IE870306L - Preparation of perhalomethanesulphinic and sulphonic acids. - Google Patents

Preparation of perhalomethanesulphinic and sulphonic acids.

Info

Publication number
IE870306L
IE870306L IE870306A IE30687A IE870306L IE 870306 L IE870306 L IE 870306L IE 870306 A IE870306 A IE 870306A IE 30687 A IE30687 A IE 30687A IE 870306 L IE870306 L IE 870306L
Authority
IE
Ireland
Prior art keywords
perhalomethanesulphinic
preparation
sulphonic acids
metal
alkaline
Prior art date
Application number
IE870306A
Original Assignee
Rhone Poulenc Chimie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Chimie filed Critical Rhone Poulenc Chimie
Publication of IE870306L publication Critical patent/IE870306L/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02—Sulfinic acids; Derivatives thereof
    • C07C313/04—Sulfinic acids; Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Catalysts (AREA)

Abstract

1. A process for the preparation of perhalomethanesulphinic acid salts of general formula (I) [X1 X2 FC - SO2 ]3-n M in which X1 and X2 represent an identical or different halogen atom chosen from F, Cl and Br, M represents an alkali metal or alkaline-earth metal, n is equal to 1 or 2 depending on the valency state of the metal M, characterized in that an alkali metal or alkaline-earth metal dithionite of general formula Mn (S2 O4 ) (II) in which n and M have the above meaning, or a hydroxymethanesulphinate is brought into contact with a perhalomethane in a polar solvent.
IE870306A 1986-02-06 1987-02-05 Preparation of perhalomethanesulphinic and sulphonic acids. IE870306L (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8601800A FR2593808B1 (en) 1986-02-06 1986-02-06 PROCESS FOR THE PREPARATION OF PERHALOGENOMETHANESULFINIC AND SULFONIC ACIDS AND THEIR SALTS

Publications (1)

Publication Number Publication Date
IE870306L true IE870306L (en) 1987-08-06

Family

ID=9331982

Family Applications (1)

Application Number Title Priority Date Filing Date
IE870306A IE870306L (en) 1986-02-06 1987-02-05 Preparation of perhalomethanesulphinic and sulphonic acids.

Country Status (9)

Country Link
EP (1) EP0237446B1 (en)
JP (1) JPS62192351A (en)
AT (1) ATE46503T1 (en)
CA (1) CA1280123C (en)
DE (1) DE3760583D1 (en)
ES (1) ES2011055B3 (en)
FR (1) FR2593808B1 (en)
GR (1) GR3000165T3 (en)
IE (1) IE870306L (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2649099B1 (en) * 1989-05-02 1991-10-25 Rhone Poulenc Chimie PROCESS FOR THE PURIFICATION OF TRIFLUOROMETHANESULFINATE AND SODIUM SULFONATE
FR2660923B1 (en) * 1990-04-13 1992-07-03 Rhone Poulenc Chimie REAGENT AND METHOD OF PERHALOGENOALKYLATION FOR NUCLEOPHILE USING SULFUR DIOXIDE.
FR2661409A1 (en) * 1990-04-27 1991-10-31 Rhone Poulenc Chimie Process for the purification of sodium trifluoromethanesulphinate and -sulphonate
SK286140B6 (en) * 1995-03-24 2008-04-07 Rhone-Poulenc Agrochimie Reagent for use in the preparation of organic sulphoxylated and fluorinated derivatives and process for their preparation
FR2732016B1 (en) * 1995-03-24 1997-06-20 Rhone Poulenc Chimie REAGENT AND METHOD FOR THE SYNTHESIS OF ORGANIC OXYSULFIDE AND FLUORINATED DERIVATIVES
US6464895B2 (en) 1995-03-24 2002-10-15 Rhodia Chimie Reagent and process which are useful for grafting a substituted difluoromethyl group onto a compound containing at least one electrophilic function
FR2743067B1 (en) * 1995-12-29 1998-03-27 Rhone Poulenc Chimie REAGENT AND METHOD FOR THE SYNTHESIS OF ORGANIC OXYSULFIDE AND FLUORINATED DERIVATIVES
FR2751961B1 (en) * 1996-08-01 1998-09-11 Rhone Poulenc Chimie PROCESS FOR THE SYNTHESIS OF OXYSULFIDE AND FLUORINATED ORGANIC DERIVATIVES
CN1230940A (en) * 1996-08-01 1999-10-06 罗狄亚化学公司 Method for grafting substituted difluoromethyle group
JP2002275151A (en) * 2001-03-21 2002-09-25 Dainippon Ink & Chem Inc Purification of sulfonic acid compound
JP4494044B2 (en) * 2004-03-05 2010-06-30 東ソ−・エフテック株式会社 Method for purifying fluorine-containing alkylsulfinate
JP5151389B2 (en) * 2006-10-24 2013-02-27 セントラル硝子株式会社 Process for producing alkoxycarbonylfluoroalkanesulfonates
FR2924116B1 (en) * 2007-11-27 2010-02-26 Rhodia Operations PROCESS FOR THE PREPARATION OF A TRIFLUOROMETHANESULFINIC ACID SALT
JP5471121B2 (en) 2008-07-30 2014-04-16 セントラル硝子株式会社 Method for producing perfluoroalkanesulfinate
FR3029519B1 (en) * 2014-12-09 2018-08-31 Rhodia Operations PROCESS FOR THE PREPARATION OF OXYSULFIDE AND FLUORINE DERIVATIVES IN THE PRESENCE OF AN ORGANIC SOLVENT
CN106748916A (en) * 2016-12-28 2017-05-31 江苏托球农化股份有限公司 A kind of production technology of Sodium trifluoromethanesulfinate
CN112457227A (en) * 2020-12-03 2021-03-09 江苏优普生物化学科技股份有限公司 High-quality sodium trifluoromethanesulphinate synthesis process

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2564829B1 (en) * 1984-05-23 1987-08-14 Rhone Poulenc Spec Chim PROCESS FOR THE PREPARATION OF TRIFLUOROMETHYLIC ACIDS

Also Published As

Publication number Publication date
CA1280123C (en) 1991-02-12
GR3000165T3 (en) 1990-12-31
DE3760583D1 (en) 1989-10-26
FR2593808B1 (en) 1988-07-29
ES2011055B3 (en) 1989-12-16
ATE46503T1 (en) 1989-10-15
JPS62192351A (en) 1987-08-22
JPH0120145B2 (en) 1989-04-14
EP0237446B1 (en) 1989-09-20
EP0237446A1 (en) 1987-09-16
FR2593808A1 (en) 1987-08-07

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