IN2014MN01923A - - Google Patents
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- Publication number
- IN2014MN01923A IN2014MN01923A IN1923MUN2014A IN2014MN01923A IN 2014MN01923 A IN2014MN01923 A IN 2014MN01923A IN 1923MUN2014 A IN1923MUN2014 A IN 1923MUN2014A IN 2014MN01923 A IN2014MN01923 A IN 2014MN01923A
- Authority
- IN
- India
- Prior art keywords
- cobalt
- aluminum
- subjected
- steps
- reduction
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0446—Leaching processes with an ammoniacal liquor or with a hydroxide of an alkali or alkaline-earth metal
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
- C01F7/141—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by neutralisation with an acidic agent
- C01F7/142—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by neutralisation with an acidic agent with carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/04—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C01G55/004—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C01G55/005—Halides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/02—Obtaining noble metals by dry processes
- C22B11/021—Recovery of noble metals from waste materials
- C22B11/026—Recovery of noble metals from waste materials from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
- C22B11/048—Recovery of noble metals from waste materials from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/06—Chloridising
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/0015—Obtaining aluminium by wet processes
- C22B21/0023—Obtaining aluminium by wet processes from waste materials
- C22B21/003—Obtaining aluminium by wet processes from waste materials from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/02—Obtaining aluminium with reducing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/026—Obtaining nickel or cobalt by dry processes from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Catalysts (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Provided is a process for the comprehensive recovery of metal cobalt ruthenium and aluminum from a waste catalyst Co Ru/AlOin a Fischer Tropsch synthesis. First a waste catalyst is subjected to hydrocarbon removal and reduction treatment to effectively separate a cobalt slag in an alkali fusion step and then the cobalt slag is subjected to the steps of acid leaching cobalt precipitation with oxalic acid or ammonium oxalate reduction of cobalt oxalate dissolution of metal cobalt with nitric acid etc. to obtain Co(?O)•6?O. A ruthenate which is dissolved by steps such as alkali fusion and leaching with deionized water is subjected to the steps of reduction with ethanol dissolution with concentrated hydrochloric acid distillation under reduced pressure etc. to obtain a ß RuCl•XHO product with a high purity. Aluminum hydroxide is prepared from a meta aluminate solution by CO carbonation by controlling the parameters such as reaction temperature flow rate of CO pH value at the end point of the reaction etc. and the aluminum hydroxide is calcined to obtain aluminum oxide with a product quality achieving the quality requirements of first class aluminum oxide in the Chinese national standard. The resulting product has a high yield wherein cobalt is = 97% ruthenium is = 95% and aluminum is = 92%.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210055817.XA CN102796873B (en) | 2012-03-05 | 2012-03-05 | Method for comprehensively recovering metallic cobalt, ruthenium and aluminum from Fischer-Tropsch synthesis dead catalyst Co-Ru/Al2O3 |
