IT201600092233A1 - POLYMER COMPOSITION AND ITS USE FOR THE ABSORPTION OF LIQUIDS - Google Patents

POLYMER COMPOSITION AND ITS USE FOR THE ABSORPTION OF LIQUIDS

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Publication number
IT201600092233A1
IT201600092233A1 IT102016000092233A IT201600092233A IT201600092233A1 IT 201600092233 A1 IT201600092233 A1 IT 201600092233A1 IT 102016000092233 A IT102016000092233 A IT 102016000092233A IT 201600092233 A IT201600092233 A IT 201600092233A IT 201600092233 A1 IT201600092233 A1 IT 201600092233A1
Authority
IT
Italy
Prior art keywords
composition
present
liquids
calcium carbonate
polymeric composition
Prior art date
Application number
IT102016000092233A
Other languages
Italian (it)
Inventor
Ugo Alampi
Original Assignee
Alampi Giovanni
Alampi Simona
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alampi Giovanni, Alampi Simona filed Critical Alampi Giovanni
Priority to IT102016000092233A priority Critical patent/IT201600092233A1/en
Publication of IT201600092233A1 publication Critical patent/IT201600092233A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/02Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/02Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G1/00Mixtures of fertilisers belonging individually to different subclasses of C05
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

Description

Descrizione di una domanda di brevetto d’invenzione avente per titolo: "Composizione polimerica e suo uso per l’assorbimento di liquidi”. Description of an invention patent application entitled: "Polymer composition and its use for the absorption of liquids".

BACKGROUND DELL’INVENZIONE BACKGROUND OF THE INVENTION

E’ noto che le colture vegetali necessitano acqua per la germinazione e la crescita. Le prime settimane dalla semina si rivelano cruciali per la vita della pianta: un’adeguata idratazione è pertanto necessaria per la crescita vegetale. It is known that vegetable crops need water for germination and growth. The first weeks after sowing are crucial for the life of the plant: adequate hydration is therefore necessary for plant growth.

E’ anche noto che i cambiamenti climatici della nostra epoca hanno causato una serie di problemi che incidono fortemente sulle coltivazioni, come per esempio l’inaridimento di ampie zone geografiche o l’aumento di piogge torrenziali tipiche di climi tropicali. It is also known that the climatic changes of our time have caused a series of problems that strongly affect crops, such as the drying up of large geographical areas or the increase in torrential rains typical of tropical climates.

E’ infine noto che la richiesta di acqua dovuta all’aumento della popolazione ed ad altre ragioni comporta una minore disponibilità della stessa per l’irrigazione agricola. Finally, it is known that the demand for water due to the increase in population and other reasons leads to a lower availability of the same for agricultural irrigation.

E’ pertanto presente la necessità di una soluzione che possa superare gli svantaggi sopra indicati per le colture vegetali in ambienti estremi (aridi e/o in presenza di piogge torrenziali), che possa superare anche gli svantaggi dei costi dovuti all’irrigazione e che possano evitare continue addizione a terreni agricoli. There is therefore a need for a solution that can overcome the disadvantages indicated above for vegetable crops in extreme environments (arid and / or in the presence of torrential rain), which can also overcome the disadvantages of costs due to irrigation and which can avoid continuous addition to agricultural land.

La composizione polimerica della presente invenzione supera inaspettatamente i problemi sopra esposti, oltre ad essere vantaggiosamente biodegradabile, atossica e termoresistente. The polymeric composition of the present invention unexpectedly overcomes the above problems, as well as being advantageously biodegradable, non-toxic and heat-resistant.

SOMMARIO DELL’INVENZIONE SUMMARY OF THE INVENTION

Oggetto della presente invenzione è una composizione polimerica comprendente cellulosa, carbonato di calcio, materiale elastomerico termoplastico. The object of the present invention is a polymeric composition comprising cellulose, calcium carbonate, thermoplastic elastomeric material.

Ulteriore oggetto della presente invenzione è l’uso della composizione polimerica della presente invenzione per l’assorbimento ed il rilascio graduato di liquidi. A further object of the present invention is the use of the polymeric composition of the present invention for the absorption and graded release of liquids.

