IL38799A - Substituted s-alkyl n-(carbamoyloxyphenyl)thiocarbamates - Google Patents
Substituted s-alkyl n-(carbamoyloxyphenyl)thiocarbamatesInfo
- Publication number
- IL38799A IL38799A IL38799A IL3879972A IL38799A IL 38799 A IL38799 A IL 38799A IL 38799 A IL38799 A IL 38799A IL 3879972 A IL3879972 A IL 3879972A IL 38799 A IL38799 A IL 38799A
- Authority
- IL
- Israel
- Prior art keywords
- formula
- compound
- hydrogen atom
- substituted
- hydrocarbon group
- Prior art date
Links
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 7
- -1 chloroformic acid ester Chemical class 0.000 claims abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- 239000011230 binding agent Substances 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- CKDWPUIZGOQOOM-UHFFFAOYSA-N Carbamyl chloride Chemical compound NC(Cl)=O CKDWPUIZGOQOOM-UHFFFAOYSA-N 0.000 abstract 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 150000002828 nitro derivatives Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- BMBJSXKEXRFGAV-UHFFFAOYSA-N phenylcarbamothioic s-acid Chemical class SC(=O)NC1=CC=CC=C1 BMBJSXKEXRFGAV-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C333/02—Monothiocarbamic acids; Derivatives thereof
- C07C333/08—Monothiocarbamic acids; Derivatives thereof having nitrogen atoms of thiocarbamic groups bound to carbon atoms of six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1385802 Phenylthiocarbamates SCHERING AG 14 Feb 1972 [23 Feb 1971] 6705/72 Heading C2C The invention comprises compounds of the general formula wherein R 1 represents a C 1 to C 3 alkyl group, R 2 represents a hydrogen atom or a C 1 to C 6 alkyl group, and R 3 represents an unsubstituted aliphatic hydrocarbon group having at least two carbon atoms (with the proviso that when R 1 represents a methyl group and R 2 represents a hydrogen atom R 3 does not represent i-propyl or t-butyl), a substituted aliphatic hydrocarbon group or a substituted or unsubstituted cycloaliphatic hydrocarbon group and, when R 2 is a hydrogen atom, R 3 may represent a substituted or unsubstituted aromatic hydrocarbon group, or R 2 and R 3 together with the adjacent nitrogen atom represent a cyclic group that may contain a further hetero atom. They may be prepared by (i) reacting a compound of the formula or a salt thereof with (a) a carbamoyl chloride of the formula in the presence of an acid binding agent, or (b) phosgene in the presence of an acid binding agent to form a chloroformic acid ester which is then reacted with an amine of the formula or (c) when R 2 represents a hydrogen atom, an isocyanate of the formula in the presence of a catalyst; or by (ii) catalytically reducing a nitro compound of the formula to form the corresponding amine which is then reacted with a compound of the formula in the presence of an acid binding agent. The compounds of the invention have herbicidal properties.
[GB1385802A]
Claims (1)
1. o chl oxy 3 fl uorome thy phenyl oxy j th ocarbama carbamoy oxy thi ocarbamate th1 phenyl orophenyl th carbamoy Toxy ocarbamate thy more com ounds of the eneral formula I are used in a total amount of A method as claimed In claim conducted substantial as described In Example 4 or 5 A method of protecting a crop area against wherein a crop area is treated with a compound of the general formula I as defined 1n claim 1 A method as claimed 1n claim wherein the crop area treated the compound claimed any one of claims 2 to A method as claimed 1n claim wherein the area 1s treated with a herblcldal prepa as claimed In any one of claims 33 to A method as claimed in any one of claims 46 to wherein a single compound of the general formula I 1s used 1n an amount of about to 5 per For the Applicant Wd and Goller insufficientOCRQuality
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2109798A DE2109798C3 (en) | 1971-02-23 | 1971-02-23 | N-3-Carbamoyloxyphenyl-Thiolcarbamate and herbicidal agent containing them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL38799A0 IL38799A0 (en) | 1972-04-27 |
| IL38799A true IL38799A (en) | 1976-06-30 |
Family
ID=5800253
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL38799A IL38799A (en) | 1971-02-23 | 1972-02-20 | Substituted s-alkyl n-(carbamoyloxyphenyl)thiocarbamates |
