IE872899L - Orange juice dispenser - Google Patents

Orange juice dispenser

Info

Publication number
IE872899L
IE872899L IE872899A IE289987A IE872899L IE 872899 L IE872899 L IE 872899L IE 872899 A IE872899 A IE 872899A IE 289987 A IE289987 A IE 289987A IE 872899 L IE872899 L IE 872899L
Authority
IE
Ireland
Prior art keywords
concentrate
water
juice
conduit
canister
Prior art date
Application number
IE872899A
Other versions
IE60558B1 (en
Original Assignee
Coca Cola Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Coca Cola Co filed Critical Coca Cola Co
Publication of IE872899L publication Critical patent/IE872899L/en
Publication of IE60558B1 publication Critical patent/IE60558B1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D3/00Apparatus or devices for controlling flow of liquids under gravity from storage containers for dispensing purposes
    • B67D3/04Liquid-dispensing taps or cocks adapted to seal and open tapping holes of casks, e.g. for beer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/08Details
    • B67D1/12Flow or pressure control devices or systems, e.g. valves, gas pressure control, level control in storage containers
    • B67D1/1202Flow control, e.g. for controlling total amount or mixture ratio of liquids to be dispensed
    • B67D1/1234Flow control, e.g. for controlling total amount or mixture ratio of liquids to be dispensed to determine the total amount

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Devices For Dispensing Beverages (AREA)
  • Beverage Vending Machines With Cups, And Gas Or Electricity Vending Machines (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

A postmix juice dispensing system for reconstituting and dispensing pliable 5 + 1 orange juice at freezer temperatures of about -10 DEG F (-23 DEG C) to 0 DEG F (-18 DEG C), including a pressurizable canister (32) for pressurizing concentrate in a flexible bag (30) for forcing the concentrate through a concentrate conduit (38) into a heat exchanger (40) then into a metering device (20) and then into a mixing chamber (16) where the concentrate mixes with water fed also through a metering device. [EP0266201A1]