DESCRIZIONE DETTAGLIATA DELL’INVENZIONE DETAILED DESCRIPTION OF THE INVENTION

Oggetto della presente invenzione è una composizione polimerica comprendente: cellulosa, carbonato di calcio, materiale elastomerico termoplastico. The object of the present invention is a polymeric composition comprising: cellulose, calcium carbonate, thermoplastic elastomeric material.

Secondo la presente invenzione con il termine carbonato di calcio si intendono tutti gli equivalenti allo stesso composto. According to the present invention, the term calcium carbonate refers to all the equivalents to the same compound.

Secondo la presente invenzione, con il termine generico di elastomero si indicano le sostanze naturali o sintetiche che hanno le proprietà chimico-fisiche tipiche del caucciù (o gomma naturale), la più peculiare delle quali è la capacità di subire grosse deformazioni elastiche, ad esempio il poter essere allungate almeno fino al doppio della loro lunghezza per riassumere la propria dimensione una volta ricreata una situazione di riposo. According to the present invention, the generic term of elastomer indicates natural or synthetic substances which have the chemical-physical properties typical of rubber (or natural rubber), the most peculiar of which is the ability to undergo large elastic deformations, for example being able to be stretched at least up to twice their length to resume their size once a situation of rest has been recreated.

Secondo la presente invenzione gli elastomeri termoplastici sono materiali polimerici che possiedono le caratteristiche tipiche degli elastomeri unite a quelle dei termoplastici, in particolare la completa riciclabilità: al contrario delle altre tipologie di elastomeri, detti per l’appunto termoindurenti, i termoplastici possono essere fusi e rilavorati più volte. According to the present invention, thermoplastic elastomers are polymeric materials that possess the typical characteristics of elastomers combined with those of thermoplastics, in particular complete recyclability: unlike other types of elastomers, called thermosetting precisely, thermoplastics can be melted and reworked several times.

Gli elastomeri termoplastici possono essere modellati nelle forme desiderate tramite i classici processi di trasformazione delle materie plastiche: i più comuni sono lo stampaggio a iniezione e l’estrusione. Thermoplastic elastomers can be molded into the desired shapes through the classic transformation processes of plastic materials: the most common are injection molding and extrusion.

Gli elastomeri termoplastici più utilizzati appartengono alle seguenti tipologie: The most used thermoplastic elastomers belong to the following types:

• Copolimeri di stirene e butadiene (TPE-S) • Poliolefine (TPO) • Copolymers of styrene and butadiene (TPE-S) • Polyolefins (TPO)

• Co-poliesteri (COPE) • Co-polyesters (COPE)

• Co-poliammidi (PEBA) • Co-polyamides (PEBA)

• Poliuretani (TPU). • Polyurethanes (TPU).

Preferibilmente, la composizione polimerica secondo la presente invenzione comprende: Preferably, the polymeric composition according to the present invention comprises:

- cellulosa in un intervallo compreso tra 30-60% (p/p); - cellulose in a range between 30-60% (w / w);

- carbonato di calcio in un intervallo compreso tra 30-60% (p/p)%; - calcium carbonate in a range between 30-60% (w / w)%;

- materiale elastomerico termoplastico compreso in un intervallo compreso tra 5-10% (p/p). - thermoplastic elastomeric material included in a range between 5-10% (w / w).

Ancor più preferibilmente, la composizione della presente invenzione comprende cellulosa al 40% (p/p), carbonato di calcio al 50% (p/p) e materiale elastomerico termoplastico al 10% (p/p). Even more preferably, the composition of the present invention comprises 40% (w / w) cellulose, 50% (w / w) calcium carbonate and 10% (w / w) thermoplastic elastomeric material.

Vantaggiosamente, la composizione della presente invenzione è biodegradabile, atossica, ed in grado di assorbire liquidi, preferibilmente acqua, rilasciandola lentamente all’ambiente circostante. Detta composizione polimerica può essere in questo modo mescolata al terreno destinato alla germinazione e crescita di colture vegetali. Preferibilmente, la composizione polimerica della presente invenzione è mescolata al terreno in un quantitativo pari a 10 Kg/m<2>(su uno spessore pari a 20 cm della zolla). Advantageously, the composition of the present invention is biodegradable, non-toxic, and capable of absorbing liquids, preferably water, slowly releasing it to the surrounding environment. Said polymeric composition can in this way be mixed with the soil intended for the germination and growth of vegetable crops. Preferably, the polymeric composition of the present invention is mixed with the soil in an amount equal to 10 Kg / m <2> (on a thickness equal to 20 cm of the clod).