| IL46111A IL46111A (en) | 1971-02-23 | 1972-02-20 | Substituted s-alkyl n-(carbamoyl-oxyphenyl)-thiocarbamate |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL46111A IL46111A (en) | 1971-02-23 | 1972-02-20 | Substituted s-alkyl n-(carbamoyl-oxyphenyl)-thiocarbamate |
Country Status (24)
| Country | Link |
|---|---|
| JP (1) | JPS5612602B1 (en) |
| AT (1) | AT315568B (en) |
| AU (1) | AU476470B2 (en) |
| BE (1) | BE779739A (en) |
| CA (1) | CA975777A (en) |
| CH (1) | CH564906A5 (en) |
| CS (1) | CS167341B2 (en) |
| DD (1) | DD95303A5 (en) |
| DE (1) | DE2109798C3 (en) |
| DK (1) | DK132114C (en) |
| ES (1) | ES400057A1 (en) |
| FR (1) | FR2127692A5 (en) |
| GB (1) | GB1385802A (en) |
| HU (1) | HU164148B (en) |
| IE (1) | IE36115B1 (en) |
| IL (2) | IL38799A (en) |
| IT (1) | IT948534B (en) |
| LU (1) | LU64679A1 (en) |
| NL (1) | NL7202392A (en) |
| NO (1) | NO135472C (en) |
| SE (1) | SE371641B (en) |
| SU (1) | SU578820A3 (en) |
| YU (1) | YU39578B (en) |
| ZA (1) | ZA72714B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2310648C3 (en) * | 1973-03-01 | 1982-05-06 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Diurethanes, processes for the preparation of these compounds and selective herbicidal agents containing them |
| DE2341079C2 (en) * | 1973-08-10 | 1982-05-06 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | m-Diurethanes and selective herbicidal agents containing these compounds as active ingredients |
-
1971
- 1971-02-23 DE DE2109798A patent/DE2109798C3/en not_active Expired
-
1972
- 1972-01-28 LU LU64679D patent/LU64679A1/xx unknown
- 1972-02-03 ZA ZA720714A patent/ZA72714B/en unknown
- 1972-02-07 CS CS758A patent/CS167341B2/cs unknown
- 1972-02-09 AU AU38828/72A patent/AU476470B2/en not_active Expired
- 1972-02-14 YU YU361/72A patent/YU39578B/en unknown
- 1972-02-14 GB GB670572A patent/GB1385802A/en not_active Expired
- 1972-02-15 IT IT20572/72A patent/IT948534B/en active
- 1972-02-15 SE SE7201800A patent/SE371641B/xx unknown
- 1972-02-17 IE IE201/72A patent/IE36115B1/en unknown
- 1972-02-20 IL IL38799A patent/IL38799A/en unknown
- 1972-02-20 IL IL46111A patent/IL46111A/en unknown
- 1972-02-22 DD DD161035A patent/DD95303A5/xx unknown
- 1972-02-22 NO NO531/72A patent/NO135472C/no unknown
- 1972-02-22 DK DK82072*#A patent/DK132114C/en not_active IP Right Cessation
- 1972-02-22 FR FR7205872A patent/FR2127692A5/fr not_active Expired
- 1972-02-22 ES ES400057A patent/ES400057A1/en not_active Expired
- 1972-02-23 BE BE779739A patent/BE779739A/en not_active IP Right Cessation
- 1972-02-23 AT AT147072A patent/AT315568B/en not_active IP Right Cessation
- 1972-02-23 JP JP1884172A patent/JPS5612602B1/ja active Pending
- 1972-02-23 SU SU7201751717A patent/SU578820A3/en active
- 1972-02-23 CA CA135,380A patent/CA975777A/en not_active Expired
- 1972-02-23 CH CH260372A patent/CH564906A5/xx not_active IP Right Cessation
- 1972-02-23 NL NL7202392A patent/NL7202392A/xx not_active Application Discontinuation
- 1972-02-23 HU HUSCHE376*1A patent/HU164148B/hu unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK132114B (en) | 1975-10-27 |
| NO135472C (en) | 1977-04-13 |
| ES400057A1 (en) | 1974-12-16 |
| GB1385802A (en) | 1975-02-26 |
| CH564906A5 (en) | 1975-08-15 |
| AU476470B2 (en) | 1976-09-23 |
| ZA72714B (en) | 1972-10-25 |
| IE36115L (en) | 1972-08-23 |
| YU39578B (en) | 1985-03-20 |
| CS167341B2 (en) | 1976-04-29 |
| SU578820A3 (en) | 1977-10-30 |
| NO135472B (en) | 1977-01-03 |
| DE2109798C3 (en) | 1979-12-20 |
| DE2109798B2 (en) | 1979-04-19 |
| FR2127692A5 (en) | 1972-10-13 |
| IE36115B1 (en) | 1976-08-18 |
| IL46111A (en) | 1976-06-30 |
| SE371641B (en) | 1974-11-25 |
| IL38799A0 (en) | 1972-04-27 |
| JPS5612602B1 (en) | 1981-03-23 |
| DK132114C (en) | 1976-03-22 |
| LU64679A1 (en) | 1972-06-26 |
| DE2109798A1 (en) | 1972-08-31 |
| DD95303A5 (en) | 1973-01-20 |
| YU36172A (en) | 1982-05-31 |
| AU3882872A (en) | 1973-08-16 |
| IT948534B (en) | 1973-06-11 |
| HU164148B (en) | 1973-12-28 |
| NL7202392A (en) | 1972-08-25 |
| AT315568B (en) | 1974-05-27 |
| CA975777A (en) | 1975-10-07 |
| BE779739A (en) | 1972-08-23 |
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