IE48260B1 - Liquid detergent cleansing compositions having low ocular and skin irritation - Google Patents
Liquid detergent cleansing compositions having low ocular and skin irritationInfo
- Publication number
- IE48260B1 IE48260B1 IE670/79A IE67079A IE48260B1 IE 48260 B1 IE48260 B1 IE 48260B1 IE 670/79 A IE670/79 A IE 670/79A IE 67079 A IE67079 A IE 67079A IE 48260 B1 IE48260 B1 IE 48260B1
- Authority
- IE
- Ireland
- Prior art keywords
- composition
- weight
- sulfobetaine
- carbon atoms
- formula
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000003599 detergent Substances 0.000 title claims abstract description 33
- 239000007788 liquid Substances 0.000 title claims abstract description 17
- 206010040880 Skin irritation Diseases 0.000 title description 9
- 230000036556 skin irritation Effects 0.000 title description 9
- 231100000475 skin irritation Toxicity 0.000 title description 9
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229940117986 sulfobetaine Drugs 0.000 claims abstract description 26
- 239000004480 active ingredient Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 13
- -1 amine salts Chemical class 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000006260 foam Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 11
- 239000003945 anionic surfactant Substances 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 6
- 239000004166 Lanolin Substances 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 229940039717 lanolin Drugs 0.000 description 6
- 235000019388 lanolin Nutrition 0.000 description 6
- 230000007794 irritation Effects 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 206010015946 Eye irritation Diseases 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 231100000013 eye irritation Toxicity 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000008363 phosphate buffer Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 231100000635 Draize test Toxicity 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 208000006069 Corneal Opacity Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 231100000269 corneal opacity Toxicity 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008055 phosphate buffer solution Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/75—Anti-irritant
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/892,803 US4186113A (en) | 1978-04-03 | 1978-04-03 | Low irritating detergent compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE790670L IE790670L (en) | 1979-10-03 |
| IE48260B1 true IE48260B1 (en) | 1984-11-14 |
Family
ID=25400515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE670/79A IE48260B1 (en) | 1978-04-03 | 1979-08-08 | Liquid detergent cleansing compositions having low ocular and skin irritation |
Country Status (16)
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3138770A1 (de) * | 1981-09-30 | 1983-04-14 | Hoechst Ag, 6230 Frankfurt | "haar- und koerperreinigungsmittel mit einem gehalt an alkylsulfatobetainen" |
| US4554098A (en) * | 1982-02-19 | 1985-11-19 | Colgate-Palmolive Company | Mild liquid detergent compositions |
| GB2181737A (en) * | 1985-08-29 | 1987-04-29 | Avent Medical Ltd | Liquid shampoo composition |
| AU596187B2 (en) * | 1986-06-16 | 1990-04-26 | Helene Curtis, Inc. | Mild detergent compositions |
| CA2004812A1 (en) * | 1988-12-12 | 1990-06-12 | Michael Massaro | Detergent composition comprising betaine and ether sulphate |
| US5075042A (en) * | 1989-05-01 | 1991-12-24 | Ppg Industries, Inc. | Surfactant blend containing an alkyl poly(ethyleneoxy)sulfonate to reduce dermal irritation |
| US5540865A (en) * | 1990-01-29 | 1996-07-30 | The Procter & Gamble Company | Hard surface liquid detergent compositions containing hydrocarbylamidoalkylenebetaine |
| US5342549A (en) * | 1990-01-29 | 1994-08-30 | The Procter & Gamble Company | Hard surface liquid detergent compositions containing hydrocarbyl-amidoalkylenebetaine |
