IL40888A - Piperidine derivatives their preparation and their use as stabilisers for polymeric materials - Google Patents
Piperidine derivatives their preparation and their use as stabilisers for polymeric materialsInfo
- Publication number
- IL40888A IL40888A IL40888A IL4088872A IL40888A IL 40888 A IL40888 A IL 40888A IL 40888 A IL40888 A IL 40888A IL 4088872 A IL4088872 A IL 4088872A IL 40888 A IL40888 A IL 40888A
- Authority
- IL
- Israel
- Prior art keywords
- carbon atoms
- residue
- alkyl
- group
- formula
- Prior art date
Links
- 239000003381 stabilizer Substances 0.000 title claims 5
- 239000000463 material Substances 0.000 title claims 2
- 150000003053 piperidines Chemical class 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 36
- 125000000217 alkyl group Chemical group 0.000 claims 16
- 125000003118 aryl group Chemical group 0.000 claims 9
- 239000000203 mixture Substances 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 5
- 125000002723 alicyclic group Chemical group 0.000 claims 4
- 125000002947 alkylene group Chemical group 0.000 claims 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 4
- 150000003839 salts Chemical class 0.000 claims 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 3
- 125000003342 alkenyl group Chemical group 0.000 claims 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 3
- 229910052698 phosphorus Inorganic materials 0.000 claims 3
- 239000011574 phosphorus Substances 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 2
- 125000002252 acyl group Chemical group 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims 2
- 239000004327 boric acid Substances 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 239000011368 organic material Substances 0.000 claims 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000006096 absorbing agent Substances 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 239000002216 antistatic agent Substances 0.000 claims 1
- 239000010425 asbestos Substances 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000006229 carbon black Substances 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 239000003995 emulsifying agent Substances 0.000 claims 1
- -1 flame-protectants Substances 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 239000003365 glass fiber Substances 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- 239000000314 lubricant Substances 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- 229910052895 riebeckite Inorganic materials 0.000 claims 1
- 125000000547 substituted alkyl group Chemical group 0.000 claims 1
- 125000003107 substituted aryl group Chemical group 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- PJANXHGTPQOBST-VAWYXSNFSA-N trans-stilbene Chemical group C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/40—Oxygen atoms
- C07D211/44—Oxygen atoms attached in position 4
- C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/04—Esters of boric acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Hydrogenated Pyridines (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Claims (4)
