IE39328B1 - Metl spinning of refractory polymers - Google Patents

Metl spinning of refractory polymers

Info

Publication number
IE39328B1
IE39328B1 IE217/74A IE21774A IE39328B1 IE 39328 B1 IE39328 B1 IE 39328B1 IE 217/74 A IE217/74 A IE 217/74A IE 21774 A IE21774 A IE 21774A IE 39328 B1 IE39328 B1 IE 39328B1
Authority
IE
Ireland
Prior art keywords
melt
temperature
assistant
polymer
refractory
Prior art date
Application number
IE217/74A
Other versions
IE39328L (en
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of IE39328L publication Critical patent/IE39328L/en
Publication of IE39328B1 publication Critical patent/IE39328B1/en

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/18Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/38Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

1452400 Melt spinning refractory polymers AMERICAN CYANAMID CO 22 Jan 1974 [5 Feb 1973 2 March 1973 23 March 1973 10 April 1973 5 July 1973] 02985/74 Heading B5B Shaped articles including filaments and films, are prepared by extruding a single phase fusion melt of a refractory polymer esp. acrylonitrile, but also other high melting point polymers, and a melt assistant i.e. a substance which is capable, when used under pressure sufficient to prevent boiling at temperatures above its atmospheric boiling point, of reducing the melting point of the refractory polymer to a temperature below the degradation range of the polymer, other than normal solvents for the polymer, at a temperature Tf which is above the single phase melt melting point temperature M and also above the boiling point at atmospheric pressure of said melt assistant through a spinnerette directly into a pressurized solidification zone wherein the following conditions obtain (1) there is a partial pressure of melt assistant such that the composition profile across the crosssection of the nascent extrudate so produced remains relatively flat: (2) the concentration of melt assistant retained in said nascent extrudate remains at a value at least 70% of the concentration of melt assistant in said single phase fusion melt, and (3) the temperature of the nascent extrudate is below said temperature Tf but not lower than 20‹ C. below said temperature M. Preferred melt assistants are 1-4C-alkanols, acetonitrile, formic or acetic acids, water or a dilute solution of an inorganic salt in water, the solution being too dilute to act as a solvent for acrylonitrile. Thus a blended mixture of polymer and melt assistant is extruded through a spinnerette 12 into a pressurized chamber 13 and the filaments 21 are drawn under tension by a rotary godet or thread advancing rolls 22 and then wound up on yarn package 30 or relaxed in a steam chamber 33 prior to wind up. [GB1452400A]
IE217/74A 1973-02-05 1974-02-05 Metl spinning of refractory polymers IE39328B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US32947973A 1973-02-05 1973-02-05
US33750673A 1973-03-02 1973-03-02
US34446373A 1973-03-23 1973-03-23
US34987773A 1973-04-10 1973-04-10
US37677873A 1973-07-05 1973-07-05

Publications (2)

Publication Number Publication Date
IE39328L IE39328L (en) 1974-08-05
IE39328B1 true IE39328B1 (en) 1978-09-13

Family

ID=27541094

Family Applications (1)

Application Number Title Priority Date Filing Date
IE217/74A IE39328B1 (en) 1973-02-05 1974-02-05 Metl spinning of refractory polymers

Country Status (23)

