IN2014KN01079A - - Google Patents

Info

Publication number
IN2014KN01079A
IN2014KN01079A IN1079KON2014A IN2014KN01079A IN 2014KN01079 A IN2014KN01079 A IN 2014KN01079A IN 1079KON2014 A IN1079KON2014 A IN 1079KON2014A IN 2014KN01079 A IN2014KN01079 A IN 2014KN01079A
Authority
IN
India
Prior art keywords
formula
transition metal
reaction
212the
platinum
Prior art date
Application number
Inventor
Leif Johnen
Heinz Strutz
Kurt Schalapski
Norman Nowotny
Wolfgang Höfs
Sebastian Geisel
Original Assignee
Oxea Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxea Gmbh filed Critical Oxea Gmbh
Publication of IN2014KN01079A publication Critical patent/IN2014KN01079A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/10—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C07C69/01—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/78—Benzoic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

212The invention relates to a continuous catalytic method for producing a vinyl ester of formula R C(O)O CH = CH by reacting a carboxylic acid of formula R C(O)OH with a transvinylation reagent of the formula R C(O)O CH = CH wherein the reaction occurs without removing a reaction partner in the presence of a transition metal catalyst containing at least one transition metal from the group of ruthenium osmium rhodium iridium palladium and platinum and subsequently the obtained reaction mixture is separated from its components.
IN1079KON2014 2012-02-06 2013-01-18 IN2014KN01079A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012002282A DE102012002282A1 (en) 2012-02-06 2012-02-06 Process for the preparation of vinyl esters
PCT/EP2013/000141 WO2013117294A1 (en) 2012-02-06 2013-01-18 Method for producing vinyl esters

Publications (1)

Publication Number Publication Date
IN2014KN01079A true IN2014KN01079A (en) 2015-10-09

Family

ID=47630236

Family Applications (1)

Application Number Title Priority Date Filing Date
IN1079KON2014 IN2014KN01079A (en) 2012-02-06 2013-01-18

Country Status (13)

Country Link
US (1) US9174922B2 (en)
EP (1) EP2812307B1 (en)
JP (1) JP6041904B2 (en)
KR (1) KR101988210B1 (en)
CN (1) CN104487411A (en)
BR (1) BR112014019187B1 (en)
DE (1) DE102012002282A1 (en)
ES (1) ES2669520T3 (en)
HK (1) HK1203189A1 (en)
IN (1) IN2014KN01079A (en)
PL (1) PL2812307T3 (en)
TW (1) TWI461400B (en)
WO (1) WO2013117294A1 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012105874A1 (en) 2012-07-02 2014-01-02 Oxea Gmbh Process for the preparation of vinyl isononanoates
DE102012105879A1 (en) 2012-07-02 2014-01-02 Oxea Gmbh Process for the preparation of isononyl derivatives
DE102012014396B4 (en) 2012-07-13 2018-01-11 Oxea Gmbh Process for the preparation of a vinyl ester mixture from a mixture of positionally isomeric aliphatic Isononansäuren starting from 2-ethylhexanol
DE102013224496A1 (en) 2013-11-29 2015-06-03 Wacker Chemie Ag Process for the ruthenium-catalyzed transvinylation of carboxylic acids
DE102013224491A1 (en) 2013-11-29 2015-06-03 Wacker Chemie Ag Process for the ruthenium-catalyzed transvinylation of carboxylic acids
DE102014206915A1 (en) 2014-04-10 2015-10-15 Wacker Chemie Ag Process for the preparation of an active ruthenium catalyst solution for the transvinylation of carboxylic acids
DE102014206916A1 (en) * 2014-04-10 2015-10-15 Wacker Chemie Ag Process for the ruthenium-catalyzed transvinylation of carboxylic acids
DE102014210835A1 (en) 2014-06-06 2015-12-17 Wacker Chemie Ag Process for the separation of high-boiling carboxylic acid vinyl ester / carboxylic acid mixtures
DE102014013123B4 (en) 2014-08-30 2020-01-02 Oxea Gmbh Process for the preparation of mixtures containing tertiary isononic acids starting from 2-ethylhexanol
EP3103786A1 (en) * 2015-06-08 2016-12-14 Hexion Research Belgium SA Process for the production of higher carboxylic acid vinyl esters
DE102015216373A1 (en) 2015-08-27 2017-03-02 Wacker Chemie Ag Process for the catalytic re-vinylation of carboxylic acids
CN108057459B (en) * 2016-11-09 2019-09-20 中国科学院福建物质结构研究所 Silica gel supported coordination palladium catalyst for vinyl exchange reaction and its preparation method and application

