IL45829A - Method and apparatus for oxygenating wastewater - Google Patents

Method and apparatus for oxygenating wastewater

Info

Publication number
IL45829A
IL45829A IL45829A IL4582974A IL45829A IL 45829 A IL45829 A IL 45829A IL 45829 A IL45829 A IL 45829A IL 4582974 A IL4582974 A IL 4582974A IL 45829 A IL45829 A IL 45829A
Authority
IL
Israel
Prior art keywords
wastewater
chamber
oxygen
gas
oxygenating
Prior art date
Application number
IL45829A
Other versions
IL45829A0 (en
Original Assignee
Airco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Airco Inc filed Critical Airco Inc
Publication of IL45829A0 publication Critical patent/IL45829A0/en
Publication of IL45829A publication Critical patent/IL45829A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1278Provisions for mixing or aeration of the mixed liquor
    • C02F3/1284Mixing devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2323Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
    • B01F23/23231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits being at least partially immersed in the liquid, e.g. in a closed circuit
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2323Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
    • B01F23/23231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits being at least partially immersed in the liquid, e.g. in a closed circuit
    • B01F23/232312Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits being at least partially immersed in the liquid, e.g. in a closed circuit the guiding constructions being baffles for guiding the flow up-and-down or from left-to-right
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/233Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
    • B01F23/2334Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements provided with stationary guiding means surrounding at least partially the stirrer
    • B01F23/23341Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements provided with stationary guiding means surrounding at least partially the stirrer with tubes surrounding the stirrer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/234Surface aerating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/234Surface aerating
    • B01F23/2341Surface aerating by cascading, spraying or projecting a liquid into a gaseous atmosphere
    • B01F23/23411Surface aerating by cascading, spraying or projecting a liquid into a gaseous atmosphere by cascading the liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/2366Parts; Accessories
    • B01F23/2368Mixing receptacles, e.g. tanks, vessels or reactors, being completely closed, e.g. hermetically closed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • B01F23/2376Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
    • B01F23/23761Aerating, i.e. introducing oxygen containing gas in liquids
    • B01F23/237612Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/75Discharge mechanisms
    • B01F35/751Discharging by opening a gate, e.g. using discharge paddles
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1278Provisions for mixing or aeration of the mixed liquor
    • C02F3/1289Aeration by saturation under super-atmospheric pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/24Activated sludge processes using free-fall aeration or spraying
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/26Activated sludge processes using pure oxygen or oxygen-rich gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/50Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Microbiology (AREA)
  • Organic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
  • Treatment Of Biological Wastes In General (AREA)
  • Activated Sludge Processes (AREA)
  • Rotary Pumps (AREA)
  • Connector Housings Or Holding Contact Members (AREA)

