IT1049374B - Acetylenes removal from hydrocarbons - by reaction with alcohol, phenol or acid in presence of mercury-contg. ion-exchange resin - Google Patents

Acetylenes removal from hydrocarbons - by reaction with alcohol, phenol or acid in presence of mercury-contg. ion-exchange resin

Info

Publication number
IT1049374B
IT1049374B IT2151775A IT2151775A IT1049374B IT 1049374 B IT1049374 B IT 1049374B IT 2151775 A IT2151775 A IT 2151775A IT 2151775 A IT2151775 A IT 2151775A IT 1049374 B IT1049374 B IT 1049374B
Authority
IT
Italy
Prior art keywords
acetylenes
contg
ion
pref
exchange resin
Prior art date
Application number
IT2151775A
Other languages
Italian (it)
Inventor
A Pacifico
C Rescalli
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AR258894A priority Critical patent/AR206714A1/en
Application filed by Snam Progetti filed Critical Snam Progetti
Priority to IT2151775A priority patent/IT1049374B/en
Priority to TR18762A priority patent/TR18762A/en
Priority to DK209775AA priority patent/DK140831B/en
Priority to YU01215/75A priority patent/YU121575A/en
Priority to GB2021175A priority patent/GB1465015A/en
Priority to DE19752521702 priority patent/DE2521702C3/en
Priority to IE1095/75A priority patent/IE41364B1/en
Priority to IN1000/CAL/75A priority patent/IN140786B/en
Priority to BG030038A priority patent/BG24792A3/en
Priority to CS368378A priority patent/CS194250B2/en
Priority to FR7515720A priority patent/FR2272054B1/fr
Priority to AT381275A priority patent/AT358541B/en
Priority to LU72541A priority patent/LU72541A1/xx
Priority to NO751786A priority patent/NO144015C/en
Priority to AU81326/75A priority patent/AU492878B2/en
Priority to CA227,298A priority patent/CA1036182A/en
Priority to ES438188A priority patent/ES438188A1/en
Priority to CH649375A priority patent/CH617100A5/de
Priority to SU752137590A priority patent/SU1068030A3/en
Priority to RO7582293A priority patent/RO67330A/en
Priority to JP5979275A priority patent/JPS554725B2/ja
Priority to SE7505803A priority patent/SE396215B/en
Priority to US05/579,691 priority patent/US4031157A/en
Priority to ZM63/75A priority patent/ZM6375A1/en
Priority to NL7505993A priority patent/NL7505993A/en
Priority to DD186164A priority patent/DD118056A5/xx
Priority to BE156543A priority patent/BE829301A/en
Priority to BR4086/75A priority patent/BR7503194A/en
Priority to US05/762,769 priority patent/US4112009A/en
Application granted granted Critical
Publication of IT1049374B publication Critical patent/IT1049374B/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Acetylenes are removed from satd. olefinic or dienic hydrocarbons or mixts. thereof by (a) reacting the acetylenes with ROH (R = alkyl. aryl, cycloalkyl or acyl) in the presence of an acid ion-exchange resin contg. Hg2+ ions; and (b) separating the products in known manner. The process is esp. useful for purifying butadiene, propylene and ethylene for use in polymerisation processes. Purified products contg. =10 ppm of acetylenes can be obtained. In step (a), the acetylenes are pref. etherified with an alcohol or glycol at -20 to +80 degrees (esp. 20-60 degrees C). The ion-exchange resin is pref. a sulphonate resin based on poly styrene, divinylbenzene or a phenolic resin, or can also be carboxylic acid resin. The Hg2+ ions are pref. introduced in the form of Hg(NO3)2 or Hg (OAc)2. The ethers formed are pref. removed by distn.
IT2151775A 1974-05-21 1975-03-21 Acetylenes removal from hydrocarbons - by reaction with alcohol, phenol or acid in presence of mercury-contg. ion-exchange resin IT1049374B (en)

Priority Applications (30)

