IN2015DN02095A - - Google Patents

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Publication number
IN2015DN02095A
IN2015DN02095A IN2095DEN2015A IN2015DN02095A IN 2015DN02095 A IN2015DN02095 A IN 2015DN02095A IN 2095DEN2015 A IN2095DEN2015 A IN 2095DEN2015A IN 2015DN02095 A IN2015DN02095 A IN 2015DN02095A
Authority
IN
India
Prior art keywords
molecular sieve
sialp
sapo
diisopropylamine
mdipa
Prior art date
Application number
Inventor
Dong Fan
Peng Tian
Zhongmin Liu
Xiong Su
Ying Zhang
Yue Yang
Original Assignee
Dalian Chemical Physics Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dalian Chemical Physics Inst filed Critical Dalian Chemical Physics Inst
Publication of IN2015DN02095A publication Critical patent/IN2015DN02095A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54Phosphates, e.g. APO or SAPO compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/84Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85Silicoaluminophosphates (SAPO compounds)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009Preparation by separation, e.g. by filtration, decantation, screening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08Silicoaluminophosphates (SAPO compounds), e.g. CoSAPO
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/76Dehydrogenation
    • B01J2231/763Dehydrogenation of -CH-XH (X= O, NH/N, S) to -C=X or -CX triple bond species

Abstract

Provided are an SAPO 34 molecular sieve and a synthesis method thereof. The anhydrous chemical composition of the molecular sieve is: mDIPA·(SiAlP)O wherein DIPA is diisopropylamine and distributed in cages and pores of the molecular sieve; m is the number of moles of diisopropylamine per mole of (SiAlP)O and m = 0.03 0.25; x y and z represent mole fractions of Si Al and P respectively ranges of them are x = 0.01 0.30 y = 0.40 0.60 and z = 0.25 0.49 respectively and x + y + z = 1. The SAPO 34 molecular sieve can be used in acid catalyzed reactions and a reaction of converting an oxygen compound into low carbon olefins.
IN2095DEN2015 2012-09-26 2012-09-26 IN2015DN02095A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2012/081995 WO2014047801A1 (en) 2012-09-26 2012-09-26 Sapo-34 molecular sieve and synthesis method thereof

Publications (1)

Publication Number Publication Date
IN2015DN02095A true IN2015DN02095A (en) 2015-08-14

Family

ID=50386791

Family Applications (1)

Application Number Title Priority Date Filing Date
IN2095DEN2015 IN2015DN02095A (en) 2012-09-26 2012-09-26

Country Status (12)

Country Link
US (1) US9695057B2 (en)
EP (1) EP2902362B1 (en)
JP (1) JP6006879B2 (en)
KR (1) KR101652209B1 (en)
AU (1) AU2012391394B2 (en)
BR (1) BR112015006461B1 (en)
DK (1) DK2902362T3 (en)
EA (1) EA026545B1 (en)
IN (1) IN2015DN02095A (en)
SG (1) SG11201501834YA (en)
WO (1) WO2014047801A1 (en)
ZA (1) ZA201501936B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112015006463B1 (en) * 2012-09-26 2020-11-17 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences frog-34 molecular sieve, method for preparing frog-34 molecular sieve, catalyst for acid-catalyzed reaction, and catalyst for an oxygenated reaction in olefins
SG11201501834YA (en) * 2012-09-26 2015-05-28 Dalian Chemical Physics Inst Sapo-34 molecular sieve and synthesis method thereof
CA3003620C (en) 2015-10-30 2023-10-24 Dow Global Technologies Llc Process to convert synthesis gas to olefins over a bifunctional chromium oxide/zinc oxide-sapo-34 catalyst
DE102017109168A1 (en) * 2016-04-28 2017-11-02 Johnson Matthey Public Limited Company STA-20, A NEW MOLECULAR SCREEN TYPE, METHOD OF MANUFACTURE AND USE
CN106732764B (en) * 2016-11-30 2019-05-14 中国石油大学(华东) A kind of low silica-alumina ratio SAPO-34 molecular sieve and its preparation method and application
CN106513036B (en) * 2016-12-01 2019-05-14 中国石油大学(华东) A kind of low silicon SAPO-34 molecular sieve and its preparation method and application
AR110362A1 (en) 2016-12-22 2019-03-20 Dow Global Technologies Llc PROCESS FOR CONVERTING SYNTHESIS GAS IN OLEFINS USING A CROMOZINC OXIDE BIFUNCTIONAL CATALYST - SAPO-34
AR111149A1 (en) 2017-02-06 2019-06-12 Dow Global Technologies Llc PROCESSES TO IMPROVE THE ACTIVITY OF HYBRID CATALYSTS
KR102197599B1 (en) * 2018-10-11 2020-12-31 포항공과대학교 산학협력단 Silicoaluminophosphate molecular sieves, manufacturing method, and selective separation of CO2 using thereof
KR102224614B1 (en) * 2018-12-31 2021-03-05 포항공과대학교 산학협력단 Silicoaluminophosphate molecular sieves with CHA topology and their manufacturing method using inorganic structure-directing agent
CN114433221B (en) * 2020-10-20 2024-01-30 中国石油化工股份有限公司 Modified metal oxide-molecular sieve compound and preparation method and application thereof

