ITGE20090006A1 - "METHOD FOR OBTAINING SAFETY PAPER WITH EFFECT SIMILAR THROUGH SCREEN PRINTING OR OFFSET, AND COMPOSITION FOR THE IMPLEMENTATION OF SUCH METHOD". - Google Patents

"METHOD FOR OBTAINING SAFETY PAPER WITH EFFECT SIMILAR THROUGH SCREEN PRINTING OR OFFSET, AND COMPOSITION FOR THE IMPLEMENTATION OF SUCH METHOD". Download PDF

Info

Publication number
ITGE20090006A1
ITGE20090006A1 IT000006A ITGE20090006A ITGE20090006A1 IT GE20090006 A1 ITGE20090006 A1 IT GE20090006A1 IT 000006 A IT000006 A IT 000006A IT GE20090006 A ITGE20090006 A IT GE20090006A IT GE20090006 A1 ITGE20090006 A1 IT GE20090006A1
Authority
IT
Italy
Prior art keywords
printing
watermark
security paper
composition
effect similar
Prior art date
Application number
IT000006A
Other languages
Italian (it)
Inventor
Michele Tecchia
Original Assignee
Emme & Emme S R L
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Emme & Emme S R L filed Critical Emme & Emme S R L
Priority to IT000006A priority Critical patent/ITGE20090006A1/en
Publication of ITGE20090006A1 publication Critical patent/ITGE20090006A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/10Watermarks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/20Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
    • B42D25/29Securities; Bank notes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • B42D2033/28
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30Identification or security features, e.g. for preventing forgery
    • B42D25/333Watermarks

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Business, Economics & Management (AREA)
  • Accounting & Taxation (AREA)
  • Finance (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)

Description

DESCRIZIONE del brevetto per invenzione industriale avente per titolo: “Metodo per l'ottenimento di carta di sicurezza con effetto simile alla filigrana mediante stampa serigrafica o offset, e composizione per l'attuazione di detto metodo” DESCRIPTION of the patent for industrial invention entitled: "Method for obtaining security paper with an effect similar to watermark by silk-screen or offset printing, and composition for the implementation of this method"

TESTO DELLA DESCRIZIONE TEXT OF THE DESCRIPTION

La presente invenzione ha per oggetto un metodo per l'ottenimento di carta di sicurezza con effetto simile alla filigrana mediante stampa serigrafica o mediante stampa offset, nonché una composizione per l'attuazione di detto metodo. The present invention relates to a method for obtaining security paper with an effect similar to watermark by screen printing or by offset printing, as well as a composition for implementing said method.

E' noto che, a parità di altre condizioni, lo spessore del foglio di carta è uno degli elementi che ne determina la trasparenza alla luce: zone più sottili sono più trasparenti, e la loro osservazione è agevole ponendo il foglio controluce. Creando volutamente queste differenze di spessore si ottiene quella che viene denominata la "filigrana". It is known that, other things being equal, the thickness of the paper sheet is one of the elements that determines its transparency to light: thinner areas are more transparent, and their observation is easy by placing the sheet against the light. By deliberately creating these differences in thickness you get what is called the "watermark".

Molti sono i sistemi in uso per la realizzazione di una filigrana su un foglio di carta. Il sistema più antico, operante a umido, consiste nel formare su una tela un disegno in rilievo che al momento di ricevere l'impasto fibroso produrrà un foglio con quelle ineguaglianze di spessore che daranno al disegno l'effetto filigrana desiderato. There are many systems in use for creating a watermark on a sheet of paper. The most ancient system, operating wet, consists in forming a relief design on a canvas which, upon receiving the fibrous mixture, will produce a sheet with those inequalities in thickness that will give the drawing the desired filigree effect.

In alternativa al sistema ad umido su impasto fibroso, si può operare con un sistema a secco su un foglio finito. Secondo tale sistema, il foglio di carta preventivamente inumidito viene sottoposto a forte pressione sotto una matrice portante in rilievo il disegno desiderato. La maggiore pressione, nei punti di maggiore rilievo della matrice, darà minore spessore e maggiore compattezza al contesto fibroso e quindi maggiore trasparenza, con formazione del disegno in filigrana. As an alternative to the wet system on fibrous mixture, it is possible to operate with a dry system on a finished sheet. According to this system, the previously moistened sheet of paper is subjected to strong pressure under a matrix bearing the desired design in relief. The greater pressure, in the most prominent points of the matrix, will give less thickness and greater compactness to the fibrous context and therefore greater transparency, with the formation of the filigree design.