| PCT/CN2013/072119 WO2013131455A1 (en) | 2012-03-05 | 2013-03-04 | Process for the comprehensive recovery of metal cobalt, ruthenium and aluminum from waste catalyst co-ru/al2o3 in fischer-tropsch synthesis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2014MN01923A true IN2014MN01923A (en) | 2015-07-10 |
Family
ID=47196168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN1923MUN2014 IN2014MN01923A (en) | 2012-03-05 | 2013-03-04 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US8986632B2 (en) |
| EP (1) | EP2824200B1 (en) |
| JP (1) | JP5852270B2 (en) |
| KR (1) | KR101609803B1 (en) |
| CN (1) | CN102796873B (en) |
| AP (1) | AP2014007990A0 (en) |
| AU (1) | AU2013230407B2 (en) |
| BR (1) | BR112014021852B1 (en) |
| CA (1) | CA2866224C (en) |
| DK (1) | DK2824200T3 (en) |
| IN (1) | IN2014MN01923A (en) |
| MX (1) | MX356685B (en) |
| MY (1) | MY157635A (en) |
| RU (1) | RU2580575C1 (en) |
| SG (1) | SG11201405393SA (en) |
| WO (1) | WO2013131455A1 (en) |
| ZA (1) | ZA201407146B (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102583580B (en) * | 2012-03-05 | 2014-03-12 | 武汉凯迪工程技术研究总院有限公司 | Method for preparing high-purity cobalt nitrate crystals from Co/SiO2 waste catalysts |
| CN102796873B (en) * | 2012-03-05 | 2014-02-26 | 阳光凯迪新能源集团有限公司 | Method for comprehensively recovering metallic cobalt, ruthenium and aluminum from Fischer-Tropsch synthesis dead catalyst Co-Ru/Al2O3 |
| JP5999478B2 (en) * | 2012-05-30 | 2016-09-28 | 国立研究開発法人産業技術総合研究所 | Method and apparatus for recovering precious metal via composite oxide |
| JP6585955B2 (en) * | 2015-07-31 | 2019-10-02 | Ｊｘ金属株式会社 | Method for separating Ru, Rh and Ir from a selenium platinum group element-containing material |
| CN105543496B (en) * | 2015-12-29 | 2017-10-20 | 武汉凯迪工程技术研究总院有限公司 | F- T synthesis dead catalyst Co Rh/Al2O3The recovery method of middle metallic cobalt, rhodium and aluminium |
| CN106861741B (en) * | 2017-01-06 | 2019-07-02 | 南京工业大学 | Post-treatment method of phenol hydrogenation Pd @ CN catalyst |
| CN107986341A (en) * | 2017-12-18 | 2018-05-04 | 西安宏星电子浆料科技有限责任公司 | Plate resistor slurry ruthenium-oxide powder and preparation method thereof |
| CN108330287B (en) * | 2018-01-31 | 2019-11-08 | 北京三聚环保新材料股份有限公司 | A method of with ruthenium in the useless agent of alkali metal ruthenic acid salt form recycling catalyst |
| CN109110793A (en) * | 2018-03-22 | 2019-01-01 | 云南大学 | A kind of preparation method of alumina load nano-cerium oxide compound gold and ru oxide |
| CN111100997B (en) * | 2018-10-26 | 2021-11-05 | 贵研资源（易门）有限公司 | Method for recovering ruthenium from catalyst for preparing chlorine by using spent hydrogen chloride |
| CN111100999B (en) * | 2018-10-26 | 2021-11-05 | 贵研资源（易门）有限公司 | Method for recovering waste catalyst ruthenium |
| KR102319523B1 (en) * | 2019-11-29 | 2021-10-29 | 주식회사 모노리스 | Separation and recovery of valuable metals from desulfurized waste catalyst |
| CN112993243A (en) * | 2019-12-17 | 2021-06-18 | 格林美（江苏）钴业股份有限公司 | Preparation method of high-density aluminum-doped cobalt oxide |
| CN115715279A (en) * | 2020-04-24 | 2023-02-24 | 纳奥盖耐斯有限责任公司 | System and method for recovering nutrients from high nitrogen liquid waste |
