IT1265287B1 - Catalyst for the preparation of high purity ethylene- propylene elastomer copolymers - Google Patents
Catalyst for the preparation of high purity ethylene- propylene elastomer copolymersInfo
- Publication number
- IT1265287B1 IT1265287B1 IT93MI002649A ITMI932649A IT1265287B1 IT 1265287 B1 IT1265287 B1 IT 1265287B1 IT 93MI002649 A IT93MI002649 A IT 93MI002649A IT MI932649 A ITMI932649 A IT MI932649A IT 1265287 B1 IT1265287 B1 IT 1265287B1
- Authority
- IT
- Italy
- Prior art keywords
- high purity
- propylene elastomer
- purity ethylene
- catalyst
- preparation
- Prior art date
Links
- 229920000181 Ethylene propylene rubber Polymers 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 239000011777 magnesium Substances 0.000 abstract 3
- 150000005826 halohydrocarbons Chemical class 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- -1 organometallic aluminium compound Chemical class 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Solid catalytic components for the synthesis of high purity ethylene-propylene elastomer copolymers obtained by contacting an organometallic aluminium compound I diluted in aliphatic hydrocarbons with a liquid II prepared by: a) dissolving an anhydrous magnesium halide in a mixture of halohydrocarbons in the presence of an aluminium trihalide, b) treating with a tetravalent titanium compound of general formula Ti(OR)4-n X n, where R is an aliphatic, cycloaliphatic or aromatic hydrocarbon radical containing from 1 to 20 carbon atoms, X is a halogen atom and n is a whole number between 0 and 4. Liquid II is characterised by a molar Mg/Ti ratio of between 1 and 5, an Al/Mg molar ratio of between 1 and 5 and a molar ratio between Al and chlorine in the mixture of halohydrocarbons which is not less than 0.1.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI002649A IT1265287B1 (en) | 1993-12-17 | 1993-12-17 | Catalyst for the preparation of high purity ethylene- propylene elastomer copolymers |
CA002136278A CA2136278A1 (en) | 1993-12-17 | 1994-11-21 | Catalyst for the preparation of elastomeric ethylene-propylene copolymers |
EP94203504A EP0659778B1 (en) | 1993-12-17 | 1994-12-02 | Catalyst for the preparation of elastomeric ethylene-propylene copolymers |
DE69408649T DE69408649T2 (en) | 1993-12-17 | 1994-12-02 | Catalyst for the production of elastomers ethylene-propylene copolymers |
AT94203504T ATE163434T1 (en) | 1993-12-17 | 1994-12-02 | CATALYST FOR THE PRODUCTION OF ELASTOMER ETHYLENEPROPYLENE COPOLYMERS |
KR1019940033205A KR100330059B1 (en) | 1993-12-17 | 1994-12-08 | Elastomer Ethylene-Propylene Copolymer Production Catalyst |
JP33236394A JP3479789B2 (en) | 1993-12-17 | 1994-12-14 | Manufacturing method of solid catalyst |
CN94113470A CN1050613C (en) | 1993-12-17 | 1994-12-15 | Catalyst for the preparation of elastomeric ethylene-propylene copolymers |
US08/595,451 US5578540A (en) | 1993-12-17 | 1996-02-05 | Catalyst for the preparation of elastomeric ethylene-propylene copolymers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI002649A IT1265287B1 (en) | 1993-12-17 | 1993-12-17 | Catalyst for the preparation of high purity ethylene- propylene elastomer copolymers |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI932649A0 ITMI932649A0 (en) | 1993-12-17 |
ITMI932649A1 ITMI932649A1 (en) | 1995-06-17 |
IT1265287B1 true IT1265287B1 (en) | 1996-10-31 |
Family
ID=11367344
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT93MI002649A IT1265287B1 (en) | 1993-12-17 | 1993-12-17 | Catalyst for the preparation of high purity ethylene- propylene elastomer copolymers |
Country Status (1)
Country | Link |
---|---|
IT (1) | IT1265287B1 (en) |
-
1993
- 1993-12-17 IT IT93MI002649A patent/IT1265287B1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
ITMI932649A0 (en) | 1993-12-17 |
ITMI932649A1 (en) | 1995-06-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19961217 |