Description

Method and apparatus for oxygenating wastewater AIROO, IHC 0. 43828 U.S. 413,409 This invention relates generally to water treatment technology and more specifically to methods and apparatus for dissolving oxygen in wastewater such as water received for purification in municipal sewage plants and the like.
The conventional activated sludge process for the treatment of wastewater involves the biological degradation of organic materials contained therein. This requires the maintenance of aerobic conditions, normally achieved by relying on open aeration to dissolve oxygen from ambient air into wastewater. While such processes have been used successfully for many years there are definite limits on the speed and efficiency of such processes. For example both the rate at which oxygen can be dissolved in the water and the maximum oxygen concentration that can be achieved are clearly limited. As a result the ever ex- . panding needs for more and better wastewater treatment to protec processes, only by a proliferation of plants for such processes at great capital expense and with the utilization of vast quanti- ties of power in their operation. \ The present invention is directed to methods and apparatus for more quickly and efficiently dissolving oxygen in wastewater to accelerate the biodegradation of organic material. This, in turn, increases the through-put of any given treatment facility and reduces the unit cost of wastewater treatment.
Cost reduction can be effected even though oxygen or oxygen enriched air (which costs money)is utilized in place of air (which is "free"). However, to keep the treatment cost to a minimum, the oxygen must be u sed efficiently, i.e., a high percentage of the oxygen supplied must be dissolved in and retained by the wastewater.
In accordance with the present invention there is provided an apparatus for treating a body of wastewater by by dissolving oxygen therein comprising a generally enclosed chamber adapted to be positioned in said body of wastewater having: an inlet for admitting a portion of said body of wastewater therein; means for oxygenating said admitted wastewater such that wastewater oxygenated in said chamber exhibits a first dissolved oxygen level; outlet means for discharging oxygenated wastewater into said body of wastewater at a predetermined rate and direction such that oxygenated wastewater is diluted in said body of wastewater and the dissolved oxygen level of said body of wastewater is raised to a second level below said first level.
The present invention further provides a structure that includes an enclosed chamber having an inlet, an outlet and an oxygenating zone therebetween. The structure may be positioned in the tank or other body of water to be oxygenated or it may be adjacent thereto. Water to be oxygenated is drawn from a main body of such water into the device through the inlet and after oxygenation it is discharged from the outlet into the same main body from which it was withdrawn, or alternatively into a second main body for mixing with and dilution of the water contained therein.
Oxygenation takes place within the unit by causing the stream of water entering the unit to pass into a pocket of oxygen rich gas maintained within the unit and impinge on the surface of the water adjacent the trapped pocket of gas in a confined turbulent zone. Parameters are established to assure adequate residence time for the stream in the turbulent zone, after which the stream enters a more quiescent zone which allows undissolved oxygen to escape from the water and return to the gas pocket for reuse. The water containing a high level of dis predetermined velocity from the unit to cause the discharged water to mix thoroughly with the main body of wastewater in the tank or pond which is usually the been withdrawn. In the preferred the unit is pumped through a trap-like channel over a weir to cause a free fall through the confined volume of oxygen rich gas maintained at suitable pressure within the unit. After impingement on the surface of the water at the foot of the fall the turbulent stream may be channeled by appropriate baffles a-way from the fall zone to the more quiescent zone for separation and recovery of undissolved oxygen.
It was known prior to the present invention to accelerate the activated sludge wastewater treatment process by substituting an oxygen enriched atmosphere for ambient air as the medium for sustaining aerobic conditions in an aeration basin. Such a process is described in the article "Aeration With A High-Oxygen Atmosphere In A. S. Process", by Harold E. Babbitt, and was published in wastes Engineering, May 1 52* pp.258-259. The Babbitt article describes a process for oxygenating wastewater wherein a gas-tight cover is provided across the top of an aeration tank with an oxygen-enriched atmosphere being maintained in the head space between the surface of the wastewater and the tank cover. A feed gas comprised of oxygen is introduced into the aeration tank by means of a submerged aerating device and the aeration gas collected in the head space is recirculated through a compressor to the aerating device. Although the afore-described process has resulted in relatively high levels of dissolved oxygen within acceptable time periods, the accumulation of large amounts of an oxygen enriched aeration gas in the head space of the aeration tank represents a serious safety hazard.
More recently, similar waste treatment processes utilizing oxygen enriched atmospheres in the head space of a covered aeration tank and mechanical agitators for dynamica13_^ mixing oxygen and wastewater have been devised in an effort to more efficiently utilize the oxygen. For example, systems similar to the apparatus and methods described in the Babbitt article are also described in five U. S. Patents numbered 3,5^7,811 through 3, 5^7,815. Again, systems illustrated in the foregoing references require the maintenance of an oxygen enriched atmo-sphere in a large head space of covered tanks and, therefore, provide an abundant supply of combustion supporting material. Furthermore, by employing mechanical agitators in the form of shaft-driven impellers, surface aerators and the like, the possibility of inadvertently producing a spark which could trigger a fire or explosion in such an oxygen enriched atmosphere is substantially increased.
In addition to preventing a possible safety hazard the foregoing attempts to upgrade the activated sludge process in an existing facility required substantial structural modification of such a facility with attendant down time and capital expense.
In U. S. Patent No. 3,503*593, the use of surface aerators in a submerged chamber for dissolving a gas such as air i a liquid is described. An air space is formed in the chamber by introduction of air under pressure. Although such a device avoids the foregoing safety hazards associated with utilization of surface aerators in an oxygen enriched atmosphere, a relatively high expenditure of mechanical power is required to dissolve oxygen in the introduced air into a liquid such as wastewater. Other apparatus for dissolving a gas in a liquid by prolonging gas bubble-liquid contact time are described in U. S.
Patent os. 3,^76,366 and 3,6 3,^03. This technique relies upon the introduc ion of gas bubbles into a downward-flowing liquid in a submerged funnel. Upwardly acting buoyant forces and downwardly acting drag forces tend to increase the contact time ' ^ between gas bubbles and the liquid. Such techniques, however, generally fail to adequately mix the liquid discharged from such a funnel with a surrounding larger body of the liquid as is required in an activated sludge process. Furthermore, such dissolution processes place heavy reliance on mere gas-liquid contact to effect a mass transfer which transfer does not necessar-ily occur in an efficient manner in practical applications.
The invention will be more clearly understood by reference to the following detailed description of an exemplary embodiment thereof in conjunction with the following drawings in which: Fig. 1 is a sectional elevational view of an exemplary oxygenating apparatus; Fig. 2 is a side sectional view of the exemplary oxy-genating apparatus illustrated in Fig. 1.
Fig. 3 is a plan view of the exemplary oxygenating apparatus illustrated in Fig. 1 Fig. 4 is an elevational sectional view of a further exemplary embodiment of an oxygenating apparatus in accordance with the present invention; Fig. 5 is a sectional view of an exemplary embodiment of an outlet nozzle; Fig. 6 is a graphical representation of oxygen consumption with respect to the superficial flov/ velocity of waste-water in an oxygenating apparatus according to the present invention; .
Fig. 7 is a sectional elevational view of yet another exemplary embodiment of oxygenating apparatus in accordance w._b^h the present invention Fig. 8 is a profile of dissolved oxygen levels in wastewater treated with oxygenating apparatus in accordance with the present invention; and Fig. 9 is a velocity profile of wastewater in a treat ent tank during operation of the oxygenating apparatus in accordance with the present invention.
Referring nov; to the drawing, and in particular to Fig. 1, illustrated therein is an exemplar embodiment of an apparatus for oxygenating wastewater which may be utilized in an activated sludge waste treatment process. In this process, untreated wastewater is commonly admitted to a primary settling basin wherein readily setfclable solids are permitted to settle and are collected on the bottom of such a basin. Wastewater is then passed to a treatment tank, along with activated sludge and an oxygen supplied in a feed gas is dissolved therein. At this stage of the process, the combined wastewater and activated sludge is many times referred to as a "mixed liquor" although for purposes of convenience, the term wastewater will be used as a -full equivalent. After retaining wastewater for a sufficient time to permit reduction in the biological oxygen demand of the wastewater to a desired level, the wastewater is passed to a clarifier wherein purified effluent is decanted and activated sludge is settled out. In order to maintain a sufficient level of microbial activity, a predetermined portion of the collected sludge is returned to the treatment tank.
The oxygenating apparatus 10 is comprised of a pair which may comprise a conventional open, secondary treatment tank for receiving wastewater to be oxygenated, is provided to confine wastewater 12 therein.
Chamber 11 is positioned within tank 13 and by way of suitable bracket members is mounted on adjustable legs 14. The upper extremities of chamber 11 extend above the surface of wastewater 12 although chamber 11 may be totally submerged in a particular tank. The bottom of chamber 11 is sufficiently spaced from the bottom of tank 13 to permit predetermined flows of oxygenated wastewater to be established in tank 13. Oxygenating apparatus 10 is provided with an inlet 15 in the form of a conventional pipe which is positioned below the surface of wastewater 12 and between chambers 11 and.11'. A pump 17 which may comprise a conventional axial flow impeller pump is disposed within inlet 15 and is mounted for rotation on a shaft in knovm manner. An electrical motor 16 mounted above wastewater 12 is drivingly coupled through the shaft to pump 17. In this manner a flow of wastewater 12 is forced through plenum l8 into chambers 11 and 11'. Plenum 18 may take the form of a bilateral fluid flow divider which is provided with bracket members 19 for rigidly connecting the lower portions of chambers 11 and 11'.