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US4310440A (en) 1980-07-07 1982-01-12 Union Carbide Corporation Crystalline metallophosphate compositions
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
CN1087292A (en) 1992-11-24 1994-06-01 中国科学院大连化学物理研究所 A kind of is the synthesized silicon phosphor aluminum molecular sieve and the preparation thereof of template with the triethylamine
CN1037334C (en) 1992-12-19 1998-02-11 中国科学院大连化学物理研究所 Synthesis silicon phosphorus aluminium molecular sieve and equipment using triethylamine as mould agent
CN1131845C (en) 1999-12-15 2003-12-24 中国科学院大连化学物理研究所 Synthesis of silicon-aluminium phosphate molecular sieve with double or multiple template agent
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JP4596116B2 (en) * 2002-05-24 2010-12-08 三菱瓦斯化学株式会社 Crystalline silicoaluminophosphate molecular sieve having 8-membered ring pores, method for producing the same, and method for producing methylamines using the same
AU2003242437A1 (en) * 2002-05-24 2003-12-12 Mitsubishi Gas Chemical Company, Inc. Crystalline silicoaluminophosphate salt molecular sieve having octaoxygen-membered ring pore, process for producing the same and process for producing methylamine with the molecular sieve as catalyst
JP2006089300A (en) * 2004-09-21 2006-04-06 Nippon Gas Gosei Kk Production method for sapo-34, and method of producing liquefied petroleum gas composed mainly of propane
CN1314587C (en) * 2005-04-14 2007-05-09 南京工业大学 Process for prepareing SAPO-34 molecular siever
EP2161243A1 (en) * 2008-08-29 2010-03-10 Total Petrochemicals Research Feluy Method for preparing metalloaluminophosphate (MeAPO) molecular sieves
TW201036957A (en) * 2009-02-20 2010-10-16 Astrazeneca Ab Novel salt 628
CN101993093B (en) * 2009-08-25 2012-10-31 中国科学院大连化学物理研究所 SAPO (silicoaluminophosphate) molecular sieve with RHO skeleton structure and preparation method thereof
CN102336413B (en) * 2010-11-29 2013-04-17 中国科学院大连化学物理研究所 Synthesis method of low-silicon SAPO-34 molecular sieves
CN102530987A (en) * 2010-12-29 2012-07-04 中国科学院大连化学物理研究所 Solvent thermal synthesis method of SAPO (silicoaluminophosphate) molecular sieve and catalyst prepared by SAPO molecular sieve
BR112015006463B1 (en) * 2012-09-26 2020-11-17 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences frog-34 molecular sieve, method for preparing frog-34 molecular sieve, catalyst for acid-catalyzed reaction, and catalyst for an oxygenated reaction in olefins
SG11201501834YA (en) * 2012-09-26 2015-05-28 Dalian Chemical Physics Inst Sapo-34 molecular sieve and synthesis method thereof
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Also Published As

Publication number Publication date
JP2015533765A (en) 2015-11-26
US9695057B2 (en) 2017-07-04
DK2902362T3 (en) 2017-08-07
EP2902362B1 (en) 2017-06-21
SG11201501834YA (en) 2015-05-28
AU2012391394B2 (en) 2016-03-03
BR112015006461A2 (en) 2019-10-01
KR101652209B1 (en) 2016-08-29
AU2012391394A1 (en) 2015-04-02
US20150232345A1 (en) 2015-08-20
EA026545B1 (en) 2017-04-28
EP2902362A4 (en) 2016-04-27
BR112015006461B1 (en) 2021-03-30
JP6006879B2 (en) 2016-10-12
ZA201501936B (en) 2016-10-26
KR20150059786A (en) 2015-06-02
WO2014047801A1 (en) 2014-04-03
EA201590589A1 (en) 2015-07-30
EP2902362A1 (en) 2015-08-05

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