IT1028362B - Tri-iso-indolo-benzene macrocycle prodn - from phthalic di-nitrile and meta-phenylene-di-amine, for pigments and dyes - Google Patents
Tri-iso-indolo-benzene macrocycle prodn - from phthalic di-nitrile and meta-phenylene-di-amine, for pigments and dyesInfo
- Publication number
- IT1028362B IT1028362B IT1926275A IT1926275A IT1028362B IT 1028362 B IT1028362 B IT 1028362B IT 1926275 A IT1926275 A IT 1926275A IT 1926275 A IT1926275 A IT 1926275A IT 1028362 B IT1028362 B IT 1028362B
- Authority
- IT
- Italy
- Prior art keywords
- macrocycle
- prodn
- pigments
- dyes
- pref
- Prior art date
Links
- 239000000975 dye Substances 0.000 title abstract 2
- 239000000049 pigment Substances 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229940018564 m-phenylenediamine Drugs 0.000 abstract 1
- 150000002678 macrocyclic compounds Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Landscapes
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Triisoindolobenzene macrocycle of the formula (I) is prefd. by reacting phthalic dinitrile (II) with m-phenylenediamine in 3-3.5:1 molar ratio in satd. aliphatic 4-10C alcohol(s) (III) as solvent at 100-150, pref 115-125 degrees C in the presence of 0.2-2% (w.r.t. (II)) of a catalyst for formula MOR (in which M is an alkali metal; and R is H or 1-10C alkyl), followed by sepn. of the end prod. pptd. from the soln., pref. by filtering or centrifuging. The amt. of (III) added is pref. 3-8 times the amt. of (II). Prod. is used in the prodn. of pigments and dyes. The process is carried out in a single stage, uses simple appts. and relatively cheap starting materials, and gives high yields. The cost is low and the reproducibility excellent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1926275A IT1028362B (en) | 1975-01-14 | 1975-01-14 | Tri-iso-indolo-benzene macrocycle prodn - from phthalic di-nitrile and meta-phenylene-di-amine, for pigments and dyes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1926275A IT1028362B (en) | 1975-01-14 | 1975-01-14 | Tri-iso-indolo-benzene macrocycle prodn - from phthalic di-nitrile and meta-phenylene-di-amine, for pigments and dyes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IT1028362B true IT1028362B (en) | 1979-01-30 |
Family
ID=11156208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT1926275A IT1028362B (en) | 1975-01-14 | 1975-01-14 | Tri-iso-indolo-benzene macrocycle prodn - from phthalic di-nitrile and meta-phenylene-di-amine, for pigments and dyes |
Country Status (1)
| Country | Link |
|---|---|
| IT (1) | IT1028362B (en) |
-
1975
- 1975-01-14 IT IT1926275A patent/IT1028362B/en active
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