| US5336445A (en) * | 1990-03-27 | 1994-08-09 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing beta-aminoalkanols |
| US5540864A (en) * | 1990-12-21 | 1996-07-30 | The Procter & Gamble Company | Liquid hard surfce detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol |
| WO1993015173A1 (en) * | 1992-01-23 | 1993-08-05 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing zwitterionic and cationic detergent surfactants and monoethanolamine and/or beta-aminoalkanol |
| US5310508A (en) * | 1992-07-15 | 1994-05-10 | Colgate-Palmolive Company | Mild personal cleansing compositions containing sodium alcohol ethoxy glyceryl sulfonate |
| US5536451A (en) * | 1992-10-26 | 1996-07-16 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing short chain amphocarboxylate detergent surfactant |
| CA2173437C (en) * | 1993-11-12 | 1999-08-31 | Ronald Anthony Masters | Liquid hard surface detergent compositions containing amphoteric detergent surfactant and perfume |
| US5531933A (en) * | 1993-12-30 | 1996-07-02 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing specific polycarboxylate detergent builders |
| US5534198A (en) * | 1994-08-02 | 1996-07-09 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics and substantive modifier to provide long lasting hydrophilicity |
| US6518229B2 (en) | 2000-12-06 | 2003-02-11 | Playtex Products, Inc. | Antibacterial composition comprising an amphoteric/anionic surfactant mixture |
| US7098180B2 (en) * | 2003-08-28 | 2006-08-29 | Johnson & Johnson Consumer Companies Inc. | Mild and effective cleansing compositions |
| US20050070452A1 (en) * | 2003-08-28 | 2005-03-31 | Joseph Librizzi | Methods of reducing irritation in personal care compositions |
| EP1673424A4 (en) | 2003-08-28 | 2006-11-15 | Johnson & Johnson Consumer | METHOD FOR REDUCING IRRITATION IN BODY CARE AGENTS |
| US20050049172A1 (en) * | 2003-08-28 | 2005-03-03 | Lukenbach Elvin R. | Mild and effective cleansing compositions |
| US20050075256A1 (en) * | 2003-08-28 | 2005-04-07 | Joseph Librizzi | Methods of reducing irritation associated with personal care compositions |
| US7119059B2 (en) * | 2003-08-28 | 2006-10-10 | Johnson & Johnson Consumer Companies, Inc. | Mild and effective cleansing compositions |
| US7157414B2 (en) * | 2003-08-28 | 2007-01-02 | J&J Consumer Companies, Inc. | Methods of reducing irritation in personal care compositions |
| US7084104B2 (en) * | 2003-08-28 | 2006-08-01 | Johnson & Johnson Consumer Company Inc. | Mild and effective cleansing compositions |
| AU2006244493B2 (en) * | 2005-05-10 | 2012-03-01 | Johnson & Johnson Consumer Companies, Inc. | Low-irritation compositions and methods of making the same |
| US7803403B2 (en) * | 2006-11-09 | 2010-09-28 | Johnson & Johnson Consumer Companies, Inc. | Low-irritation compositions and methods of making the same |
| US7820608B2 (en) * | 2007-07-17 | 2010-10-26 | Johnson & Johnson Consumer Companies, Inc. | Methods of cleansing dyed hair |
| WO2011042379A1 (en) | 2009-10-07 | 2011-04-14 | Akzo Nobel Chemicals International B.V. | Superhydrophilic amphiphilic copolymers and processes for making the same |
| ES2745987T3 (es) | 2009-10-07 | 2020-03-04 | Johnson & Johnson Consumer Inc | Composiciones que comprenden copolímeros anfifílicos superhidrófilos y métodos de uso de los mismos |
| US20110081310A1 (en) * | 2009-10-07 | 2011-04-07 | Fevola Michael J | Compositions comprising superhydrophilic amphiphilic copolymers and methods of use thereof |
| US8399590B2 (en) * | 2009-10-07 | 2013-03-19 | Akzo Nobel Chemicals International B.V. | Superhydrophilic amphiphilic copolymers and processes for making the same |
| US8258250B2 (en) | 2009-10-07 | 2012-09-04 | Johnson & Johnson Consumer Companies, Inc. | Compositions comprising superhydrophilic amphiphilic copolymers and methods of use thereof |