| CN112645372B (en) * | 2021-01-19 | 2023-05-05 | 广西化工研究院有限公司 | Method for recycling waste activated alumina regenerant for hydrogen peroxide |
| CN112981105B (en) * | 2021-02-06 | 2022-12-09 | 昆明贵研新材料科技有限公司 | Method for recovering noble metal from waste alumina carrier noble metal catalyst |
| CN112939094B (en) * | 2021-02-23 | 2023-05-09 | 华电光大(宜昌)环保技术有限公司 | Method for preparing nano cobalt tungstate and recovering crude titanium slag |
| CN113215402A (en) * | 2021-04-07 | 2021-08-06 | 武汉理工大学 | Method for recycling ruthenium from waste super capacitor |
| CN113559859A (en) * | 2021-07-23 | 2021-10-29 | 中国地质大学（武汉） | Supported cobalt-based hydrogenation catalyst and preparation method and application thereof |
| KR102445476B1 (en) * | 2021-09-15 | 2022-09-21 | 주식회사 한내포티 | Method of extracting valuable metals containing denitrification waste catalyst using an alkali sintered body |
| WO2023043095A1 (en) * | 2021-09-15 | 2023-03-23 | 주식회사 한내포티 | Method for extracting waste denitrification catalyst-containing valuable metals |
| CN113921800B (en) * | 2021-10-11 | 2024-01-09 | 吉林大学 | Preparation of porous silicon as lithium ion battery anode material by magnesian clay magnesian reduction |
| CN115055181A (en) * | 2022-07-06 | 2022-09-16 | 四川大学 | Method for preparing high-performance CO catalyst by recycling waste noble metal catalyst |
| CN115814565B (en) * | 2022-11-30 | 2024-05-31 | 攀钢集团攀枝花钢铁研究院有限公司 | Potassium-sodium absorption method and absorbent for preparing vanadium-nitrogen alloy by pushed slab kiln calcination |
| WO2024194272A1 (en) * | 2023-03-20 | 2024-09-26 | Velocys Technologies Limited | Process |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4822824A (en) | 1986-07-02 | 1989-04-18 | Exxon Research And Engineering Company | Cobalt-ruthenium catalysts for Fischer-Tropsch synthesis |
| FR2668938B1 (en) * | 1990-11-12 | 1995-03-17 | Inst Francais Du Petrole | NOVEL PROCESS FOR ANTI-POLLUTION TREATMENT OF A REFINING CATALYST IN THE USED CONDITION AND TOTAL RECOVERY OF THE DIFFERENT METAL CONSTITUENTS OF SAID CATALYST. |
| US20040219082A1 (en) * | 2000-08-29 | 2004-11-04 | Matjie Ratale Henry | Selective recovery of aluminium, cobalt and platinum values from a spent catalyst composition |
| JP3733909B2 (en) * | 2002-01-07 | 2006-01-11 | 住友金属鉱山株式会社 | Method for purifying ruthenium |
| JP2004002927A (en) * | 2002-05-31 | 2004-01-08 | Mitsui Mining & Smelting Co Ltd | Method for processing super hard alloy scrap |
| RU2239666C1 (en) * | 2003-04-24 | 2004-11-10 | Институт неорганической химии им. А.В. Николаева СО РАН (статус государственного учреждения) | Method of preparing rhodium, palladium, and ruthenium concentrates from nitric acid solutions |
| CN1292450C (en) | 2004-11-05 | 2006-12-27 | 中国科学院上海光学精密机械研究所 | Short-distance molybdenum foil sealed pulse xenon lamp |
| DE102005061954A1 (en) | 2005-12-23 | 2007-07-05 | Basf Ag | Recycling of ruthenium from an used ruthenium catalyst comprises treating the catalyst containing ruthenium oxide in a hydrogen stream and treating the carrier material containing ruthenium metal with hydrochloric acid |
| GB0604285D0 (en) * | 2006-03-03 | 2006-04-12 | Johnson Matthey Plc | Catalyst reprocessing |
| CN100387344C (en) | 2006-06-21 | 2008-05-14 | 浙江工业大学 | Method for recovering ruthenium catalyst carried by active carbon |
