IE910220A1 - A method for electrical assembly cleaning - Google Patents
A method for electrical assembly cleaningInfo
- Publication number
- IE910220A1 IE910220A1 IE22091A IE22091A IE910220A1 IE 910220 A1 IE910220 A1 IE 910220A1 IE 22091 A IE22091 A IE 22091A IE 22091 A IE22091 A IE 22091A IE 910220 A1 IE910220 A1 IE 910220A1
- Authority
- IE
- Ireland
- Prior art keywords
- liquid
- boiling point
- vapor
- electrical assembly
- cleaned
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/26—Cleaning or polishing of the conductive pattern
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/024—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/04—Apparatus
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/07—Treatments involving liquids, e.g. plating, rinsing
- H05K2203/0779—Treatments involving liquids, e.g. plating, rinsing characterised by the specific liquids involved
- H05K2203/0783—Using solvent, e.g. for cleaning; Regulating solvent content of pastes or coatings for adjusting the viscosity
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/15—Position of the PCB during processing
- H05K2203/1509—Horizontally held PCB
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Detergent Compositions (AREA)
Abstract
A mixture of a primary liquid and a secondary liquid is heated in a cleaning apparatus. The mixture is heated to at least the boiling point of the secondary liquid but less than the boiling point of the primary liquid. The secondary liquid vaporizes (102), forming a vapor layer above the primary liquid (103). Condensing elements (101) near the top of the cleaning apparatus condense the vapor (102), returning it to the heated primary liquid (103) to be vaporized again. The electronic assembly (104) to be cleaned is lowered through the vapor and then immersed in the primary liquid (103) before being positioned in the vapor (102) where it may be sprayed by the primary liquid (105) to remove any remaining contaminants. The vapor (102) mixes with the atomized primary liquid formed from the spraying, and returns it to the primary liquid (103).
Description
A METHOD FOR ELECTRICAL ASSEMBLY CLEANING
Background of the Invention 1 θ
Soldering components to a circuit board assembly typically leaves contaminants such as solder flux, resins, and ionic compounds. These contaminants must be removed if the circuit board assembly is to be sealed from the elements by a
protective coating. The protective coating may not properly adhere to an assembly containing contaminants. The contaminants may also be removed for aesthetic purposes, to prevent corrosion, or to increase the assembly’s insulation resistance.
0 The cleaning process to remove the contaminants is usually done with chlorofluorocarbon (CFC) based solvents in liquid or vapor form. These solvents are frequently an azeotrope of trichloro-trifluoroethane and another solvent such as an alcohol, an example being methanol. One such
solvent is a fluorinated hydrocarbon manufactured by Ε. I.
DuPont de Nemours & Co and marketed under the trade name FREON TMS.
The cleaning process is typically accomplished by placing the solvent in a container having heating elements at
0 the bottom and condensing elements near the top. The solvent is then heated to its boiling temperature of 43.3°C, producing a solvent vapor above the liquid solvent. The circuit board or electronic assembly to be cleaned is placed in the vapor. The electronic assembly, being at a lower temperature than the
vapor, causes the vapor to condense on the assembly, thereby
-2CE00254R
IE 91220 cleaning off the contaminants by dissolving or flushing off the contaminants.
The vapor that did not condense on the electronic assembly is retained in the cleaning apparatus by the condensing elements. These elements, typically operated at a temperature of 10°C, cause the higher temperature vaporized solvent to condense back to liquid, returning to the bottom of the container to repeat the cycle. While the condensing elements in the container keep most of the solvent in the
0 container, some of the solvent diffuses across the air-solvent interface and therefore escapes into the atmosphere. In addition, the assemblies being cleaned may retain small amounts of solvent on their surfaces after removal from the cleaning apparatus. Also, the spilling of solvent by workers
refilling the cleaning apparatus can release the solvent into the atmosphere
The solvent must be retained in the apparatus due to its expense and because of environmental concerns. In recent years, scientific studies have shown that CFCs have been
0 depleting the protective ozone layer above the Earth, causing holes to form in this layer. This allows harmful ultraviolet rays from the sun, normally filtered out by the ozone layer, to reach the Earth. The increased ultraviolet rays will increase incidence of skin cancer and add to the warming of the
atmosphere.
