IL27026A - Process for the production of phenol by catalytic dehydrogenation of cyclohexanol,cyclohexanone or their mixtures in the presence of platinum and catalyst therefor - Google Patents

Process for the production of phenol by catalytic dehydrogenation of cyclohexanol,cyclohexanone or their mixtures in the presence of platinum and catalyst therefor

Info

Publication number
IL27026A
IL27026A IL27026A IL2702666A IL27026A IL 27026 A IL27026 A IL 27026A IL 27026 A IL27026 A IL 27026A IL 2702666 A IL2702666 A IL 2702666A IL 27026 A IL27026 A IL 27026A
Authority
IL
Israel
Prior art keywords
cyclohexanol
cyclohexanone
platinum
phenol
mixtures
Prior art date
Application number
IL27026A
Other languages
English (en)
Original Assignee
Inst Francais Du Petrole
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole
Publication of IL27026A publication Critical patent/IL27026A/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation
    • C07C37/07—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation with simultaneous reduction of C=O group in that ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
IL27026A 1965-12-08 1966-12-07 Process for the production of phenol by catalytic dehydrogenation of cyclohexanol,cyclohexanone or their mixtures in the presence of platinum and catalyst therefor IL27026A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR41481A FR1499878A (fr) 1965-12-08 1965-12-08 Procédé de fabrication de phénol par déshydrogénation catalytique de cyclohexanol, de cyclohexanone ou de leurs mélanges
FR64576A FR1536181A (fr) 1965-12-08 1966-06-07 Procédé de fabrication de phénol par deshydrogénation catalytique de cyclohexanol, de cyclohexanone ou de leurs mélanges, en présence d'un catalyeur de deshydrogénation à très faible teneur en platine
FR64755A FR1536182A (fr) 1965-12-08 1966-06-08 Procédé de fabrication de phénol par deshydrogénation catalytique de cyclohexanol, de cyclohexanone ou de leurs mélanges, en présence d'un catalyseur de deshydrogénation à très faible teneur en platine

Publications (1)

Publication Number Publication Date
IL27026A true IL27026A (en) 1970-10-30

Family

ID=27242766

Family Applications (1)

Application Number Title Priority Date Filing Date
IL27026A IL27026A (en) 1965-12-08 1966-12-07 Process for the production of phenol by catalytic dehydrogenation of cyclohexanol,cyclohexanone or their mixtures in the presence of platinum and catalyst therefor

Country Status (7)

Country Link
US (1) US3534110A (xx)
BE (1) BE690722A (xx)
DE (1) DE1543710A1 (xx)
FR (3) FR1499878A (xx)
GB (1) GB1162397A (xx)
IL (1) IL27026A (xx)
NL (1) NL6617118A (xx)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3670033A (en) * 1968-05-02 1972-06-13 Asahikasei Kogyo Kk Process for the preparation of 2,6-dialkylphenols
US3850747A (en) * 1969-12-09 1974-11-26 Exxon Research Engineering Co Hydrocarbon conversion using an iridium-gold catalyst
US3978002A (en) * 1972-12-04 1976-08-31 National Petro Chemicals Corporation Catalyst useful for olefin polymerization process
DE2437929A1 (de) * 1974-08-07 1976-02-19 Hoechst Ag Verfahren zur herstellung von hydrochinon
US4161615A (en) * 1975-01-17 1979-07-17 Hoechst Aktiengesellschaft Dehydrogenation of cyclic ketones to beta-naphthols
US4271091A (en) * 1978-06-17 1981-06-02 Standard Oil Company Vapor phase catalytic oxidation and/or ammoxidation of cyclohexanone and/or cyclohexanol to phenol and/or aniline
DE3314372A1 (de) * 1983-04-20 1984-10-25 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von substituierten phenolen
US4582815A (en) * 1984-07-06 1986-04-15 Mobil Oil Corporation Extrusion of silica-rich solids
US4624140C1 (en) * 1984-07-30 2001-01-30 Jack A Ekchian Liquid medium capacitive displacement sensor
JPH01146837A (ja) * 1987-12-03 1989-06-08 Mitsui Petrochem Ind Ltd シクロヘキセノンの脱水素方法
JPH01226840A (ja) * 1988-03-07 1989-09-11 Mitsui Petrochem Ind Ltd フェノール類および／またはシクロヘキサノン類の製造方法
US8222459B2 (en) * 1997-06-13 2012-07-17 Exxonmobil Chemical Patents Inc. Process for producing cyclohexanone
JP5386584B2 (ja) 2008-08-29 2014-01-15 エクソンモービル・ケミカル・パテンツ・インク フェノールの製造方法
US20120316365A1 (en) * 2010-02-05 2012-12-13 Teng Xu Dehydrogenation Process
WO2011096990A2 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation catalyst and process
SG181455A1 (en) * 2010-02-05 2012-07-30 Exxonmobil Chem Patents Inc Dehydrogenation of cyclohexanone to produce phenol
US20120271076A1 (en) 2010-02-05 2012-10-25 Soled Stuart L Iridium-Containing Catalysts, Their Production and Use
CN102711985B (zh) 2010-02-05 2016-02-03 埃克森美孚化学专利公司 脱氢方法
WO2011096992A1 (en) * 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation process
WO2011096993A2 (en) * 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation process
WO2011096999A2 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Cyclohexanone dehydrogenation catalyst and process
WO2011096989A1 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation of cyclohexanone to produce phenol
SG10201503888PA (en) 2010-06-25 2015-06-29 Exxonmobil Chem Patents Inc Dehydrogenation process
SG189124A1 (en) 2010-10-11 2013-05-31 Exxonmobil Chem Patents Inc Process for producing phenol
WO2012134552A1 (en) 2011-03-28 2012-10-04 Exxonmobil Chemical Patents Inc. Dehydrogenation process
CN106238045A (zh) 2010-12-17 2016-12-21 埃克森美孚化学专利公司 脱氢催化剂和方法
TWI549749B (zh) * 2015-05-07 2016-09-21 China Petrochemical Dev Corp Taipei Taiwan A catalyst composition for preparing o-phenylphenol and a process for preparing o-phenylphenol using the catalyst composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2503641A (en) * 1947-04-09 1950-04-11 Ici Ltd Dehydrogenation of organic compounds
FR1344298A (fr) * 1962-08-30 1963-11-29 Progil Fabrication de phénols lourds