In un’altra forma di realizzazione la presente invenzione fa riferimento all’uso della composizione della presente invenzione per l’assorbimento di liquidi, preferibilmente olii ed acqua, e preferibilmente per l’irrigazione di colture vegetali. Dette colture vegetali posso essere preferibilmente colture agricole, forestali, floricolture, orticolture e colture idroponiche. A seconda delle condizioni climatiche delle zone da coltivare, la composizione polimerica può essere in forma: In another embodiment the present invention refers to the use of the composition of the present invention for the absorption of liquids, preferably oils and water, and preferably for the irrigation of vegetable crops. Said vegetable crops can preferably be agricultural, forestry, floriculture, horticulture and hydroponic crops. Depending on the climatic conditions of the areas to be cultivated, the polymer composition can be in the form:

- idratata; o - hydrated; or

- disidratata. - dehydrated.

Se idratata, la composizione polimerica della presente invenzione ha un lento rilascio che può coprire un periodo temporale fino a 40 giorni, preferibilmente 30 giorni, ancor più preferibilmente 20 giorni. If hydrated, the polymeric composition of the present invention has a slow release which can cover a time period of up to 40 days, preferably 30 days, even more preferably 20 days.

Una volta posizionata nel terreno, la composizione polimerica della presente invenzione è in grado di assorbire l’acqua piovana e rilasciarla lentamente alla pianta prolungando così il suo effetto nel tempo. Once placed in the ground, the polymer composition of the present invention is able to absorb rainwater and slowly release it to the plant, thus prolonging its effect over time.

Vantaggiosamente, la composizione polimerica della presente invenzione mostra inoltre caratteristiche di termo-resistenza. Tale caratteristica consente vantaggiosamente di usare la composizione della presente invenzione per evitare di ghiacciare terreni, asfalti o tappeti erbosi in condizioni climatiche nevose o di temperature rigide. Advantageously, the polymeric composition of the present invention also exhibits thermo-resistance characteristics. This characteristic advantageously allows the composition of the present invention to be used to avoid freezing soils, asphalts or lawns in snowy climatic conditions or cold temperatures.

L’aggiunta di tale composizione evita pertanto l’addizione di sale in queste situazioni estreme e richiede solamente un’unica applicazione, a differenza dell’aggiunta di sale – che richiede più applicazioni su un arco temporale prolungato. The addition of this composition therefore avoids the addition of salt in these extreme situations and requires only a single application, unlike the addition of salt - which requires multiple applications over a prolonged period of time.

Sono pertanto evidenti gli innumerevoli vantaggi della composizione qui rivendicata, essendo la stessa: The innumerable advantages of the composition claimed here are therefore evident, being the same:

- completamente biodegradabile ed atossica – e pertanto miscelabile liberamente coi terreni dedicati a colture vegetali; - completely biodegradable and non-toxic - and therefore freely mixable with soils dedicated to vegetable crops;

- a lento rilascio – adatta cioè a modulare i quantitativi di acqua essendo a lento rilascio; e - slow release - that is, suitable for modulating the quantities of water being slow release; And

- termoresistente -costituendo quindi un’ottima alternativa all’addizione di Sali per evitare il ghiaccio su manti erbosi e su asfalti. - heat-resistant - thus constituting an excellent alternative to the addition of salts to avoid ice on lawns and asphalts.

A seguire sono illustrati alcuni esempi rappresentativi e non limitativi volti a dimostrare le vantaggiose proprietà della presente invenzione. Some representative and non-limiting examples aimed at demonstrating the advantageous properties of the present invention are illustrated below.

ESEMPI CRESCITA PIANTE DA ORTO E CEREALI EXAMPLES GROWTH OF GARDEN PLANTS AND CEREALS

E’ stata preparata una composizione polimerica secondo la presente invenzione miscelando cellulosa (40% p/p), carbonato di calcio (50% p/p) e materiale elastomerico termoplastico (10% p/p). A polymeric composition was prepared according to the present invention by mixing cellulose (40% w / w), calcium carbonate (50% w / w) and thermoplastic elastomeric material (10% w / w).

