IT202100033083A1 - Method and related plant for the creation of conductive pigments from production waste from laser and plasma cutting processes - Google Patents

Method and related plant for the creation of conductive pigments from production waste from laser and plasma cutting processes Download PDF

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Publication number
IT202100033083A1
IT202100033083A1 IT102021000033083A IT202100033083A IT202100033083A1 IT 202100033083 A1 IT202100033083 A1 IT 202100033083A1 IT 102021000033083 A IT102021000033083 A IT 102021000033083A IT 202100033083 A IT202100033083 A IT 202100033083A IT 202100033083 A1 IT202100033083 A1 IT 202100033083A1
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Italy
Prior art keywords
phase
creation
production waste
metal
pigment
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IT102021000033083A
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Italian (it)
Inventor
Sergio Coretti
Tommaso Francesco Lamagna
Sara Quarto
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Sergio Coretti Srl
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Priority to IT102021000033083A priority Critical patent/IT202100033083A1/en
Publication of IT202100033083A1 publication Critical patent/IT202100033083A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62Metallic pigments or fillers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62Metallic pigments or fillers
    • C09C1/622Comminution, shaping or abrasion of initially uncoated particles, possibly in presence of grinding aids, abrasives or chemical treating or coating agents; Particle solidification from melted or vaporised metal; Classification
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Processing Of Solid Wastes (AREA)

Description

DESCRIZIONE DESCRIPTION

La presente invenzione riguarda un metodo e relativo impianto per la creazione di pigmenti conduttivi a partire da scarti di produzione di tagli laser. The present invention concerns a method and related plant for the creation of conductive pigments starting from laser cutting production waste.