Additionally, the upper portions of chambers 11 and 11' may be affixed to one another by suitable bracket members 22, Alternately, chambers 11 and 11' may be positioned externally of tank 13 and adapted to receive wastewater from and discharge oxygenated wastewater into tank 13.
Chamber 11, which is generally enclosed, is comprised of inlet 20, static mixing zone 24, liquid and gas accumulation spaces 25 and 26, respectively, and an outlet 31. Inlet 20 of chamber 11 is a substantially vertical channel defined by an external vertical wall of chamber 11 and partition 21. A vertical baffle 23 is suitably mounted in chamber 11 spaced away from and parallel to a portion of partition 21. The top of baffle 23 is spaced away from the ceiling of chamber 11 and the lower extremity of baffle 23 is spaced away from a substantially T horizontal portion of baffle 27 extending from partition 21.
Accordingly, partition 21 and baffle 23 are effective to define a static mixing zone 2 as will be described in greater detail hereafter.
A gas accumulation space 26 is formed in the upper reaches of chamber 11 by the introduction therein of an oxygen containing feed gas under an appropriate pressure. The extent of gas accumulation space 26 and, therefore, the depth of liquid in space 25, is determined by the pressure of the gas fed through inlet 29 to the upper reaches of chamber 11. It will be appreciated that the gas present in space 26 during operation of apparatus 10 is comprised of the feed gas, oxygen disentrained from wastewater in liquid accumulation space 25 and other gases stripped from the wastewater. Accordingly, the gas within gas space 26 is hereafter referred to as the "oxygenating gas".
Communication between gas accumulation space 26 and the static mixing zone 2k is provided through passage 28 which passage is defined by the top of chamber 11 and the uppermost extremity of baffle 23. The feed gas introduced into the upper reaches of chamber 11 is preferably comprised of an oxygen enriched gas containing at least 40^ oxygen. A vent, or outlet, 30 is provided to permit the removal of spent or waste gases such as nitrogen which is stripped from wastewater during the oxygenation thereof and is collected in gas accumulation space 26. Preferably, vent 30 is located away from gas accumulation space 26 in order to prevent any foam, which may develop therein in the course of oxygenating wastewater, from entering the vent line.
A discharge outlet for oxygenated wastewater is provided in the lower reaches of chambers 11 and 11*. The particular configuration of such an outlet will be determined by the particular flow pattern to be maintained in wastewater 12 to maintain activated solids (suspended solids) in suspension r ^ " and to mix oxygenated wastewater with wastewater 12. As required flow patterns of wastewater 12 are additionally affected by the particular geometry of tank 13, it will be appreciated that either flap 31 or nozzle 33 (Fig. 2), or a combination of both, may be utilized to produce such flow patterns. An adjustable flap 31 which is hinged about, and preferably extends across, the bottom of chamber 11 is provided. A similar flap is provided in like manner with chamber 11'. A control rod 32 is suitably connected at the lower extremity thereof to flap 31 an extends upwardly through, and is sealed to the top of chamber 11. Externally effected adjustments of the opening of flap 31, and hence, the velocity of oxygenated wastewater discharged from chamber 11, are achieved by manually raising or lowering control rod 32.
A nozzle 33 and a mechanical control arrangement therefor are provided with chamber 11 and for purposes of clarity, this structure is illustrated in Fig. 2. The nozzle 33, which may generally comprise a spout is configured to extend over a substantially shorter portion of the bottom of chamber 11 than does flap 31. Accordingly, the oxygenated wastewater discharged from chamber 11 through nozzle 33 will exhibit a greater velocity and smaller cross-section area than the oxygenated wastewater discharged through flap 31. As will be described in greater detail hereafter, the directionality and opening of nozzle 33 wa be controlled to establish predetermined flow patterns in waste-water 12.
Referring now to Fig. 2, an exemplary mechanical ar-rangement for enabling externally effected adjustments to be made to flap 31 and nozzle 33 is illustrated. It is realized in conjunction with chamber 11 , a substantially identical arrangement (not shown) is provided to control a similar flap and nozzle outlet con iguration of chamber 11 ' .
The control arrangement for nozzle 33 is specifically adapted to facilitate nozzle opening and direction control by an operator from a point external to chamber 11 above wastewater 12. Although a detailed description of nozzle 33 is set forth hereafter in connection with the nozzle illustrated in Fig. 5* other suitable nozzle configurations may be utilized. The control arrangement for nozzle 33 comprises a torque tube 3^ having a handle 36 affixed thereto and a control rod 35. The directionality of nozzle 33 is controlled by rotating handle 36 and consequently torque tube 3^ in a horizontal plane while the opening of nozzle 33 is controlled by merely raising and lowering rod 35 which in turn closes and opens a discharge spout of nozzle 33 as will be described in greater detail hereafter.
A pressure relief device is provided as a precaution-ary measure in chamber 11 and is comprises of a tubular cup 37 and conduit 39 having an outlet at the upper end thereof. Tubular cup 37 and conduit 39 are disposed about torque tube 3^ a a predetermined level in liquid accumulation space 25 and form a liquid seal which under normal conditions inhibits the escape of any gas from the outlet of conduit 39· However, in the event that the pressure of an oxygenating gas supplied to the upper reaches of chamber 11 is sufficient to depress the level of water in liquid accumulation space 25 below the lower extremity of conduit 39J the aforedescribed water seal is broken thereby venting such gas and imposing an upper limit to the pressure of a supplied oxygenating gas by venting such gas to the atmosphere. In addition, the water seal acts as a bubble baffle to prevent bubbles of oxygenating gas from escaping upwardly through tube 39.
A plan view of chambers 11 and 11' is shown in Fig. 3· In additio j the flow of wastewater 12, particularly at the surface thereof, is schematically illustrated by arrows. It wil]^ be realized that as motor 16 drives pump 17 (Fig. 1) wastewater 12 is subjected to a suction force and is drawn into the space between chambers 11 and II1 prior to the actual pumping of wastewater into such chambers as previously mentioned.
Prior to describing the operation of the oxygenating apparatus 10, illustrated in Fig. 1, it is important that several requisites of wastewater treatment to be satisfied by such an apparatus are clearly understood and appreciated. A first requirement for effective operation is to maximize the amount of oxygen dissolved in wastewater in relation to the energy required to effect stfch dissolution. A second requirement is to dissolve in wastewater as much of the supplied oxygen as possible and accordingly, to vent a minimum amount of oxygen from the apparatus. Thus, the greater the percent of oxygen consumption by an oxygenating apparatus, the more efficient is such an apparatus in terms of oxygen utilization and hence, in terms of the cost of oxygen supplied thereto. A third requirement is particularly important with respect to the oxygenating apparatus utilized in connection with activated sludge waste treatment processes wherein in order to permit the consumption of organic waste material by bacterial action, the bacterial sludge must be maintained in suspension in the wastewater. Accordingly, the wastewater in an aeration tank must be stirred effectively notwithstanding the fact that such stirrin has previously resulted in increased "mixing" energy consumed in terms of the amount of oxygen dissolved in the wastewater. In the course of describing the operation of oxygenating apparatus 10 hereafter, the ability of the present invention to satisfy the . foregoing requirements will become readily apparent.
The operation of the oxygenating apparatus as illustrated in Fig. 1 is as follows. Wastewater 12 in tank 13 is introduced into an inlet conduit 15 and is pumped by way of ' f pump 17 into plenum 18. Hydraulic kinetic energy is thus imparted to wastewater 12 which is divided into two approximately equal flow streams in plenum 18 and is then pumped under pressure upwardly through inlet channel 20 of chamber 11 and flows over the top edge of partition 21. It is noted that by virtue of forcing a flow of wastewater upwardly through inlet channel 20, a water seal is maintained between a gas accumulation space in 26 in chamber 11 and hydraulic pump 17.
Simultaneous with the introduction of wastewater 12 into chamber 11, an oxygen-containing feed gas is introduced under pressure through inlet 29 into the upper reaches of chamber 11 thereby depressing the level of wastewater within liquid accumulation space 25 to a point corresponding to the magnitude of the pressure of the oxygenating gas.
As previously mentioned, static mixing zone 24 is defined by partition 21 and baffles 23 and 27 with the particular type of static mixing zone illustrated herein being of the gravi tational fall type. It is realized that other forms of static mixing devices, such as an eductor may be utilized in lieu of a gravitational fall zone. Wastewater is caused to flow over the top of baffle 21 and then falls under the influence of gravity into zone 24 to impinge upon wastewater therein. This impingement results in a state of high wastewater-gas turbulence and the production of a froth column within mixing zone 24. As a consequence of providing a high degree of liquid turbulence, bubbles of oxygenating gas, having relatively large surface area are thoroughly' dispersed in the liquid. In addition, the high liquid phase turbulence is effective to promote a greater rate of mass transfer across the interfacial area created b the Although the importance of creating a turbulent condition will be understood from the foregoing discussion, a further parameter, namely the "superficial" flow velocity of water y through zone 2k is also an important factor in obtaining a maximum utilization of the oxygenating gas supplied to zone 24. The superficial flow velocity of wastewater may readily be calculated by dividing the flow rate by the cross-section area between parti tion 21 and baffle 23. It has been found that for a particular fall height which is defined, for example, by the distance between the top of a partition or weir and the depressed level of such water as tap water in a liquid accumulation space, the amoun of oxygen dissolved in tap water will vary as a function of the superficial flow velocity of water through a static mixing zone. Thus, for a particular fall zone, the "deficit reduction ratio" of oxygen may be plotted against different superficial flow velocities of water. Such a graphical representation is depicted in Fig. 6, wherein the deficit reduction ratio, which may be defined Cout~Cin by. the expression -— is plotted along the ordinate. The us - ^in terms Cou¾ and C^n represent the concentrations of oxygen dissolved in tap water after and before, respectively, the water has undergone a gravitational fall in a static mixing zone. The term Cs represents the saturated concentration of dissolved oxygen in water under experimental conditions. Thus, the foregoing expression, or the deficit reduction ratio, represents a measure of the efficiency of the gravitational fall zone in utilizing supplied oxygen. Accordingly, this ratio reflects the amount of oxygen actually dissolved in water in the fall zone against the experimental maximum amount which could be so dissolved.
