IE58634B1 - Novel reinforced fluoropolymer composite and method for making same - Google Patents
Novel reinforced fluoropolymer composite and method for making sameInfo
- Publication number
- IE58634B1 IE58634B1 IE93184A IE93184A IE58634B1 IE 58634 B1 IE58634 B1 IE 58634B1 IE 93184 A IE93184 A IE 93184A IE 93184 A IE93184 A IE 93184A IE 58634 B1 IE58634 B1 IE 58634B1
- Authority
- IE
- Ireland
- Prior art keywords
- substrate
- fluoroelastomer
- composite
- composite according
- blend
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Glass Compositions (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Paints Or Removers (AREA)
Abstract
A novel composite comprises a substrate having a coating matrix including an initial layer of a perfluoropolymer and an overcoat comprising a fluoroelastomer, a fluoroplastic, a fluoroelastomer/fluoroplastic blend, or a combination thereof. The perfluoropolymer in the initial layer may be a perfluoroplastic, a perfluoroelastomer, or blends thereof. In a separate embodiment, the novel composite includes a substrate coated solely with one or more layers of perfluoroelastomer alone or as a blend with a perfluoroplastic. Where the substrate is not susceptible to hydrogen fluoride corrosion, the composite may include solely one or more layers of a blend of a fluoroelastomer and a hydrogen-containing perfluoroplastic. Cross-linking accelerators may be used to cross-link one or more of the resins contained in the coating layers. Each composite may be topcoated with the layer or layers of a fluoroplastic, fluoroelastomer, and/or a blend thereof. The composite is flexible, exhibits good matrix cohesion and possesses substantial adhesion of the matrix to the material acting as the reinforcement or substrate. A method for making such a composite comprises the unique deployment of a perfluoropolymer directly onto the substrate in a relatively small amount sufficient to protect the substrate from chemical corrosion without impairing flexibility, followed by the application of the overcoat layer.
Description
This invention relates to new and useful fluoro-
Claims (23)
1. A composite having a low modulus of stiffness and good chemical resistance which comprises a substrate coated with a matrix comprising: 5 a) fin initial layer of a perfluoropolymer selected from a perfluoroplastic, a perfluoroelastomer, a blend of perfluoroplastic and perfluoroelastomer, said initial layer being applied as a relatively light coating to maintain a low stiffness modulus for the composite and 10 to provide the substrate with chemical resistance; and b) an overcoat layer of a fluoroelastomer, a fluoroelastomer/fluoroplastic blend, said fluoroelastomer comprising from 10% to 90% by weight of the blend, or a combination thereof. 15
2. A composite according to claim 1 wherein said initial layer is applied to the substrate in an amount sufficient to provide chemical resistance while at the same time leaving any openings in the substrate substantially open so as to maintain flexibility. 20
3. A composite according to claim 1 wherein the initial layer comprises a perfluoropolymer and a lubricating agent.
4. A composite according to claim 1 wherein the substrate is treated with a coupling agent to promote 25 bonding.
5. A composite according to claim 1 wherein said fluoroelastomer comprises from 25% to 60% by weight of said blend.
6. A composite according to claim 1 wherein an 30 intermediate layer comprising a fluoroelastomer is interposed between said initial layer and said overcoat layer.
7. A composite according to claim 1 having a topcoat selected from a fluoroplastic, a fluoroelastomer, a fluoroplastic/fluoroelastomer blend or a combination thereof.
8. A composite according to claim 1 wherein resins in said layers, are at least partially cross-linked.
9. A composite according to claim 1 wherein only one face of said substrate is coated with a matrix.
10. A composite according to claim 1 wherein said substrate is reinforcement material capable of withstanding composite formation temperatures.
11. A composite according to claim 10 wherein said substrate is a yarn, filament, monofilament, or other fibrous material.
12. A composite according to claim 10 wherein said substrate is a textile selected from woven and non-woven materials.
13. A composite according to claim 1 or 10 wherein said substrate is selected from glass, fibreglass, ceramics, graphite, polybenzimidazole, polyaramides, PTFE, metal, polyolefins, polyesters, polyamides, copolymers of TFE, polyether sulfones, polyimides, polyether ketones, polyethenimides, novoloid phenolic fibers, natural and synthetic textiles.
14. A composite according to claim 1 or 7 wherein said fluoroplastic comprises PTFE, PFA, or FEP.
15. A composite according to claim 1 or 7 wherein said fluoroelastomer is selected from copolymers of vinylidene fluoride and at least one other fluorinated monomer selected from hexafluoropropylene; tetrafluoroethylene; chlorotrifluoroethylene; and pentafluoropropylene.