I rifiuti speciali sono quei rifiuti che derivano prevalentemente dalle produzioni di tipo industriale e che necessitano di un loro personale percorso ai fini dello smaltimento. A differenza di quelli urbani, che consistono nei rifiuti che buttiamo nei bidoni di casa, che vengono raccolti per le strade o nelle aree pubbliche e quelli vegetali provenienti dalle aree verdi, i rifiuti speciali necessitano interventi di smaltimento particolari e appositi, per la maggior parte delle volte effettuati da privati, come ad esempio i rifiuti derivanti da lavorazione industriali, i rifiuti di attivit? commerciali, i fanghi che derivano dal trattamento delle acque e depurazione delle acque reflue e da abbattimento di fumi, i rifiuti derivanti da attivit? sanitarie o ancora quelli derivanti da macchinari e apparecchiature vecchi o rovinati o da veicoli a motore e rimorchi ormai inutilizzabili. A differenza dei rifiuti urbani, che vengono raccolti e gestiti dalla pubblica amministrazione, lo smaltimento dei rifiuti speciali viene effettuato da un sistema di aziende private; avviene prevalentemente attraverso il recupero di materia, ovvero il riciclo, oppure attraverso lo smaltimento in discarica, l?incenerimento, l?avvio al recupero di energia. Tra i rifiuti speciali va tenuta in considerazione la sottocategoria riguardante i rifiuti pericolosi, che necessitano di un altro tipo di gestione. Vengono considerati rifiuti speciali pericolosi tutti quei rifiuti generati dalle attivit? produttive che contengono al loro interno un?elevata dose di sostanze inquinanti: i rifiuti prodotti dalle industrie manifatturiere o dalle attivit? di trattamento rifiuti e risanamento, cos? come pu? trattarsi anche di scarti derivanti dalla raffinazione del petrolio, dall?industria fotografica, dalle produzioni che utilizzano processi chimici, da solventi, dall?industria metallurgica o da oli esauriti. Nel nostro ambito, le polveri derivanti dal taglio laser, sono considerate rifiuti speciali non pericolosi, poich? non rientrano nelle categorie sopra elencate. Tuttavia, vista la grossa mole di produzione rappresentano un grosso costo pi? che un problema per l?azienda; anche se questi scarti vengono utilizzati in agricoltura come fertilizzante per i campi, ? necessario rimetterli in circolo con nuove funzionalit? e, vista la capacit? superconduttiva di queste polveri metalliche, si ? pensato di riqualificarle al fine di creare delle vernici conduttive, amalgamandole con una soluzione colloidale (quale pu? essere il polivinilacetato oppure amido di mais e aceto che rappresenta un?ottima soluzione home-made) con l?aggiunta di un pigmento nero al fine di uniformare il colore della vernice. A tal proposito potrebbe essere interessante utilizzare la polvere lavica, altra sostanza naturale considerata e trattata come rifiuto speciale, come pigmento per la vernice: nell?abito della nostra invenzione, infatti, rappresenterebbe un?ottima soluzione in quanto, avendo anch?essa propriet? conduttive, non andrebbe ad impattare negativamente sulla conducibilit? della nostra soluzione fungendo, allo stesso tempo, da pigmento, in quanto nera. Special waste is that waste which mainly derives from industrial production and which requires its own personal path for disposal. Unlike urban waste, which consists of waste that we throw in the bins at home, which is collected on the streets or in public areas and plant waste coming from green areas, special waste requires particular and specific disposal interventions, mostly often carried out by private individuals, such as waste resulting from industrial processing, waste from industrial activities? commercial, the sludge deriving from water treatment and purification of waste water and from fume abatement, waste deriving from activities? healthcare or even those resulting from old or ruined machinery and equipment or from motor vehicles and trailers that are no longer usable. Unlike municipal waste, which is collected and managed by the public administration, the disposal of special waste is carried out by a system of private companies; occurs mainly through the recovery of material, i.e. recycling, or through landfill disposal, incineration, or the initiation of energy recovery. Among special waste, the subcategory concerning hazardous waste, which requires another type of management, must be taken into consideration. Are all those wastes generated by activities considered special hazardous waste? productive ones that contain within them a high dose of polluting substances: the waste produced by manufacturing industries or activities of waste treatment and rehabilitation, so? how can? these may also be waste resulting from oil refining, from the photographic industry, from productions that use chemical processes, from solvents, from the metallurgical industry or from spent oils. In our field, the dust resulting from laser cutting is considered non-hazardous special waste, since it is do not fall into the categories listed above. However, given the large amount of production they represent a large cost. what a problem for the company; even if these wastes are used in agriculture as fertilizer for the fields,? Is it necessary to put them back into circulation with new features? and, given the capacity? superconducting of these metal powders, yes? thought of redeveloping them in order to create conductive paints, mixing them with a colloidal solution (which could be polyvinyl acetate or corn starch and vinegar which represents an excellent home-made solution) with the addition of a black pigment in order to uniform the color of the paint. In this regard, it could be interesting to use lava powder, another natural substance considered and treated as special waste, as a pigment for paint: in the context of our invention, in fact, it would represent an excellent solution as, having also properties conductive, wouldn't it have a negative impact on the conductivity? of our solution acting, at the same time, as a pigment, as it is black.

Scopo della nostra invenzione ? quello dunque di proporre un metodo e relativo impianto per la creazione di pigmenti conduttivi a partire da scarti di produzione di tagli laser che prevede: Purpose of our invention? that is therefore to propose a method and related system for the creation of conductive pigments starting from laser cutting production waste which involves:

- una fase di selezione di scarti di produzione metalliche tramite modulo selettore (1); - a selection phase of metal production waste via selector module (1);

- una fase di polverizzazione degli scarti di produzione mediante polverizzatore (2); - a pulverization phase of production waste using a pulverizer (2);

- una fase di setacciamento mediante filtro ad ultrasuoni (3) delle polveri metalliche prodotte; - a sieving phase using an ultrasonic filter (3) of the metal powders produced;

- una eventuale fase di ripetizione delle due fasi precedenti al fine di ripolverizzare e setacciare i quantitativi residui; - a possible repetition phase of the two previous phases in order to pulverize and sieve the residual quantities;

- una fase di amalgama delle polveri di metallo setacciate con composto collante quale mastice naturale o polivinilacetato o composto collante fatto da amido di mais ed aceto in opportuna vasca (4); - a phase of amalgam of the sieved metal powders with a gluing compound such as natural mastic or polyvinyl acetate or a gluing compound made from corn starch and vinegar in a suitable tank (4);

- una eventuale fase di triturazione di polvere lavica mediante trituratore (6); - a possible lava dust shredding phase using a shredder (6);

- una eventuale fase di aggiunta di polvere lavica triturata quale pigmento per il composto; - a possible phase of adding crushed lava powder as a pigment for the compound;

- una fase di confezionamento del pigmento conduttivo tramite linea di confezionamento definita (5). - a packaging phase of the conductive pigment via a defined packaging line (5).