Description

v ' 6 C 5 5 8 This invention relates to juice dispensing and in a preferred embodiment to dispensing orange juice from 5 4-1 concentrate (5 parts water to 1 part concentrate) at ~10°F to O'F. 5 Postmix orange juice dispensing systems are known for example from FR 2126102. Orange juice concentrate is distributed frosea. Restaurants remove concentrate from the freeser and thaw the concentrate in a cooler prior to dispensing. The restaurant has to estimate its -j o juice requirements at least two days in advance and place sufficient concentrate in its cooler. If the restaurant's estimates are incorrect or if someone forgetsthe restaurant will run out of thawed concentrate. Also,, there is often a limited amount of .j 5 cooler space available for thawing orange juice concentrate, when a restaurant runs out of thawed concentrate,, measures are sometimes taken to quickly thaw frosen concentrate and such measures often are inefficient and ineffective and also sometimes affect 2q the taste of the resulting product. Orange juice concentrate has typically been 3+1 concentrate. The present invention is useful with 5+1 concentrate. The reduced amount of water in 5 + 1 concentrate prevents a phase change or freesingP at typical freeser 25 temperatures of -10'F (-23" C) to (TP (~18"C)... The 5+1 concentrate at freeser temperatures does not readily flow by gravity. A container of 0"F (-18*C) product can be inverted and no product will flow out. Alsothe product is so thick that a pump's suction cannot pull product from the container. However, the product is still pliable.
Viewed from one aspect the present invention provides apparatus for reconstituting and dispensing 30 3 juice comprising: (a) a canister arranged to hold and dispense a quantity of juice concentrate? (b) a mixing chamber and a nozzle for dispensing 5 a beverage therefrom; (c) a concentrate conduit extending from said canister to said mixing chamber; (d) a water conduit extending into said mixing chamber; and 10 (e) metering means in said conduits for controlling the ratio of water to concentrate fed to said mixing chamber, characterised in that said canister is pressurizable and is arranged to dispense pliable juice 15 concentrate at a temperature be lot? 32 "F (0" C) f means are provided for pressurising said canister so that pressure in said canister forces concentrate into said concentrate conduitt and means for heating concentrate in said concentrate conduit are provided. 2o According to a second aspect of the invention,, there is provided a method of reconstituting and dispensing juice comprising: (a) forcing juice concentrate out of container into a concentrate conduit? 25 (b) feeding the concentrate to a metering device; (c) feeding water to a metering device; and (d) feeding a controlled ratio of water to concentrate to a mixing chamber. characterised in that the juice is pliable and is forced at a temperature of below 32 "F (0*C) out of the container which is in the form of a bag and by the step of heating the concentrate in said concentrate conduit to above 32"? (G'C) . 30 In a preferred form the invention provides a postmix beverage dispensing system for dispensing S + 1 concentrate at freeser temperatures from a flexible bag including placing the bag in a rigid, pressurizable container,, pressurizing the container to force concentrate out of the bag, feeding concentrate through a heat exchanger to raise the temperature to about 32°F (0°C) to 40°F (4°C)c. feeding the thawed concentrate to a metering device along with water for controlling the mixture rati©,, and then feeding the water and concentrate to a mixing chamber of a dispensing valve for dispensing the fixture as an orange juice beverage into a cup. The concentrate bag preferably incorporates a dip tube or dip strip with slots larger than the pulp in the concentrate and with an internal cross-sectional area much greater than that of the slots to facilitate flowing of 'the concentrate and, to reduce pressure drops. The tube prevents the bag from blocking the internal passageway therethrough.
Concentrate emerging from the bag can be as cold as ~10°P (~23°C)« The heat exchanger can use recirculating soda water and a heating element to prevent the water frosa freezing. The proper portioning of water and orange juice concentrate during reconstitution preferably incorporates a volumetric piston pump operated by the pressurised water. Alternatively, the water and orange juice concentrate can be metered by use of a flow meter to measure the water flow rate and a volumetric pump with motor drive at a fixed speed to meter the concentrate. Control electronics, such as a microcontroller,can regulate the water flow rate by use .of a motorized control valve. 2he concentrate pump's motor can be adjustable and the control electronics can then also or alternatively regulate the speed of the pump motor depending on the water flow rate. The 5 actual reconstituting of the metered water and concentrate can incorporate either a static or a dynamic mixer.