1. &0888-2 CLAIMS: 1. A or a salt thereof, wherein n is 1, 2 or 3, is an alkyl residue having from 1 to 12 carbon atoms or a substituted alkyl residue having the formula -CH2-CH2-X1 or -CH2-X2 wherein Xl is -CN, -OH, -0CH3, -0-C-R3 or -0-C-NH-R4, 0 & is phenyl, or -jj-OR R^ is alkyl having from 1 to 20 carbon atoms, alkenyl having from 2 to 4 carbon atoms or aryl having 6 or 7 carbon atoms, R^ is alkyl having from 1 to 12 carbon atoms, R^ is alkyl having from 1 to 20 carbon atoms, or is a group -C0-Y or -CO- H-Z, wherein Y is alkyl having 1 to 4 carbon atoms, alkenyl having 2 or 3 carbon atoms, and Z is alkyl having 1 to 12 carbon atoms, aryl or substituted aryl having 6 to 10 carbon atoms, and when n is 1, R is a monovalent residue and is -CH -CH9 -C nzyl or an acyl group where Rf- is benzyl, vinyl, propenyl, cyclohexyl, a group - -ST- 40888/3 ■■Ύ or Rg is R^' and R^ 1 is alkyl having from 1 to 20 carbon atoms or an aromatic group having from 6 to 10 carbon atoms or an aromatic group substitut with alkyl having from 1 to 4 carbon atoms, or R is a carbamoyl residue -C-NH-R-, wherein I II 7 0 is a monovalent residue and is an alkyl residue having from 1 to 20 carbon atoms, an alkenyl residue having 3 or 4 carbon atoms, an alicyclic residue having from 5 to 12 carbon atoms or an aromatic residue having from 6 to 12 carbon atoms, or R2 is a monovalent residue obtained by removing one hydroxyl group from a phosphorus containing acid, when n is 2, R2 is a divalent residue and is one of the groups -C-C-, -C-Ro-C- or -C-NH-Rn- H-C- , wherein II II II 8 II II 9 II 0 0 0 0 0 0 R0 is an alkylene residue having up to 18 carbon o atoms, a phenylene residue or the group -(CH2)2S(CH2)2-, R^ is an alkylene residue having up to 20 carbon atoms, a divalent alicyclic residue having from 5 to 15 carbon atoms or a divalent aromatic residue having from 6 to 15 carbon atoms, or R2 is a divalent residue obtained by removing two hydroxyl groups from a phosphorus containing acid or when n is 3, R9 is a trivalent residue * derived . from phosphoric, phosphorus or boric acid, provided that when R2 represents -CORg, -CO-CO- , -CO-Rg-CO- or a trivalent group derived from phosphoric, phosphorous or boric acid, the number of carbon atoms of alkyl group designated by R^ is limited to 5 to 12, and provided that only one of R^ and R2 can represent an unsaturated acyl group.
2. A compound as claimed in claim 1 having the formula or a salt thereof, wherein n is 1 or 2 and R^ is an alkyl residue having from 1 to 12 carbon atoms, allyl or benzyl and when, n is 1, is cyclohexyl, vinyl, propenyl, benzyl, or is and is alkyl having from 1 to 20 carbon atoms or an aromatic group having from 6 to 10 carbon atoms and when n is 2, R1Q is -CH2-CH2-S-CH2-CH2- or R1() is R^ and is an alkylene group having .1 to 18 carbon atoms or a phenylene group, provided that when , the number of carbon atoms of alkyl groups designated by R^ is limited to 5 to 12.
3. A compound as claimed in claim 1 having the formula or a salt thereof, where n is 1 or 2 and is an alkyl residue having from 1 to 12 carbon atoms, a benzyl residue or an allyl residue, and when n is 1, is a monovalent residue and is an aliphatic residue having from 1 to 20 carbon atoms, an alicyclic residue having from 5 to 12 carbon atoms or an aromatic residue having from 6 to 12 carbon atoms or when n is 2, is a divalent residue and is an alkylene residue having up to 20 carbon atoms, an alicyclic residue having 5 to 15 carbon atoms or an aromtic residue having from 6 to 15 carbon atoms.