Il metodo viene implementato mediante specifico impianto per creazione di pigmenti conduttivi composto da: The method is implemented using a specific plant for the creation of conductive pigments composed of:

- cruscotto di interazione uomo macchina per definizione semantica, selezione collante e creazione pigmento (16); - human-machine interaction dashboard for semantic definition, glue selection and pigment creation (16);

- base di conoscenza semantica (13); - semantic knowledge base (13);

- modulo selettore (1); - selector module (1);

- modulo polverizzatore (2); - atomizer module (2);

- modulo trituratore (6); - shredder module (6);

- setaccio ad ultrasuoni (3); - ultrasonic sieve (3);

- vasca (4); - tub (4);

- amalgamatore (15); - amalgamator (15);

- serbatoio di polveri metalliche (10); - metal powder tank (10);

- serbatoio di mastici/collanti (7); - putty/glue tank (7);

- erogatore (16); - dispenser (16);

- serbatoio di polvere lavica (11); - lava powder tank (11);

- linea di confezionamento (5); - packaging line (5);

- aspiratore/filtro di polvere metallica (12); - metal dust aspirator/filter (12);

- CNC/PLC/elaboratore per controllo impianto (8). - CNC/PLC/computer for plant control (8).

L?impianto ? inoltre collegabile o dotato di un modulo aspiratore in grado di aspirare le polveri derivanti dai processi di taglio laser. The plant? It can also be connected to or equipped with a suction module capable of sucking up dust resulting from laser cutting processes.

L?unita in figura ? una rappresentazione esemplificativa e non limitativa dell?impianto oggetto della presente invenzione. The unit in the figure is an exemplary and non-limiting representation of the system which is the subject of the present invention.

Claims (5)