Some embodiments of the invention will now described 5 by way of example and with reference to the accompanying drawings, in which: FIG. I is a partly diagrammatic^ partly schematic illustration of a postanix juice dispensing system according to the present invention; 10 FIG- 2 is a partly diagrammatic,, partly schematic * ** illustration of another embodiment of a postmix juice dispensing system according to the invention; FIG. 3 is a partly cross-sectional, partly diagrammatic,, partly schematic illustration of a 15 metering system for use in a system of the present invention? FIG. 4 is a perspective view of an orange juice concentrate container for use in shipping- and storing orange juice concentrate at freeser temperatures; 20 FIG. 5 is a partial, cross-sectional view through a concentrate bag, spout and dip tube? FIG. S is a partial, cross-sectional view through the top of a pressurizable canister or vessel for holding the flexible concentrate bag; and 25 FIG. 7 is a partly diagrammatic, partly schematic illustration of another embodiment of a postmix juice dispensing system according to the present invention.
With reference now to the drawings, FIG. 1 shows a postmix juice dispensing system 10 for dispensing a 6 finished juice beverage from a nozzle 12 of a mixing chamber 16 into a cup 14. The system 10 feeds water and juice concentrate, in a desired ratio., for example, S parts of water to 1 part of concentrate, into the 5 mixing chamber 16 wherein complete mixing of the concentrate and 'water takes place.
The water is fed through a water conduit 10 to a metering device 20 and then to the mixing chamber 16.
The concentrate is contained in a concentrate 10 bag 30 at freezer temperatures of about -10°? (-23°C) to about 0°P (-18°C). The bag 30 is preferably a nonreturnableP flexible bag. The bag 30 is removed fross, a freezer and placed in a rigid,, pressurizable canister 32 which is then pressurized toy a pressure source (such as a CO or 15 compressed air cylinder 34) and a pressure regulator 36. The pressure forces the concentrate., which is sot froze® (it has not undergone a phase changeJ because of its low water content but which is pliable, through a concentrate conduit 38 to a heat 20 exchanger 40, then to the metering device 20, and then to the mixing chamber IS.
This design allows dispensing of a 5 1 concentrate at freezer temperatures. The pliable concentrate contained in the flexible foacp 30 is 25 preferably shipped in a cylindrical container 41 (see FIG. 4) to facilitate insertion of the bag 30 into the cylindrical canister 32. The restaurant simply inserts the frozen bag 30 directly fro^s, the freezer into the canister 32, without, requiring any thawing. 30 ETIG. 5 is a partial view ©£ the bag 30 showing a dip tube or strip 42 connected to a spout 43. The dip •strip 42 includes a central passageway 44 and a plurality of openings 46 into the passageway 44. The openings 46 are of a size sufficiently large to allow pulp to pass into the passageway 44 while preventing 1 the bag from entering into and blocking the passageway 44. The larger cross-sectional area of the passageway 44 facilitates flowing of the concentrate and reduces pressure drops due to friction.
The canister 32 is shown iri more detail in FIG. 6 and includes a removable lid 48 that hermetically seals to the wall 49 of the canister The lid 48 includes a fitting 50 for pressurizing the canister 32 (with CO^ or air5 for example) and a concentrate fitting 52 for connecting the spout 43 of the bag 30 Ho the concentrate conduit 38.
As stated above, the concentrate in the bag 30 is preferably 5 + 1 concentrate. The canister is preferably pressurised to about 40 psig. This pressure forces the concentrate out of the bag to the heat exchanger 40 and then to the metering device 20 and finally to the mixing chamber 16.
The heat exchanger 40 includes a heat.-source 60 and can be any known type of heat exchanger and heat source. The heat exchanger preferably elevates the temperature of the concentrate to about 32°F (0°C) to 40°F (4°C).
The heat source 60 can be a thermostatically controlled electrical heating element.
The metering device 20 (which can be any known type of metering device) provides the proper portioning of the water and orange juice concentrate. The device 20 can use two connected double-acting pistons in a volumetric piston pump for each of the water and concentrate conduits. The ratio of the volume of the vater chambers to the concentrate chambers is the same as the desired mixture ratio, such as, for example 5:1 .(water to concentrate}. The water pistons can be connected to the concentrate pistons so that the pressurised water can be used to operate both pumps.
Hie system of FIG. 1 also includes a solenoid on-off valve 19 in the water line, operated by a microcontroller 64. When it is desired to dispense a drink,, for example when a cup 14 engages a lever 15, the microcontroller 64 causes the valve 19 to open, and when dispensing is completed, it closes the valve 19.
In addition, the microcon'croller S4 also operates the inlet arad outlet valves for the water and concentrate to and from the metering device 20.. in response,, for example, to sensed positions of the pistons. Volumetric piston pumps are well-known and thus need not be described in detail here.
FIG. 2 shows a preferred embodiment of the systfjm of FIG. 1 in which a recirculating water conduit 59 is in heat exchange relationship to the concentrate conduit 38, in addition to the use of separate heat source 60. The water conduit 59 can be a recirculating soda water line available in the restaurant, for example. The heat source 60 prevents the water from freesiiag,.