Alcohols such as isopropyl, methanol, or ethanol have been tried as an alternative to CFC based solvents. The assembly to be cleaned is initially immersed in and then sprayed with isopropyl alcohol, dissolving and/or washing off
0 the contaminants. Alcohol, while it adequately removes ionic material from the assembly, may leave a white residue. Customers buying the assembly might get the impression that the assembly has not been cleaned or is defective in some way.
There is therefore a need for an environmentally safe 3 5 cleaning solvent that removes ionic material and does not leave a residue on the assembly being cleaned.
-3CE00254R
91220
Summary of the Invention
The present invention is a method for cleaning 5 electronic assemblies without the use of CFCs. The process is accomplished by heating a mixture of a high boiling point primary liquid, such as a terpene, and a lower boiling point secondary liquid, used as a rinsing/drying agent, such as pentafluoropropanol. The primary/secondary liquid mixture is heated in an apparatus having condensing elements near the top. The mixture is heated to a temperature that is greater than the boiling point of the secondary liquid but less than the boiling point of the primary liquid. This will cause the secondary liquid to vaporize, forming a vapor layer above the
primary liquid. The vapor is retained in the cleaning apparatus condensing on the condensing elements and returned, in liquid form, to the heated mixture to be vaporized again.
The assembly to be cleaned is immersed through the
0 vapor and then placed in the primary liquid or sprayed with the primary liquid to dissolve the flux. The assembly is then placed in the vapor and rinsed with the primary liquid either by spraying or immersion in the distilled primary liquid. The vapor layer, by mixing with the atomized primary liquid from
the assembly and condensing on the condensing elements, will contain the primary liquid within the apparatus, returning it to the heated primary liquid for reuse.
Brief Description of the Drawings
Figure 1 shows the cross section of an apparatus for practicing the present method on a single electronic assembly or a batch of electronic assemblies;
Figure 2 shows the cross section of an apparatus for
practicing the present method on multiple electronic assemblies continuously moving through the apparatus; and
-4CE00254R
IE 91220
Figure 3 shows an alternate embodiment for practicing the present method on multiple electronic assemblies continuously moving through the apparatus.
Detailed Description of the Preferred Embodiment
The method of cleaning electronic assemblies disclosed herein operates without the use of CFCs that damage the ozone layer. This is accomplished by using a primary or
0 solvent liquid with a high boiling point and a secondary or rinsing/drying liquid with a lower boiling point. In the preferred embodiment, a terpene hydrocarbon is used as the primary or first liquid and pentafluoropropanol as the secondary or second liquid.
Terpenes represent a broad family of unsaturated, isoprene-type hydrocarbons and alcohols that exist naturally in most essential oils and oleoresins of plants. For example, one simple terpene, limonene (C10Hi6), is a major component of a cleaning solvent mixture marketed by Petroleum
0 Fermentations, N.V. under the trade name BIOACT EC-7.
This solvent system possesses the following significant properties:
Boiling point at atmospheric pressure - 170°C; Flash point at atmospheric pressure - C.O.C.
71°C and T.C.C. 47°C; and
Vapor pressure - 1.6mm Hg at 20°C.
In addition, terpene, when atomized, can be explosive if exposed to air at a temperature lower than T.C.C.
Pentafluoropropanol, CF3CF2CH2OH, is a non3 0 chlorofluorocarbon, alcohol-type cleaning agent marketed by
Daikin Industries LTD. under the name PEFOL. Pentafluoropropanol, which has a zero ozone depletion potential, has the following significant properties:
Boiling point at atmospheric pressure - 80.7°C;
Flash point at atmospheric pressure - none; and
Vapor pressure - 33 mm Hg at 20°C.
-5CE00254R
IE 91220
In the embodiment shown in Figure 1, the bottom of the apparatus is filled with the primary and secondary liquid mixture. The mixture is heated to approximately 95°C, greater than the the boiling point of the secondary liquid. The secondary liquid will then vaporize into a layer (102) above the primary liquid (103). The primary liquid (103), because it has a higher boiling point than 95°C, will remain in liquid form below the vapor layer (102).