The superficial flow velocity of water is plotted on the abcissa and this velocity may be easily varied by controlling the speed of operation of hydraulic pump 17 in a conventional Referring again to Fig. 6, it is noted that for a particular fall height a maximum deficit reduction ratio occurs at approximately the same superficial flow velocity of water therethrough. That is, a maximum deficit reduction ratio occurs at a superficial flow velocity of approximately 1.0 ft. /sec. regardless of the fall height of a gravitational fall zone.
One possible explanation of the occurrence of an optimum superficial flow velocity and the relationships between superficial flow velocities and deficit reduction ratios illustrated in Pig. 6 is as follows. As the superficial flow velocit of water increases, additional turbulence in the fall zone can be expected to occur which promotes greater oxygenation, i.e. greater dissolution of oxygen in water as previously mentioned. However, as the superficial flow velocity increases the period of time during which oxygenation may take place in the fall zone is reduced and accordingly, the actual degree of oxygenation in the fall zone is correspondingly diminished. It has been found that superficial flow velocities in the range of 0.33 ft. /sec. to 3.0 ft. /sec. will result in maximum deficit reduction ratios for a particular fall height.
Prom the foregoing, it will be appreciated that by maintaining a highly turbulent condition of wastewater in a confined static mixing zone 24, and by providing an optimum superficial flow velocity of wastewater therethrough, a high concentration of dissolved oxygen in wastewater is achieved.
The flow of wastewater exiting from static mixing zone 2k carries therewith entrained bubbles of the oxygenating gas. Thus, as wastewater flows beneath the lowermost extremity of baffle 23 and upwardly toward the depressed wastewater level in liquid accumulation space 25, a circulating pattern of wastewater with gas bubbles entrained therein, is established generally in such a flow, the turbulence is dissipated in the relatively quiescent liquid accumulation zone 25 which permits the disen- trainment of gas bubbles. Larger gas bubbles are disen trained* into gas accumulation space 26 relatively rapidly as the velocity of the flow from mixing zone 24 diminishes in liquid accumulation space 5. Smaller gas bubbles will also be disentrained from the wastewater although a greater tendency to drag such smaller bubbles downwardly within liquid accumulation space 25 exists. A further opportunity for dissolution of the oxygenating gas into the liquid in liquid accumulation space 25 is thus provided and although some very small gas bubbles are emitted from this space through flap 31 or nozzle 33 or both, such amounts are emitted near the bottom of tank 13 and are still available for dissolution in wastewater 12. Additionally, the amounts of oxygenating gas which may escape to the surface of wastewater 12 are well within both economical and safety limits even during the treatment of wastex^ater exhibiting high detergent concentrations.
It has been found in practice that most of the entrained oxygenating gas in wastewater exiting from static mixing zone 24 is disentrained into gas accumulation space 26. The disentrained oxygenating gas is thus returned or recycled to the static mixing zone 24 via passage 28.
The dissolution of oxygen in wastewater causes certain other gases such as nitrogen to be stripped from the wastewater and released into gas accumulation space 26. In order to prevent the excessive buildup of impurities such as nitrogen which would reduce the oxygen content of the oxygenating gas below acceptable levels, a venting conduit 3 is provided. The venting of the oxygenating gas containing such impurities may be either intermittent or continuous and may be controlled by suitable valve devices (not shown) in a conventional manner. It has been It will be understood that efficient dissolution of oxygen is facilitated by recycling the oxygenating not initially dissolved in zone 24. The flow of wastewater through the "" mixing zone is effective to sweep gas downwardly through zone 24 into liquid accumulation space 25. However, the normal buoyant forces acting on bubbles of the entrained oxygenating gas causes a disentrainment of the gas into gas accumulation space 2β and thereby forces the oxygenating gas upwardly toward passage 28. In this manner, the oxygenating gas is recycled to mixing zone 24 and is again available for dissolution in the incoming wastewater.
The oxygenated wastewater contained within liquid accumulation space 25, which will have a relatively high oxygen concentration, such as for example, 15 mg./l., is emitted from chamber 11 at an increased velocity through flap 31 or nozzle 33 or both into the main body of wastewater 12. The oxygenated wastewater in liquid accumulation space 25 is maintained under a pressure head such that oxygenated wastewater may be emitted from chamber 11 at an increased velocity sufficient to cause an adequate stirring of wastewater 12 in tank 13 and thereby maintain activated sludge particles in suspension. Furthermore, by adjusting the opening of flap 31 and/or the direc ionality and opening of nozzle 33, a predetermined flow pattern of highly oxygenated wastewater may be established in tank 13. Production of such a flow pattern will permit a relatively constant dilution of the highly oxygenated wastewater emitted from liquid accumulation space 25 thereby assuring that wastewater in substantially all parts of tank 13 will be oxygenated to a level, such as 0.5 p. p.m., which level is sufficient to sustain aerobic conditions therein. Furthermore, by adjusting the opening and directionali y of each of nozzles 33 in chambers 11 and 11', f om uch nozzles ma be arran ed to coo erate in establishing a predetermined flow pattern of highly oxygenated wastewater within tank 13.
It is realized that the foregoing tank stirring ope-r¾f- tions may be effected by utilization of oxygenation apparatus 10 without the additional requirement of mechanical agitating devices. Also, in accordance with the present invention, the enriched oxygen atmosphere maintained within oxygenating apparatus 10 does not extend across the surface of wastewater 12 and as no moving parts are utilized within gas accumulation space 2β, the possibility of a spark being produced therein is highly unlikely Moreover, as the oxygenating apparatus 10 according to the present invention is at least partially submerged in wastewater 12 and contains only relatively small amounts of oxygenating gas, the possibility of fire damage is still further minimized. At certain portions and particularly lower depths in tank 13 , relatively high dissolved oxygen levels are exhibited. This effect occurs primarily due to the discharge of highly oxygenated waste water from the bottom of apparatus 10 which achieves a "bottom scouring" of tank 13 as will be described in greater detail here after. However, notwithstanding such high dissolved oxygen levels below the surface at wastewater 12, surface oxygen concen trations are clearly within prescribed safety limits.
The oxygenating apparatus 10 illustrated in Figs.1-3 has been experimentally tested. The wastewater to be treated experimentally comprised the industrial waste of a meat processing plant fed to a treatment tank 13 from a stirred retention basin. The particular treatment tank 13 utilized in the activated sludge waste treatment process is 25 feet square and 10 feet deep. Each of chambers 11 and 11 ' of apparatus 10 are approximately feet square and exhibit a height of approximately 10 feet. Both flaps 3 and nozzles 33 were adjusted to estab lish predetermined flow patterns of oxygenated wastewater within The -biological oxygen demand (BOD) of the industrial wastewater to be treated typically ranged from 800 to 2500 mg/l which demands are considerably greater than the average BOD of^f"' sewage to be treated in municipal facilities. Although the subject treatment tank was originally designed to process 40,000 gallons of 400 p. p.m. BOD wastewater per day using a conventional surface aerator, treatment rates of up to 100,000 g.p.d. of approximately 1100 p.p.m. BOD have been obtained utilizing only oxygenating apparatus 10 in such a treatment tank.
Referring now to Fig. 8, there is illustrated a profile of the levels of oxygen dissolved in the wastewater taken at twelve points throughout the treatment tank. In addition, at each such measurement point, DO levels were read at several test depths of 9.5, 7.0, 4.6 and 1.0 feet below the wastewater surface. A standard membrane dissolved oxygen probe was utilized to measure such concentrations which are depicted in Fig. 8 in units of milligrams per liter. In the tests conducted, each of flaps 31 and 31' were adjusted to a 2 inch opening while nozzles 33 and 33' were closed. Untreated wastewater was admitted to the treatment tank at a corner remote from apparatus 10 with the treated effluent being removed from a point on the side of the tank opposite to the wastewater inlet. A sludge return line was arranged to discharge sludge into the treatment tank at a point adjacent to the wastewater inlet.
From the DO level measurements obtained a generally even distribution of such levels throughout the treatment tank is observed. Thus, at each of points 1-12 and at various depths at each point, dissolved oxygen levels between 4.5 and 7.0 mg/l have been observed. Furthermore, such dissolved oxygen levels are more than adequate for maintaining aerobic conditions in the industrial wastewater to be treated. Certain higher DO levels have been measured during the o eration of oxy enatin apparatus 10.
For example, at point 3, depth D, a DO level of 11. 0 mg/l has been measured. As this measurement is taken in close proximity to flap 31 (which as aforesaid is provided at the bottom of chamber 11) a relatively high DO level is to be expected as the highly oxygenated wastewater from chamber 11 has not been thoroughly diluted in the wastewater within the treatment tank. In addition, it is noted that relatively high DO levels have been obtained at depth D for points 4 and 5 which points are aligned with flap 31 and are at approximately the same depth within the treatment tank. Similarly, relatively high DO levels are obtained at depth D for points 6, 7 and 8 which points are aligned with flap 31 ' of chamber 11 ' . Satisfactory DO levels have also been measured at points 1 and 9 which points are not directly exposed to the discharged oxygenated wastewater from apparatus 10. Accordingly, the measured DO levels at points 1 and 9 indicate that an adequate dilution and mixing of wastewater in the treatment tank has been effected and that sufficient oxygen is dissolved to maintain aerobic conditions in substantially all portions of the treatment tank.
