IT1245397B - Procedimento per la decomposizione catalitica selettiva di eteri alchilici ed alcooli in una carica proveniente dalla sintesi del metil ter amil etere - Google Patents

Procedimento per la decomposizione catalitica selettiva di eteri alchilici ed alcooli in una carica proveniente dalla sintesi del metil ter amil etere

Info

Publication number
IT1245397B
IT1245397B ITMI910779A ITMI910779A IT1245397B IT 1245397 B IT1245397 B IT 1245397B IT MI910779 A ITMI910779 A IT MI910779A IT MI910779 A ITMI910779 A IT MI910779A IT 1245397 B IT1245397 B IT 1245397B
Authority
IT
Italy
Prior art keywords
alcohols
synthesis
selective catalytic
ethers
catalytic decomposition
Prior art date
Application number
ITMI910779A
Other languages
English (en)
Inventor
Francesco Ancillotti
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Snam Progetti filed Critical Snam Progetti
Publication of ITMI910779A0 publication Critical patent/ITMI910779A0/it
Priority to ITMI910779A priority Critical patent/IT1245397B/it
Priority to EP92200690A priority patent/EP0504980B1/en
Priority to DK92200690.3T priority patent/DK0504980T3/da
Priority to ES92200690T priority patent/ES2056685T3/es
Priority to AT92200690T priority patent/ATE106276T1/de
Priority to DE69200156T priority patent/DE69200156T2/de
Priority to KR1019920004397A priority patent/KR950004891B1/ko
Priority to MX9201181A priority patent/MX9201181A/es
Priority to CA002063307A priority patent/CA2063307A1/en
Priority to HU9200939A priority patent/HU209424B/hu
Priority to SU925011239A priority patent/RU2021241C1/ru
Publication of ITMI910779A1 publication Critical patent/ITMI910779A1/it
Application granted granted Critical
Publication of IT1245397B publication Critical patent/IT1245397B/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Viene descritto un procedimento per la decomposizione catalitica selettiva di eteri alchilici ed alcooli in una carica proveniente dalla sintesi del metil ter amil etere (TAME) che consiste nel far reagire detta carica in presenza di un catalizzatore costituito da silice modificata con l'aggiunta di allumina in quantità compresa fra lo 0,1 e l'1,5% in peso rispetto alla silice operando ad una temperatura compresa fra 200 e 250°C e ad una velocità spaziale (LHSV) compresa fra 4 e 15 h- 1.
ITMI910779A 1991-03-22 1991-03-22 Procedimento per la decomposizione catalitica selettiva di eteri alchilici ed alcooli in una carica proveniente dalla sintesi del metil ter amil etere IT1245397B (it)

Priority Applications (11)

Application Number Priority Date Filing Date Title
ITMI910779A IT1245397B (it) 1991-03-22 1991-03-22 Procedimento per la decomposizione catalitica selettiva di eteri alchilici ed alcooli in una carica proveniente dalla sintesi del metil ter amil etere
EP92200690A EP0504980B1 (en) 1991-03-22 1992-03-11 Process for the selective catalytic decomposition of alkyl ethers and alcohols in a feedstock originating from the synthesis of methyl tert-amyl ether
DK92200690.3T DK0504980T3 (da) 1991-03-22 1992-03-11 Fremgangsmåde til selektiv katalytisk dekomponering af alkylethere og alkylalkoholer i et råmateriale stammende fra syntesen af methyl tertamylether
ES92200690T ES2056685T3 (es) 1991-03-22 1992-03-11 Procedimiento para la descomposicion catalitica selectiva de eteres alkilos y alcoholes en un deposito originados por la sintesis de eter tert-amilo de metilo.
AT92200690T ATE106276T1 (de) 1991-03-22 1992-03-11 Verfahren für die katalytische, selective zersetzung von alkyläthern und alkoholen in einen einsatz, entstehend aus der synthese von methyl- tertamyläther.
DE69200156T DE69200156T2 (de) 1991-03-22 1992-03-11 Verfahren für die katalytische, selective Zersetzung von Alkyläthern und Alkoholen in einen Einsatz, entstehend aus der Synthese von Methyl-Tertamyläther.
KR1019920004397A KR950004891B1 (ko) 1991-03-22 1992-03-18 메틸-tert-아밀에테르 합성으로 나온 공급물내에서의 알킬에테르와 알코올의 선택적 촉매 분해법
MX9201181A MX9201181A (es) 1991-03-22 1992-03-18 Procedimiento para la descomposicion catalitica selectiva de alquil eteres y alcoholes en un surtidor de alimentacion que se origina de la sintesis demetil ter-amil eter.
CA002063307A CA2063307A1 (en) 1991-03-22 1992-03-18 Process for the selective catalytic decomposition of alkyl ethers and alcohols in a feedstock originating from the synthesis of methyl tert-amyl ether
HU9200939A HU209424B (en) 1991-03-22 1992-03-20 Process for the selective catalytic decomposition of alkyl ethers and alkyl-alcohols in a feedstock originating from the synthesis of methyl-tert-amyl ether
SU925011239A RU2021241C1 (ru) 1991-03-22 1992-03-20 Способ очистки фракции c4 - олефинов