The assembly (104) to be cleaned is first placed in the 1 0 primary liquid (103) by passing it through the vapor. Next, the assembly (104) is positioned in the vapor layer (102) where it can he sprayed with the primary liquid (105) to remove the remaining contaminants. The primary liquid (105), when it strikes the assembly (104), will atomize. This atomization
may present the risk of explosion if the atomized mist was exposed to the atmosphere. One purpose of the vapor (102), therefore, is to isolate the primary liquid (103) from the atmosphere.
The vapor (102) mixes with the atomized primary liquid
0 from the assembly being cleaned. This vapor mixture is then condensed by the condensing elements (101). The now liquid primary and secondary mixture is returned to the heated primary liquid (103) below where the secondary liquid is again vaporized to repeat the cycle. The condensing elements (101), therefore, retains the vapor (102) which, in turn, retains the primary liquid (103).
Another function of the secondary liquid is to rinse off the primary liquid that is contaminated with flux. The secondary liquid then evaporates more rapidly than the
0 primary liquid because of its higher vapor pressure. The evaporation dries the assembly.
Figure 2 illustrates another embodiment of this invention. This embodiment is suited for assembly line cleaning of electronic assemblies. The electronic assembly is
first moved into a terpene wash (201) where it is emersed in heated terpene. The assembly next travels through a high
-6CE00254R
91220 pressure terpene spray (202) to remove any remaining impurities. The assembly finally travels through an isopropyl alcohol immersion (203) to remove the terpene residue.
Figure 3 illustrates yet another embodiment of this 5 invention. In this embodiment, the electronic assembly is lowered through the vapor layer (302) for either immersion in the primary liquid (305) or spraying with primary liquid (301). The primary liquid (305) should be kept at a temperature above 83°C to prevent the vapor (302) from condensing on the surface of the primary liquid. The assembly is next immersed in the secondary liquid (306) to remove the primary liquid (305) and any contaminants dissolved by the primary liquid (305). Finally, the assembly is withdrawn through the vapor (302), sprayed with clean secondary liquid distillate (303), and
allowed to drain before removal from the vapor (302). As in the first embodiment, the level of the vapor layer (302) is controlled by condensing elements (304). The distillate is produced from the distillation of the secondary liquid (306) to remove the primary liquid (305) and contaminants.
0 While the preferred embodiment uses terpene hydrocarbons as the primary or solvent liquid and pentafluoropropanol as the secondary liquid or rinsing/drying agent, any liquids with properties similar to these can be used. Examples of a pentafluoropropanol replacement are alcohol (methanol, ethanol, n-propanol, isopropanol, etc.), an alcohol water mixture, water, or hydrochlorofluorocarbon. Examples of a terpene hydrocarbon replacement are terpene alcohol, mineral spirits, naphtha, N-methyl pyrrolidinone (NMP), or mixtures thereof. However, since these elements
0 have varying boiling points, the primary and secondary liquid mixture will be kept at different temperatures. For example, a mixture of a terpene as the primary or first liquid and methanol as the secondary or second liquid requires a temperature of at least 65°C, the boiling point of the methanol, to 170°C, the boiling point of a terpene. A mixture of a terpene
IE 91220
-7CE00254R and isolpropyl alcohol requires a temperature of at least 82°C, the boiling point of isopropyl alcohol, to 170°C.
The present invention provides cleaning Of electrical assemblies without the use of ozone depleting chemicals. This method removes ionic materials without leaving a residue on the assembly while maintaining safe conditions for people near the cleaning apparatus.
Claims (18)
1. A method for cleaning contaminants from an electrical assembly, the steps characterized by: a) establishing a body of liquid comprising a terpene having a first boiling point and a second liquid having a second boiling point that is less than the first boiling point; b) establishing a body of condensible vapor above the body of liquid, substantially isolating the body of liquid from other gases, by continuously heating the body of liquid to a predetermined temperature range that is less than the first boiling point but greater than the second boiling point; c) condensing the vapor of the body of condensible vapor to form the second liquid that is returned to the body of liquid; d) placing the electrical assembly to be cleaned into the terpene; e) moving the electrical assembly to be cleaned into the body of condensible vapor; and the steps further characterized by f) spraying the electrical assembly to be cleaned with a liquid comprised of the terpene. -9CE00254R IE 91220
