IL39865A - Process for forming a metal oxide coating on a substrate - Google Patents
Process for forming a metal oxide coating on a substrateInfo
- Publication number
- IL39865A IL39865A IL39865A IL3986572A IL39865A IL 39865 A IL39865 A IL 39865A IL 39865 A IL39865 A IL 39865A IL 3986572 A IL3986572 A IL 3986572A IL 39865 A IL39865 A IL 39865A
- Authority
- IL
- Israel
- Prior art keywords
- process according
- substrate
- solution
- solvent
- metal
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 22
- 239000000758 substrate Substances 0.000 title claims abstract 16
- 238000000576 coating method Methods 0.000 title claims abstract 11
- 239000011248 coating agent Substances 0.000 title claims abstract 10
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract 10
- 150000004706 metal oxides Chemical class 0.000 title claims abstract 10
- 239000002904 solvent Substances 0.000 claims abstract 15
- 229910052751 metal Inorganic materials 0.000 claims abstract 8
- 239000002184 metal Substances 0.000 claims abstract 8
- 239000000203 mixture Substances 0.000 claims abstract 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract 6
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims abstract 4
- 125000005595 acetylacetonate group Chemical group 0.000 claims abstract 4
- 150000004985 diamines Chemical class 0.000 claims abstract 4
- 239000011521 glass Substances 0.000 claims abstract 3
- 238000010438 heat treatment Methods 0.000 claims abstract 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims abstract 3
- 229910052776 Thorium Inorganic materials 0.000 claims abstract 2
- 150000001412 amines Chemical class 0.000 claims abstract 2
- 229910052804 chromium Inorganic materials 0.000 claims abstract 2
- 229910052802 copper Inorganic materials 0.000 claims abstract 2
- 238000011065 in-situ storage Methods 0.000 claims abstract 2
- 229910052738 indium Inorganic materials 0.000 claims abstract 2
- 229910052748 manganese Inorganic materials 0.000 claims abstract 2
- 229910052720 vanadium Inorganic materials 0.000 claims abstract 2
- 229910052725 zinc Inorganic materials 0.000 claims abstract 2
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- -1 alkylene amine Chemical class 0.000 claims 2
- 125000003277 amino group Chemical group 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 150000002736 metal compounds Chemical class 0.000 claims 2
- 150000002739 metals Chemical class 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 1
- SDIXRDNYIMOKSG-UHFFFAOYSA-L disodium methyl arsenate Chemical compound [Na+].[Na+].C[As]([O-])([O-])=O SDIXRDNYIMOKSG-UHFFFAOYSA-L 0.000 claims 1
- 239000012153 distilled water Substances 0.000 claims 1
- 239000005357 flat glass Substances 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 abstract 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 abstract 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 abstract 2
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 238000000137 annealing Methods 0.000 abstract 1
- 239000000010 aprotic solvent Substances 0.000 abstract 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 abstract 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052727 yttrium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/229—Non-specific enumeration
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemically Coating (AREA)
Abstract
1397741 Metal oxide coatings GLAVERBEL 22 June 1972 [8 July 1971] 29382/72 Headings C1A and C1N [Also in Division C2] A metal oxide coating is formed on a substrate by applying to the substrate a solution containing a metal acetyl acetonate of a mixture of metal acetyl acetonates in an aprotic solvent of dielectric constant greater than 15 and of dipolar moment greater than 3 Debye units, a substituted or unsubstituted monocarboxylic acid solvent, an amine or diamine solvent, or a mixture of two or more solvents selected from solvents of those classes, the oxide being formed in situ by heating. A large number of metal oxides are exemplified. The heat required may be supplied by pre-heating the substrate and the solution may be applied in droplet form. The coating may be formed on glass such as glass sheet during its manufacture or in the annealing lehr, or, generally, on substrates which are at least partly vitreous. Specified oxides are those of Fe, Ni, Co, Zn, V, Mn, Cu, In, Al, Ti, Zr, Th, Cr, Mg, Bi, Y, W and Ce and their mixtures. Specified solvents are dimethylformamide, dimethylacetamide, tetramethylurea, dimethylsulphoxide, acetonitrile, nitrobenzene, ethylene carbonate, tetramethylenesulphone, hexamethylphosphoramide, acetic acid, butyric acid, acrylic acid, thioglycolic acid, formic acid, ethylenediamine, propylenediamine, butylamine, and propylamine. The process of Specification 1,397,742 is disclaimed.
[GB1397741A]
Claims (4)
1. ,39865/2 WHAT IS CLAIMED IS: 1. A process for forming a metal oxide coating on a substrate wherein a solution of at least one metal compound in an organic solvent is applied to the substrate and said compound is converted in situ by heating to leave a coating of at least one metal oxide, characterised in that the solution used for coating the substrate is a solution of a metal acetyl acetonate or a mixture of metal acetyl acetonates in an aprotonic solvent having a dielectric constant greater than 15 and a dipolar moment greater than 3 D, a substituted or unsubstituted monocarboxylic acid solvent, en amine or diamine solvent, or a mixture of two or more solvents selected from solvents of those classes.
