IE36193B1 - Substituted-p-menthanes - Google Patents
Substituted-p-menthanesInfo
- Publication number
- IE36193B1 IE36193B1 IE95/72A IE9572A IE36193B1 IE 36193 B1 IE36193 B1 IE 36193B1 IE 95/72 A IE95/72 A IE 95/72A IE 9572 A IE9572 A IE 9572A IE 36193 B1 IE36193 B1 IE 36193B1
- Authority
- IE
- Ireland
- Prior art keywords
- radical
- carbon atoms
- ammonium
- alkali
- compounds
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/32—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/203—Alicyclic compounds
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/34—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a carbocyclic ring other than a six-membered aromatic ring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
- C07D317/24—Radicals substituted by singly bound oxygen or sulfur atoms esterified
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
- A61K2800/244—Endothermic; Cooling; Cooling sensation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q9/00—Preparations for removing hair or for aiding hair removal
- A61Q9/02—Shaving preparations
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Polymers & Plastics (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Nutrition Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Confectionery (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
1353381 Comestibles WILKINSON SWORD Ltd 26 Jan 1972 [4 Feb 1971] 3934/71 Heading A2B [Also in Divisions A4 AS C2 C4 C5 and C6] A comestible composition comprises an edible base, a flavourant or colourant and one or more p-menthane-3-carboxylic acid derivatives of the formula wherein R is CONH 2 or COOR<SP>1</SP>, where R is H, an alkali or alkaline earth metal atom, or an ammonium or substituted ammonium radical; a hydroxyaliphatic radical of up to 10 carbon atoms containing a hydroxyl group in the 2- or 3-position and an unsubstituted hydrogen atom in the 1-position, or an acyl or ketal derivative of such a radical; a hydroxyaryl radical having up to 10 carbon atoms and a hydroxy group in the 2- or 3-position relative to the ester grouping; or a carboxyaliphatic radical of up to 10 carbon atoms containing a carboxy group in the 1-, 2- or 3-position, or C 1-4 alkyl ester thereof or an alkali, alkaline earth metal, ammonium or substituted ammonium salt thereof. The compounds may be added to boiled sweet, mint sweets, chewing gum and ice cream. The compounds are capable of stimulating the cold receptors of the nervous system of the human body.
[GB1353381A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB393471 | 1971-02-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE36193L IE36193L (en) | 1972-08-04 |
| IE36193B1 true IE36193B1 (en) | 1976-09-15 |
Family
ID=9767638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE95/72A IE36193B1 (en) | 1971-02-04 | 1972-01-25 | Substituted-p-menthanes |
Country Status (27)
| Country | Link |
|---|---|
| JP (1) | JPS5112690B1 (en) |
| AR (1) | AR195787A1 (en) |
| AT (1) | AT335069B (en) |
| AU (2) | AU450078B2 (en) |
| BE (2) | BE778951A (en) |
| BR (1) | BR7200576D0 (en) |
| CA (2) | CA1019551A (en) |
| CH (2) | CH549952A (en) |
| DD (1) | DD97824A5 (en) |
| DE (2) | DE2202535C3 (en) |
| DK (1) | DK134051B (en) |
| EG (1) | EG11027A (en) |
| FI (1) | FI55329C (en) |
| FR (2) | FR2127011B1 (en) |
| GB (1) | GB1353381A (en) |
| HK (1) | HK50078A (en) |
| HU (1) | HU165167B (en) |
| IE (1) | IE36193B1 (en) |
| IL (1) | IL38606A (en) |
| IT (2) | IT1030526B (en) |
| LU (1) | LU64713A1 (en) |
| NL (2) | NL7201524A (en) |
| NO (2) | NO140089C (en) |
| RO (1) | RO67319A (en) |
| SE (1) | SE402404B (en) |
| TR (1) | TR18113A (en) |
| ZA (1) | ZA72420B (en) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4033994A (en) * | 1972-01-28 | 1977-07-05 | Wilkinson Sword Limited | Substituted p-menthanes |
| GB1471894A (en) | 1973-12-12 | 1977-04-27 | Wilkinson Sword Ltd | Compositions for application to or consumption by the body and containing a compound having a physiological cooling effect |
| IL59407A (en) * | 1979-03-06 | 1983-12-30 | Sanofi Sa | Di-n-propylacetic acid diesters of glycerol,their preparation and pharmaceutical compositions containing them |
| JPS5888334A (en) * | 1981-11-20 | 1983-05-26 | Takasago Corp | 3-l-menthoxypropane-1,2-diol |
| JPH0772150B2 (en) * | 1990-07-18 | 1995-08-02 | 花王株式会社 | α- (Alkylcyclohexyloxy) -β-alkanols and fragrance composition containing the same |
| ATE128351T1 (en) * | 1991-04-04 | 1995-10-15 | Procter & Gamble | EDIBLE PHARMACEUTICAL COMPOSITIONS FOR TREATING DIGESTIVE TRACT PAIN. |
| JPH08502288A (en) * | 1992-10-09 | 1996-03-12 | ザ、プロクター、エンド、ギャンブル、カンパニー | Pharmaceutical composition and method for treating sensational symptoms |
