IT1035068B - Alkane and alkene oxidn. to alcohols and ketones - with tert. butyl hydro-peroxide in presence of chromium catalysts in liquid phase at moderate temps
- Google Patents
Alkane and alkene oxidn. to alcohols and ketones - with tert. butyl hydro-peroxide in presence of chromium catalysts in liquid phase at moderate temps
Info
Publication number
IT1035068B
IT1035068BIT4768074AIT4768074AIT1035068BIT 1035068 BIT1035068 BIT 1035068BIT 4768074 AIT4768074 AIT 4768074AIT 4768074 AIT4768074 AIT 4768074AIT 1035068 BIT1035068 BIT 1035068B
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlantic Richfield CofiledCriticalAtlantic Richfield Co
Priority to IT4768074ApriorityCriticalpatent/IT1035068B/en
Application grantedgrantedCritical
Publication of IT1035068BpublicationCriticalpatent/IT1035068B/en
Organic Low-Molecular-Weight Compounds And Preparation Thereof
(AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts
(AREA)
Abstract
Oxidn. of 3-20 C alkanes, pref. 2,3-dimethylbutane, cyclohexane, octane, n-butane and propane, and monoalkenes to alcohols and ketones is effected by contact with tert. Bu hydroperoxide (A) pref. mixed with BuOH in the presence of a Cr catalyst, pref. Cr acetyl acetonate, at 80-110 degrees C. Pref. a liquid phase maintained, if necessary, by using a superatmos. press.
IT4768074A1974-01-141974-01-14Alkane and alkene oxidn. to alcohols and ketones - with tert. butyl hydro-peroxide in presence of chromium catalysts in liquid phase at moderate temps
IT1035068B
(en)