Questo secondo sistema pur essendo più pratico di quello ad umido, resta tuttavia notevolmente costoso dato che richiede l'uso di una pressa e l'approntamento di una matrice in acciaio per ciascun disegno che si desidera imprimere in filigrana. Although this second system is more practical than the wet one, it is nevertheless considerably expensive since it requires the use of a press and the preparation of a steel matrix for each design to be imprinted in filigree.

Costituisce pertanto lo scopo della presente invenzione un metodo per l'ottenimento di carta di sicurezza con effetto simile alla filigrana mediante stampa serigrafica o mediante stampa in offset. Therefore, the object of the present invention is a method for obtaining security paper with an effect similar to the watermark by silk-screen printing or by offset printing.

Ulteriore scopo della presente invenzione è una composizione per l'attuazione di detto metodo. A further object of the present invention is a composition for carrying out said method.

Il sistema di stampa serigrafica è ben noto. Secondo tale sistema per l'approntamento del cliché di stampa serigrafica si prepara dapprima su una pellicola di acetato di cellulosa, mediante un procedimento di stampa da computer o fotografico, il marchio da riprodurre in filigrana. The screen printing system is well known. According to this system for the preparation of the silk-screen printing plate, the brand to be reproduced in watermark is first prepared on a cellulose acetate film, by means of a computer or photographic printing process.

Successivamente, su un telaio costituito da una cornice nella quale è tesa una tela di seta sintetica coperta da uno strato di gelatina fotosensibile, si applica la pellicola in acetato di cellulosa recante il marchio da riprodurre in serigrafia, e il telaio con la pellicola viene esposto ad una sorgente di luce UV per qualche minuto. Questo trattamento rende insolubile all'acqua la gelatina che era stata esposta alla luce, mentre resta solubile quella parte di gelatina che era schermata dalla luce grazie all disegno del marchio. Si procede pertanto allo sviluppo del cliché serigrafico mediante un getto di acqua che rimuove la gelatina non insolubilizzata, facendo così emergere il cliché di stampa. A questo punto il cliché di stampa è pronto per l'uso. Subsequently, on a frame consisting of a frame in which a synthetic silk cloth covered with a layer of photosensitive gelatin is stretched, the cellulose acetate film is applied bearing the brand to be silkscreened, and the frame with the film is exposed to a UV light source for a few minutes. This treatment makes the gelatine that had been exposed to light insoluble to water, while that part of the gelatine that was shielded from light by the design of the brand remains soluble. Therefore, the screen printing cliché is developed by means of a jet of water which removes the non-insolubilized gelatin, thus making the printing cliché emerge. At this point the printing plate is ready for use.

Secondo la presente invenzione, per l'ottenimento di carta di sicurezza con effetto simile alla filigrana mediante un cliché per stampa serigrafica del tipo di cui sopra, è necessario procedere alla preparazione della composizione di stampa. According to the present invention, in order to obtain security paper with an effect similar to the watermark by means of a cliché for screen printing of the above type, it is necessary to proceed with the preparation of the printing composition.

A tale scopo, si prepara una composizione contenente, in percentuale in peso: For this purpose, a composition is prepared containing, in percentage by weight:

glicolato di butile dal 20% al 30% 20% to 30% butyl glycolate

1 metossi-2propanolo dal 19% al 29% 1 methoxy-2propanol from 19% to 29%

etil lattato dal 0% al 10% ethyl lactate 0% to 10%

Resina acrilica dal 22% al 32% 22% to 32% acrylic resin

Nafta solvente aromatica leggera dal 12% al 22 % Light aromatic solvent naphtha from 12% to 22%

