IE50287B1 - Ethylene copolymers capable of being processed into films and production process for these copolymers - Google Patents
Ethylene copolymers capable of being processed into films and production process for these copolymersInfo
- Publication number
- IE50287B1 IE50287B1 IE594/80A IE59480A IE50287B1 IE 50287 B1 IE50287 B1 IE 50287B1 IE 594/80 A IE594/80 A IE 594/80A IE 59480 A IE59480 A IE 59480A IE 50287 B1 IE50287 B1 IE 50287B1
- Authority
- IE
- Ireland
- Prior art keywords
- reactor
- ethylene
- propylene
- copolymerization
- copolymers
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title claims description 44
- 238000004519 manufacturing process Methods 0.000 title description 7
- 229920001038 ethylene copolymer Polymers 0.000 title description 2
- 239000005977 Ethylene Substances 0.000 claims abstract description 35
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 34
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 28
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 230000008569 process Effects 0.000 claims abstract description 20
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 17
- 230000003197 catalytic effect Effects 0.000 claims abstract description 13
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 11
- 150000003624 transition metals Chemical class 0.000 claims abstract description 11
- 239000010936 titanium Substances 0.000 claims abstract description 8
- 239000012190 activator Substances 0.000 claims abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 4
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 4
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 3
- 150000004678 hydrides Chemical class 0.000 claims abstract description 3
- 150000002739 metals Chemical class 0.000 claims abstract description 3
- 150000002902 organometallic compounds Chemical class 0.000 claims abstract description 3
- 230000000737 periodic effect Effects 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 125000005843 halogen group Chemical group 0.000 claims abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 239000004711 α-olefin Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 2
- 239000008246 gaseous mixture Substances 0.000 claims 2
- GLGNXYJARSMNGJ-VKTIVEEGSA-N (1s,2s,3r,4r)-3-[[5-chloro-2-[(1-ethyl-6-methoxy-2-oxo-4,5-dihydro-3h-1-benzazepin-7-yl)amino]pyrimidin-4-yl]amino]bicyclo[2.2.1]hept-5-ene-2-carboxamide Chemical compound CCN1C(=O)CCCC2=C(OC)C(NC=3N=C(C(=CN=3)Cl)N[C@H]3[C@H]([C@@]4([H])C[C@@]3(C=C4)[H])C(N)=O)=CC=C21 GLGNXYJARSMNGJ-VKTIVEEGSA-N 0.000 claims 1
- 229940125758 compound 15 Drugs 0.000 claims 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract description 6
- 229940093470 ethylene Drugs 0.000 description 29
- 239000000203 mixture Substances 0.000 description 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 7
- -1 hydrocarbon radical Chemical group 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910010062 TiCl3 Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000002901 organomagnesium compounds Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Cell Separators (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7907349A FR2451924A1 (fr) | 1979-03-23 | 1979-03-23 | Copolymeres de l'ethylene capables d'etre transformes en films et procede de production desdits copolymeres |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE800594L IE800594L (en) | 1980-11-23 |
| IE50287B1 true IE50287B1 (en) | 1986-03-19 |
Family
ID=9223478
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE594/80A IE50287B1 (en) | 1979-03-23 | 1980-03-21 | Ethylene copolymers capable of being processed into films and production process for these copolymers |
Country Status (13)
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56161407A (en) * | 1980-05-17 | 1981-12-11 | Mitsubishi Petrochem Co Ltd | Polymerization of ethylene |
| FR2483430B1 (fr) * | 1980-05-28 | 1985-06-07 | Charbonnages Ste Chimique | Copolymeres de l'ethylene capables d'etre moules et/ou injectes et un procede pour leur production |
| FR2654108B1 (fr) * | 1989-11-08 | 1993-08-20 | Norsolor Sa | Nouveaux caoutchoucs polyolefiniques et leur procede de preparation. |
| DE69502312T2 (de) * | 1994-02-18 | 1998-10-08 | Mitsui Chemicals Inc | Ethylenpolymer und Verfahren zur Herstellung desselben |
| JP3472935B2 (ja) * | 1994-02-18 | 2003-12-02 | 三井化学株式会社 | エチレン系重合体およびその製造方法、エチレン重合用固体状チタン触媒成分ならびにエチレン重合用触媒 |
| JP3365668B2 (ja) * | 1994-03-02 | 2003-01-14 | 三井化学株式会社 | エチレン系重合体、エチレン重合用固体状チタン触媒成分、該触媒成分を含むエチレン重合用触媒および該触媒を用いるエチレン系重合体の製造方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA986250A (en) * | 1970-05-29 | 1976-03-23 | Teiji Kato | Non-elastic ethylene copolymers and process for preparation of same |
| ES456321A1 (es) * | 1976-02-25 | 1978-01-16 | Charbonnages Ste Chimique | Procedimiento mejorado de polimerizacion ionica del etileno bajo alta presion. |
-
1979
- 1979-03-23 FR FR7907349A patent/FR2451924A1/fr active Granted
-
1980
- 1980-03-13 MX MX181545A patent/MX153849A/es unknown
- 1980-03-17 PT PT70960A patent/PT70960A/pt unknown
- 1980-03-18 GR GR61477A patent/GR67992B/el unknown
- 1980-03-20 DE DE8080400371T patent/DE3065973D1/de not_active Expired
- 1980-03-20 AT AT80400371T patent/ATE5729T1/de not_active IP Right Cessation
- 1980-03-20 BR BR8001680A patent/BR8001680A/pt not_active IP Right Cessation
- 1980-03-20 EP EP80400371A patent/EP0016707B1/fr not_active Expired
- 1980-03-21 IE IE594/80A patent/IE50287B1/en unknown
- 1980-03-21 ES ES489831A patent/ES489831A1/es not_active Expired
- 1980-03-21 DK DK124780A patent/DK124780A/da not_active Application Discontinuation
- 1980-03-21 JP JP3599880A patent/JPS55131007A/ja active Granted
- 1980-03-23 CA CA000348198A patent/CA1153499A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2451924B1 (enrdf_load_stackoverflow) | 1984-08-10 |
| ES489831A1 (es) | 1980-09-16 |
| EP0016707A2 (fr) | 1980-10-01 |
| EP0016707B1 (fr) | 1983-12-28 |
| DK124780A (da) | 1980-09-24 |
| JPS55131007A (en) | 1980-10-11 |
| BR8001680A (pt) | 1980-11-18 |
| JPS617205B2 (enrdf_load_stackoverflow) | 1986-03-05 |
| MX153849A (es) | 1987-01-22 |
| ATE5729T1 (de) | 1984-01-15 |
| EP0016707A3 (en) | 1980-10-15 |
| IE800594L (en) | 1980-11-23 |
| DE3065973D1 (en) | 1984-02-02 |
| CA1153499A (fr) | 1983-09-06 |
| PT70960A (fr) | 1980-04-01 |
| GR67992B (enrdf_load_stackoverflow) | 1981-10-26 |
| FR2451924A1 (fr) | 1980-10-17 |
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