2. The method of claim 1 characterized in that the second liquid is isopropyl alcohol.
3. The method of claim 1 characterized in that the second 5 liquid is a hydrochlorofluorocarbon.
4. The method of claim 1 characterized in that the second liquid is pentafluoropropanol.
5. B) establishing a second body of liquid having a second boiling point that is lower than the first boiling point; c) establishing a body of condensible vapor above the first and second bodies of liquid by heating the second body of liquid at a predetermined temperature that is greater than the 5 liquid. 5 second boiling point that is less than the first boiling point; b) establishing a body of condensible vapor above the body of liquid by continuously heating the body of liquid to a predetermined temperature range that is less than the first boiling point hut greater than the second boiling point;
6. The method of claim 1 characterized in that the second
7. A method for cleaning contaminants from an electrical assembly, the steps characterized by: a) establishing a body of liquid comprising a terpene having a first boiling point and a second liquid having a
8. The method of claim 7 and further characterized by the steps of placing the electrical assembly to be cleaned into the body of condensible vapor before spraying the electrical assembly to be cleaned with a liquid comprised of the first
9. The method of claim 7 characterized in that the second liquid is a hydrochlorofluorocarbon.
10. C) condensing the vapor of the body of condensible vapor to form the second liquid that is returned to the body of liquid; and the steps further characterized by d) spraying the electrical assembly to be cleaned with the terpene. -11CE00254R IE 91220 10 5. The method of claim 1 characterized in that the second liquid is isopropyl alcohol and the predetermined temperature range is at least 82°C and less than 170°C.
11. The method of claim 7 characterized in that the second liquid is isopropyl alcohol.
12. The method of claim 7 characterized in that the second liquid is isopropyl alcohol and the predetermined temperature range is at least 82°C and less than 170°C. 20
13. The method of claim 7 characterized in that the second liquid is methanol and the predetermined temperature range is at least 65°C and less than 170°C. -12CE00254R 91220
14. A method for cleaning contaminants from an electrical assembly, the steps characterized by: a) establishing a first body of liquid having a first boiling point;
15. The method of claim 14 characterized in that the second body of liquid is a hydrochlorofluorocarbon. 15 ly f) spraying the electrical assembly to be cleaned with a liquid comprised of the second body of liquid. -13CE00254R IE 91220
16. The method of claim 14 characterized in that the second 5 body of liquid is pentafluoropropanol.
17. The method of claim 14 characterized in that the second body of liquid is isopropyl alcohol.
18. A method according to any of the preceding claims, substantially as described herein by way of Example.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US46911790A | 1990-01-24 | 1990-01-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
IE910220A1 true IE910220A1 (en) | 1991-07-31 |
Family
ID=23862491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE22091A IE910220A1 (en) | 1990-01-24 | 1991-01-23 | A method for electrical assembly cleaning |
Country Status (2)
Country | Link |
---|---|
IE (1) | IE910220A1 (en) |
WO (1) | WO1991011269A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2614980B2 (en) * | 1991-06-14 | 1997-05-28 | ペトロファーム インコーポレイテッド | Composition and method for removing rosin soldering fluxes with terpenes and hydrocarbons |
MX9206771A (en) * | 1991-12-02 | 1993-06-01 | Allied Signal Inc | IMPROVEMENTS IN MULTIPLE SOLVENT CLEANING SYSTEM |
US6355113B1 (en) | 1991-12-02 | 2002-03-12 | 3M Innovative Properties Company | Multiple solvent cleaning system |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB329156A (en) * | 1929-05-10 | 1930-05-15 | Carrier Engineering Co Ltd | Improvements in or relating to method and means for degreasing articles |
GB1440438A (en) * | 1972-09-07 | 1976-06-23 | Ici Ltd | Cleaning process |
US4640719A (en) * | 1985-07-01 | 1987-02-03 | Petroleum Fermentations N.V. | Method for printed circuit board and/or printed wiring board cleaning |
US4828751A (en) * | 1987-08-28 | 1989-05-09 | Pcr, Inc. | Solvent composition for cleaning silicon wafers |
US4867800B1 (en) * | 1988-07-21 | 1995-02-14 | Du Pont | Cleaning composition of terpene compound and dibasic ester |
-
1991
- 1991-01-18 WO PCT/US1991/000594 patent/WO1991011269A1/en unknown
- 1991-01-23 IE IE22091A patent/IE910220A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO1991011269A1 (en) | 1991-08-08 |
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