In addition, FIG. 2 shows a particular metering device 20 which can be used. FIG. 2 shows a water pump 65 with two connected pistons, connected in turn to two connected pistons of a concentrate pump 66. A water control valve 67 of the water pump is mechanically operated by a linkage 68 connected to a reciprocating shaft 69 connecting to the two water pistons. Inlet and outlet valves 70 of the concentrate pump 66 are preferably controlled by the microcontroller 64 in response to sensed positions of the concentrate pistoas™ In FIG. 1, the sensing of the positions of the pistons is shown at 62, and the control of the islet and outlet valves at 61.
§ FIG. 3 shows an alternative means for metering the water and the orange juice concentrate. This means includes a flow meter 80 in the water conduit 18 for measuring the water flow rate; electrical pulses whose 5 period is proportional to the water flow rate are inputted into a microcontroller 82. A volumetric pump 84 meters the concentrate through the concentrate conduit 38. The concentrate: pump 84 incorporates two chambers 85 and 87 with connected pistons 88 and 89. 10 Each piston stroke finds one piston expelling a fixed volume of concentrate while the attached chamber is filling with concentrate. A motor 90 moves the pistons 88 and 89. The motor speed can be fixed. The water flow rat® is controlled by means of a variable 15 size corixice in a motorized control valve 92 operated by a DC stepping motor 94. The microcontroller 82 controls the motor 94 to regulate the water flow rate.
Alternatively, "the motor 90 can be adjustable with the microcontroller 82 regulating the speed of the 20 motor 90 to control the concentrate flow rate depending on the water flow rate as measured by the flow meter 80, to control the mixture ratio. The microcontroller ©2 can also control both the motor 90 and the control valve 92. 25 FIG. 7 shows another embodiment of the present invention of a dispensing system 100 in which the concentrate is fed to a vented reservoir 102- FIG. 7 shows a water conduit 104 corrected to a mixing chamber 103 and having a water flow meter 105, a 30 motorized control valve 106 operated by a B.C. stepping motor 108, and a solenoid controlled on-off valve 110.
FIG. 7 also shows a concentrate conduit 114 which feeds pliable concentrate jTstomj a flexible container 116 in a, pressurised canister 118, through a heat 35 exchanger 120 (including a heat source 99 and a 10 recirculating soda water line 101}, through a solenoid controlled on-off valve 122, to the reservoir 102. The reservoir 102 includes high and low level indicators 126 and 128, respectively, connected to a 5 microcontroller 130, which "opens and closes 'the on-off valve 122 in response to signals from the level indicators. A concentrate conduit 132 extends from the reservoir 102 to a flexible vane pump 134 (or a gerotor pump, for example), and then to the mixing chamber 103 10 where it mixes with the water to form a final beverage which is dispensed fro® a nozzle 136 into a cup 133.
In addition to the microcontroller 130 controlling the level of concentrate in the reservoir 102, it also controls the speed of a D.C. motor 140 with encoder 142 15 to control the concentrate flow rate, and it controls the water flow rate by controlling the motorized water control valve 106 in response to signals from the water flow meter 105. The microcontroller 130 also controls the solenoid controlled,, water on-off valve 110 in 20 response to actuation of the dispensing system 100,, such as by the cup 138 engaging a lever arm 152.
While preferred embodiments of this invention has been described in detail, it is to be understood that variations and modifications can be made therein 25 without departing frois, the scope of the present invention as set forth in the appended claims. For example, this invention can be used with various juices other than the preferred orange juice. Also, ■che juice can be thawed juice, such as thawed 3*1 30 juice; that is, this invention is not limited to use with pliable 5*1 concentrate at freezer temperatures. Also, the preferred temperature ranges are only preferred, other fress^r temperatures belcw 32°F (0°C) can be used, and the heat exchanger, can raise the temperature 35 to any desired temperature above 32°P (0#C). Also, the heat 11 exchanger can include a water conduit, such as a recirculating soda water line that is available in the restaurant, in heat exchange relationship thereto.
It will thus be seen that the present invention, at least in its preferred forms,, provides a postmix juice dispensing system for use with 5+1 concentrate at freezer temperatures ? and furthermore provides a postmix juice dispensing system for use with 5+1 concentrate at freezer temperatures in which the concentrate is contained in a flexible bag which is then placed in a pressurizable vessel which is pressurised to about 40 psig to force concentrate out of the bag; and furthermore provides a postxuix juice dispensing system for dispensing 5+1 concentrate at freezer temperatures including elevating the concentrate temperature to about 32"F (0*C) to 40°F (4°C) « forcing the thawed concentrate to a metering device, and then feeding the thawed and metered concentrate to a mixing chamber of a dispensing valve? and furthermore provides a postmix juice dispensing system in which 5+1 concentrate at freezer temperatures is placed in a flexible bag in a pressurizable vessel and forced by pressure out of the flexible bag, fed through a heat exchanger, then fed through a Metering device,, and finally fed to a mixing chamber of a dispensing valve? and furthermore provides a juice dispensing system for any juice or syrup which has been cooled but which has not experienced a phase change froii liquid to solid. it