| US8191052B2 (en) | 2006-12-01 | 2012-05-29 | Murex S.A.S. | Producer graph oriented programming and execution |
| CN101270420A (en) * | 2008-05-19 | 2008-09-24 | 中国科学院山西煤炭化学研究所 | Process for recovering cobalt from cobalt based fischer-tropsch synthetic catalyst |
| CN101698152A (en) | 2009-10-20 | 2010-04-28 | 武汉凯迪科技发展研究院有限公司 | Cobalt-based compounded catalyst and preparing method and application thereof |
| CN101700913B (en) * | 2009-11-17 | 2011-05-18 | 中南民族大学 | Method for preparing high-purity cobalt nitrate by utilizing alumina-supported cobalt-based spent catalyst for Fischer-Tropsch synthesis |
| US7935173B1 (en) * | 2010-07-23 | 2011-05-03 | Metals Recovery Technology Inc. | Process for recovery of precious metals |
| CN102108444B (en) | 2011-04-01 | 2013-04-17 | 开滦能源化工股份有限公司 | Method for recycling ruthenium in supported type ruthenium catalyst |
| CN102796873B (en) * | 2012-03-05 | 2014-02-26 | 阳光凯迪新能源集团有限公司 | Method for comprehensively recovering metallic cobalt, ruthenium and aluminum from Fischer-Tropsch synthesis dead catalyst Co-Ru/Al2O3 |
-
2012
- 2012-03-05 CN CN201210055817.XA patent/CN102796873B/en active Active
-
2013
- 2013-03-04 IN IN1923MUN2014 patent/IN2014MN01923A/en unknown
- 2013-03-04 EP EP13758445.4A patent/EP2824200B1/en not_active Not-in-force
- 2013-03-04 BR BR112014021852-8A patent/BR112014021852B1/en not_active IP Right Cessation
- 2013-03-04 CA CA2866224A patent/CA2866224C/en not_active Expired - Fee Related
- 2013-03-04 MY MYPI2014002567A patent/MY157635A/en unknown
- 2013-03-04 AU AU2013230407A patent/AU2013230407B2/en not_active Ceased
- 2013-03-04 RU RU2014140159/02A patent/RU2580575C1/en not_active IP Right Cessation
- 2013-03-04 AP AP2014007990A patent/AP2014007990A0/en unknown
- 2013-03-04 WO PCT/CN2013/072119 patent/WO2013131455A1/en active Application Filing
- 2013-03-04 JP JP2014560232A patent/JP5852270B2/en not_active Expired - Fee Related
- 2013-03-04 DK DK13758445.4T patent/DK2824200T3/en active
- 2013-03-04 MX MX2014010727A patent/MX356685B/en active IP Right Grant
- 2013-03-04 SG SG11201405393SA patent/SG11201405393SA/en unknown
- 2013-03-04 KR KR1020147027927A patent/KR101609803B1/en active IP Right Grant
-
2014
- 2014-09-05 US US14/477,935 patent/US8986632B2/en not_active Expired - Fee Related
- 2014-10-02 ZA ZA2014/07146A patent/ZA201407146B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN102796873B (en) | 2014-02-26 |
| MX356685B (en) | 2018-06-07 |
| CA2866224A1 (en) | 2013-09-12 |
| EP2824200A1 (en) | 2015-01-14 |
| SG11201405393SA (en) | 2014-10-30 |
| BR112014021852B1 (en) | 2019-04-16 |
| KR20140131998A (en) | 2014-11-14 |
| KR101609803B1 (en) | 2016-04-06 |
| EP2824200A4 (en) | 2015-12-02 |
| JP2015513614A (en) | 2015-05-14 |
| CN102796873A (en) | 2012-11-28 |
| WO2013131455A1 (en) | 2013-09-12 |
| DK2824200T3 (en) | 2018-08-27 |
| CA2866224C (en) | 2016-12-20 |
| RU2580575C1 (en) | 2016-04-10 |
| ZA201407146B (en) | 2015-12-23 |
| US8986632B2 (en) | 2015-03-24 |
| MX2014010727A (en) | 2015-03-10 |
| US20140377151A1 (en) | 2014-12-25 |
| AU2013230407A1 (en) | 2014-10-16 |
| JP5852270B2 (en) | 2016-02-03 |
| AU2013230407B2 (en) | 2015-10-08 |
| EP2824200B1 (en) | 2018-05-16 |
| MY157635A (en) | 2016-07-15 |
| AP2014007990A0 (en) | 2014-10-31 |
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