4. A compound as claimed in claim 1 having the formula or a salt thereof, wherein n is 1 or 2 arid is an alkyl residue having from 1 to 12 carbon atoms or an allyl residue, and when n is 1, R^ is an alkyl residue having from 1 to 8 carbon atoms, the cyclohexyl residue or an aryl residue having from 6 to 10 carbon atoms or I when n is 2, R, , is a hexamethylene, toluylene or diphenyl- - #T - 40888-2 10. A composition as Claimed in claim 7 wherein the poly-meric material is a condensation polymer containing amide or urethane groupings. 11. A composition as claimed in claim 7 wherein the amount of the compound of formula I is within the range of from 0.01% to 5% by weight based on the weight of untreated organic material, 12. A composition as claimed in claim 11 wherein the amount of the compound of formula I is within the range of from 0,1% to 2% by weight based on the weight of untreated organic material. 13. A composition as claimed in claim 7 wherein one or more further additives useful in polymer formulations are present . 14. A composition as claimed in claim 13 wherein the further additives are antioxidants of the phenol or amine type, U.V. absorbers and light protectants, phosphite stabilisers, peroxide decomposers, polyamide stabilisers, basic co-stabilisers, polyvinyl chloride stabilisers, lubricants, emulsifiers, anti-static agents, flame-protectants , pigments carbon black,, asbestos, glass fibres, kaolin or talc.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5548771 | 1971-11-30 | ||
| GB2845872*[A GB1399239A (en) | 1971-11-30 | 1972-06-17 | Piperidine derivatives |
| GB3547372 | 1972-07-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL40888A0 IL40888A0 (en) | 1973-01-30 |
| IL40888A true IL40888A (en) | 1976-10-31 |
Family
ID=27258723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL40888A IL40888A (en) | 1971-11-30 | 1972-11-21 | Piperidine derivatives their preparation and their use as stabilisers for polymeric materials |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | USRE31343E (en) |
| JP (1) | JPS5920709B2 (en) |
| AT (1) | AT324009B (en) |
| BE (1) | BE792043A (en) |
| CA (1) | CA997767A (en) |
| CH (2) | CH585714A5 (en) |
| CS (1) | CS190377B2 (en) |
| DD (1) | DD106190A5 (en) |
| DE (2) | DE2258752C2 (en) |
| ES (1) | ES409079A1 (en) |
| FR (3) | FR2182789B1 (en) |
| GB (1) | GB1399239A (en) |
| HK (1) | HK47877A (en) |
| HU (1) | HU167244B (en) |
| IL (1) | IL40888A (en) |
| IT (1) | IT971346B (en) |
| MY (1) | MY7800025A (en) |
| NL (1) | NL174942C (en) |
| RO (2) | RO64573A (en) |
| SE (1) | SE454277B (en) |
| SU (1) | SU584795A3 (en) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1402888A (en) * | 1972-10-21 | 1975-08-13 | Ciba Geigy Ag | Piperidine derivatives |
| CH589056A5 (en) * | 1973-12-10 | 1977-06-30 | Ciba Geigy Ag | |
| JPS51132242A (en) * | 1975-03-22 | 1976-11-17 | Adeka Argus Chem Co Ltd | Light stabilising composition for synthetic resin |
| DE2627688A1 (en) * | 1975-06-30 | 1977-01-27 | Ciba Geigy Ag | DISABLED PIPERIDINE CARBONIC ACIDS, METAL SALTS THEREOF AND THEREFORE STABILIZED POLYMERS |