Etossipropilacetato dal 0% al 7% Ethoxypropylacetate 0% to 7%

La resina acrilica è costituita acido poliacrilico o acido polimetacrilico o ancora da una miscela di questi due acidi. Essa ha lo scopo sia di regolare la viscosità del prodotto finale che di regolare il contrasto della filigrana chimica prodotta. Tale resina viene disciolta a freddo in una miscela solvente costituita dal 20 al 30% di gliconato di butile e dal 19 al 29% di 1-metossi propanolo, con la eventuale aggiunta di una percentuale massima del 10% di etil lattato. Alla soluzione così ottenuta si aggiunge dal 12 al 22 % di nafta solvente aromatica leggera e, se necessario per favorire la solubilità della nafta, si aggiunge sino al massimo del 7% di etossipropilacetato. Il composto fluido così ottenuto viene spalmato sul clichè di stampa preventivamente preparato, e si procede successivamente alla stampa su carta. The acrylic resin consists of polyacrylic acid or polymethacrylic acid or a mixture of these two acids. It has the purpose of both regulating the viscosity of the final product and regulating the contrast of the chemical watermark produced. This resin is cold dissolved in a solvent mixture consisting of 20 to 30% of butyl glyconate and 19 to 29% of 1-methoxy propanol, with the possible addition of a maximum percentage of 10% of ethyl lactate. To the solution thus obtained is added from 12 to 22% of light aromatic solvent naphtha and, if necessary to favor the solubility of the naphtha, up to a maximum of 7% of ethoxypropyl acetate is added. The fluid compound thus obtained is spread on the previously prepared printing plate, and then it is printed on paper.

In maniera del tutto sorprendente si ottiene sui fogli di carta una stampa serigrafica che presenta un effetto ottico del tutto analogo a quello ottenibile mediante i procedimenti di impressione della filigrana. In a completely surprising way, a silk-screen printing is obtained on the sheets of paper which has an optical effect which is entirely similar to that which can be obtained by means of the watermark printing procedures.

I vantaggi ottenibili con il procedimento e con la composizione di cui sopra sono evidenti. Il procedimento di creazione di una filigrana viene notevolmente semplificato. Il costo per l'approntamento del cliché di stampa è una frazione di quello necessario per la preparazione dei cliché di impressione usati nei procedimenti di realizzazione delle filigrane. Pertanto il costo finale risulta molto ridotto, mentre l'effetto di "sicurezza" fornito dalla stampa ottenute è del tutto paragonabile a quello ottenibile con i sistemi tradizionali di impressione di una filigrana. The advantages obtainable with the above process and composition are evident. The process of creating a watermark is greatly simplified. The cost for the preparation of the printing plate is a fraction of that necessary for the preparation of the printing plates used in the processes of making watermarks. Therefore, the final cost is very low, while the "security" effect provided by the printing obtained is completely comparable to that obtainable with traditional watermark printing systems.

Naturalmente la presente invenzione non è limitata a quanto descritto, ma comprende tutte quelle varianti e modifiche rientranti nell'ambito del concetto inventivo, sostanzialmente come a seguito rivendicato. Naturally, the present invention is not limited to what has been described, but includes all those variations and modifications falling within the scope of the inventive concept, substantially as claimed hereinafter.

Così, ad esempio, la composizione secondo l'invenzione può essere impiegata per il medesimo scopo invece che in un procedimento di stampa serigrafica, anche in combinazione con un procedimento di stampa offset, al posto dei comuni inchiostri di stampa. Thus, for example, the composition according to the invention can be used for the same purpose instead of in a screen printing process, also in combination with an offset printing process, instead of common printing inks.

Claims (1)