2. A process according to Claim 1, characterised in that the substrate is pre-heated to a sufficiently high temperature to provide the heat required to effect said conversion of the metal compound or compounds .
3. A process according to Claim 2, characterised in that the substrate is pre-heated to bring the temperature of the surface to be coated to a value within the range 300° to 700°C.
4. A process according to any preceding Claim, characterised in that the solution is applied in droplet form. 6» A process according to Claim characterised in that dimet ylforraanide is used as a solvent, A process according to Claim characterised in that an aprotonic solvent specifically identified herein as such, other than dimethylformamide , is used. 7. a. A process according to any preceding Claim, characterised in that a substituted or unsubstituted mono-carboxylic acid solvent specifically identified herein as such, is used. 8. 9·· A process according to any preceding Claim, characterised in that the solvent used comprises an alkyl or alkylene amine or diamine in which the amino group or groups is ■ or are unsubstituted. 9. Q I/O.. A process according to Claim y , characterised in that an alkyl or alkylene amine or diamine solvent specifically identified herein as euch, is used. 10. -LL. A process according to any preceding Claim, characterised in that the solution applied to the substrate comprises a solution of an acetyl acetonate of a metal selected from the group: Fe , Ni , Co, Zn, V, Mn, Cu, In, Al , Ti , Zr , Th, Cr , or a mixture of acetyl acetonates of two or more metals of such group. 11. q !Π . A process according to any of Claims 1 to £0, characterised in that the solution applied to the substra comprises a solution of an acetyl acetonate of a metal selected from the group: g, Bi , Y, ¥ and Ce , or a mixture of acetyl acetonates of two or more metals of such group. 3¾. 12. A process according to any preceding Claim, characterised in that said solution is applied to a substrate which is at least partly vitreous. f 1*5r..' A process according to Claim 12 characterised in that said solution is applied so as to form a light-transmitting metal oxide coating. A process according to Claim _έ, characterised in that the formed metal oxide coating has a thickness in the range to X. A process according to any preceding Claim, characterised in that said substrate is flat glass which is in course of being manufactured as a continuous ribbon. 16. 15 ±7. A process according to Claim lo , characterised in that said solution is applied to the glass ribbon at a zone where its temperature is in the range to °C. A process according to any preceding Claim, characterised in that the solution applied to the substrate contains no water or contains distilled water in a proportion of not more than 10% by volume. A process according to Claim and substantially according to any of the Examples herein. A vitreous or partly vitreous substrate bearing a metal oxide coating formed by a process according to any preceding Claim. jr.* A non-vitreous substrate bearing a metal oxide coating formed by a process according to any of Claims to ii. t COHEN - ZEDEK &4 SPISBACH P. 0. B ox 331 16 , Te l - A v i v A tto rn e y s f o r A p p l i c a n t
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU63490 | 1971-07-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL39865A0 IL39865A0 (en) | 1972-09-28 |
| IL39865A true IL39865A (en) | 1976-09-30 |
Family
ID=19726758
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL39865A IL39865A (en) | 1971-07-08 | 1972-07-07 | Process for forming a metal oxide coating on a substrate |
Country Status (21)
| Country | Link |
|---|---|
| JP (1) | JPS556586B1 (en) |
| AR (1) | AR197194A1 (en) |
| AT (1) | AT332988B (en) |
| BE (1) | BE785764A (en) |
| BR (1) | BR7204535D0 (en) |
| CA (1) | CA994183A (en) |
| CH (1) | CH555413A (en) |
| DD (1) | DD98895A5 (en) |
| DE (1) | DE2233594C2 (en) |
| DK (1) | DK149306C (en) |
| ES (1) | ES405066A1 (en) |
| FI (1) | FI53696C (en) |
| FR (1) | FR2158176B1 (en) |
| GB (1) | GB1397741A (en) |
| IL (1) | IL39865A (en) |
| IT (1) | IT964466B (en) |
| NL (1) | NL173386C (en) |
| NO (1) | NO129564B (en) |