Measurements of flow velocities at several points in the treatment tank have been made and a profile of such velocities is depicted in Fig. 9- At each of points 1-7, flow velocities were measured at several test depths although the accuracy of such measurements is not considered to be totally reliable because of the particular instrumentation utilized. Measurements of flow velocities at a depth of 8. 5 feet below the wastewater surface at points 2-5 ranged from 0.67 to 0. 95 ft. /sec. The higher flow velocities at this depth are not unexpected as such readings were taken at points and at a depth aligned with the discharge of flaps 31 and 31 ' prior to substantial dilution of the highly oxygenated wastewater. However, lower readings of flow tank appear to result from the general mixing and dilution of the highly oxygenated ■wastewater within the treatment tank.
Furthermore, the rate at which wastewater was admitted to the treatment tank was subject to fluctuations which were reflected in uneven flow velocities at various measurement points.
Several flow velocities 'measured at various depths at points 1-7, are near the lower end of the range of flow velocities generally considered as acceptable for adequate mixing of the suspended solids in the secondary stage of an activated sludge process. However, for the velocity profile illustrated in Fig. 9, nozzles 33 and 33' were closed. Thus, further adjustment of flaps 31 and 31' and the opening of nozzles 33 and 33 r may be effected to obtain other flow patterns and velocities within the treatment tank. Although flow velocities in certain portions of tank 13 are less than the velocities traditionally considered necessary for maintaining solids in suspension (e.g. 0.5-1.0 ft. /sec. at the wastewater surface), apparatus 10 is particularly effective to generate satisfactory flow velocities at lower depths in tank 13- The importance of this effect resides in the fact that most solids tend to accumulate toward the bottom of tank 13 and as lower portions of the tank are subjected to the greatest flow velocities, activated sludge particles are consistently stirred and thereby maintained in suspension. Thus, the foregoing "bottom scouring" of tank 13 effectively provides the requisite stirring of wastewater 12 without reliance upon mechanical devices. Accordingly, the greatest flow velocities of oxygenated wastewater discharged from apparatus 10 are provided at depths at which stirring is most important.
Preliminary measurements of mixed liquor suspended solids have indicated uniform concentrations of approximately 3200 mg/1. with volatile solids comprising 75-8 of the total suspended solids. The foregoing suspended solids concentrations have been recorded at depths of 1.5, 5.0 and 8.0 feet -^y below the wastewater surface in tank 13. Accordingly, the stir ring of wastewater 12 by apparatus 10 is sufficient to maintain suspended solids concentrations necessary for continuance of the activated sludge process.
In addition to measuring dissolved oxygen levels and flow velocities at various points within treatment tank 13, several operating parameters of oxygenating apparatus 10 have been recorded. As indicated in Table I, the rates at which oxygen is supplied to and vented from apparatus 10 have been measured for varying fall heights. Particular fall heights were, measured by means of a calibrated differential pressure gauge and oxygen flow rates were measured by conventional flow meters. The dissolved oxygen levels of wastewater at the inlet and outlet of oxygenating apparatus 10 were measured by a standard membrane dissolved oxygen probe with the change in DO levels indicated below.
TABLE I •21 9.0 15.9 2.1 63 37 12.0 I .9 2.0 67 42 3 .0 22.8 6.0 71 52 1 .5 23.2 7.4 69 63 16.5 24.8 9.2 72 Pump 17 was operated to supply wastewater to plenum l8 at a flow rate which was measured by a weir measurement Samples of wastewater 12 taken during testing of oxygenating apparatus 10 indicated an average wastewater temperature of 29°C. The input wastewater contained an average B0¾ of 1100 mg/1 with 99 BOD removal measurements being consistently obtained.
As the data set forth above have been observed during the experimental testing of oxygenating apparatus 10, it will be understood that such data are merely exemplary of this operation. Accordingly, operating conditions have not been optimized although it is clearly desirable to increase the ratio of dissolved oxygen per horsepower hour and to reduce the percentage of oxygen vented from apparatus 10 as far as possible. For example, in order to preclude the possibility of a 'short circuiting' of the feed gas supplied through inlet 29 to vent 30, it may be desirable to rearrange the location of the feed and vent conduits. Furthermore, although a commercially pure oxygen supply has been utilized in the course of testing apparatus 10, less than commercially pure oxygen may be utilized.
Preferably, the oxygen supply will exhibit an oxygen concentration of at least 40 .
Referring now to Fig. 4 of the drawing, illustrated therein is a further exemplary embodiment of oxygenating apparatus 40 suitable for emplacement within a body of wastewater 12. Oxygenating apparatus 40 is comprised of a generally enclosed submerged chamber 43 having an inlet 45 in the form of a suitable pipe or conduit sealed to the top of chamber 43 by suitable sealing means 44. A hydraulic pump 46 which may comprise a rota table impeller pump mounted for rotation on shaft 47 is disposed within inlet conduit 45. The outlet of conduit 4 communicates with a liquid space defined by a portion of the exterior 3, a portion of baffle 50 and a portion of a substantia lly vertically disposed partition 9 which, at the lower extremity thereof, is rigidly affixed to baffle 50. A static mixing zone 1 is defined within chamber 43 by a further portion of baffle 50 and a baffle 52, which is spaced away from and oriented substantially parallel with baffle 49. The lower portion of static mixing zone 51 communicates with liquid accumulation space 53 with the remaining portion of chamber 3 being substantially comprised of gas accumulation space 54 formed in the upper reaches thereof. An inlet 56 is provided to permit the introduction of a feed gas under pressure into the upper reaches of chamber 3 and a passage 55 is defined by the upper extremity of baffle 52 and the top wall of chamber 43 thereby providing communication between gas accumulation space and the upper reaches of the static mixing zone 51. A suitable venting means, schematically illustrated as conduit 57, is provided to permit the venting of waste gases from gas accumulation space 54.
An outlet from chamber 43 is provided in a lower portion thereof and may take the form of a nozzle 58, the opening and directionality of which may be controlled by an operator located exterior to apparatus 40 and above wastewater 12. An exemplary control arrangement for nozzle 58 may comprise a torque tube 59 extending from an accessible point above wastewater 12 through the top wall of chamber 43 to nozzle 58. A control rod 60 is loosely fitted within torque tube 59 and, by raising the lowering control rod βθ, the extent of opening of nozzle 58 wa be controlled. Similarly, rotation of torque tube 59 which is nested within conduit 6l is effective to control the directionality o flow through nozzle 58. Conduit 6l is utilized to form a pressure relief and bubble baffle in a manner similar to like structure illustrated in Fig. 2. A detailed description of a described hereafter in connection with Fig. 5.
Oxygenating apparatus 40 is similar to apparatus 10 in that both are designed for ready insertion into a wastewater treatment tank 13. However, it is realized that upon insertion of apparatus 40 (which preferably represents one half of a twin unit) in such a tank, buoyant forces acting on chamber 43 will tend to prevent the proper orientation of the apparatus in tank 13. Unbalanced buoyant forces act on chamber 43 as a result of gas accumulation in space 5 not being symmetrically formed therein. Accordingly, oxygenating apparatus 4o is especially suited to treatment tank 13 wherein chamber 43 may be rigidly affixed to either a side wall or mounted on legs (not shown) and affixed to a bottom wall of such a treatment tank. In Fig. 4, bracket means 62 are illustrated as suitable connecting elements for affixing chamber 43 to a side wall of treatment tank 13. However, it will be understood that other means for retaining chamber 43 in order to provide a proper orientation thereof may be utilized. In addition, supporting legs (not shown) may be utilized to maintain chamber 43 , spaced away from the bottom of treatment tank 13.
The operation of oxygenating apparatus 4θ is substantially identical to the operation of apparatus 10 illustrated in Fig. 1. In oxygenating apparatus 40, wastewater is pumped under pressure b pump 43 through conduit 45. Wastewater exiting from conduit 45 is then caused to flov; upwardly through channel 48 formed between conduit 4 and baffle 9, as well as through channel 48' which is defined by a side wall of chamber 43 and conduit 45. It will be understood that a water seal is provided between gas accumulation space 5 and pump G in a manner similar to the water seal provided in the oxygenating apparatus 10 illustrated in Fig. 1. Wastewater is then subjected to a gravitational fall pon passing over the uppermost edge of baffle 4 .
An oxygen-containing feed gas is introduced through conduit 56 into the upper reaches of chamber 43 under a pressure which is effective to depress the level of water therein to a predetermined level. A gas accumulation space 4 is thereby formed in chamber 3 with the extent of this space being determined by the pressure of the supplied feed gas.
The wastewater undergoing a gravitational fall within the upper reaches of static mixing zone 1 impinges upon the wastewater therein which results in a highly turbulent condition and promotes an effective dissolution of oxygen supplied to zone 51 in the turbulent wastewater in a manner substantially identical to the oxygenation of wastewater in static mixin zone 24 of the apparatus illustrated in Fig. 1. It will be appreciated that the flov; rate of wastewater into static mixing zone 51 is adjusted to an optimum superficial velocity, which for example may be approximately 1 ft. /sec.