RIVENDICAZIONI 1. Metodo per la creazione di pigmenti conduttivi a partire da scarti di produzione di processi di taglio laser caratterizzato dal fatto che prevede le seguenti fasi:1. Method for the creation of conductive pigments starting from production waste from laser cutting processes characterized by the fact that it involves the following phases: - una fase di selezione di scarti di produzione metalliche tramite modulo selettore (1);- a selection phase of metal production waste via selector module (1); - una fase di polverizzazione degli scarti di produzione mediante polverizzatore (2);- a pulverization phase of production waste using a pulverizer (2); - una fase di setacciamento mediante filtro ad ultrasuoni (3) delle polveri metalliche prodotte;- a sieving phase using an ultrasonic filter (3) of the metal powders produced; - una fase di amalgama delle polveri di metallo setacciate con composto collante quale mastice naturale o polivinilacetato o composto collante fatto da amido di mais ed aceto in vasca (4);- a phase of amalgam of the sieved metal powders with a gluing compound such as natural mastic or polyvinyl acetate or a gluing compound made from corn starch and vinegar in the tank (4); - una fase di confezionamento del pigmento conduttivo tramite linea di confezionamento definita (5).- a packaging phase of the conductive pigment via a defined packaging line (5). 2. Metodo secondo la rivendicazione 1 caratterizzato, inoltre, dal fatto che le fasi di selezione, polverizzazione e setacciamento sono ripetute almeno due volte.2. Method according to claim 1 characterized, furthermore, by the fact that the selection, pulverization and sieving phases are repeated at least twice. 3. Metodo secondo la rivendicazione 1 caratterizzato, inoltre, da una fase di triturazione di polvere lavica mediante trituratore (6) e relativa aggiunta quale pigmento al composto.3. Method according to claim 1 characterized, furthermore, by a phase of trituration of lava powder using a shredder (6) and relative addition as pigment to the compound. 4. Metodo secondo la rivendicazione 1 caratterizzato, inoltre, da una fase iniziale di acquisizione delle polveri metalliche oggetto del metodo mediante aspiratore/filtro (12) da macchinari di lavorazione di ferro e lamiere metalliche. 4. Method according to claim 1 characterized, furthermore, by an initial phase of acquisition of the metal powders object of the method by means of an aspirator/filter (12) from iron and sheet metal processing machinery. 5. Impianto per la creazione di pigmenti conduttivi caratterizzato da:5. Plant for the creation of conductive pigments characterized by: - cruscotto di interazione uomo macchina per definizione semantica, selezione collante e creazione pigmento (16);- human-machine interaction dashboard for semantic definition, glue selection and pigment creation (16); - base di conoscenza semantica (13);- semantic knowledge base (13); - modulo selettore (1);- selector module (1); - modulo polverizzatore (2);- atomizer module (2); - modulo trituratore (6);- shredder module (6); - setaccio ad ultrasuoni (3);- ultrasonic sieve (3); - vasca (4);- tub (4); - amalgamatore (15);- amalgamator (15); - serbatoio di polveri metalliche (10);- metal powder tank (10); - serbatoio di mastici/collanti (7);- putty/glue tank (7); - erogatore (16);- dispenser (16); - serbatoio di polvere lavica (11);- lava powder tank (11); - linea di confezionamento (5);- packaging line (5); - aspiratore/filtro di polvere metallica (12);- metal dust aspirator/filter (12); - CNC/PLC/elaboratore per controllo impianto (8). - CNC/PLC/computer for plant control (8).
IT102021000033083A 2021-12-30 2021-12-30 Method and related plant for the creation of conductive pigments from production waste from laser and plasma cutting processes IT202100033083A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3041303A (en) * 1955-08-03 1962-06-26 Monsanto Chemicals Molding powder comprising polystyrene, white inorganic pigment and finely divided metal powder
US4834800A (en) * 1986-10-15 1989-05-30 Hoeganaes Corporation Iron-based powder mixtures
US5098942A (en) * 1989-11-24 1992-03-24 Fraunhofer-Gesellschaft Zur Forderung Der Andewandten Forschung E.V. Binder for metal or ceramic powder
JPH05310835A (en) * 1992-04-30 1993-11-22 Nippon Synthetic Chem Ind Co Ltd:The Production of metal-containing polyvinyl alcohol

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3041303A (en) * 1955-08-03 1962-06-26 Monsanto Chemicals Molding powder comprising polystyrene, white inorganic pigment and finely divided metal powder
US4834800A (en) * 1986-10-15 1989-05-30 Hoeganaes Corporation Iron-based powder mixtures
US5098942A (en) * 1989-11-24 1992-03-24 Fraunhofer-Gesellschaft Zur Forderung Der Andewandten Forschung E.V. Binder for metal or ceramic powder
JPH05310835A (en) * 1992-04-30 1993-11-22 Nippon Synthetic Chem Ind Co Ltd:The Production of metal-containing polyvinyl alcohol

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DE SOUZA JOSÉ ET AL: "Analysis of Metallic Waste from Laser Cutting for Utilization in Parts Manufactured by Conventional Powder Metallurgy Characterization of galvanic sludge for verification of viability of obtaining ceramic pigments View project Metallurgycal Powder of elementary elements View project", 1 November 2016 (2016-11-01), XP055967271, Retrieved from the Internet <URL:https://www.researchgate.net/publication/309814377_Analysis_of_Metallic_Waste_from_Laser_Cutting_for_Utilization_in_Parts_Manufactured_by_Conventional_Powder_Metallurgy> [retrieved on 20221003], DOI: 10.6084/m9.figshare.12317483 *
ZUBKO MACIEJ ET AL: "Analysis of Stainless Steel Waste Products Generated during Laser Cutting in Nitrogen Atmosphere", METALS, vol. 10, no. 12, 25 November 2020 (2020-11-25), pages 1572, XP055967276, DOI: 10.3390/met10121572 *

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