IL43377A - N-(1'-alkoxycarbonyl-ethyl)-n-haloacetyl-2,6-dialkylanilines their preparation and their use for the control of phytopathogenic fungi - Google Patents
N-(1'-alkoxycarbonyl-ethyl)-n-haloacetyl-2,6-dialkylanilines their preparation and their use for the control of phytopathogenic fungiInfo
- Publication number
- IL43377A IL43377A IL43377A IL4337773A IL43377A IL 43377 A IL43377 A IL 43377A IL 43377 A IL43377 A IL 43377A IL 4337773 A IL4337773 A IL 4337773A IL 43377 A IL43377 A IL 43377A
- Authority
- IL
- Israel
- Prior art keywords
- formula
- ethyl
- methoxycarbonyl
- methyl
- dimethylaniline
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
1445387 N - (1<SP>1</SP> - alkoxycarbonylethyl)- N- haloacetyl - 2,6 - dialkylanilines CIBAGEIGY AG 12 Oct 1973 [13 Oct 1972 29 Aug 1973] 47857/73 Heading C2C The invention comprises compounds having the formula wherein Y is a halogen atom. They may be prepared by reacting a compound of formula with an alpha-halopropionic acid ester and reacting the resulting intermediate of formula with a haloacetylating agent. The compounds of the invention may be used for the control of phytopathogenic fungi and bacteria.
[GB1445387A]
Claims (19)
1. Phytofungicidal agents containing as active substance a compound of formula I wherein one of and R represents the methyl group and the other represents the methyl or ethyl group, and Y represents fluorine, chlorine, bromine or iodine, .together with suitable carriers and/or additives.
2. Phytofungicidal agents according to Claim 1 containing < as actis/e substance N.r (1 ' -methoxycarbonyl-ethyl) -Nrchloroacetyl- ■ 2 , 6-dimethylaniline; of -the "formula <.
3. Phy.tofungicidal...agents_according.. to Claim 1 containing as activei. substance N (1 · Tinethoxycarbonyl-ethyl) -N-fluo"roacetyl-2 , 6-dimethyianiline of -tfte—formula 43377/2
4. Phytofungicidal agents according to Claim 1 containing as active substance N- (1 ' -methoxycarbonyl-ethyl) -N-bromoacetyl-2 , 6-dimethylaniline of the formula
5. Phytofungicidal agents according to Claim 1 containing as active substance N- (11 -methoxycarbonyl-ethyl) -N-iodoacetyl-2 , 6-dimethylaniline or the formula
6. Process 5fo the preparation < of-..compounds ·. of formula in which process an a-anilinopropionic acid ester of the formula 43377/2 wherein one of and R2 represents the methyl group and the other represents the methyl or ethyl group, is allowed to react with a haloacetylating agent.
7. Process according to Claim 6, wherein the haloacetylation is performed with the halide or anhydride of the respective monofluoro-, monochloro-, monobromo- or monoiodoacetic acid.
8. Process according to Claim 6, wherein a- (2 , 6-dimethyl-anilino) -propionic acid methyl ester is allowed to react with the halide or anhydride of monochloro- acetic acid.
9. Process for the control of fungi, which process comprises treatment with a compound of formula I wherein one of and ^represents the -'methyl -group iand-the -other represents ;the methyl or ethyl group, and Yl represents -fluorine, chlorine, bromine. or iodine.
10. Process for the control of fungi according to Claim 9 comprising treatment with Nr (.1-' -methoxycarbonyl-ethyl) -N- ._- -chloroacetyl- ., 6-dimethylanilihe:.---,
11. Process for the control of fungi according to Claim 9 comprising treatment with N- (1 ' -methoxycarbonyl-ether) -N-fluoro-acetyl-2 , 6-dimethylaniline.
12. Process for the control of fungi according to Claim 9 comprising treatment with N- (11 -methoxycarbonyl-ethyl) -N- - - 43377
13. Process for the control of fungi according to Claim 9 comprising treatment with N- (11 -methoxycarbonyl-ethyl) -N-iodo-acetyl-2 , 6-dimethylaniline .