Oxygenated wastewater is emitted from static mixing zone 53 into a liquid accumulation space 53 through an opening provided between the lowermost edge of baffle 52 and baffle 50. The general flov; pattern of wastewater within space 53 is a circulating one wherein wastewater initially flows upwardly toward gas accumulation space and subsequently flows downwardly toward the lower reaches of chamber 3. As the oxygenated wastewater flows toward gas accumulation space 4 , large en-trained bubbles of theoxygenating gas are i^apidly disentrained into gas accumulation space 4 and may be recycled through passage to static mixing zone 51. Upon entering the liquid accumulation space 3 , the velocity of oxygenated wastewater decreases to a relatively low value which in turn promotes the disentrainment of gas bubbles therefrom. In addition, a further dissolution of the oxygenating gas into the wastewater in liquid gas bubbles are not di sent. rained from the oxygenated wastewater and are- dragged downwardly toward the lower reaches of chamber 3, it has been found that only a small fraction of oxygenating gas is emitted through no»: ie 58 into wastewater 12.
During the pro ess of oxygenating .''wastewater in static mixing zone 51, certain impurities in the wastewater such as for example nitrogen gases are stripped therefrom and are disentrain ed into gas accumulation s ace 54. A venting conduit 57 is provided in communication with gas space and through either a continuous or intermittent venting operation by conventional valving means (not shown), such impurities are removed from cham ber 43. Although such venting also entails removal of oxygen, it has been found that only a minor portion of such gas is vente Oxygenated wastewater contained in liquid accumulation space 53 is discharged fro:¾ chamber 43 through nozzle 58 in a manner substantially identical to the discharge of oxygenated wastewater from chamber ΐχ as previously described in connection with the apparatus illustrated in Fig. 1. Thus, torque tube 59 and control rod βθ are oPe ated to control the directionality and opening of nozzle 8, respectively, to thereby establish a predetermined flow of oxy≤Snafced wastewater within the main body of wastewater 12. In this manner, wastewater 12 is stirred and the dissolved oxygen content thereof is increased such that in an activated sludge rocess, sludge will be maintained in susper; sion in wastewater 12 an- erobic conditions will be sustained as well.
Referring now p g> 5^ there is illustrated an exemplary embodiment of a diS r:-,arge nozzle suitable for use in connection with oxygenating -vparatus illustrated in Figs. 2 and 4. Nozzle 33 is comprised o- . plate 100, a spout 102 and control means in the form of tor: ,., tube 34. and control rod 35 for con wall of chamber 11 (Fig. 1) and, if desired, may be rotatably sealed thereto by means of a suitable circumferential seal means 101. Spout 102 is comprised of an upper inclined portion 103 VJhich is rigidly affixed to torque tube 3^ with the lower end of portion 103 being firmly attached to plate 100 at point 109.
The upper end of portion 103 is rigidly affixed to bracing rods I05 and 106 which in turn are likewise affixed at the lower ends thereof to plate 100. An aperture is defined in plate 100, which aperture is preferabl rectangular. A lower portion lO of spout 102 is pivotable along a line extending through point I07. A substantially vertical rear wall 110 of spout 102 is formed between portions 103 and 10k. Control rod 35 is loosely positioned within torque tube 3^· and extends downwardly through lower portion 104 of spout 102. Rod 35 is operatively connected to portion 10k by way of a protrusion or a clevis nut formed at the lower extremity of rod 35.
The operation of nozzle 33 will now be described. As previously mentioned, torque tube 3k and control rod 35 extend upwardly from chamber 11 above wastewater 12, preferably to a point at which external operation of such members may be effected. The extent of the opening of nozzle 102 is controlled by the raising or lowering of rod 35 which in turn is effective to pivot the lower portion 10k of spout 103 about a line through point 107. Thus, upon raising control rod 35, portion 10^ of spout 102 is translated to a position indicated by the dashed line illustrated in Fig. 5. During this operation, however, upper portion 103 of spout 102 remains substantially stationary.
Accordingly, in the foregoing manner, the extent of the opening of nozzle 33 may be simply controlled. In order to control the directionality of the flow of wastewater emitted through nozzle 33, torque tube .3^ is rotated in a substantially horizontal plate 100 and to torque tube 3^ plate 100 is rotated about i s axis with the extent of such rotation being de ermina ive of the azimuthal direction of wastewater discharged through nozzle 33 - ' It will be appreciated that as plate 100 is seated on a shoulder formed in the bottom wall of chamber 11 , the pressure of wastewater thereabove is effective to assist in sealing plate 100 to such a bottom wall, yet nonetheless permit rotation of plate 100 in response to a similar rotation of torque tube 3^ . In the foregoing manner, therefore, a relatively simple directionality control of nozzle 33 is effected.
In accordance with another exemplary embodiment of an apparatus for oxygenating wastewater, there is illustrated in Fig. 7 an apparatus 70 generally suitable for emplacement within a waste treatment tank containing a body of wastewater 12. A generally enclosed chamber 71 having an open bottom is provided with an inlet 72 for admitting wastewater into the upper reaches thereof. A hydraulic pump 73 > which may comprise a conventional axial flow impeller pump mounted, for rotation on a shaft 7^ . An electrical motor (not shown) is positioned at a suitable location above wastewater 12 for rotating shaft 7^ thereby driving pump 73 and forcing wastewater into chamber 71. A partition 7β is disposed interiorally of chamber 71 and preferably comprises a substantially horizontal portion 77 extending from one side-wall of chamber 71 and a substantially vertical portion 78 depending from the opposite end of horizontal portion 77. A small passage 87 is defined in the horizontal portion 77 preferably at a point remote from inlet 72 ; or such a passage may be formed in vertical portion 78 of partition 76 immediately below horizontal portion 77. A substantially horizontal channel 75 is thus formed and extends from inlet 72 across the upper reaches of chamber 71 to a point approximately above the upper portions of are so disposed so as to form a static mixing zone 88 or the gravitational fall type within chamber 71. A baffle 79 is provided at the lower portion of static mixing zone 73 and is '"'7 spaced away from the lower extremity of partition 78 to permit liquid flow from static mixing zone 88 into a liquid accumulation space 83. A conduit 80 is provided to communicate between chamber 71 and through valve 82 to a source of feed gas. As will be described hereafter, a gas accumulation space 8 is formed immediately beneath horizontal portion 77 of partition 6 and the oxygenating gas within space Qh is permitted to communicate with the upper reaches of the static mixing device and channel 75 through passage 87 in portion 77. A conduit 85 is also provided to communicate with the upper reaches of the static mixing zone 88 for the purpose of venting gas therefrom through a suitable valve means 86. In addition, a pressure regulating device 8.1 may be used in connection with valve 82 in order to maintain the oxygenating gas under a predetermined pressure and hence maintain the liquid level within liquid accumulation space 83 at a substantially constant height.
The operation of the wastewater oxygenating apparatus 70 illustrated in Fig. 7 will now be described. Prior to operation of apparatus 70, chamber 71 is substantially filled with wastewater, pump 73 is energized and thereby forces wastewater into channel 75 under pressure. Upon the subsequent introduction of a feed gas under pressure through conduit 80 into chamber 71, the level of wastewater within chamber 71 is depressed to an extent corresponding to the magnitude of the pressure of the supplied feed gas. Accordingly, a gas accumulation space 8-is formed within chamber 71. The wastewater admitted into channel 75 then undergoes a gravitational fall at the upper portion of static mixing zone 83. However, as the oxygenating gas is ainta ned in communica ion with channel throu h an a erture 87 formed in portion 77 of partition 76, a further gas space is maintained in the upper reaches of the static mixing zone 88. , As the wastewater undergoes the aforementioned gravitational fall, a highly turbulent condition is caused in the static mixing zone 88 which in turn results in a high level of oxygen dissolution in the wastewater in a manner substantially identical to that as previously described in connection with oxygenating apparatus 10 illustrated in Fig. 1. The oxygenated wastewater is subsequently emitted from static mixing zone 88 and enters the liquid accumulation space 83 while entrained bubbles of the oxygenating gas are disentrained from the l-iastewater in space 83 and returned to gas accumulation space 84. The oxygenating gas so returned to space 84 is thus available for recycling and is subsequently returned to the static mixing zone 88 through aperture 87 as previously described. The oxygenated wastewater introduced into liquid accumulation space 83 is permitted to flow from the lower reaches of chamber 71 into the main body of wastewater 12 for admixture therein. In the foregoing manner, the highly oxygenated wastewater emitted from liquid accumulatio space 83 of the chamber 8l is diluted in the body of wastewater 12. Accordingly, the dissolved oxygen level of wastewater 12 is increased to a level such as 0.5 p. p.m. which is suitable for sustaining aerobic conditions within wastewater 12.
The methods and apparatus according to the present invention have been described hereinbefore in connection with the oxygenation of wastewater and particularly in an activated sludg waste treatment process. It will be appreciated by those skill in the art that- the present invention is not limited to the dissolution of oxygen in wastewater but may be utilized generally t dissolve a gas in a liquid such as, for example, ozone in water, or to dissolve carbon dioxide in an aqueous solution to adjust the pH level thereof. Alternatively, the present invention may be utilized to oxygenate industrial waste materials such as "black liquor" in paper production processes'.
It will also be understood that the apparatus embodying the present invention is highly modular in and readily in-sertable in a body of wastewater to be oxygenated. Thus, a plurality of oxygenating apparatus such as apparatus 10 or 0 ccmld be positioned in such wastewater with the discharge of each apparatus cooperating to provide a predetermined flow pat-tern in, for example, a treatment tank.
While the foregoing oxygenating apparatus has been described as positioned within a treatment tank, it will be realized that this apparatus may be arranged to float in or be positioned adjacent to a treatment tank. In the latter instance, suitable piping and conduits may be provided to introduce untreated wastev/ater into the oxygenating apparatus and to return oxygenated wastewater to the treatment tank. Additionally, it will be realized that the present oxygenating apparatus may be formed in geometries other than rectangular.
While the present invention has been particularly described in terms of specific embodiments thereof, it will be understood that numerous variations upon the invention are now enabled to those skilled in the art, which variations are yet within the scope of the instant teaching.

