Fe 55.51% Experimental elemental analysis: C 28.77%, 3.03%, O 13.09%, Mg 55.11% Solubility in water> 10 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

Traumatato ferrico Traumatized ferric

Formula: C36H54012Fe2Formula: C36H54012Fe2

Peso molecolare = 1241.68 Molecular weight = 1241.68

Analisi elementare calcolata: C 34.79%, H 4.35%, O 15.47%, Fe 45.39% Analisi elementare sperimentale: C 34.23%, H 4.02%, O 15.88%, Fe 45.87% Solubilità in acqua > 10 mg/ml, Calculated elemental analysis: C 34.79%, H 4.35%, O 15.47%, Fe 45.39% Experimental elemental analysis: C 34.23%, H 4.02%, O 15.88%, Fe 45.87% Solubility in water> 10 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

e) Traumatato di manganese e) Manganese injury

Formula: Ci2HigC>4Mn Formula: Ci2HigC> 4Mn

Peso molecolare = 280.9 Molecular weight = 280.9

Analisi elementare calcolata: C 51.25 %, H 6.41 %, O 22.78 %, Mn 19.56 % Analisi elementare sperimentale: C 50.87 %, H 6.12%, O 23.08 %, Mn 19.93 % Solubilità in acqua > 2 mg/ml, Calculated elemental analysis: C 51.25%, H 6.41%, O 22.78%, Mn 19.56% Experimental elemental analysis: C 50.87%, H 6.12%, O 23.08%, Mn 19.93% Solubility in water> 2 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

f) Traumatato di magnesio f) Magnesium injury

Formula: Ci2H1804Mg Formula: Ci2H1804Mg

Peso molecolare = 250.3 Molecular weight = 250.3

Analisi elementare calcolata: C 57.53%, H 7.19%, O 25.57%, Mg 9.71% Analisi elementare sperimentale: C 57.18%, H 6.89%, O 26.01%, Mg 9.92% Calculated elemental analysis: C 57.53%, H 7.19%, O 25.57%, Mg 9.71% Experimental elemental analysis: C 57.18%, H 6.89%, O 26.01%, Mg 9.92%

Solubilità in acqua > 10 mg/ml, Solubility in water> 10 mg / ml,

A <L-Poco solubile in solvente organico A <L-Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

g) Traumatato di molibdeno g) Molybdenum injury

Formula: C36H54O12M02 Formula: C36H54O12M02

Peso molecolare = 869.9 Molecular weight = 869.9

Analisi elementare calcolata: C 49.66%, H 6.21%, O 22.07%, Mo 22.06% Calculated elemental analysis: C 49.66%, H 6.21%, O 22.07%, Mo 22.06%

Analisi elementare sperimentale: C 50.05%, H 5.88%, O 22.45%, Mo 21.62% Experimental elemental analysis: C 50.05%, H 5.88%, O 22.45%, Mo 21.62%

Solubilità in acqua > 5 mg/ml, Solubility in water> 5 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

h) Traumatato di potassio h) Potassium trauma

Formula: Ci2H1g04K2Formula: Ci2H1g04K2

Peso molecolare = 304.2 Molecular weight = 304.2

Analisi elementare calcolata: C 47.34%, H 5.92%, O 21.03%, K 25.71% Calculated elemental analysis: C 47.34%, H 5.92%, O 21.03%, K 25.71%

Analisi elementare sperimentale: C 47.62%, H 6.01%, 021.15%, K 25.22% Experimental elemental analysis: C 47.62%, H 6.01%, 021.15%, K 25.22%

Solubilità in acqua > 10 mg/ml, Solubility in water> 10 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

i) Traumatato di zinco i) Zinc trauma

Formula: Ci2H1804Zn Formula: Ci2H1804Zn

Peso molecolare = 291.39 Molecular weight = 291.39

Analisi elementare calcolata: C 49.42%, H 6.18%, O 21.96%, Zn 22.44% Calculated elemental analysis: C 49.42%, H 6.18%, O 21.96%, Zn 22.44%

Analisi elementare sperimentale: C 49.22%, H 6.08%, O 22.10%, K 22.60% Experimental elemental analysis: C 49.22%, H 6.08%, O 22.10%, K 22.60%