RIVENDICAZIONI 1) Composizione utilizzabile in un procedimento di stampa serigrafica o offset per l'ottenimento di carta di sicurezza con effetto simile alla filigrana caratterizzata dal fatto che comprende, in percentuali in peso: glicolato di butile dal 20% al 30% 1 metossi-2propanolo dal 19% al 29% etil lattato dal 0% al 10% Resina acrilica dal 22% al 32% Nafta solvente aromatica leggera dal 12% al 22 % Etossipropilacetato dal 0% al 7% 2) Composizione secondo la rivendicazione 1, in cui detta resina acrilica è costituita acido poliacrilico o acido polimetacrilico o ancora da una miscela di questi due acidi. 3) Composizione secondo le rivendicazioni 1 o 2, in cui detta resina viene disciolta a freddo in una miscela solvente costituita dal 20 al 30% di gliconato di butile e dal 19 al 29% di 1-metossi propanolo, con la eventuale aggiunta di una percentuale massima del 10% di etil lattato. 4) Composizione secondo la rivendicazione 3, in cui alla soluzione di resina così ottenuta si aggiunge dal 12 al 22 % di nafta solvente aromatica leggera e, se necessario per favorire la solubilità della nafta, si aggiunge sino al massimo del 7% di etossipropilacetato. 5) Metodo per l'ottenimento di carta di sicurezza con effetto simile alla filigrana mediante stampa serigrafica caratterizzato dal fatto che si prepara un cliché di stampa serigrafica sul quale viene poi spalmata la composizione di stampa di cui alle rivendicazioni 1 a 4, procedendo poi alla stampa dei fogli di carta di sicurezza con effetto filigrana ottica. 6) Metodo per l'ottenimento di carta di sicurezza con effetto simile alla filigrana mediante stampa offset caratterizzato dal fatto che si prepara un cliché di stampa offset, venendo su detto cliché alimentata dal rullo di trasporto la composizione di stampa di cui alle rivendicazioni 1 a 4, procedendo poi alla stampa dei fogli di carta di sicurezza con effetto filigrana ottica. 7) Fogli di carta di sicurezza provvisti di filigrana ottica ottenuti mediante stampa serigrafica o offset, utilizzando quale inchiostro di stampa la composizione di cui alle rivendicazioni 1 a 4.CLAIMS 1) Composition usable in a screen printing or offset printing process to obtain security paper with an effect similar to watermark characterized by the fact that it includes, in percentages by weight: 20% to 30% butyl glycolate 1 methoxy-2propanol from 19% to 29% ethyl lactate 0% to 10% 22% to 32% acrylic resin Light aromatic solvent naphtha from 12% to 22% Ethoxypropyl acetate from 0% to 7% 2) Composition according to claim 1, wherein said acrylic resin is constituted by polyacrylic acid or polymethacrylic acid or by a mixture of these two acids. 3) Composition according to claims 1 or 2, in which said resin is cold dissolved in a solvent mixture consisting of 20 to 30% of butyl glyconate and 19 to 29% of 1-methoxy propanol, with the possible addition of a maximum percentage of 10% of ethyl lactate. 4) Composition according to claim 3, in which 12 to 22% of light aromatic solvent naphtha is added to the resin solution thus obtained and, if necessary to favor the solubility of the naphtha, up to a maximum of 7% of ethoxypropyl acetate is added. 5) Method for obtaining security paper with an effect similar to watermark by screen printing characterized in that a screen printing cliché is prepared on which the printing composition referred to in claims 1 to 4 is then spread, then proceeding to printing of security paper sheets with optical watermark effect. 6) Method for obtaining security paper with an effect similar to watermark by means of offset printing characterized in that an offset printing plate is prepared, the printing composition according to claims 1 a being fed onto said plate from the transport roller 4, then proceeding to print the sheets of security paper with optical watermark effect. 7) Sheets of security paper provided with optical watermark obtained by silk-screen or offset printing, using the composition referred to in claims 1 to 4 as printing ink.
IT000006A 2009-02-06 2009-02-06 "METHOD FOR OBTAINING SAFETY PAPER WITH EFFECT SIMILAR THROUGH SCREEN PRINTING OR OFFSET, AND COMPOSITION FOR THE IMPLEMENTATION OF SUCH METHOD". ITGE20090006A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
IT000006A ITGE20090006A1 (en) 2009-02-06 2009-02-06 "METHOD FOR OBTAINING SAFETY PAPER WITH EFFECT SIMILAR THROUGH SCREEN PRINTING OR OFFSET, AND COMPOSITION FOR THE IMPLEMENTATION OF SUCH METHOD".

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT000006A ITGE20090006A1 (en) 2009-02-06 2009-02-06 "METHOD FOR OBTAINING SAFETY PAPER WITH EFFECT SIMILAR THROUGH SCREEN PRINTING OR OFFSET, AND COMPOSITION FOR THE IMPLEMENTATION OF SUCH METHOD".