Claims (10)

45829/2 C L A I M S
1. A method of oxygenating a body of wastewater containing organic solids, as in the secondary stage of an activated sludge waste treatment process, by pumping at least a portion of the body of wastewater into a chamber and introducing an oxygenating gas under pressure to form a gas space therein, the method comprises, subjecting the pumped wastewater to a gravitational fall over a weir into a confined fall zone and through the oxygenating gas so that the impingement of the falling wastewater upon wastewater in the fall zone generates sufficient turbulence to oxygenate the wastewater which is then passed together with entrained, but undissolved, oxygen to a quiet zone in the chamber wherein the wastewater turbulence is dissipated and entrained oxygen is released to the gas space of the chamber while oxygenated wastewater is discharged through a nozzle from the quiet zone into the lower portion of the body of wastewater at a velocity sufficient to stir the body of wastewater so that the organic solids are kept in suspension such that aerobic digestion of such solids will be effected.
2. A method according to claim 1, which includes recycling oxygen released into the gas space from wastewater in the quiet zone to the gravitational fall zone for further dissolution into the turbulent wastewater.
3. A method according to claim 1 or 2 , wherein pumped wastewater is subjected to the gravitational fall at a predetermined velocity such that the turbulence 45829/2 mixing energy to oxygenate the wastewater while the velocity of wastewater flowing through the fall zone is limited to provide enough time to achieve such oxygenation.
4. A device for carrying out the method defined in claim 1, which comprises internal baffles provided in the chamber for separating the gravitational fall zone from the quiet zone within the chamber.
5. A device according to claim 4, wherein the internal baffles include a vertical baffle spaced from the weir and a baffle extending from the weir and spaced from the bottom of the vertical baffle for defining the bottom of the fall zone.
6. A device according to claim 5, wherein the vertical baffle is mounted to define a return path for oxygen disentrained from wastewater in the quiet zone to the gravitational fall zone such that the utilization of oxygen is thereby improved.
7. A device according to any one of claims 4 to 6 , wherein the nozzle is adjustable with respect to opening and directionality.
8. A device according to claim 4, which includes an inlet conduit provided with said chamber to form with the weir a re-entrant well thereby sealing the gas space from the body of wastewater under treatment.
9. A method of oxygenating a body of wastewater containing organic solids, substantially as hereinbefore described with reference to the accompanying drawings.
10. A device for carrying out the method of claim 1, substantially as herebefore described with reference to toe accompanying drawings.
IL45829A 1973-11-06 1974-10-11 Method and apparatus for oxygenating wastewater IL45829A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41340973A 1973-11-06 1973-11-06