Application Number Priority Date Filing Date Title
AR258894A AR206714A1 (en) 1974-05-21 1975-01-01 PROCEDURE TO REMOVE ACETYLENE COMPOUNDS FROM OLEFINIC AND DIENIC SATURATED HYDROCARBONS OR MIXTURE OF THEM
IT2151775A IT1049374B (en) 1975-03-21 1975-03-21 Acetylenes removal from hydrocarbons - by reaction with alcohol, phenol or acid in presence of mercury-contg. ion-exchange resin
TR18762A TR18762A (en) 1974-05-21 1975-05-03 PROCEDURE FOR EXTRACTING ESSENTIAL COMPOSITIONS FROM SATURATED, OLEFINIC AND DIESEL HYDROCARBONS OR THEIR MIXTURES
DK209775AA DK140831B (en) 1974-05-21 1975-05-13 Process for removing acetylenic compounds from saturated, olefinic and dienic hydrocarbons or mixtures thereof.
YU01215/75A YU121575A (en) 1974-05-21 1975-05-13 Process for the separation of acetylene compounds from saturated olefinic and dienic hydrocarbons or mixtures thereof
GB2021175A GB1465015A (en) 1974-05-21 1975-05-13 Process for reducing the concentration of acetylenic compounds in a hydrocarbon mixture
DE19752521702 DE2521702C3 (en) 1974-05-21 1975-05-15 Process for the separation of acetylene compounds from other hydrocarbons
IE1095/75A IE41364B1 (en) 1974-05-21 1975-05-15 Process for reducing the concentration of acetylenic compounds in a hydrocarbon mixture
IN1000/CAL/75A IN140786B (en) 1974-05-21 1975-05-19
AU81326/75A AU492878B2 (en) 1975-05-20 Process for reducing the concentration of acetylenic compounds ina hydrocarbon mixture
FR7515720A FR2272054B1 (en) 1974-05-21 1975-05-20
AT381275A AT358541B (en) 1974-05-21 1975-05-20 METHOD FOR SEPARATING ALKINES FROM SATURED, OLEFINIC OR DIENIC HYDROCARBONS OR THEIR MIXTURES
LU72541A LU72541A1 (en) 1974-05-21 1975-05-20
NO751786A NO144015C (en) 1974-05-21 1975-05-20 PROCEDURE FOR AA SEPARATE ACETYLENE COMPOUNDS FROM THEIR MIXTURES WITH Saturated, OLEFINUMETTED OR DIENUMETTED HYDROCARBONS OR MIXTURES THEREOF, BY ESTABLISHMENT AND DISPOSAL
BG030038A BG24792A3 (en) 1974-05-21 1975-05-20 Method of separating acetylene combinations from saturated ethylene and dien hydrocarbons or their salts
CA227,298A CA1036182A (en) 1974-05-21 1975-05-20 Method for removing acetylenic compounds from saturated, olefinic and dienic hydrocarbons or mixtures thereof
ES438188A ES438188A1 (en) 1974-05-21 1975-05-20 Method for removing acetylenic compounds from saturated, olefinic and dienic hydrocarbons or mixtures thereof
CS368378A CS194250B2 (en) 1975-03-21 1975-05-20 Method for removing acetylenic compounds from unsaturated,olefinic and dienic hydrocarbons or mixtures thereof
NL7505993A NL7505993A (en) 1974-05-21 1975-05-21 PROCESS FOR THE REMOVAL OF ACETYLENE COMPOUNDS FROM SATURATED, ALKES AND DIESEL, HYDROCARBONS OR MIXTURES THEREOF.
RO7582293A RO67330A (en) 1974-05-21 1975-05-21 PROCEDURE FOR INDEPENDENCE OF ACETYLENE COMPOUNDS FROM SATURATED, OLEFINIC OR DIENIC HYDROCARBONS, OR OF THEIR MIXTURES
JP5979275A JPS554725B2 (en) 1974-05-21 1975-05-21
SE7505803A SE396215B (en) 1974-05-21 1975-05-21 WAY TO REMOVE ACETYLENE COMPOUNDS FROM THE SATURATED CARBON, OLEFIN OR DIENE CARBON OR MIXTURES THEREFORE BY BRINGING THE ACETYLENE COMPOUNDS TO REACTION WITH COMPOUNDS OF TYPE R-OH ...
US05/579,691 US4031157A (en) 1974-05-21 1975-05-21 Method for removing acetylenic compounds from saturated, olefinic and dienic hydrocarbons or mixtures thereof
ZM63/75A ZM6375A1 (en) 1974-05-21 1975-05-21 Method for removing acetylenic compounds from saturated,olefinic and dienic hydrocarbons or mixtures thereof
CH649375A CH617100A5 (en) 1974-05-21 1975-05-21
DD186164A DD118056A5 (en) 1974-05-21 1975-05-21
BE156543A BE829301A (en) 1974-05-21 1975-05-21 PROCESS FOR REMOVING ACETYLENIC COMPOUNDS CONTAINED IN SATURATED, OLEFINIC AND DIENIC HYDROCARBONS OR MIXTURES OF SUCH HYDOCARBONS
SU752137590A SU1068030A3 (en) 1974-05-21 1975-05-21 Process for purifying propane, or propylene, or butadiene from impurities of acetylene hydrocarbons
BR4086/75A BR7503194A (en) 1974-05-21 1975-05-22 METHODS FOR REMOVING ACETYLENE COMPOUND FROM SATURATED HYDROCARBONS AND OLEFINS
US05/762,769 US4112009A (en) 1974-05-21 1977-01-26 Method for removing acetylenic compounds from saturated, olefinic and dienic hydrocarbons or mixtures thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2151775A IT1049374B (en) 1975-03-21 1975-03-21 Acetylenes removal from hydrocarbons - by reaction with alcohol, phenol or acid in presence of mercury-contg. ion-exchange resin

Publications (1)

Publication Number Publication Date
IT1049374B true IT1049374B (en) 1981-01-20

Family

ID=11182972

Family Applications (1)

Application Number Title Priority Date Filing Date
IT2151775A IT1049374B (en) 1974-05-21 1975-03-21 Acetylenes removal from hydrocarbons - by reaction with alcohol, phenol or acid in presence of mercury-contg. ion-exchange resin

Country Status (2)

Country Link
CS (1) CS194250B2 (en)
IT (1) IT1049374B (en)

Also Published As

Publication number Publication date
CS194250B2 (en) 1979-11-30

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