Also Published As

Publication number Publication date
FR1499878A (fr) 1967-11-03
FR1536181A (fr) 1968-08-27
GB1162397A (en) 1969-08-27
US3534110A (en) 1970-10-13
DE1543710A1 (de) 1970-01-02
FR1536182A (fr) 1968-08-27
NL6617118A (xx) 1967-06-09
BE690722A (xx) 1967-06-05

Similar Documents

Publication Publication Date Title
IL27026A (en) Process for the production of phenol by catalytic dehydrogenation of cyclohexanol,cyclohexanone or their mixtures in the presence of platinum and catalyst therefor
BE751009A (fr) Support fortement calcine, catalyseur l'utilisant et procede dedeshydrogenation catalytique
FR1502141A (fr) Procédés et catalyseurs de dimérisation du 1, 3-butadiène et de l'isoprène
IT954882B (it) Procedimento per la produzione di catalizzatori solfitizzati di pla tino su carbonio
CA946364A (en) Catalytic dehydrogenation process
BR6794779D0 (pt) Processo e catalisador de fabricacao de cetonas ciclicas por deshidrogenacao catalitica de alcoois ciclicos
IL23897A (en) Catalytic acrylonitrile production
IL24102A (en) Indan-1,3-dione compounds and processes for their preparation
NL170726C (nl) Werkwijze voor de bereiding van cyclohexanon door selectieve hydrogenering van fenol in de gasfase.
CA695865A (en) Process for the preparation of naphthoquinone by catalytic gasphase oxidation, and catalysts for this process
BE799490A (fr) Procede et installation pour la deshydrogenation catalytique des hydrocarbures,
ZM3173A1 (en) Catalysts for the ammoxidation and oxidation of olefines,process for their preparation and uses thereof
ZA731241B (en) Oxidation and ammoxidation catalysts,process for their preparation and utilisations thereof
CA703422A (en) Catalyst and dehydrogenation process
CA711692A (en) Process for the purification of hydrocarbons and for the manufacture of catalyst therefor
CA700376A (en) Catalytic dehydrogenation process
AU5865465A (en) Hyddrocarbon dehydrogenation catalyst and process
CA690359A (en) Oxidation process and catalyst therefor
CA660339A (en) Catalytic dehydrogenation process
CA844646A (en) Catalytic dehydrogenation process
CA695208A (en) Process and catalyst for the production of polychloroethylenes
CA724235A (en) Process for preparing cyclohexanone and cyclohexanol
AU282109B2 (en) Improved process and catalyst for catalytic hydrogenation of adiponitrile
CA670113A (en) Catalyst and dehydrogenation process
ES331811A1 (es) Procedimiento perfeccionado de fabricacion de ciclohexanona por deshidrogenacion del ciclohexanol.