16. A composite according to claim 1 wherein said perfluoroelastomer comprises a copolymer of TFE and perfluorovinylether such as PMVE or PPVE.
17. A composite according to claim 1 wherein any fluoropolymer component may contain a functional group selected from carboxyl and sulfonic acid and salts thereof, halogen, and a reactive hydrogen on an alkyl 5 side chain.
18. A method for the manufacture of a composite including a substrate coated with a matrix, wherein the said matrix is formed by a gradation of fluoropolymer layers, which comprises the steps of: 10 i) first applying an initial layer comprising a perfluoropolymer in an amount sufficient to substantially shield the substrate from chemical corrosion without impairing flexibilty; ii) thereafter applying to said initial layer an 15 overcoat layer comprising a fluoroelastomer, a fluoroelastomer/fluoroplastic blend comprising 10-90% by weight of the fluoroelastomer, or a combination thereof.
19. A method according to claim 18 wherein said initial layer comprises a perfluoropolymer, a lubricating 20. Agent, and a coupling agent.
20. A method according to claim 18 wherein the outermost layer is applied as a foam.
21. A composite according to claim 1, substantially as hereinbefore described and exemplified. 25
22. A method according to claim 18 for the manufacture of a composite including a substrate coated with a matrix, substantially as hereinbefore described and exemplified.
23. a composite including a substrate coated with a matrix, whenever manufactured by a method claimed in a
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48459483A | 1983-04-13 | 1983-04-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE840931L IE840931L (en) | 1984-10-13 |
| IE58634B1 true IE58634B1 (en) | 1993-10-20 |
Family
ID=23924791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE93184A IE58634B1 (en) | 1983-04-13 | 1984-04-13 | Novel reinforced fluoropolymer composite and method for making same |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0125955B1 (en) |
| JP (1) | JPS6046244A (en) |
| AT (1) | ATE46730T1 (en) |
| AU (1) | AU575320B2 (en) |
| BR (1) | BR8401745A (en) |
| CA (1) | CA1264618A (en) |
| DE (2) | DE3479906D1 (en) |
| DK (3) | DK193284A (en) |
| ES (1) | ES8706334A1 (en) |
| FI (1) | FI841492A (en) |
| IE (1) | IE58634B1 (en) |
| IL (1) | IL71547A (en) |
| NO (1) | NO163600C (en) |
| ZA (1) | ZA842785B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62189153A (en) * | 1985-10-07 | 1987-08-18 | 株式会社クラレ | Waterproof cloth and manufacture thereof |
| US4946736A (en) * | 1987-08-06 | 1990-08-07 | W. L. Gore & Associates, Inc. | Protective electromagnetically transparent window |
| DE3807904A1 (en) * | 1988-03-10 | 1989-09-21 | Behringwerke Ag | MAGNETIC PROTEIN CONJUGATES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE |
| GB8913628D0 (en) * | 1989-06-14 | 1989-08-02 | Courtaulds Plc | Flexible coated substrate |
| US5484173A (en) * | 1994-09-12 | 1996-01-16 | Garlock Inc. | Flowing arch expansion joint using FEP liner bonded to fiberglass fabric layer and reinforced with plurality of fabric plies covered with elastomeric outer layer |
| BR0107915A (en) | 2000-01-19 | 2002-11-05 | Chemfab Corp | Uncoiled composite membranes with different opposite faces, methods for producing them and their use in various applications |
| US7927684B2 (en) | 2000-01-19 | 2011-04-19 | Saint-Gobain Performance Plastics Corporation | Low coefficient of friction polymer film |
| US20100044382A1 (en) * | 2008-08-22 | 2010-02-25 | Saint-Gobain Performance Plastics Corporation | Fluoropolymer coated article |
| MX2011006681A (en) * | 2008-12-22 | 2011-07-12 | Saint Gobain Performance Plast | Modified perfluoropolymer sheet material and methods for making same. |
| US8673449B2 (en) * | 2009-12-18 | 2014-03-18 | Saint-Gobain Performance Plastics Corporation | Cooking release sheet materials and release surfaces |