Publications (1)

Publication Number Publication Date
ITGE20090006A1 true ITGE20090006A1 (en) 2010-08-07

Family

ID=42041585

Family Applications (1)

Application Number Title Priority Date Filing Date
IT000006A ITGE20090006A1 (en) 2009-02-06 2009-02-06 "METHOD FOR OBTAINING SAFETY PAPER WITH EFFECT SIMILAR THROUGH SCREEN PRINTING OR OFFSET, AND COMPOSITION FOR THE IMPLEMENTATION OF SUCH METHOD".

Country Status (1)

Country Link
IT (1) ITGE20090006A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3985927A (en) * 1975-02-24 1976-10-12 Nekoosa Edwards Paper Company, Inc. Compositions and method for producing a chemical watermark on finished paper products
US4600629A (en) * 1985-09-16 1986-07-15 Westvaco Corporation Selectively absorbent mask printing process
US4919044A (en) * 1985-11-04 1990-04-24 Westvaco Corporation Simulated watermark printing system
EP1338431A2 (en) * 2002-02-08 2003-08-27 Fuji Photo Film Co., Ltd. Visible image receiving material having surface hydrophilicity

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3985927A (en) * 1975-02-24 1976-10-12 Nekoosa Edwards Paper Company, Inc. Compositions and method for producing a chemical watermark on finished paper products
US4600629A (en) * 1985-09-16 1986-07-15 Westvaco Corporation Selectively absorbent mask printing process
US4919044A (en) * 1985-11-04 1990-04-24 Westvaco Corporation Simulated watermark printing system
EP1338431A2 (en) * 2002-02-08 2003-08-27 Fuji Photo Film Co., Ltd. Visible image receiving material having surface hydrophilicity

Similar Documents

Publication Publication Date Title
JP2014046694A5 (en) Ink-type digital printing method and dampening solution used therefor
PL2293946T3 (en) Procédé et dispositif d'impression de papier imprimé
CN104553414A (en) Prior-ironing and after-printing online printing method of cigarette packing box
CN103317872B (en) Paper light line typography
CN100591530C (en) Waterproof jet ink plate-making transparent film for print plate-making industry and its preparation
CN108396573A (en) A kind of towel printing technology
CN202986300U (en) Intaglio press for easy-to-stretch printing materials
US20060078673A1 (en) Method for printing using invisible inks
WO2011139338A3 (en) Processless development of printing plate
ITGE20090006A1 (en) "METHOD FOR OBTAINING SAFETY PAPER WITH EFFECT SIMILAR THROUGH SCREEN PRINTING OR OFFSET, AND COMPOSITION FOR THE IMPLEMENTATION OF SUCH METHOD".
WO2011109349A3 (en) Luminous printing
CN102107554B (en) Printing process and printing auxiliary agent used by same
KR20110080566A (en) A transfer paper for printing cloth, the manufacturing method thereof and the printing method thereby
CN102516846B (en) Production technique of coating fluid and miniaturized anti-counterfeiting transfer printing mark
JP2012148406A (en) Construction method for printing on sheet such as film by using concrete surface setting retarder as ink base stock in connection with technique for forming decorative concrete by using concrete surface setting retarder
BR112016019848B1 (en) METHOD OF TRANSFERRING PRINTS FROM A SUBSTRATE TO A SURFACE
DE832544C (en) Printing process for combined gravure and flat printing
CN104708892B (en) Improved multicolor stone thick plate printing plate-making method
DE445078C (en) Material and process for the production of photographic images and prints with an easily transferable, unreinforced and unhardened light-sensitive layer
ATE454990T1 (en) METHOD AND DEVICE FOR PRINTING A SUBSTRATE
TW550189B (en) Method for applying computer-aided design in coating curve faces by means of water trans-printing
DE87472C (en)
SU16681A1 (en) The method of obtaining prints of inscriptions or images intended for conversion to wood, fabrics and other suction materials
DE441265C (en) Process for the production of master copies for offset printing, gravure printing or the like.
US1521747A (en) Process of lithographing