| DE2718458A1 (en) * | 1976-05-04 | 1977-11-24 | Ciba Geigy Ag | NEW STABILIZERS |
| DE2805838A1 (en) * | 1977-02-24 | 1978-08-31 | Ciba Geigy Ag | NEW 4-ACYLOXYPIPERIDINE |
| JPS5469162A (en) * | 1977-11-15 | 1979-06-02 | Dainichi Seika Kogyo Kk | Stabilized urethane polymer |
| DE2861955D1 (en) * | 1977-12-02 | 1982-09-02 | Ciba Geigy Ag | Malonic acid derivatives of sterically hindered piperidines, process for their preparation and stabilised organic matter |
| JPS559064A (en) * | 1978-07-03 | 1980-01-22 | Sankyo Co Ltd | Novel stabilizer |
| EP0007736B1 (en) * | 1978-07-25 | 1983-10-12 | Imperial Chemical Industries Plc | Polyolefin articles sterilisable by gamma-irradiation |
| US4311820A (en) * | 1979-02-14 | 1982-01-19 | Ciba-Geigy Corporation | Homopolymers and copolymers of vinyl ethers of polyalkylpiperidinols and their use as stabilizers for plastics |
| IT7928324A0 (en) * | 1979-12-21 | 1979-12-21 | Chimosa Chimica Organica Spa | PIPERIDINE DERIVATIVES, STABILIZERS FOR SYNTHETIC POLYMERS. |
| DE3201415A1 (en) * | 1981-01-28 | 1982-08-26 | Sandoz-Patent-GmbH, 7850 Lörrach | 4-Aminomethylpolyalkylpiperidines |
| CS229069B1 (en) * | 1981-09-23 | 1984-05-14 | Julius Durmis | Composition for stabilizing polymers and method of preparing same |
| JPS58113236A (en) * | 1981-12-28 | 1983-07-06 | Tounen Sekiyu Kagaku Kk | Polyolefin composition |
| US4590268A (en) * | 1982-05-10 | 1986-05-20 | Ciba-Geigy Corporation | Process for the preparation of 1-diorganocarbamoyl-polyalkylpiperidines |
| US4569997A (en) * | 1982-08-10 | 1986-02-11 | Ciba Geigy Corporation | Polyalkylpiperidine compounds |
| DE3312611A1 (en) * | 1983-04-08 | 1984-10-11 | Röhm GmbH, 6100 Darmstadt | METHOD FOR PRODUCING UV-PROTECTED MULTILAYERED PLASTIC MOLDED BODIES |
| DE3345376A1 (en) * | 1983-12-15 | 1985-06-27 | Basf Ag, 6700 Ludwigshafen | FURAN-3-CARBONSAEUR DERIVATIVES |
| DE3522678A1 (en) * | 1985-06-25 | 1987-01-08 | Basf Ag | TETRAHYDROFURANCARBONSAEUR DERIVATIVES |
| JPS6248745A (en) * | 1985-08-28 | 1987-03-03 | Mitsubishi Petrochem Co Ltd | Polyolefin composition |
| IT1189095B (en) * | 1986-05-02 | 1988-01-28 | Enichem Sintesi | PROCEDURE FOR THE SYNTHESIS OF ALLILATED DERIVATIVES OF 2,2,6,6-TETRALKYLPIPERIDINOLS |
| IT1191804B (en) * | 1986-06-11 | 1988-03-23 | Enichem Sintesi | PROCEDURE FOR THE PREPARATION OF N-ALYL-PIPERIDINE DERIVATIVES |
| DE3724222A1 (en) * | 1987-07-22 | 1989-02-02 | Huels Chemische Werke Ag | LIGHT STABILIZERS |
| IT1222647B (en) * | 1987-09-11 | 1990-09-05 | Eniricerche Spa | AMERICAN COMPOUNDS STERICALLY PREVENTED AND PROCEDURE FOR THEIR PREPARATION |
| DE3735577A1 (en) | 1987-10-21 | 1989-05-03 | Basf Ag | MIXTURE FOR STABILIZING POLYURETHANES |
| EP0344114B1 (en) * | 1988-05-27 | 1994-04-06 | Ciba-Geigy Ag | Unsaturated derivatives of 2,2,6,6-tetramethyl piperidine |
| ES2050274T3 (en) * | 1988-06-14 | 1994-05-16 | Ciba Geigy Ag | PROCEDURE FOR THE PHOTOCHEMICAL STABILIZATION OF UNDYED AND DYED POLYPROPYLENE FIBERS. |
| US4927898A (en) * | 1988-09-06 | 1990-05-22 | Union Carbide Chemicals And Plastics Company Inc. | Polysiloxanes with sterically hindered heterocyclic moiety |