| SE (1) | SE379529B (en) |
| SU (1) | SU608465A3 (en) |
| ZA (1) | ZA724630B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4204028A (en) * | 1978-03-16 | 1980-05-20 | Ppg Industries, Inc. | Conductive metal oxide film for solar energy control |
| GB2150044B (en) * | 1983-12-22 | 1986-12-17 | Glaverbel | Coated glazing material |
| DE3819413C1 (en) * | 1988-06-07 | 1989-02-09 | W.C. Heraeus Gmbh, 6450 Hanau, De | |
| GB2248243B (en) * | 1990-09-01 | 1994-06-22 | Glaverbel | Coated glass and method of manufacturing same |
| GB9019117D0 (en) * | 1990-09-01 | 1990-10-17 | Glaverbel | Coated glass and method of manufacturing same |
| DE69213782T2 (en) * | 1991-02-22 | 1997-02-06 | Honjo Chem Kk | Process for the production of transparent zinc oxide films |
| US5273776A (en) * | 1991-12-06 | 1993-12-28 | Mitsubishi Materials Corporation | Method for forming thermistor thin film |
| GB9304575D0 (en) * | 1993-03-05 | 1993-04-21 | Glaverbel | Coated glass and method of manufacturing same |
| SG81880A1 (en) * | 1993-12-28 | 2001-07-24 | Nippon Shaat Glass Co Ltd | Heat ray-reflecting glass |
| DE19609942C1 (en) * | 1996-03-14 | 1997-10-30 | Heraeus Gmbh W C | Luster color for the decoration of glass, ceramics and porcelain |
| FI20080264L (en) * | 2008-04-03 | 2009-10-04 | Beneq Oy | Coating method and device |
| US9574271B2 (en) | 2009-09-02 | 2017-02-21 | Toshiba Mitsubishi-Electric Industrial Systems Corporation | Method for forming metal oxide film, metal oxide film and apparatus for forming metal oxide film |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3081200A (en) * | 1959-04-10 | 1963-03-12 | Armour Res Found | Method of applying an oxide coating onto a non-porous refractory substrate |
| NL127148C (en) * | 1963-12-23 | |||
| GB1293061A (en) * | 1969-06-13 | 1972-10-18 | Nippon Sheet Glass Co Ltd | Process for the manufacture of heat reflecting glass sheets |
-
0
- BE BE785764D patent/BE785764A/xx not_active IP Right Cessation
-
1972
- 1972-06-22 GB GB2938272A patent/GB1397741A/en not_active Expired
- 1972-07-03 FR FR7224069A patent/FR2158176B1/fr not_active Expired
- 1972-07-04 DK DK332172A patent/DK149306C/en not_active IP Right Cessation
- 1972-07-04 FI FI1895/72A patent/FI53696C/en active
- 1972-07-04 NO NO02405/72*[A patent/NO129564B/no unknown
- 1972-07-04 SE SE7208789A patent/SE379529B/xx unknown
- 1972-07-05 AT AT576372A patent/AT332988B/en not_active IP Right Cessation
- 1972-07-05 ZA ZA724630A patent/ZA724630B/en unknown
- 1972-07-05 IT IT69151/72A patent/IT964466B/en active
- 1972-07-06 CH CH1012972A patent/CH555413A/en not_active IP Right Cessation
- 1972-07-06 NL NLAANVRAGE7209456,A patent/NL173386C/en not_active IP Right Cessation
- 1972-07-07 AR AR242976A patent/AR197194A1/en active
- 1972-07-07 SU SU721807916A patent/SU608465A3/en active
- 1972-07-07 IL IL39865A patent/IL39865A/en unknown
- 1972-07-07 JP JP6814272A patent/JPS556586B1/ja active Pending
- 1972-07-07 CA CA146,667A patent/CA994183A/en not_active Expired
- 1972-07-07 DE DE2233594A patent/DE2233594C2/en not_active Expired
- 1972-07-08 ES ES405066A patent/ES405066A1/en not_active Expired
- 1972-07-10 DD DD164310A patent/DD98895A5/xx unknown
- 1972-07-10 BR BR4535/72A patent/BR7204535D0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2158176B1 (en) | 1979-09-07 |
| ZA724630B (en) | 1973-04-25 |
| BE785764A (en) | 1973-01-03 |
| SE379529B (en) | 1975-10-13 |
| CH555413A (en) | 1974-10-31 |
| NL173386C (en) | 1984-01-16 |
| ES405066A1 (en) | 1975-07-16 |
| CA994183A (en) | 1976-08-03 |
| DD98895A5 (en) | 1973-07-12 |
| SU608465A3 (en) | 1978-05-25 |
| ATA576372A (en) | 1976-02-15 |
| IL39865A0 (en) | 1972-09-28 |
| NL7209456A (en) | 1973-01-10 |
| JPS556586B1 (en) | 1980-02-18 |
| AT332988B (en) | 1976-10-25 |
| BR7204535D0 (en) | 1973-05-31 |
| FI53696B (en) | 1978-03-31 |
| DK149306C (en) | 1986-09-01 |
| NO129564B (en) | 1974-04-29 |
| GB1397741A (en) | 1975-06-18 |
| DE2233594C2 (en) | 1982-10-07 |
| AR197194A1 (en) | 1974-03-22 |
| IT964466B (en) | 1974-01-21 |
| DE2233594A1 (en) | 1973-01-25 |
| FR2158176A1 (en) | 1973-06-15 |
| FI53696C (en) | 1978-07-10 |
| NL173386B (en) | 1983-08-16 |
| DK149306B (en) | 1986-04-28 |
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