IN2014MN01923A - - Google Patents

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Publication number
IN2014MN01923A
IN2014MN01923A IN1923MUN2014A IN2014MN01923A IN 2014MN01923 A IN2014MN01923 A IN 2014MN01923A IN 1923MUN2014 A IN1923MUN2014 A IN 1923MUN2014A IN 2014MN01923 A IN2014MN01923 A IN 2014MN01923A
Authority
IN
India
Prior art keywords
cobalt
aluminum
subjected
steps
reduction
Prior art date
Application number
Inventor
Qianqian Liu
Yiming Han
Dechen Song
Li Xu
Bo Lai
Original Assignee
Sunshine Kaidi New Energy Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sunshine Kaidi New Energy Group Co Ltd filed Critical Sunshine Kaidi New Energy Group Co Ltd
Publication of IN2014MN01923A publication Critical patent/IN2014MN01923A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0407—Leaching processes
    • C22B23/0446—Leaching processes with an ammoniacal liquor or with a hydroxide of an alkali or alkaline-earth metal
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
    • C01F7/141—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by neutralisation with an acidic agent
    • C01F7/142—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by neutralisation with an acidic agent with carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/80—Compounds containing cobalt, with or without oxygen or hydrogen, and containing one or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/004—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/005—Halides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/02—Obtaining noble metals by dry processes
    • C22B11/021—Recovery of noble metals from waste materials
    • C22B11/026—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C22B11/042—Recovery of noble metals from waste materials
    • C22B11/048—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/06—Chloridising
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00—Obtaining aluminium
    • C22B21/0015—Obtaining aluminium by wet processes
    • C22B21/0023—Obtaining aluminium by wet processes from waste materials
    • C22B21/003—Obtaining aluminium by wet processes from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00—Obtaining aluminium
    • C22B21/02—Obtaining aluminium with reducing
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/02—Obtaining nickel or cobalt by dry processes
    • C22B23/026—Obtaining nickel or cobalt by dry processes from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Provided is a process for the comprehensive recovery of metal cobalt ruthenium and aluminum from a waste catalyst Co Ru/AlOin a Fischer Tropsch synthesis. First a waste catalyst is subjected to hydrocarbon removal and reduction treatment to effectively separate a cobalt slag in an alkali fusion step and then the cobalt slag is subjected to the steps of acid leaching cobalt precipitation with oxalic acid or ammonium oxalate reduction of cobalt oxalate dissolution of metal cobalt with nitric acid etc. to obtain Co(?O)•6?O. A ruthenate which is dissolved by steps such as alkali fusion and leaching with deionized water is subjected to the steps of reduction with ethanol dissolution with concentrated hydrochloric acid distillation under reduced pressure etc. to obtain a ß RuCl•XHO product with a high purity. Aluminum hydroxide is prepared from a meta aluminate solution by CO carbonation by controlling the parameters such as reaction temperature flow rate of CO pH value at the end point of the reaction etc. and the aluminum hydroxide is calcined to obtain aluminum oxide with a product quality achieving the quality requirements of first class aluminum oxide in the Chinese national standard. The resulting product has a high yield wherein cobalt is = 97% ruthenium is = 95% and aluminum is = 92%.
IN1923MUN2014 2012-03-05 2013-03-04 IN2014MN01923A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201210055817.XA CN102796873B (en) 2012-03-05 2012-03-05 Method for Comprehensive Recovery of Cobalt, Ruthenium and Aluminum from Fischer-Tropsch Synthesis Spent Catalyst Co-Ru/Al2O3
PCT/CN2013/072119 WO2013131455A1 (en) 2012-03-05 2013-03-04 Process for the comprehensive recovery of metal cobalt, ruthenium and aluminum from waste catalyst co-ru/al2o3 in fischer-tropsch synthesis

Publications (1)

Publication Number Publication Date
IN2014MN01923A true IN2014MN01923A (en) 2015-07-10

Family

ID=47196168

Family Applications (1)

Application Number Title Priority Date Filing Date
IN1923MUN2014 IN2014MN01923A (en) 2012-03-05 2013-03-04

Country Status (17)