Solubilità in acqua > 10 mg/ml, Solubility in water> 10 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

j) Traumatato di ammonio j) Traumatized by ammonium

Formula: CI2H2604N2Formula: CI2H2604N2

Peso molecolare = 262.0 Molecular weight = 262.0

Analisi elementare calcolata: C 54.96%, H 9.92%, O 24.44%, N 10.68% Analisi elementare sperimentale: C 54.96%, H 9.92%, O 24.44%, N 10.68% Solubilità in acqua > 10 mg/ml, Calculated elemental analysis: C 54.96%, H 9.92%, O 24.44%, N 10.68% Experimental elemental analysis: C 54.96%, H 9.92%, O 24.44%, N 10.68% Solubility in water> 10 mg / ml,

Poco solubile in solvente organico Slightly soluble in organic solvent

Altamente solubile in soluzione tampone (pH>7.2). Highly soluble in buffer solution (pH> 7.2).

Claims (15)

RIVENDICAZIONI 1) Sali dell’acido traumatico, dove lo ione positivo detiene delle proprietà agronomicamente e botanicamente rilevanti per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. CLAIMS 1) Traumatic acid salts, where the positive ion has agronomically and botanically relevant properties for the treatment, nutrition and plant growth regulation of Monocotyledonous or Dicotyledonous plants. 2) Sale di cui alla rivendicazione 1, dove lo ione positivo è il Boro: Traumatato di boro (cis- e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 2) Salt as per claim 1, where the positive ion is Boron: Boron traumatate (cis- and trans-) for the treatment, nutrition and phytoregulation of Monocotyledonous or Dicotyledonous plants. 3) Sale di cui alla rivendicazione 1, dove lo ione positivo è il Calcio: Traumatato di calcio ( cis - e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 3) Salt as per claim 1, where the positive ion is Calcium: Calcium traumatate (cis - and trans-) for the treatment, nutrition and phyto-regulation of Monocotyledonous or Dicotyledonous plants. 4) Sale di cui alla rivendicazione 1 , dove lo ione positivo è il Rame: Traumatato di rame (cis- e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 4) Salt as per claim 1, where the positive ion is Copper: Copper trauma (cis- and trans-) for the treatment, nutrition and phytoregulation of Monocotyledonous or Dicotyledonous plants. 5) Sale di cui alla rivendicazione 1, dove lo ione positivo è il Ferro: Traumatato ferrico e Traumatato ferroso (cis- e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 5) Salt as per claim 1, where the positive ion is Iron: Ferric traumatate and ferrous traumatate (cis- and trans-) for the treatment, nutrition and phyto-regulation of Monocotyledonous or Dicotyledonous plants. 6) Sale di cui alla rivendicazione 1, dove lo ione positivo è il Manganese in qualsiasi stato di coordinazione: Traumatato di manganese (cis- e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 6) Salt as per claim 1, where the positive ion is Manganese in any state of coordination: Manganese traumatate (cis- and trans-) for the treatment, nutrition and phyto-regulation of Monocotyledonous or Dicotyledonous plants. 7) Sale di cui alla rivendicazione 1, dove lo ione positivo è il Magnesio: Traumatato di magnesio (cis- e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 7) Salt as per claim 1, where the positive ion is Magnesium: Magnesium traumatate (cis- and trans-) for the treatment, nutrition and phytoregulation of Monocotyledonous or Dicotyledonous plants. 8) Sale di cui alla rivendicazione 1, dove lo ione positivo è il Molibdeno in qualsiasi stato di coordinazione: Traumatato di molibdeno (c/s- e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 8) Salt as per claim 1, where the positive ion is Molybdenum in any state of coordination: Molybdenum trauma (c / s- and trans-) for the treatment, nutrition and phyto-regulation of Monocotyledonous or Dicotyledonous plants. 9) Sale di cui alla rivendicazione 1, dove lo ione positivo è il Potassio: Traumatato di (cis- e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 9) Salt as per claim 1, where the positive ion is Potassium: Traumatate of (cis- and trans-) for the treatment, nutrition and phytoregulation of Monocotyledonous or Dicotyledonous plants. 10) Sale di cui alla rivendicazione 1, dove lo ione positivo è lo Zinco: Traumatato di zinco ( cis - e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 10) Salt as per claim 1, where the positive ion is Zinc: Traumatized zinc (cis - and trans-) for the treatment, nutrition and phytoregulation of Monocotyledonous or Dicotyledonous plants. 11) Sale di cui alla rivendicazione 1, dove lo ione positivo è l’ammonio quaternario derivante da qualsiasi fonte rilevante: Traumatato di ammonio (c/s- e trans-) per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni. 11) Salt as per claim 1, where the positive ion is the quaternary ammonium deriving from any relevant source: Traumatate of ammonium (c / s- and trans-) for the treatment, nutrition and phyto-regulation of Monocotyledonous or Dicotyledonous plants . 12) Il formulato terapeutico per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni, contenente almeno uno dei sali di cui alle rivendicazioni da 1 a 11 comprese, sotto forma di granuli solubili in acqua o in soluzione tampone fosfatica. 12) The therapeutic formulation for the treatment, nutrition and plant growth regulation of Monocotyledonous or Dicotyledonous plants, containing at least one of the salts referred to in claims 1 to 11 inclusive, in the form of granules soluble in water or in phosphate buffer solution. 13) Il formulato terapeutico per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni, contenente almeno uno dei sali di cui alle rivendicazioni da 1 a 11 comprese, sotto forma di soluzione acquosa o soluzione tampone fosfatica. 13) The therapeutic formulation for the treatment, nutrition and phytoregulation of Monocotyledonous or Dicotyledonous plants, containing at least one of the salts referred to in claims 1 to 11 inclusive, in the form of an aqueous solution or phosphate buffer solution. 14) Il formulato terapeutico per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni, contenente almeno uno dei sali di cui alle rivendicazioni da 1 a 1 1 comprese, sotto forma di sospensione acquosa o sospensione in soluzione tampone fosfatica. 14) The therapeutic formulation for the treatment, nutrition and phytoregulation of Monocotyledonous or Dicotyledonous plants, containing at least one of the salts referred to in claims 1 to 1 inclusive, in the form of aqueous suspension or suspension in phosphate buffer solution. 15) Il formulato terapeutico per il trattamento, la nutrizione e la fitoregolazione di piante Monocotiledoni o Dicotiledoni, contenente almeno uno dei sali di cui alle rivendicazioni da 1 a 11 comprese, sotto forma di pasta, pomata o gel a base di acqua o lipidi.15) The therapeutic formulation for the treatment, nutrition and phytoregulation of Monocotyledonous or Dicotyledonous plants, containing at least one of the salts referred to in claims 1 to 11 inclusive, in the form of a paste, ointment or gel based on water or lipids.
IT000027A 2009-03-12 2009-03-12 PHYSIOLOGICALLY AND BIOLOGICALLY ACTIVE SALTS OF CIS-AND TRANS-TRAUMATIC ACID FOR THE TREATMENT OF MONOCOTILEDON AND DICOTILEDON PLANTS ITPI20090027A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3532636A (en) * 1968-02-14 1970-10-06 Purex Corp Ltd Detergent composition
US3640698A (en) * 1970-03-19 1972-02-08 Union Oil Co Fertilizer urea solutions containing micronutrients
EP0599188A1 (en) * 1992-11-23 1994-06-01 LIFEGROUP S.p.A. Trans and CIS traumatic acid salts having cicatrizant activity associated to bacteriostatic, antiviral, antibiotic or antifungal activity