Claims (10)

1. CLAIMS: 1. Apparatus for reconstituting and dispensing juice, comprising: (a) a canister arranged to hold and dispense a quantity of juice concentrate? (b) a mixing chamber and a nozzle for dispensing a beverage therefrom? (c) a concentrate conduit extending from said canister to said mixing chamber; (d) a water conduit extending into said mixing chamber ; and (®) metering means in said conduits for controlling the ratio of water to concentrate fed to said mixing chamber , characterised in that said canister is pressurizable and is arranged to dispense pliable juice concentrate at a temperature below 32"F (O'C), means are provided for pressurizing said canister ■ so that pressure in said canister forces concentrate into said concentrate conduit. and means for heating concentrate in said concentrate conduit are provided.
2. Apparatus as claimed in claim 1 wherein said heating means includes a recirculating water conduit located in heat exchange relationship to said concentrate conduit.
3. Apparatus as claimed in claim 1 or 2 wherein said metering means comprises a volumetric piston pump in at least one of said concentrate conduit and said water conduit.
4. Apparatus as claimed in claim 3 including a volumetric piston pump in each of said conduits , and wherein the ratio of the pump volumes is the desired mixture ratio.
5. Apparatus as claimed in claim 1 or 2 wherein said metering means includes a microcontroller , a flow meter in said water line, and a motorized control 13 valve in said water line , said flow meter and motorized control valve being connected to said microcontroller .
6. Apparatus as claimed in claim 5 including a 5 concentrate reservoir, means for autoincitically maintaining said reservoir filled with concentrate, said concentrate conduit feeding concentrate from said heating means to said reservoir, and means for feeding a controlled 10 volume of concentrate from said reservoir to said mixing chamber during dispensing.
7. Apparatus as claimed in claim 5 wherein said feeding means comprises a pump and a D.C. motor with an encoder connected to said 15 microcor.trol ler.
8. Apparatus as claimed in claim 7 wherein said pump is a flexible vane pump.
9. Apparatus as claimed in claim 1 or 2 including a solenoid controlled on-off valve in said water 20 line.
10. Apparatus as claimed in any preceding claim wherein said pressurizable canister includes a removable lid and a bag of pliable juice concentrate located in said canister. 25 11- Apparatus as claimed in claim 10 wherein said bag of concentrate is at a temperature of from about = 10"F (-23"C) to 0 * F (-18"C) .;12. Apparatus as claimed in any preceding claim wherein said pressuring means includes a pressurised C02 source;3q and a pressure regulator-;13. A method of reconstituting and dispensing juice comprising:;(a) forcing juice concentrate out of container into . & concentrate conduit;;i;(b) feeding the concentrate to a metering device;;35;(c) feeding water to a metering device; and;14;(d) feeding a controlled ratio of water to concentrate to a fixing chamber ,;characterised in that the juice is pliable and is forced at a temperature of below 32 "F (0"C) out of the container which is in the form of a bag and by the step of heating the concentrate in said concentrate conduit to above 32 "F (0"C) -;14- A method as claimed in claim 13 wherein said juice is 5 + 1 orange juice and said forcing step comprises placing a flexible bag of said, concentrate at a temperature off from about ~10"F (~23"C) to 0"F (-18*C) in a pressurizable canister and pressurizing said canister with co2 at about 40 psig. 15. Apparatus as claimed in claim 1, substantially as hereinbefore described with particular reference to and as illustrated is the accompanying drawings. 16. A method as claimed in claim 13, substantially as hereinbefore described with particular reference to and as illustrated in the accompanying drawings. F. R. KELLY & CO., AGENTS FOR THE APPLICANTS
IE289987A 1986-10-29 1987-10-28 Post-mix juice dispensing system IE60558B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US92438186A 1986-10-29 1986-10-29

Publications (2)

Publication Number Publication Date
IE872899L true IE872899L (en) 1988-04-29
IE60558B1 IE60558B1 (en) 1994-07-27

Family

ID=25450150

Family Applications (1)

Application Number Title Priority Date Filing Date
IE289987A IE60558B1 (en) 1986-10-29 1987-10-28 Post-mix juice dispensing system

Country Status (10)