Country Link
US (1) US8986632B2 (en)
EP (1) EP2824200B1 (en)
JP (1) JP5852270B2 (en)
KR (1) KR101609803B1 (en)
CN (1) CN102796873B (en)
AP (1) AP2014007990A0 (en)
AU (1) AU2013230407B2 (en)
BR (1) BR112014021852B1 (en)
CA (1) CA2866224C (en)
DK (1) DK2824200T3 (en)
IN (1) IN2014MN01923A (en)
MX (1) MX356685B (en)
MY (1) MY157635A (en)
RU (1) RU2580575C1 (en)
SG (1) SG11201405393SA (en)
WO (1) WO2013131455A1 (en)
ZA (1) ZA201407146B (en)

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CN111100997B (en) * 2018-10-26 2021-11-05 贵研资源（易门）有限公司 Method for recovering ruthenium from catalyst for preparing chlorine by using spent hydrogen chloride
KR102319523B1 (en) * 2019-11-29 2021-10-29 주식회사 모노리스 Separation and recovery of valuable metals from desulfurized waste catalyst
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CN112645372B (en) * 2021-01-19 2023-05-05 广西化工研究院有限公司 A method for recycling waste activated alumina regeneration agent for hydrogen peroxide
CN112981105B (en) * 2021-02-06 2022-12-09 昆明贵研新材料科技有限公司 Method for recovering noble metal from waste alumina carrier noble metal catalyst
CN112939094B (en) * 2021-02-23 2023-05-09 华电光大(宜昌)环保技术有限公司 A method for preparing nano-cobalt tungstate and reclaiming coarse titanium slag
CN113215402A (en) * 2021-04-07 2021-08-06 武汉理工大学 Method for recycling ruthenium from waste super capacitor
CN113559859A (en) * 2021-07-23 2021-10-29 中国地质大学（武汉） A supported cobalt-based hydrogenation catalyst and its preparation method and application
KR102445476B1 (en) * 2021-09-15 2022-09-21 주식회사 한내포티 Valuable metal extraction method containing denitrification spent catalyst using alkali sintered compact
WO2023043095A1 (en) * 2021-09-15 2023-03-23 주식회사 한내포티 Method for extracting waste denitrification catalyst-containing valuable metals
CN113921800B (en) * 2021-10-11 2024-01-09 吉林大学 Magnesium thermal reduction of oceanic clay to prepare porous silicon as anode material for lithium-ion batteries
CN115055181A (en) * 2022-07-06 2022-09-16 四川大学 Method for preparing high-performance CO catalyst by recycling waste noble metal catalyst
CN117904443A (en) * 2022-10-12 2024-04-19 中国石油化工股份有限公司 Method for recovering ruthenium from ruthenium-containing catalyst
CN115814565B (en) * 2022-11-30 2024-05-31 攀钢集团攀枝花钢铁研究院有限公司 Potassium-sodium absorption method and absorbent for preparing vanadium-nitrogen alloy by pushed slab kiln calcination
KR20250163366A (en) * 2023-03-20 2025-11-20 벨로시스 테크놀로지스 리미티드 process
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FR3163583A1 (en) 2024-06-25 2025-12-26 IFP Energies Nouvelles Process for producing a catalyst comprising at least one metal from group VIIIB and a support based on oxide(s)
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Also Published As

Publication number Publication date
KR101609803B1 (en) 2016-04-06
EP2824200A4 (en) 2015-12-02
DK2824200T3 (en) 2018-08-27
JP5852270B2 (en) 2016-02-03
CA2866224C (en) 2016-12-20
JP2015513614A (en) 2015-05-14
MX2014010727A (en) 2015-03-10
US8986632B2 (en) 2015-03-24
WO2013131455A1 (en) 2013-09-12
BR112014021852B1 (en) 2019-04-16
CA2866224A1 (en) 2013-09-12
AU2013230407A1 (en) 2014-10-16
SG11201405393SA (en) 2014-10-30
MY157635A (en) 2016-07-15
EP2824200A1 (en) 2015-01-14
KR20140131998A (en) 2014-11-14
ZA201407146B (en) 2015-12-23
CN102796873A (en) 2012-11-28
AU2013230407B2 (en) 2015-10-08
RU2580575C1 (en) 2016-04-10
CN102796873B (en) 2014-02-26
US20140377151A1 (en) 2014-12-25
MX356685B (en) 2018-06-07
AP2014007990A0 (en) 2014-10-31
EP2824200B1 (en) 2018-05-16

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