Publications (2)

Publication Number Publication Date
IL45829A0 IL45829A0 (en) 1974-12-31
IL45829A true IL45829A (en) 1977-03-31

Family

ID=23637112

Family Applications (1)

Application Number Title Priority Date Filing Date
IL45829A IL45829A (en) 1973-11-06 1974-10-11 Method and apparatus for oxygenating wastewater

Country Status (20)

Country Link
JP (1) JPS555398B2 (en)
AR (1) AR209918A1 (en)
AT (1) AT338708B (en)
AU (1) AU472869B2 (en)
BE (1) BE821507A (en)
BR (1) BR7409231A (en)
CA (3) CA1040759A (en)
CH (1) CH608470A5 (en)
DD (1) DD116213A5 (en)
DE (1) DE2452295C3 (en)
ES (1) ES430997A1 (en)
FR (1) FR2249844B1 (en)
GB (1) GB1450612A (en)
IL (1) IL45829A (en)
IN (1) IN142402B (en)
IT (1) IT1022500B (en)
NL (1) NL7413332A (en)
PL (1) PL92389B1 (en)
SE (1) SE7411730L (en)
ZA (1) ZA746555B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103880154A (en) * 2014-02-17 2014-06-25 江苏亚洲环保有限公司 Integrated oxygen-enriched bioreactor

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3983031A (en) * 1975-04-02 1976-09-28 Airco, Inc. Methods and apparatus for controlling the supply of a feed gas to dissolution devices
EP0027912A1 (en) * 1979-10-02 1981-05-06 Union Carbide Corporation Apparatus for contacting liquid with a gas
DE3068364D1 (en) * 1979-10-02 1984-08-02 Union Carbide Corp Apparatus for contacting liquid with a gas
FR2627864A1 (en) * 1988-02-29 1989-09-01 Asulab Sa DISPLAY DEVICE FOR MEASURING INSTRUMENT
US8899823B2 (en) * 2011-12-09 2014-12-02 Advanced Stimulation Technology, Inc. Gel hydration unit
CN108499413A (en) * 2018-06-15 2018-09-07 浙江乐匠新材料科技有限公司 A kind of water paint production paint mixing tank

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3371033A (en) * 1965-08-11 1968-02-27 Fmc Corp Method of treating sewage and apparatus therefor
US3732160A (en) * 1968-08-21 1973-05-08 Research Corp Submerged filter-horizontal flow mode

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103880154A (en) * 2014-02-17 2014-06-25 江苏亚洲环保有限公司 Integrated oxygen-enriched bioreactor
CN103880154B (en) * 2014-02-17 2016-04-20 江苏亚洲环保有限公司 A kind of integrated oxygen enrichment bio-reactor

Also Published As

Publication number Publication date
IN142402B (en) 1977-07-02
PL92389B1 (en) 1977-04-30
AU7495674A (en) 1976-05-06
SE7411730L (en) 1975-05-07
GB1450612A (en) 1976-09-22
JPS5079167A (en) 1975-06-27
AR209918A1 (en) 1977-06-15
ATA890674A (en) 1976-12-15
AT338708B (en) 1977-09-12
ZA746555B (en) 1975-11-26
CH608470A5 (en) 1979-01-15
FR2249844B1 (en) 1979-08-03
JPS555398B2 (en) 1980-02-06
IL45829A0 (en) 1974-12-31
NL7413332A (en) 1975-05-09
IT1022500B (en) 1978-03-20
FR2249844A1 (en) 1975-05-30
BR7409231A (en) 1976-05-11
DD116213A5 (en) 1975-11-12
DE2452295C3 (en) 1979-10-04
CA1044603A (en) 1978-12-19
DE2452295B2 (en) 1978-02-02
DE2452295A1 (en) 1975-05-15
AU472869B2 (en) 1976-05-06
ES430997A1 (en) 1977-01-16
CA1053766A (en) 1979-05-01
BE821507A (en) 1975-04-25
CA1040759A (en) 1978-10-17

Similar Documents

Publication Publication Date Title
US4136023A (en) Methods and apparatus for treating wastewater
US7455776B2 (en) Method for mixing high viscous liquids with gas
CA1039419A (en) Method and apparatus for treating liquor containing biodegradable wastes
US4267052A (en) Aeration method and apparatus
US4844843A (en) Waste water aerator having rotating compression blades
US3983031A (en) Methods and apparatus for controlling the supply of a feed gas to dissolution devices
US4287070A (en) Method maintaining a constant gas to solids ratio in effluent from a long vertical shaft bioreactor
US3933640A (en) Methods and apparatus for treating wastewater
KR20010070464A (en) Submersible in-situ oxygenator
US3574331A (en) Aeration tank for waste treatment
EP0583509B1 (en) Enhanced gas dissolution
EP2188223B1 (en) Method and apparatus for aeration
EP0903325B1 (en) Method for ozone treatment of sewage sludge
US4094774A (en) Method and apparatus for oxygenating aerobically decomposable liquors
US4440645A (en) Dissolving gas in a liquid
US4070279A (en) Eductor for dissolving gases in liquids
IL45829A (en) Method and apparatus for oxygenating wastewater
US5772886A (en) Aquaculture process
CA2670028C (en) System and method for mixing high viscous liquids with gas
US4452701A (en) Biological treatment of sewage
US3207313A (en) Apparatus for aeration of waste products
US4202762A (en) Process and device for the aeration of waste water
US3951758A (en) Method of operating a purifying plant and tank for practicing said method
Stanković Comparison of ozone and oxygen mass transfer in a laboratory and pilot plant operation
US3058908A (en) Method of dispersing gases