IL119387A - Process for the recovery of lactic acid by liquid-liquid extraction with a basic extractant - Google Patents
Process for the recovery of lactic acid by liquid-liquid extraction with a basic extractantInfo
- Publication number
- IL119387A IL119387A IL11938796A IL11938796A IL119387A IL 119387 A IL119387 A IL 119387A IL 11938796 A IL11938796 A IL 11938796A IL 11938796 A IL11938796 A IL 11938796A IL 119387 A IL119387 A IL 119387A
- Authority
- IL
- Israel
- Prior art keywords
- lactic acid
- extractant
- aqueous solution
- process according
- lactate salt
- Prior art date
Links
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 title claims abstract description 296
- 239000004310 lactic acid Substances 0.000 title claims abstract description 148
- 235000014655 lactic acid Nutrition 0.000 title claims abstract description 148
- 238000000034 method Methods 0.000 title claims abstract description 56
- 238000011084 recovery Methods 0.000 title claims abstract description 21
- 238000000622 liquid--liquid extraction Methods 0.000 title description 11
- 238000000638 solvent extraction Methods 0.000 title description 11
- 239000007864 aqueous solution Substances 0.000 claims abstract description 44
- 150000003893 lactate salts Chemical class 0.000 claims abstract description 34
- 239000000284 extract Substances 0.000 claims abstract description 33
- 239000000243 solution Substances 0.000 claims abstract description 29
- 238000000605 extraction Methods 0.000 claims description 51
- 239000002253 acid Substances 0.000 claims description 31
- 238000000855 fermentation Methods 0.000 claims description 23
- 230000004151 fermentation Effects 0.000 claims description 23
- 239000000047 product Substances 0.000 claims description 15
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000001540 sodium lactate Substances 0.000 claims description 10
- 229940005581 sodium lactate Drugs 0.000 claims description 10
- 235000011088 sodium lactate Nutrition 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- 239000006227 byproduct Substances 0.000 claims description 5
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims description 5
- 239000001527 calcium lactate Substances 0.000 claims description 5
- 229960002401 calcium lactate Drugs 0.000 claims description 5
- 235000011086 calcium lactate Nutrition 0.000 claims description 5
- 239000004251 Ammonium lactate Substances 0.000 claims 1
- 229940059265 ammonium lactate Drugs 0.000 claims 1
- 235000019286 ammonium lactate Nutrition 0.000 claims 1
- RZOBLYBZQXQGFY-HSHFZTNMSA-N azanium;(2r)-2-hydroxypropanoate Chemical compound [NH4+].C[C@@H](O)C([O-])=O RZOBLYBZQXQGFY-HSHFZTNMSA-N 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 description 16
- 239000008346 aqueous phase Substances 0.000 description 12
- 239000003623 enhancer Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 239000012074 organic phase Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 8
- 229940001447 lactate Drugs 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 6
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- -1 lactate ester Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000002798 polar solvent Substances 0.000 description 3
- 150000001447 alkali salts Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003637 basic solution Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000011067 equilibration Methods 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 230000005588 protonation Effects 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WBPAQKQBUKYCJS-UHFFFAOYSA-N 2-methylpropyl 2-hydroxypropanoate Chemical compound CC(C)COC(=O)C(C)O WBPAQKQBUKYCJS-UHFFFAOYSA-N 0.000 description 1
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000186660 Lactobacillus Species 0.000 description 1
- 240000001046 Lactobacillus acidophilus Species 0.000 description 1
- 235000013956 Lactobacillus acidophilus Nutrition 0.000 description 1
- 241000186673 Lactobacillus delbrueckii Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000000061 acid fraction Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 229960005069 calcium Drugs 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940039696 lactobacillus Drugs 0.000 description 1
- 229940039695 lactobacillus acidophilus Drugs 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL11938796A IL119387A (en) | 1996-10-09 | 1996-10-09 | Process for the recovery of lactic acid by liquid-liquid extraction with a basic extractant |