Sono stati successivamente preparati due campioni di terreno: Two soil samples were subsequently prepared:

A: terreno comune in assenza della composizione polimerica della presente invenzione; A: common ground in the absence of the polymeric composition of the present invention;

B: terreno comprendente la composizione polimerica della presente invenzione in una quantità pari a 10 Kg/m<2>. B: medium comprising the polymeric composition of the present invention in an amount equal to 10 Kg / m <2>.

Entrambi i campioni di terreno A e B sono stati seminati con semi di piante da orto (zucchine, pomodori, melanzane) ed irrigati solo una volta la settimana (con lo stesso quantitativo di acqua). A tempi regolari è stata controllata la crescita delle piante. A seguire i risultati: Both soil samples A and B were sown with vegetable seeds (courgettes, tomatoes, aubergines) and irrigated only once a week (with the same amount of water). Plant growth was checked at regular intervals. Following are the results:

Giorno 0 Giorno 10 Giorno 30<A>- Germogliazione Crescita delle piante delle piante 30% 5%<B>- Germogliazione Crescita delle piante delle piante 80% 98% Gli stessi esperimenti sono stati effettuati usando dei campioni di terreno tipici degli ambienti semidesertici (con tendenza a disperdere velocemente l’acqua, non trattenendola) seminando piante quali cereali, ottenendo risultati analoghi. Come sopra riportato, il campione comprendente la composizione della presente invenzione mostra un incremento netto in termini di germogliazione e crescita delle piante già dopo 10 giorni rispetto al campione in cui di terreno in cui la composizione è assente. Day 0 Day 10 Day 30 <A> - Sprouting Plant growth of plants 30% 5% <B> - Sprouting Plant growth of plants 80% 98% The same experiments were carried out using soil samples typical of semi-desert environments ( with a tendency to quickly disperse water, not retaining it) sowing plants such as cereals, obtaining similar results. As reported above, the sample comprising the composition of the present invention shows a net increase in terms of sprouting and growth of the plants already after 10 days with respect to the sample in which of soil in which the composition is absent.

E’ chiaro quindi dai dati sopra riportati come la composizione polimerica della presente invenzione sia particolarmente indicata per la crescita delle colture vegetali, anche in condizioni estreme come quelle degli ambienti della steppa o semidesertici, in quanto riesce a trattenere ed assorbire grandi quantitativi di acqua rilasciandola lentamente quando necessita. It is therefore clear from the above data that the polymeric composition of the present invention is particularly suitable for the growth of vegetable crops, even in extreme conditions such as those of the steppe or semi-desert environments, as it is able to retain and absorb large quantities of water by releasing it slowly when needed.

La composizione polimerica della presente invenzione è stata anche testata per le seguenti caratteristiche: The polymeric composition of the present invention was also tested for the following characteristics:

Caratteristiche Protocollo/norma Risultato Disintegrazione UNI11183/06 8-10 anni in suolo Characteristics Protocol / standard Result Disintegration UNI11183 / 06 8-10 years in soil

Ecotossicità ENI13432/02 Completamente atossica Ecotoxicity ENI13432 / 02 Completely non-toxic

Biodegradabilità UNI EN ISO Inizio processo 14855-1/2013 biodegradativo dopo 6 mesi Biodegradability UNI EN ISO Beginning of process 14855-1 / 2013 biodegradation after 6 months

UNI EN UNI EN

14046/2003 14046/2003

Inizio processo Biodegradabilità ISO 17556:2003 biodegradativo in suolo in suolo dopo 6 mesi Start of process Biodegradability ISO 17556: 2003 biodegradation in soil in soil after 6 months

Alla luce degli esempi sopra riportati si confermano le caratteristiche vantaggiose e sorprendenti della composizione polimerica qui rivendicata in termini di: In light of the above examples, the advantageous and surprising characteristics of the polymeric composition claimed herein are confirmed in terms of:

- Biodegradabilità; - Biodegradability;

- vantaggi economici; - termoresistenza; - economic benefits; - thermistor;

- completa atossicità. - complete non-toxicity.