14. Process according to one of Claims 9 to 13 for the control of phytopathogenic fungi.
15. Compounds of the formula wherein one of and R2 represents the methyl group and the other represents the methyl or ethyl group, and Y represents fluorine, -chlorine, ^bromine* or dodine.
16.16 The> compound -N÷ (1 ' r-methoxycarbonyl-e-t-hyi;) -N-chlorbacetyl- 2, 6-dimethylaniline of the formula
17.1,· Thev compound ÷ CI 1 fmethoxycaxboriy.l-rethyl) -N-fluoroacetyl- l- 2,6-dime.thylai"iline of the formula, i.a
18. The compound N- (1 ' -methoxycarbonyl-ethyl) -N-bromoacetyl-2 , 6-dimethylaniiine of the formula
19. The compound N- (1 'methoxycarbonyl-ethyl) -N-iodoacetyl-2 , 6-dimethylaniline of the formula HE:mr : n--
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1504472A CH585179A5 (en) | 1972-10-13 | 1972-10-13 | Antifungal alpha-halo-acetanilides - prepd from alpha-anilino propionic acid ester |
CH1237273A CH591205A5 (en) | 1973-08-29 | 1973-08-29 | Antifungal alpha-halo-acetanilides - prepd from alpha-anilino propionic acid ester |
Publications (2)
Publication Number | Publication Date |
---|---|
IL43377A0 IL43377A0 (en) | 1974-01-14 |
IL43377A true IL43377A (en) | 1976-11-30 |
Family
ID=25710135
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IL43377A IL43377A (en) | 1972-10-13 | 1973-10-04 | N-(1'-alkoxycarbonyl-ethyl)-n-haloacetyl-2,6-dialkylanilines their preparation and their use for the control of phytopathogenic fungi |
Country Status (17)
Country | Link |
---|---|
JP (1) | JPS5726241B2 (en) |
CS (1) | CS171293B2 (en) |
DD (1) | DD109498A5 (en) |
DE (1) | DE2350944C2 (en) |
DK (1) | DK139675B (en) |
EG (1) | EG11528A (en) |
ES (1) | ES419560A1 (en) |
FR (1) | FR2202650B1 (en) |
GB (1) | GB1445387A (en) |
HU (1) | HU169982B (en) |
IE (1) | IE38351B1 (en) |
IL (1) | IL43377A (en) |
IT (1) | IT998743B (en) |
NL (1) | NL180311C (en) |
PH (1) | PH11825A (en) |
SE (1) | SE397191B (en) |
YU (1) | YU267073A (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2265726B1 (en) * | 1974-04-01 | 1978-03-17 | Ciba Geigy Ag | |
OA04979A (en) * | 1974-04-09 | 1980-11-30 | Ciba Geigy | New aniline derivatives useful as microbicidal agents and their preparation process. |
SE429917B (en) * | 1974-04-09 | 1983-10-10 | Ciba Geigy Ag | USE OF CERTAIN N-ACYL ANILINETIC ACID ESTERS FOR COMBATING PHYTHOPATHOGENIC Fungi |
CH623458A5 (en) * | 1975-09-30 | 1981-06-15 | Ciba Geigy Ag | |
US4098895A (en) * | 1975-09-30 | 1978-07-04 | Ciba-Geigy Corporation | Triazolylacetanilide compounds and microbicidal compositions |
CH618320A5 (en) * | 1975-09-30 | 1980-07-31 | Ciba Geigy Ag | |
DE2648074A1 (en) * | 1976-10-23 | 1978-04-27 | Bayer Ag | N-CHLORACETYL-N-PHENYL-ALANINE ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES |
US4243819A (en) * | 1978-02-16 | 1981-01-06 | Zoecon Corporation | Substituted amino acids |
CH627343A5 (en) * | 1977-03-28 | 1982-01-15 | Ciba Geigy Ag | Microbicide |