| US09/284,160 US7019170B2 (en) | 1996-10-09 | 1997-10-02 | Process for the recovery of lactic acid by contacting aqueous solutions containing the same with a basic organic extractant |
| CA002268313A CA2268313C (en) | 1996-10-09 | 1997-10-02 | Process for the recovery of lactic acid by contacting aqueous solutions containing the same with a basic organic extractant |
| BR9712227-0A BR9712227A (pt) | 1996-10-09 | 1997-10-02 | Processo para recuperação de ácido láctico e produtos do mesmo |
| PCT/US1997/015844 WO1998015517A2 (en) | 1996-10-09 | 1997-10-02 | Process for the recovery of lactic acid by contacting aqueous solutions containing the same with a basic organic extractant |
| DK97911585T DK0932592T3 (da) | 1996-10-09 | 1997-10-02 | Fremgangsmåde til indvinding af mælkesyre |
| DE69714277T DE69714277T2 (de) | 1996-10-09 | 1997-10-02 | Verfahren zur gewinnung von milchsäure aus wässrigen lösungen, die sie enthalten, mit hilfe eines basischen organischen extraktionsmittels |
| ES97911585T ES2180951T3 (es) | 1996-10-09 | 1997-10-02 | Procedimiento para la recuperacion de acido lactico. |
| AU48914/97A AU4891497A (en) | 1996-10-09 | 1997-10-02 | Process for the recovery of lactic acid |
| AT97911585T ATE221041T1 (de) | 1996-10-09 | 1997-10-02 | Verfahren zur gewinnung von milchsäure aus wässrigen lösungen, die sie enthalten, mit hilfe eines basischen organischen extraktionsmittels |
| EP97911585A EP0932592B1 (de) | 1996-10-09 | 1997-10-02 | Verfahren zur gewinnung von milchsäure aus wässrigen lösungen, die sie enthalten, mit hilfe eines basischen organischen extraktionsmittels |
| PT97911585T PT932592E (pt) | 1996-10-09 | 1997-10-02 | Processo para a recuperacao de acido lactico |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL11938796A IL119387A (en) | 1996-10-09 | 1996-10-09 | Process for the recovery of lactic acid by liquid-liquid extraction with a basic extractant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL119387A0 IL119387A0 (en) | 1997-01-10 |
| IL119387A true IL119387A (en) | 2001-06-14 |
Family
ID=11069359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL11938796A IL119387A (en) | 1996-10-09 | 1996-10-09 | Process for the recovery of lactic acid by liquid-liquid extraction with a basic extractant |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7019170B2 (de) |
| EP (1) | EP0932592B1 (de) |
| AT (1) | ATE221041T1 (de) |
| AU (1) | AU4891497A (de) |
| BR (1) | BR9712227A (de) |
| CA (1) | CA2268313C (de) |
| DE (1) | DE69714277T2 (de) |
| DK (1) | DK0932592T3 (de) |
| ES (1) | ES2180951T3 (de) |
| IL (1) | IL119387A (de) |
| PT (1) | PT932592E (de) |
| WO (1) | WO1998015517A2 (de) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6475759B1 (en) | 1997-10-14 | 2002-11-05 | Cargill, Inc. | Low PH lactic acid fermentation |
| US6229046B1 (en) | 1997-10-14 | 2001-05-08 | Cargill, Incorported | Lactic acid processing methods arrangements and products |
| US20020102672A1 (en) * | 1999-10-04 | 2002-08-01 | Joseph Mizrahi | Process for producing a purified lactic acid solution |
| ATE393137T1 (de) * | 2001-05-07 | 2008-05-15 | Cargill Inc | Verfahren zur herstellung von carbonsäuren und deren derivaten |
| DE102005033432A1 (de) * | 2005-07-18 | 2007-01-25 | Basf Ag | Verfahren zur Extraktion von Milchsäure aus wässrigen Suspensionen |
| JP2009067775A (ja) * | 2007-09-17 | 2009-04-02 | Rohm & Haas Co | ヒドロキシカルボン酸、またはその塩を、不飽和カルボン酸および／またはそのエステルに変換する方法 |
| DE102008040193A1 (de) | 2008-07-04 | 2010-01-07 | Evonik Röhm Gmbh | Verfahren zur Herstellung freier Carbonsäuren |
| DE102009009580A1 (de) | 2009-02-19 | 2010-08-26 | Evonik Degussa Gmbh | Verfahren zur Herstellung freier Säuren aus ihren Salzen |
| DE102010002065B4 (de) | 2010-02-17 | 2014-04-10 | Deutsches Institut Für Lebensmitteltechnik E.V. | Vorrichtung und integriertes Herstellungsverfahren für Ammoniumlactat |
| US8900834B2 (en) | 2010-10-28 | 2014-12-02 | Total Research & Technology Feluy S.A. | Process for polylactic acid production using monascus |
| PT106039A (pt) * | 2010-12-09 | 2012-10-26 | Hcl Cleantech Ltd | Processos e sistemas para o processamento de materiais lenhocelulósicos e composições relacionadas |
| GB2524906B8 (en) | 2011-04-07 | 2016-12-07 | Virdia Ltd | Lignocellulose conversion processes and products |