| DE3844356A1 (en) * | 1988-12-30 | 1990-07-05 | Basf Ag | 4- (2'-ETHYLHEXANOYLOXY) -2,2,6,6-TETRAMETHYL PIPERIDINE |
| GB9023023D0 (en) * | 1990-10-23 | 1990-12-05 | Barlow Richard B | Pharmaceutical compositions |
| US5180830A (en) * | 1991-04-24 | 1993-01-19 | Himont Incorporated | Process for preparing hindered amine light stabilizers |
| NL9101619A (en) * | 1991-09-25 | 1993-04-16 | Harcros Chemicals Bv | STABILIZERS FOR ORGANIC MATERIALS. |
| US5169949A (en) * | 1991-09-30 | 1992-12-08 | Himont Incorporated | Monomeric hindered amine esters of monocarboxylic resin acid having 20 carbon atoms |
| WO1997013752A1 (en) * | 1995-10-12 | 1997-04-17 | Ciba Specialty Chemicals Holding Inc. | Thermally stable hindered amines as stabilizers |
| EP1184442A1 (en) * | 2000-08-30 | 2002-03-06 | Clariant International Ltd. | Liquid crystal mixture |
| US6414155B1 (en) | 2000-11-03 | 2002-07-02 | Cytec Technology Corp. | Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6727300B2 (en) | 2000-11-03 | 2004-04-27 | Cytec Technology Corp. | Polymeric articles containing hindered amine light stabilizers based on multi-functional carbonyl compounds |
| US6545156B1 (en) * | 2000-11-03 | 2003-04-08 | Cytec Technology Corp. | Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6492521B2 (en) | 2000-11-03 | 2002-12-10 | Cytec Technology Corp. | Hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6525131B1 (en) | 2001-09-18 | 2003-02-25 | Crompton Corporation | Aromatic diamine polyurethane curatives with improved stability |
| EP1444222A1 (en) * | 2001-10-23 | 2004-08-11 | Council Of Scientific And Industrial Research | Tinuvin p-hindred amine light stabilizer and derivatives thereof, and a process for the preparation thereof |
| US6492518B1 (en) | 2001-10-30 | 2002-12-10 | Council Of Scientific And Industrial Research | Tinuvin P-hindred amine light stabilizer and derivatives thereof |
| JP5283153B2 (en) | 2007-10-25 | 2013-09-04 | 株式会社Ａｄｅｋａ | Synthetic resin composition and automotive interior / exterior material |
| KR101602750B1 (en) | 2008-03-10 | 2016-03-11 | 가부시키가이샤 아데카 | Synthetic resin composition, and automotive interior/exterior material comprising the same |
| JP5656213B2 (en) * | 2010-01-19 | 2015-01-21 | 日本化薬株式会社 | Carboxylic acid composition and curable resin composition containing the carboxylic acid composition |
| CN105358528B (en) * | 2013-07-08 | 2021-07-20 | 巴斯夫欧洲公司 | Novel light stabilizers |
| DE102013012622A1 (en) * | 2013-07-30 | 2015-02-05 | Clariant lnternational Ltd | New sterically hindered cyclic amines |
| CN106459489B (en) * | 2014-05-21 | 2019-07-12 | 索尔维特殊聚合物美国有限责任公司 | Stabilizer compounds |
| DE102015000124A1 (en) * | 2015-01-07 | 2016-07-07 | Clariant International Ltd. | Process for the stabilization of polyamides |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2746964A (en) * | 1953-11-02 | 1956-05-22 | Lakeside Lab Inc | Dicarboxylic acid esters of nu-alkyl-3-hydroxypiperidine and salts thereof |
| US3120540A (en) * | 1961-09-25 | 1964-02-04 | Warner Lambert Pharmaccutical | Bis (polymethyl)-4-piperidinol alkanoates |
| US3640928A (en) * | 1968-06-12 | 1972-02-08 | Sankyo Co | Stabilization of synthetic polymers |
| US3705166A (en) * | 1969-08-15 | 1972-12-05 | Sankyo Co | Acrylic acid derivatives of 2,2,6,6-tetramethylpiperidines |