DE2845454A1 (en) * | 1977-11-01 | 1979-05-10 | Chevron Res | 3- (N-ACYL-N-ARYLAMINO) - GAMMA -BUTYROLACTONE AND - GAMMA -BUTYROTHIOLACTONE AND FUNGICIDE AGENTS |
DE2802211A1 (en) * | 1978-01-19 | 1979-07-26 | Basf Ag | N-SUBSTITUTED 2,6-DIALKYLANILINES AND METHOD FOR PREPARING N-SUBSTITUTED 2,6-DIALKYLANILINES |
BG28977A3 (en) * | 1978-02-02 | 1980-08-15 | Montedison Spa | Fungicide means and method for fungus fighting |
DE2916692A1 (en) * | 1979-04-25 | 1980-11-06 | Bayer Ag | N-ALLENYL ACETANILIDES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES |
MA19215A1 (en) * | 1980-07-25 | 1982-04-01 | Ciba Geigy Ag | NOVEL ARYLAMINE DERIVATIVES, PROCESS FOR THEIR MANUFACTURE AND USE AS MICROBICIDES. |
GB8504181D0 (en) * | 1985-02-19 | 1985-03-20 | Sandoz Ltd | Fungicides |
CN101088986B (en) * | 2007-06-09 | 2010-06-23 | 大庆石油管理局 | Metalaxyl synthesizing process |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2212268C3 (en) * | 1971-03-15 | 1979-09-13 | Sumitomo Chemical Co., Ltd., Osaka (Japan) | N-haloacetylanilinoacetic acid esters, processes for their preparation and herbicidal compositions containing them |
-
1973
- 1973-09-28 SE SE7313236A patent/SE397191B/en unknown
- 1973-10-04 IL IL43377A patent/IL43377A/en unknown
- 1973-10-05 NL NLAANVRAGE7313750,A patent/NL180311C/en not_active IP Right Cessation
- 1973-10-05 IE IE1780/73A patent/IE38351B1/en unknown
- 1973-10-10 DE DE2350944A patent/DE2350944C2/en not_active Expired
- 1973-10-10 PH PH15104A patent/PH11825A/en unknown
- 1973-10-11 CS CS6998A patent/CS171293B2/cs unknown
- 1973-10-11 EG EG394A patent/EG11528A/en active
- 1973-10-11 YU YU02670/73A patent/YU267073A/en unknown
- 1973-10-11 ES ES419560A patent/ES419560A1/en not_active Expired
- 1973-10-12 FR FR7336554A patent/FR2202650B1/fr not_active Expired
- 1973-10-12 DD DD174022A patent/DD109498A5/xx unknown
- 1973-10-12 JP JP11460373A patent/JPS5726241B2/ja not_active Expired
- 1973-10-12 HU HUCI1417A patent/HU169982B/hu not_active IP Right Cessation
- 1973-10-12 GB GB4785773A patent/GB1445387A/en not_active Expired
- 1973-10-12 DK DK555273AA patent/DK139675B/en unknown
- 1973-10-12 IT IT30084/73A patent/IT998743B/en active
Also Published As
Publication number | Publication date |
---|---|
DE2350944A1 (en) | 1974-04-25 |
IL43377A0 (en) | 1974-01-14 |
EG11528A (en) | 1977-11-30 |
ES419560A1 (en) | 1976-07-01 |
DK139675C (en) | 1979-10-15 |
JPS4971138A (en) | 1974-07-10 |
GB1445387A (en) | 1976-08-11 |
DD109498A5 (en) | 1974-11-12 |
IT998743B (en) | 1976-02-20 |
HU169982B (en) | 1977-03-28 |
YU267073A (en) | 1981-11-13 |
DE2350944C2 (en) | 1982-12-23 |
FR2202650B1 (en) | 1976-06-18 |
CS171293B2 (en) | 1976-10-29 |
DK139675B (en) | 1979-03-26 |
JPS5726241B2 (en) | 1982-06-03 |
AU6137573A (en) | 1975-04-17 |
IE38351L (en) | 1974-04-13 |
FR2202650A1 (en) | 1974-05-10 |
PH11825A (en) | 1978-07-19 |
NL180311C (en) | 1987-02-02 |
SE397191B (en) | 1977-10-24 |
NL7313750A (en) | 1974-04-16 |
IE38351B1 (en) | 1978-02-15 |
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