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3532636A (en) * 1968-02-14 1970-10-06 Purex Corp Ltd Detergent composition
US3640698A (en) * 1970-03-19 1972-02-08 Union Oil Co Fertilizer urea solutions containing micronutrients
EP0599188A1 (en) * 1992-11-23 1994-06-01 LIFEGROUP S.p.A. Trans and CIS traumatic acid salts having cicatrizant activity associated to bacteriostatic, antiviral, antibiotic or antifungal activity

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
KATO S. ET AL.: "Isolation and Identification of a Substance Interfering with Local Lesion Formation Produced in Cowpea Leaves Locally Infected with Cucumber Mosaic Virus", ANN. PHYTOPATH.SOC.JAPAN, vol. 42, 1976, pages 450 - 455, XP002572186 *
LONERAGAN J.F.: "Plant mineral nutrition", ACCESSSCIENCE@MCGRAW-HILL, XP002572185, Retrieved from the Internet <URL:http://www.accessscience.com> [retrieved on 20100309] *
SWAMY B G L ET AL: "WOUND HEALING RESPONSES IN MONOCOTYLEDONS PART 2 RESPONSES TO CHEMICAL TREATMENTS", PHYTOMORPHOLOGY, vol. 25, no. 3, 1975, pages 255 - 261, XP009130572, ISSN: 0031-9449 *

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