IE40516L - Cation exchanging aluminium silicates - Google Patents

Cation exchanging aluminium silicates

Info

Publication number
IE40516L
IE40516L IE741840A IE184074A IE40516L IE 40516 L IE40516 L IE 40516L IE 741840 A IE741840 A IE 741840A IE 184074 A IE184074 A IE 184074A IE 40516 L IE40516 L IE 40516L
Authority
IE
Ireland
Prior art keywords
alkali metal
alumosilicate
water
ionic surfactants
mol
Prior art date
Application number
IE741840A
Other versions
IE40516B1 (en
Original Assignee
Henkel Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AT777173A external-priority patent/AT330100B/en
Priority claimed from AT838273A external-priority patent/AT330101B/en
Priority claimed from AT1009873A external-priority patent/AT330102B/en
Application filed by Henkel Kgaa filed Critical Henkel Kgaa
Publication of IE40516L publication Critical patent/IE40516L/en
Publication of IE40516B1 publication Critical patent/IE40516B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/09Inorganic material
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/26Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28Base exchange silicates, e.g. zeolites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/36Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/46Amorphous silicates, e.g. so-called "amorphous zeolites"
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/128Aluminium silicates, e.g. zeolites
    • C11D3/1286Stabilised aqueous aluminosilicate suspensions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Detergent Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Paper (AREA)

Abstract

Novel alkali metal alumosilicates are prepared, which exchange cations, are insoluble in water, contain bound water and are amorphous in terms of X-ray diffraction, by reacting aqueous solutions of alkali metal silicate and alkali metal aluminate. The procedure comprises the following steps: a) mixing together the alkali metal silicate solution and the alkali metal aluminate solution in the presence of 0.005-10% by weight (based on the entire reaction batch) of ionic surfactants which are stable with respect to hard water and are selected from the group of the anionic, zwitterionic and cationic surfactants under atmospheric pressure and at room temperature of the solutions, b) stirring this mixture continuously for approximately 30 minutes, the alumosilicate being precipitated, c) separating the precipitation product present as a suspension in the aqueous phase from the aqueous phase, d) freeing the precipitation product of mother liquor clinging thereto by washing with water which may, if appropriate, contain the same ionic surfactants, and e) subsequent drying at temperatures of 20-150 DEG C. In doing so, the process steps are tailored to one another in such a way, that the process product obtained is the novel alkali metal alumosilicate, which contains ionic surfactants in amounts of 0.01-50% by weight, based on the mixture of anhydrous alkali metal alumosilicate and surfactant, and bound water and which, per mole of Al2O3, has 0.7-1.5 mol of Cat2/nO (Cat = a cation of valency n) and 0.8-6 mol of SiO2 and a calcium-binding capacity of 50-200, especially of 80-160 mg CaO/g of anhydrous alkali metal alumosilicate and a particle size below 30 mu , preferably at most 8 mu . [GB1483610A]
IE1840/74A 1973-09-07 1974-09-04 Cation-exchanging aluminium silicates and aprocess for ther manufacture IE40516B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AT777173A AT330100B (en) 1973-09-07 1973-09-07 PROCESS FOR THE PRODUCTION OF NEW, RONT-GENERAL AMORPHERIC, CATION-EXCHANGING ALUMINUM SILICATES, WHICH MAY CONTAIN BONDED WATER
AT838273A AT330101B (en) 1973-10-01 1973-10-01 PROCESS FOR THE PRODUCTION OF NEW, RONT-GENERAL AMORPHERIC, CATION-EXCHANGING ALUMINUM SILICATES, WHICH MAY CONTAIN BONDED WATER
AT1009873A AT330102B (en) 1973-12-03 1973-12-03 PROCESS FOR THE PRODUCTION OF NEW, RONT-GENERAL AMORPHERIC, CATION-EXCHANGING ALUMINUM SILICATES, WHICH MAY CONTAIN BONDED WATER

Publications (2)

Publication Number Publication Date
IE40516L true IE40516L (en) 1975-03-07
IE40516B1 IE40516B1 (en) 1979-06-20

Family

ID=27150880

Family Applications (1)

Application Number Title Priority Date Filing Date
IE1840/74A IE40516B1 (en) 1973-09-07 1974-09-04 Cation-exchanging aluminium silicates and aprocess for ther manufacture

Country Status (13)

Country Link
JP (1) JPS583967B2 (en)
AR (1) AR202039A1 (en)
BR (1) BR7407455D0 (en)
CH (1) CH624914A5 (en)
DE (1) DE2439572C2 (en)
DK (1) DK436674A (en)
FR (1) FR2243154B1 (en)
GB (1) GB1483610A (en)
IE (1) IE40516B1 (en)
IT (1) IT1020728B (en)
LU (1) LU70854A1 (en)
NL (1) NL178310C (en)
SE (1) SE420911B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT335035B (en) * 1974-10-10 1977-02-25 Henkel & Cie Gmbh STABLE SUSPENSIONS OF WATER-INSOLUBLE, SILICATES CAPABLE OF BINDING CALCIUMIONS AND THEIR USE FOR THE MANUFACTURE OF DETERGENTS AND DETERGENTS
US4169075A (en) * 1974-10-10 1979-09-25 Henkel Kommanditgesellschaft Auf Aktien Process for the production of powdery washing agents by spray-drying
DE2847439A1 (en) * 1978-11-02 1980-05-22 Henkel Kgaa Cosmetic cleanser e.g. shampoo contg. alkali aluminium silicate - prepd. from initial components by co-pptn. during cleanser prodn.
US4248728A (en) * 1979-02-28 1981-02-03 Chemed Corporation Liquid scouring cleanser
JPH0662289B2 (en) * 1985-08-23 1994-08-17 善次 萩原 Amorphous aluminosilicate filler and method for producing the same

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3313594A (en) * 1963-07-05 1967-04-11 Mobil Oil Corp Method for producing crystalline aluminosilicate zeolitic particles of uniform size
FR2105475A5 (en) * 1970-09-02 1972-04-28 Sifrance

Also Published As

Publication number Publication date
DE2439572C2 (en) 1987-08-20
DK436674A (en) 1975-05-05
FR2243154B1 (en) 1977-10-28
LU70854A1 (en) 1975-06-11
FR2243154A1 (en) 1975-04-04
NL178310C (en) 1987-07-16
NL7410948A (en) 1975-03-11
IT1020728B (en) 1977-12-30
SE420911B (en) 1981-11-09
JPS583967B2 (en) 1983-01-24
JPS5054599A (en) 1975-05-14
AR202039A1 (en) 1975-05-09
BR7407455D0 (en) 1975-07-08
CH624914A5 (en) 1981-08-31
GB1483610A (en) 1977-08-24
DE2439572A1 (en) 1975-03-13
SE7410437L (en) 1975-03-10
IE40516B1 (en) 1979-06-20

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