Country Link
JP (1) JPS5747283B2 (en)
AR (1) AR203097A1 (en)
BR (1) BR7400787D0 (en)
CA (1) CA1052064A (en)
CH (1) CH577038A5 (en)
DD (1) DD111411A5 (en)
DE (1) DE2403947C2 (en)
DK (1) DK147767C (en)
FI (1) FI57792C (en)
FR (1) FR2216372B1 (en)
GB (1) GB1452400A (en)
HK (1) HK53477A (en)
IE (1) IE39328B1 (en)
IL (1) IL43990A (en)
IN (1) IN141349B (en)
IT (1) IT1002836B (en)
LU (1) LU69307A1 (en)
NL (1) NL186972C (en)
NO (1) NO740055L (en)
PH (1) PH12950A (en)
RO (1) RO85291B (en)
TR (1) TR17984A (en)
YU (1) YU36393B (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4205039A (en) * 1977-11-17 1980-05-27 American Cyanamid Company Process for melt-spinning acrylonitrile polymer fiber
US4301107A (en) * 1978-08-30 1981-11-17 American Cyanamid Company Melt-spinning a plurality of acrylonitrile polymer fibers
US4220617A (en) * 1978-08-30 1980-09-02 American Cyanamid Company Process for melt-spinning acrylonitrile polymer fiber
US4219523A (en) * 1978-08-30 1980-08-26 American Cyanamid Company Melt-spinning acrylonitrile polymer fiber from low molecular weight polymers
US4220616A (en) * 1978-08-30 1980-09-02 American Cyanamid Company Melt-spinning acrylonitrile polymer fiber using spinnerette of high orifice density
DE2963480D1 (en) * 1978-08-30 1982-09-30 American Cyanamid Co Process for melt spinning acrylonitrile polymer fibres
US4238442A (en) * 1978-12-29 1980-12-09 E. I. Du Pont De Nemours And Company Process for melt spinning acrylonitrile polymer hydrates
US4283365A (en) * 1979-02-21 1981-08-11 American Cyanamid Company Process for melt-spinning acrylonitrile polymer fiber using vertically disposed compression zone
EP0014803A1 (en) * 1979-02-21 1980-09-03 American Cyanamid Company Process for preparing acrylonitrile polymer fiber of hollow or open structure
US4271056A (en) * 1979-09-17 1981-06-02 American Cyanamid Company Hydrophilic acrylonitrile polymers for melt-spinning
DE3115281A1 (en) * 1980-04-21 1982-04-08 American Cyanamid Co., Wayne, N.J. METHOD FOR PRODUCING FIBERS
JPS5915480U (en) * 1982-07-21 1984-01-30 株式会社安西製作所 Chute for color sorter
JPS60199909A (en) * 1984-03-22 1985-10-09 Toray Ind Inc Spinning device in atmosphere under pressure
JPS6183305A (en) * 1984-09-25 1986-04-26 Mitsui Petrochem Ind Ltd Extremely thin yarn bundle and its production
DE3729062A1 (en) * 1987-08-31 1989-03-09 Hoechst Ag METHOD FOR PRODUCING PREPARATION-FREE STRETCHED FIBERS
US4935180A (en) * 1988-08-25 1990-06-19 Basf Aktiengesellschaft Formation of melt-spun acrylic fibers possessing a highly uniform internal structure which are particularly suited for thermal conversion to quality carbon fibers
US4921656A (en) * 1988-08-25 1990-05-01 Basf Aktiengesellschaft Formation of melt-spun acrylic fibers which are particularly suited for thermal conversion to high strength carbon fibers
US5318417A (en) * 1988-11-10 1994-06-07 Kopp Clinton V Extrusion head for forming polymeric hollow fiber
JPH0389981A (en) * 1989-08-31 1991-04-15 Kinki Kogyo Kk Apparatus for sorting cullet
JPH0416273A (en) * 1990-05-08 1992-01-21 Takumi Kaneshige Apparatus for sorting cullet by color
JP3343897B2 (en) * 1995-01-09 2002-11-11 日本エクスラン工業株式会社 Method for producing improved acrylonitrile polymer homogeneous phase melt
WO2017194103A1 (en) 2016-05-11 2017-11-16 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Method for producing a multifilament yarn and multifilament yarn
CN112226829B (en) * 2019-07-15 2022-04-05 中国石油化工股份有限公司 Preparation method of high-strength polyacrylonitrile precursor
CN117802595B (en) * 2024-02-29 2024-05-28 北京蓝晶微生物科技有限公司 Polyhydroxyalkanoate monofilament and continuous preparation method thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL41606C (en) * 1934-12-08
GB555569A (en) * 1940-04-26
US2404713A (en) * 1943-06-23 1946-07-23 Du Pont Method for preparing polymeric solutions
US2585444A (en) * 1948-07-29 1952-02-12 Du Pont Preparation of shaped articles from acrylonitrile polymers
US2648649A (en) * 1951-05-28 1953-08-11 Dow Chemical Co Acrylonitrile polymers plasticized with aqueous inroganic salt solutions
US2648648A (en) * 1951-05-28 1953-08-11 Dow Chemical Co High acrylonitrile polymer solutions
BE790107A (en) * 1971-10-14 1973-04-13 Du Pont COMPOSITIONS OF MELTED ACRYLONITRILE POLYMERS, PROCESS FOR THEIR PREPARATION, AND FILAMENTS AND FILAMENTS PRODUCED THEREOF

Also Published As

Publication number Publication date
CH577038A5 (en) 1976-06-30
IL43990A0 (en) 1974-05-16
PH12950A (en) 1979-10-18
DK147767B (en) 1984-12-03
IN141349B (en) 1977-02-19
NL186972C (en) 1991-04-16
FI57792C (en) 1980-10-10
JPS5747283B2 (en) 1982-10-08
NL7401503A (en) 1974-08-07
YU36393B (en) 1983-06-30
TR17984A (en) 1976-08-20
NL186972B (en) 1990-11-16
RO85291A (en) 1984-09-29
AR203097A1 (en) 1975-08-14
JPS5046917A (en) 1975-04-26
BR7400787D0 (en) 1974-11-05
CA1052064A (en) 1979-04-10
IL43990A (en) 1976-08-31
GB1452400A (en) 1976-10-13
IE39328L (en) 1974-08-05
FR2216372A1 (en) 1974-08-30
DE2403947A1 (en) 1974-08-08
DK147767C (en) 1985-05-28
IT1002836B (en) 1976-05-20
FR2216372B1 (en) 1977-09-16
YU26874A (en) 1981-11-13
AU6513774A (en) 1975-08-07
RO85291B (en) 1984-10-30
LU69307A1 (en) 1974-05-29
DD111411A5 (en) 1975-02-12
NO740055L (en) 1974-08-06
HK53477A (en) 1977-10-28
FI57792B (en) 1980-06-30
DE2403947C2 (en) 1990-12-06

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