| JP2011189309A (en) * | 2010-03-16 | 2011-09-29 | Yoshida Skt:Kk | Method for producing fluororesin material, and fluororesin material |
| JP2019515817A (en) * | 2016-03-21 | 2019-06-13 | サン−ゴバン パフォーマンス プラスティックス コーポレイション | Architectural membrane |
| KR102270374B1 (en) | 2016-10-24 | 2021-07-01 | 생-고뱅 퍼포먼스 플라스틱스 코포레이션 | Polymer Compositions, Materials and Methods of Making |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3019206A (en) * | 1958-09-24 | 1962-01-30 | Minnesota Mining & Mfg | Polyblends of a thermoplastic tetrafluoroethylene polymer latex and an elastomeric fluorocarbon polymer latex and article coated therewith |
| US3790403A (en) * | 1972-01-13 | 1974-02-05 | Du Pont | Glass fabric coated with crack-free fluorocarbon resin coating and process for preparing |
| IT977430B (en) * | 1972-03-27 | 1974-09-10 | Pennwalt Corp | PROCESS FOR THE PRODUCTION OF FABRIC COVERED WITH A COMPOSITION OF POLYTETRAPHY ETHYLENE AND GLASS BEADS PRODUCT OBTAINED AND COMPOSITION USED |
| JPS5419910B2 (en) * | 1973-12-03 | 1979-07-18 | ||
| GB1544099A (en) * | 1975-08-11 | 1979-04-11 | Occidental Petroleum Corp | Flash pyrolysis of organic solid waste |
| FR2334733A1 (en) * | 1975-12-09 | 1977-07-08 | Ugine Kuhlmann | PROCESS FOR BONDING A FIBROUS SUBSTRATE ON VINYLIDENE POLYFLUORIDE |
| DE2601569B1 (en) * | 1976-01-16 | 1977-06-08 | Chem Fab Corp | Process for the production of a smooth, non-porous coating made of fluoropolymers on a textile-like substrate |
| JPS6016345B2 (en) * | 1976-11-09 | 1985-04-25 | 旭硝子株式会社 | Synthetic resin laminate with excellent weather resistance and corrosion resistance |
-
1984
- 1984-04-13 DE DE8484400741T patent/DE3479906D1/en not_active Expired
- 1984-04-13 CA CA000452005A patent/CA1264618A/en not_active Expired - Lifetime
- 1984-04-13 DE DE198484400741T patent/DE125955T1/en active Pending
- 1984-04-13 JP JP59074838A patent/JPS6046244A/en active Granted
- 1984-04-13 AU AU27252/84A patent/AU575320B2/en not_active Ceased
- 1984-04-13 EP EP84400741A patent/EP0125955B1/en not_active Expired
- 1984-04-13 IL IL71547A patent/IL71547A/en not_active IP Right Cessation
- 1984-04-13 IE IE93184A patent/IE58634B1/en not_active IP Right Cessation
- 1984-04-13 ZA ZA842785A patent/ZA842785B/en unknown
- 1984-04-13 NO NO841501A patent/NO163600C/en unknown
- 1984-04-13 DK DK193284A patent/DK193284A/en not_active Application Discontinuation
- 1984-04-13 FI FI841492A patent/FI841492A/en not_active Application Discontinuation
- 1984-04-13 ES ES531602A patent/ES8706334A1/en not_active Expired
- 1984-04-13 AT AT84400741T patent/ATE46730T1/en not_active IP Right Cessation
- 1984-04-13 BR BR8401745A patent/BR8401745A/en not_active IP Right Cessation
-
1996
- 1996-02-12 DK DK014196A patent/DK14196A/en not_active Application Discontinuation
- 1996-02-12 DK DK014096A patent/DK14096A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU575320B2 (en) | 1988-07-28 |
| IL71547A0 (en) | 1984-07-31 |
| EP0125955A2 (en) | 1984-11-21 |
| IE840931L (en) | 1984-10-13 |
| DK193284A (en) | 1984-10-14 |
| DK14196A (en) | 1996-02-12 |
| FI841492A0 (en) | 1984-04-13 |
| NO163600C (en) | 1990-06-27 |
| ZA842785B (en) | 1984-12-24 |
| BR8401745A (en) | 1984-11-27 |
| DE125955T1 (en) | 1985-06-05 |
| ATE46730T1 (en) | 1989-10-15 |
| JPS6046244A (en) | 1985-03-13 |
| JPH049141B2 (en) | 1992-02-19 |
| EP0125955A3 (en) | 1985-08-21 |
| CA1264618A (en) | 1990-01-23 |
| EP0125955B1 (en) | 1989-09-27 |
| ES531602A0 (en) | 1987-06-16 |
| NO841501L (en) | 1984-10-15 |
| DK193284D0 (en) | 1984-04-13 |
| DE3479906D1 (en) | 1989-11-02 |
| ES8706334A1 (en) | 1987-06-16 |
| AU2725284A (en) | 1984-10-18 |
| NO163600B (en) | 1990-03-19 |
| IL71547A (en) | 1989-09-28 |
| DK14096A (en) | 1996-02-12 |
| FI841492A (en) | 1984-10-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Patent lapsed |