| NL154241C (en) * | 1971-01-29 | 1900-01-01 | ||
| US4021432A (en) * | 1971-11-30 | 1977-05-03 | Ciba-Geigy Corporation | Piperidine derivatives |
| US4049647A (en) * | 1971-11-30 | 1977-09-20 | Ciba-Geigy Corporation | Bis piperidyl carboxylates |
-
0
- BE BE792043D patent/BE792043A/en not_active IP Right Cessation
-
1972
- 1972-06-17 GB GB2845872*[A patent/GB1399239A/en not_active Expired
- 1972-11-21 IL IL40888A patent/IL40888A/en unknown
- 1972-11-21 SE SE7215112A patent/SE454277B/en unknown
- 1972-11-28 CH CH263676A patent/CH585714A5/xx not_active IP Right Cessation
- 1972-11-28 CH CH1729872A patent/CH586252A5/xx not_active IP Right Cessation
- 1972-11-29 RO RO7283993A patent/RO64573A/en unknown
- 1972-11-29 HU HUCI1307A patent/HU167244B/hu unknown
- 1972-11-29 CS CS728130A patent/CS190377B2/en unknown
- 1972-11-29 CA CA157,753A patent/CA997767A/en not_active Expired
- 1972-11-29 ES ES409079A patent/ES409079A1/en not_active Expired
- 1972-11-29 FR FR7242421A patent/FR2182789B1/fr not_active Expired
- 1972-11-29 RO RO7283383A patent/RO71050A/en unknown
- 1972-11-29 SU SU7201851503A patent/SU584795A3/en active
- 1972-11-29 IT IT32252/72A patent/IT971346B/en active
- 1972-11-30 NL NLAANVRAGE7216278,A patent/NL174942C/en not_active IP Right Cessation
- 1972-11-30 DE DE2258752A patent/DE2258752C2/de not_active Expired
- 1972-11-30 DD DD167212A patent/DD106190A5/xx unknown
- 1972-11-30 AT AT1019972A patent/AT324009B/en not_active IP Right Cessation
- 1972-11-30 JP JP47121099A patent/JPS5920709B2/en not_active Expired
- 1972-11-30 DE DE19722258752D patent/DE2258752A1/en active Granted
-
1973
- 1973-05-16 FR FR7318099A patent/FR2183293B1/fr not_active Expired
- 1973-05-16 FR FR7318100A patent/FR2183294B1/fr not_active Expired
-
1977
- 1977-09-15 HK HK478/77A patent/HK47877A/en unknown
-
1978
- 1978-09-01 US US05/938,849 patent/USRE31343E/en not_active Expired - Lifetime
- 1978-09-01 US US05/938,974 patent/USRE31342E/en not_active Expired - Lifetime
- 1978-12-31 MY MY197825A patent/MY7800025A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH585714A5 (en) | 1977-03-15 |
| JPS4865180A (en) | 1973-09-08 |
| MY7800025A (en) | 1978-12-31 |
| CS190377B2 (en) | 1979-05-31 |
| NL174942B (en) | 1984-04-02 |
| NL174942C (en) | 1984-09-03 |
| DE2258752C2 (en) | 1989-10-26 |
| DE2258752A1 (en) | 1973-06-07 |
| RO64573A (en) | 1979-08-15 |
| USRE31343E (en) | 1983-08-09 |
| FR2183294B1 (en) | 1978-05-26 |
| SE454277B (en) | 1988-04-18 |
| USRE31342E (en) | 1983-08-09 |
| FR2183293A1 (en) | 1973-12-14 |
| IL40888A0 (en) | 1973-01-30 |
| IT971346B (en) | 1974-04-30 |
| FR2182789B1 (en) | 1976-01-30 |
| FR2182789A1 (en) | 1973-12-14 |
| NL7216278A (en) | 1973-06-04 |
| CA997767A (en) | 1976-09-28 |
| HU167244B (en) | 1975-09-27 |
| RO71050A (en) | 1981-09-24 |
| GB1399239A (en) | 1975-06-25 |
| BE792043A (en) | 1973-05-29 |
| JPS5920709B2 (en) | 1984-05-15 |
| AT324009B (en) | 1975-08-11 |
| FR2183293B1 (en) | 1977-07-29 |
| FR2183294A1 (en) | 1973-12-14 |
| ES409079A1 (en) | 1976-04-16 |
| DD106190A5 (en) | 1974-06-05 |
| CH586252A5 (en) | 1977-03-31 |
| HK47877A (en) | 1977-09-23 |
| SU584795A3 (en) | 1977-12-15 |
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