| EP2862890A1 (de) | 2012-05-03 | 2015-04-22 | Virdia Ltd. | Verfahren zur Extraktion von Lignin aus Biomasse |
| US9493851B2 (en) | 2012-05-03 | 2016-11-15 | Virdia, Inc. | Methods for treating lignocellulosic materials |
| NZ743055A (en) | 2013-03-08 | 2020-03-27 | Xyleco Inc | Equipment protecting enclosures |
| SE538899C2 (en) | 2015-02-03 | 2017-01-31 | Stora Enso Oyj | Method for treating lignocellulosic materials |
| CN105367405B (zh) * | 2015-11-27 | 2017-05-10 | 河南金丹乳酸科技股份有限公司 | 乳酸衍生转化生产丙酮酸中的丙酮酸提纯工艺 |
| WO2019160862A1 (en) * | 2018-02-13 | 2019-08-22 | Lygos, Inc. | Method for preparation of diester derivatives of malonic acid |
| WO2021139894A1 (en) | 2020-01-10 | 2021-07-15 | BluCon Biotech GmbH | Extreme thermophilic bacteria of the genus caldicellulosiruptor suitable for the conversion of cellulosic and starchy biomass |
| CN114929851A (zh) | 2019-04-18 | 2022-08-19 | 布鲁克生物科技公司 | 适合于纤维素和淀粉生物质的转化的解糖热纤维素菌属的极端嗜热细菌 |
| CN112745215B (zh) * | 2019-10-31 | 2022-11-11 | 中国石油化工股份有限公司 | 一种从乳酸盐的含水原料中转化乳酸和提取乳酸相耦合的方法 |
| WO2021139895A1 (en) | 2020-01-10 | 2021-07-15 | BluCon Biotech GmbH | Methods of producing lactic acid from unmodified starch |
| CN114380683B (zh) * | 2021-12-21 | 2024-06-25 | 安徽丰原发酵技术工程研究有限公司 | 一种从含乳酸钙的发酵液中提取乳酸的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2820942A1 (de) * | 1978-05-12 | 1979-11-22 | Sueddeutsche Kalkstickstoff | Uebersaure feste metallactate, verfahren zu deren herstellung und verwendung |
| US4444881A (en) * | 1981-10-26 | 1984-04-24 | Cpc International Inc. | Recovery of organic acids from a fermentation broth |
| JPS62146595A (ja) | 1985-12-20 | 1987-06-30 | Daicel Chem Ind Ltd | 醗酵による有機酸の連続製造方法 |
| US5252473A (en) * | 1990-01-23 | 1993-10-12 | Battelle Memorial Institute | Production of esters of lactic acid, esters of acrylic acid, lactic acid, and acrylic acid |
| US5210296A (en) * | 1990-11-19 | 1993-05-11 | E. I. Du Pont De Nemours And Company | Recovery of lactate esters and lactic acid from fermentation broth |
| US5132456A (en) | 1991-05-07 | 1992-07-21 | The Regents Of The University Of California | Sorption of carboxylic acid from carboxylic salt solutions at PHS close to or above the pKa of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine |
| US5510526A (en) * | 1993-06-29 | 1996-04-23 | Cargill, Incorporated | Lactic acid production, separation and/or recovery process |
| DE4341770A1 (de) * | 1993-12-08 | 1995-06-14 | Basf Ag | Verfahren zur Herstellung von Milchsäureestern |
| IL109003A (en) * | 1994-03-16 | 1999-09-22 | Yissum Res Dev Co | Process and extractant composition for extracting water-soluble carboxylic and mineral acids |
| US5766439A (en) * | 1996-10-10 | 1998-06-16 | A. E. Staley Manufacturing Co. | Production and recovery of organic acids |
-
1996
- 1996-10-09 IL IL11938796A patent/IL119387A/en not_active IP Right Cessation
-
1997
- 1997-10-02 AT AT97911585T patent/ATE221041T1/de not_active IP Right Cessation
- 1997-10-02 ES ES97911585T patent/ES2180951T3/es not_active Expired - Lifetime
- 1997-10-02 US US09/284,160 patent/US7019170B2/en not_active Expired - Fee Related
- 1997-10-02 CA CA002268313A patent/CA2268313C/en not_active Expired - Fee Related
- 1997-10-02 DE DE69714277T patent/DE69714277T2/de not_active Expired - Fee Related
- 1997-10-02 DK DK97911585T patent/DK0932592T3/da active
- 1997-10-02 EP EP97911585A patent/EP0932592B1/de not_active Expired - Lifetime
- 1997-10-02 WO PCT/US1997/015844 patent/WO1998015517A2/en not_active Ceased
- 1997-10-02 BR BR9712227-0A patent/BR9712227A/pt not_active IP Right Cessation
- 1997-10-02 PT PT97911585T patent/PT932592E/pt unknown
- 1997-10-02 AU AU48914/97A patent/AU4891497A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| PT932592E (pt) | 2002-11-29 |
| WO1998015517A8 (en) | 2008-08-07 |
| EP0932592A2 (de) | 1999-08-04 |
| ES2180951T3 (es) | 2003-02-16 |
| IL119387A0 (en) | 1997-01-10 |
| DE69714277D1 (de) | 2002-08-29 |
| BR9712227A (pt) | 2002-02-05 |
| DK0932592T3 (da) | 2002-09-02 |
| US7019170B2 (en) | 2006-03-28 |
| WO1998015517A2 (en) | 1998-04-16 |
| ATE221041T1 (de) | 2002-08-15 |
| CA2268313A1 (en) | 1998-04-16 |
| AU4891497A (en) | 1998-05-05 |
| CA2268313C (en) | 2007-02-20 |
| DE69714277T2 (de) | 2003-03-06 |
| EP0932592B1 (de) | 2002-07-24 |
| WO1998015517A3 (en) | 1998-05-22 |
| US20030187300A1 (en) | 2003-10-02 |
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