Country Link
EP (1) EP0266201B1 (en)
JP (1) JPS63211489A (en)
KR (1) KR880005027A (en)
AU (1) AU607440B2 (en)
CA (1) CA1302366C (en)
DE (1) DE3776753D1 (en)
HK (1) HK63493A (en)
IE (1) IE60558B1 (en)
NZ (1) NZ222325A (en)
SG (1) SG42693G (en)

Families Citing this family (10)

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Publication number Priority date Publication date Assignee Title
US4886190A (en) * 1986-10-29 1989-12-12 The Coca-Cola Company Postmix juice dispensing system
US4860923A (en) * 1986-10-29 1989-08-29 The Coca-Cola Company Postmix juice dispensing system
EP0387477A1 (en) * 1989-03-16 1990-09-19 ROPA Wasseraufbereitungs-anlagenbau Gesellschaft m.b.H. Method for preparing fixed amounts of mixed drinks, and device for carrying out the method
US5012955A (en) * 1989-10-30 1991-05-07 Abc/Sebrn Techcorp. Syrup dispensing system
DE3940876A1 (en) * 1989-12-11 1991-06-13 Bosch Siemens Hausgeraete DRIVE DEVICE IN A LIQUID DISPENSING DEVICE, IN PARTICULAR IN A DRINKING MACHINE
DE3940879C1 (en) * 1989-12-11 1991-08-08 Bosch-Siemens Hausgeraete Gmbh, 8000 Muenchen, De
US5305923A (en) * 1990-06-06 1994-04-26 The Coca-Cola Company Postmix beverage dispensing system
US5494193A (en) * 1990-06-06 1996-02-27 The Coca-Cola Company Postmix beverage dispensing system
DE4108586A1 (en) * 1991-03-14 1992-09-17 Schenk Helga ARRANGEMENT FOR PUMPING AND DISPENSING HIGH VISCOSITY LIQUIDS OR THE LIKE
ES2127083B1 (en) * 1995-04-03 1999-11-16 Ascaso Carmelo Cepero IMPROVEMENTS INTRODUCED IN THE PURPOSE OF PATENT N-9500658, FROM CONCENTRATE DISPENSER FOR JUICE SUPPLIERS.

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FR1063927A (en) * 1951-07-16 1954-05-10 Baele Sa Usine Dosing and mixing device
DE1245156B (en) * 1962-02-16 1967-07-20 Licentia Gmbh Arrangement for automatic mixing of liquids
FR2126102A1 (en) * 1971-02-25 1972-10-06 Boujarel Gabriel Syrup proportioning device - for mfr of refreshing beverages
IT1101304B (en) * 1978-12-04 1985-09-28 Molinari & Tansini DISPENSER-DOSER OF FLUIDS, PARTICULARLY SUITABLE FOR THE FORMATION OF DRINKS BASED ON DENSY OR SEMI-DENSE AND SIMILAR LIQUIDS
US4487333A (en) * 1982-02-26 1984-12-11 Signet Scientific Co. Fluid dispensing system
JPS5927389A (en) * 1982-08-02 1984-02-13 ザ・コカ−コ−ラ・カンパニ− Method of conveying and cooking condensed syrup and mount used therefor
DE8414000U1 (en) * 1984-05-09 1986-08-14 Coca Cola Gmbh, 4300 Essen Dispenser for post-mix beverages
EP0172385B1 (en) * 1984-08-22 1990-01-03 Bosch-Siemens HausgerÀ¤te GmbH Device for mixing beverages
US4660741A (en) * 1985-05-24 1987-04-28 The Coca-Cola Company Water purification system and method for a post-mix beverage dispenser

Also Published As

Publication number Publication date
HK63493A (en) 1993-07-09
CA1302366C (en) 1992-06-02
AU8047387A (en) 1989-05-04
SG42693G (en) 1993-06-11
EP0266201B1 (en) 1992-02-19
JPS63211489A (en) 1988-09-02
AU607440B2 (en) 1991-03-07
NZ222325A (en) 1991-04-26
KR880005027A (en) 1988-06-27
EP0266201A1 (en) 1988-05-04
DE3776753D1 (en) 1992-03-26
IE60558B1 (en) 1994-07-27

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