Claims (9)

RIVENDICAZIONI 1.Composizione polimerica comprendente cellulosa, carbonato di calcio, materiale elastomerico termoplastico. CLAIMS 1. Polymeric composition comprising cellulose, calcium carbonate, thermoplastic elastomeric material. 2. Composizione polimerica secondo la rivendicazione 1, dove detta composizione comprende: - cellulosa in un intervallo compreso nell’intervallo 30-60% p/p; - carbonato di calcio in un intervallo compreso nell’intervallo 30-60% p/p%; - materiale elastomerico termoplastico compreso nell’intervallo 5-10% p/p. 2. Polymeric composition according to claim 1, wherein said composition comprises: - cellulose in a range of 30-60% w / w; - calcium carbonate in a range between 30-60% w / w%; - thermoplastic elastomeric material in the range 5-10% w / w. 3. La composizione secondo la rivendicazione 1 in cui detti: - cellulosa è pari al 40% p/p; - carbonato di calcio è pari al 50% p/p%; - materiale elastomerico termoplastico è pari al 10% p/p. The composition according to claim 1 wherein said: - cellulose is equal to 40% w / w; - calcium carbonate is equal to 50% w / w%; - thermoplastic elastomeric material is equal to 10% w / w. 4. Uso della composizione secondo una o più delle rivendicazioni precedenti per assorbire liquidi e rilasciarli a lento rilascio. 4. Use of the composition according to one or more of the preceding claims to absorb liquids and release them at slow release. 5. Uso secondo la rivendicazione 4, in cui detti liquidi sono acqua. 5. Use according to claim 4, wherein said liquids are water. 6. Uso secondo una o più delle rivendicazioni precedenti nelle colture vegetali, per assorbire olii, per applicazioni antighiaccio. 6. Use according to one or more of the preceding claims in vegetable crops, to absorb oils, for de-icing applications. 7. Uso secondo la rivendicazione 6 in cui dette colture vegetali sono colture agricole, forestali, floricolture, orticolture e colture idroponiche. 7. Use according to claim 6 wherein said vegetable crops are agricultural, forestry, floriculture, horticulture and hydroponic crops. 8. Terreno per colture vegetali comprendente la composizione secondo una o più delle rivendicazioni 1-3. Vegetable culture medium comprising the composition according to one or more of claims 1-3. 9. Terreno per colture vegetali secondo la rivendicazione 8, in cui detta composizione è miscelata a detto terreno in una quantità pari a 10 Kg/m<2>.9. Soil for vegetable crops according to claim 8, wherein said composition is mixed with said soil in an amount equal to 10 Kg / m <2>.
IT102016000092233A 2016-09-13 2016-09-13 POLYMER COMPOSITION AND ITS USE FOR THE ABSORPTION OF LIQUIDS IT201600092233A1 (en)

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Citations (6)

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US20060272205A1 (en) * 2004-12-30 2006-12-07 Aerogrow International, Inc. Time-release, oxygen-generating, and effervescing nutrient compositions and methods for growing plants
EP2336235A1 (en) * 2009-12-18 2011-06-22 Actega Artistica S.A. Water-based dispersion of thermoplastic polymer and non-thermoplastic elastomer
US20110218283A1 (en) * 2010-03-02 2011-09-08 Nadeem Akhtar Bokhari Reactor thermoplastic polyolefin elastomer composition
EP2471820A1 (en) * 2009-10-05 2012-07-04 Nec Corporation Cellulose resin and process for production thereof
WO2015179750A1 (en) * 2014-05-22 2015-11-26 The Procter & Gamble Company Heterogeneous mass containing foam

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060272205A1 (en) * 2004-12-30 2006-12-07 Aerogrow International, Inc. Time-release, oxygen-generating, and effervescing nutrient compositions and methods for growing plants
JP2006225563A (en) * 2005-02-18 2006-08-31 Kaneka Corp Powder for surface skin molding for automobile interiors and surface skin for automobile interiors
EP2471820A1 (en) * 2009-10-05 2012-07-04 Nec Corporation Cellulose resin and process for production thereof
EP2336235A1 (en) * 2009-12-18 2011-06-22 Actega Artistica S.A. Water-based dispersion of thermoplastic polymer and non-thermoplastic elastomer
US20110218283A1 (en) * 2010-03-02 2011-09-08 Nadeem Akhtar Bokhari Reactor thermoplastic polyolefin elastomer composition
WO2015179750A1 (en) * 2014-05-22 2015-11-26 The Procter & Gamble Company Heterogeneous mass containing foam

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