| US11173106B2 (en) | 2009-10-07 | 2021-11-16 | Johnson & Johnson Consumer Inc. | Compositions comprising a superhydrophilic amphiphilic copolymer and a micellar thickener |
| US9060956B2 (en) * | 2009-10-07 | 2015-06-23 | Johnson & Johnson Consumer Companies, Inc. | Compositions comprising a low-DP polymerized surfactant and a micellar thickener |
| US8329626B2 (en) | 2010-06-24 | 2012-12-11 | Johnson & Johnson Consumer Companies, Inc. | Low-irritating, clear cleansing compositions with relatively low pH |
| US8329627B2 (en) | 2010-06-24 | 2012-12-11 | Johnson & Johnson Consumer Companies, Inc. | Low-irritating, clear cleansing compositions with relatively low pH |
| US8343902B2 (en) | 2010-06-24 | 2013-01-01 | Johnson & Johnson Consumer Companies, Inc. | Low-irritating, clear cleansing compositions with relatively low pH |
| US8338348B2 (en) | 2010-12-21 | 2012-12-25 | Johnson & Johnson Consumer Companies, Inc. | Skin cleansing compositions with polyglycerol esters and hydrophobically modified polymers |
| US8470753B2 (en) | 2011-01-28 | 2013-06-25 | Rhodia Operations | Personal cleansing systems exhibiting low eye irritation potential |
| US9937118B2 (en) | 2016-06-21 | 2018-04-10 | Johnson & Johnson Consumer Inc. | Clear suspending personal care cleansing compositions |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3842847A (en) * | 1971-04-21 | 1974-10-22 | Colgate Palmolive Co | Shampoo compositions and method for treating the human hair and scalp employing certain astringent salts |
| CA1018893A (en) * | 1972-12-11 | 1977-10-11 | Roger C. Birkofer | Mild thickened shampoo compositions with conditioning properties |
| US3928251A (en) * | 1972-12-11 | 1975-12-23 | Procter & Gamble | Mild shampoo compositions |
| US3950417A (en) * | 1975-02-28 | 1976-04-13 | Johnson & Johnson | High-lathering non-irritating detergent compositions |
| GB1547361A (en) * | 1975-03-24 | 1979-06-13 | Unilever Ltd | Hair shampoos |
| GB1540384A (en) * | 1975-06-12 | 1979-02-14 | Beecham Inc | Shampoo |
| JPS5238507A (en) * | 1975-09-22 | 1977-03-25 | Kao Corp | Detergent composition |
-
1978
- 1978-04-03 US US05/892,803 patent/US4186113A/en not_active Expired - Lifetime
-
1979
- 1979-03-26 IN IN297/CAL/79A patent/IN150596B/en unknown
- 1979-03-27 AU AU45435/79A patent/AU525729B2/en not_active Expired
- 1979-03-27 NZ NZ190020A patent/NZ190020A/xx unknown
- 1979-03-29 GR GR58722A patent/GR64908B/el unknown
- 1979-03-30 EP EP79300526A patent/EP0004755B1/en not_active Expired
- 1979-03-30 PH PH22340A patent/PH15163A/en unknown
- 1979-03-30 CA CA324,512A patent/CA1099177A/en not_active Expired
- 1979-04-02 ZA ZA791554A patent/ZA791554B/xx unknown
- 1979-04-02 AR AR276033A patent/AR218967A1/es active
- 1979-04-02 JP JP3846179A patent/JPS54139614A/ja active Granted
- 1979-04-02 MX MX177180A patent/MX149550A/es unknown
- 1979-04-02 ES ES479207A patent/ES479207A1/es not_active Expired
- 1979-04-02 PT PT69427A patent/PT69427A/pt unknown
- 1979-04-03 BR BR7902021A patent/BR7902021A/pt unknown
- 1979-08-08 IE IE670/79A patent/IE48260B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AR218967A1 (es) | 1980-07-15 |
| NZ190020A (en) | 1981-03-16 |
| PT69427A (en) | 1979-05-01 |
| IN150596B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1982-11-13 |
| ZA791554B (en) | 1980-11-26 |
| US4186113A (en) | 1980-01-29 |
| CA1099177A (en) | 1981-04-14 |
| AU525729B2 (en) | 1982-11-25 |
| JPS54139614A (en) | 1979-10-30 |
| MX149550A (es) | 1983-11-23 |
| JPH0231759B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-07-16 |
| ES479207A1 (es) | 1979-12-01 |
| AU4543579A (en) | 1979-10-18 |
| IE790670L (en) | 1979-10-03 |
| EP0004755A1 (en) | 1979-10-17 |
| PH15163A (en) | 1982-08-27 |
| GR64908B (en) | 1980-06-07 |
| EP0004755B1 (en) | 1982-08-11 |
| BR7902021A (pt) | 1979-11-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK9A | Patent expired |