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2245131A (en) 1941-06-10 Process of preparing vinyl esters
US2299862A (en) 1942-10-27 Preparation of vinyl esters
US2997495A (en) * 1956-08-27 1961-08-22 Air Reduction Preparation of vinyl esters
DE1222493B (en) 1962-04-25 1966-08-11 Rohm & Haas Process for the preparation of vinyl esters
DE2823660A1 (en) * 1977-10-13 1979-04-26 Shin Etsu Vinyl Acetate Co PROCESS FOR PRODUCING AN ALKENYLESTER FROM CARBONIC ACIDS
DE3047347A1 (en) * 1980-12-16 1982-07-22 Wacker-Chemie GmbH, 8000 München PALLADIUM (II) CATALYST, ITS PRODUCTION AND USE
US5155253A (en) 1988-06-30 1992-10-13 Union Carbide Chemicals & Plastics Technology Corporation Transvinylation process for the preparation of thermally labile vinyl compounds and for vinyl compounds prepared from thermally labile acids
US4981973A (en) * 1988-06-30 1991-01-01 Union Carbide Chemicals And Plastics Company, Inc. Transvinylation reaction
JPH02172946A (en) * 1988-12-26 1990-07-04 Shinetsu Sakusan Vinyl Kk Production of alkenyl carboxylate
ECSP910793A (en) * 1990-11-30 1992-12-21 Union Carbide Chem Plastics Co Inc AZEOTROPIC ASSISTED TRANSVINILATION TECHNOLOGY
FR2671346B1 (en) 1991-01-04 1993-04-23 Hoechst France TRANSVINYLATION PROCESS AND ITS APPLICATION.
US5210207A (en) * 1991-01-31 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Transvinylation process by reactive distillation
US5214172A (en) 1991-05-06 1993-05-25 Air Products And Chemicals, Inc. Catalytic transvinylation of vinyl esters
US5741925A (en) 1997-01-13 1998-04-21 Air Products And Chemicals, Inc. Transvinylation of naphthenic acids
DE19925385A1 (en) 1999-06-02 2000-12-07 Oxeno Olefinchemie Gmbh Process for the catalytic implementation of multiphase reactions, in particular vinylations of carboxylic acids
JP2002322125A (en) 2001-04-26 2002-11-08 Japan Vam & Poval Co Ltd Method for producing carboxylic vinyl ester
US7119222B2 (en) * 2002-08-30 2006-10-10 Mitsubishi Chemical Corporation Method for producing allyl compound, and ether or ester compound produced thereby
US8975437B2 (en) * 2010-05-04 2015-03-10 Celanese International Corporation Process for the continuous transvinylation of carboxylic acids with vinyl acetate

Also Published As

Publication number Publication date
EP2812307A1 (en) 2014-12-17
JP6041904B2 (en) 2016-12-14
DE102012002282A1 (en) 2013-08-08
BR112014019187A2 (en) 2017-06-20
CN104487411A (en) 2015-04-01
BR112014019187B1 (en) 2020-01-21
KR20140113708A (en) 2014-09-24
ES2669520T3 (en) 2018-05-28
PL2812307T3 (en) 2018-07-31
BR112014019187A8 (en) 2017-07-11
US9174922B2 (en) 2015-11-03
TWI461400B (en) 2014-11-21
JP2015508064A (en) 2015-03-16
KR101988210B1 (en) 2019-06-13
TW201343624A (en) 2013-11-01
US20140343310A1 (en) 2014-11-20
HK1203189A1 (en) 2015-10-23
WO2013117294A1 (en) 2013-08-15
EP2812307B1 (en) 2018-03-14

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