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI910779A IT1245397B (it) 1991-03-22 1991-03-22 Procedimento per la decomposizione catalitica selettiva di eteri alchilici ed alcooli in una carica proveniente dalla sintesi del metil ter amil etere

Publications (3)

Publication Number Publication Date
ITMI910779A0 ITMI910779A0 (it) 1991-03-22
ITMI910779A1 ITMI910779A1 (it) 1992-09-22
IT1245397B true IT1245397B (it) 1994-09-20

Family

ID=11359195

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI910779A IT1245397B (it) 1991-03-22 1991-03-22 Procedimento per la decomposizione catalitica selettiva di eteri alchilici ed alcooli in una carica proveniente dalla sintesi del metil ter amil etere

Country Status (11)

Country Link
EP (1) EP0504980B1 (it)
KR (1) KR950004891B1 (it)
AT (1) ATE106276T1 (it)
CA (1) CA2063307A1 (it)
DE (1) DE69200156T2 (it)
DK (1) DK0504980T3 (it)
ES (1) ES2056685T3 (it)
HU (1) HU209424B (it)
IT (1) IT1245397B (it)
MX (1) MX9201181A (it)
RU (1) RU2021241C1 (it)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7087794B2 (en) 2002-11-15 2006-08-08 Exxonmobil Chemical Patents Inc. Oxygenate conversion in the presence of highly unsaturated compounds

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2908426A1 (de) * 1979-03-05 1980-09-25 Basf Ag Verfahren zur gewinnung von isobuten aus isobuten enthaltenden c tief 4 -kohlenwasserstoffgemischen
US4371718A (en) * 1981-07-02 1983-02-01 Phillips Petroleum Company Using butenes to fractionate methanol from methyl-tertiary-butyl ether
DE3150755A1 (de) * 1981-12-22 1983-06-30 Deutsche Texaco Ag, 2000 Hamburg "verfahren zur abtrennung von methanol aus den bei der veraetherung von c(pfeil abwaerts)4(pfeil abwaerts) bis c(pfeil abwaerts)7(pfeil abwaerts)-isoolefinen mit methanol anfallenden reaktionsprodukten"
IT1219692B (it) * 1988-05-06 1990-05-24 Eniricerche Spa Gel di silice e allumina cataliticamente attivo e procedimento per la sua preparazione

Also Published As

Publication number Publication date
ITMI910779A0 (it) 1991-03-22
ITMI910779A1 (it) 1992-09-22
ES2056685T3 (es) 1994-10-01
HU209424B (en) 1994-06-28
MX9201181A (es) 1992-09-01
DE69200156T2 (de) 1994-11-17
KR920017992A (ko) 1992-10-21
KR950004891B1 (ko) 1995-05-15
RU2021241C1 (ru) 1994-10-15
HU9200939D0 (en) 1992-06-29
DE69200156D1 (de) 1994-07-07
HUT60645A (en) 1992-10-28
EP0504980A1 (en) 1992-09-23
DK0504980T3 (da) 1994-09-12
EP0504980B1 (en) 1994-06-01
ATE106276T1 (de) 1994-06-15
CA2063307A1 (en) 1992-09-23

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TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19970313