| JPH08509725A (en) * | 1993-04-30 | 1996-10-15 | ザ、プロクター、エンド、ギャンブル、カンパニー | Coated pharmaceutical composition |
| JP3152294B2 (en) * | 1997-03-17 | 2001-04-03 | ダイキン工業株式会社 | Filler-free polytetrafluoroethylene granular powder and method for producing the same |
| US8512718B2 (en) | 2000-07-03 | 2013-08-20 | Foamix Ltd. | Pharmaceutical composition for topical application |
| IL152486A0 (en) | 2002-10-25 | 2003-05-29 | Meir Eini | Alcohol-free cosmetic and pharmaceutical foam carrier |
| US9265725B2 (en) | 2002-10-25 | 2016-02-23 | Foamix Pharmaceuticals Ltd. | Dicarboxylic acid foamable vehicle and pharmaceutical compositions thereof |
| US7820145B2 (en) | 2003-08-04 | 2010-10-26 | Foamix Ltd. | Oleaginous pharmaceutical and cosmetic foam |
| US9668972B2 (en) | 2002-10-25 | 2017-06-06 | Foamix Pharmaceuticals Ltd. | Nonsteroidal immunomodulating kit and composition and uses thereof |
| US8900554B2 (en) | 2002-10-25 | 2014-12-02 | Foamix Pharmaceuticals Ltd. | Foamable composition and uses thereof |
| US7704518B2 (en) | 2003-08-04 | 2010-04-27 | Foamix, Ltd. | Foamable vehicle and pharmaceutical compositions thereof |
| US9211259B2 (en) | 2002-11-29 | 2015-12-15 | Foamix Pharmaceuticals Ltd. | Antibiotic kit and composition and uses thereof |
| US10117812B2 (en) | 2002-10-25 | 2018-11-06 | Foamix Pharmaceuticals Ltd. | Foamable composition combining a polar solvent and a hydrophobic carrier |
| AU2003279493B2 (en) | 2002-10-25 | 2009-08-20 | Foamix Pharmaceuticals Ltd. | Cosmetic and pharmaceutical foam |
| US7700076B2 (en) | 2002-10-25 | 2010-04-20 | Foamix, Ltd. | Penetrating pharmaceutical foam |
| US8486376B2 (en) | 2002-10-25 | 2013-07-16 | Foamix Ltd. | Moisturizing foam containing lanolin |
| US20080138296A1 (en) | 2002-10-25 | 2008-06-12 | Foamix Ltd. | Foam prepared from nanoemulsions and uses |
| US7575739B2 (en) | 2003-04-28 | 2009-08-18 | Foamix Ltd. | Foamable iodine composition |
| US8486374B2 (en) | 2003-08-04 | 2013-07-16 | Foamix Ltd. | Hydrophilic, non-aqueous pharmaceutical carriers and compositions and uses |
| US8795693B2 (en) | 2003-08-04 | 2014-08-05 | Foamix Ltd. | Compositions with modulating agents |
| WO2005023968A1 (en) * | 2003-09-05 | 2005-03-17 | Shiseido Co., Ltd. | Perfume composition for temperature sense control, sense control article, method of sense control and perfume map |
| CN100582089C (en) | 2003-11-21 | 2010-01-20 | 吉万奥丹股份有限公司 | N-substituted p-menthane carbosamided |
| US20080260655A1 (en) | 2006-11-14 | 2008-10-23 | Dov Tamarkin | Substantially non-aqueous foamable petrolatum based pharmaceutical and cosmetic compositions and their uses |
| US8636982B2 (en) | 2007-08-07 | 2014-01-28 | Foamix Ltd. | Wax foamable vehicle and pharmaceutical compositions thereof |
| WO2009069006A2 (en) | 2007-11-30 | 2009-06-04 | Foamix Ltd. | Foam containing benzoyl peroxide |
| WO2009072007A2 (en) | 2007-12-07 | 2009-06-11 | Foamix Ltd. | Carriers, formulations, methods for formulating unstable active agents for external application and uses thereof |
| WO2010041141A2 (en) | 2008-10-07 | 2010-04-15 | Foamix Ltd. | Oil-based foamable carriers and formulations |
| WO2009090558A2 (en) | 2008-01-14 | 2009-07-23 | Foamix Ltd. | Poloxamer foamable pharmaceutical compositions with active agents and/or therapeutic cells and uses |
| US8632792B2 (en) | 2008-04-01 | 2014-01-21 | Takasago International Corporation | Cooling sensation agent composition and sensory stimulation agent composition |
| ES2538789T3 (en) * | 2008-08-15 | 2015-06-24 | The Procter & Gamble Company | Synthesis of cyclohexane derivatives useful as refreshing compounds in consumer products |
| US20120087872A1 (en) | 2009-04-28 | 2012-04-12 | Foamix Ltd. | Foamable Vehicles and Pharmaceutical Compositions Comprising Aprotic Polar Solvents and Uses Thereof |
| CA2769625C (en) | 2009-07-29 | 2017-04-11 | Foamix Ltd. | Non surfactant hydro-alcoholic foamable compositions, breakable foams and their uses |
| WO2011013008A2 (en) | 2009-07-29 | 2011-02-03 | Foamix Ltd. | Non surface active agent non polymeric agent hydro-alcoholic foamable compositions, breakable foams and their uses |
| US9849142B2 (en) | 2009-10-02 | 2017-12-26 | Foamix Pharmaceuticals Ltd. | Methods for accelerated return of skin integrity and for the treatment of impetigo |
| CN102686205A (en) | 2009-10-02 | 2012-09-19 | 弗艾米克斯有限公司 | Topical tetracycline compositions |
| GB201103103D0 (en) | 2011-02-23 | 2011-04-06 | Givaudan Sa | Organic compounds |
| EP2606746B2 (en) | 2011-12-22 | 2018-10-24 | International Flavors & Fragrances, Inc. | Cooling enhancing compositions |
| MX2017011630A (en) | 2016-09-08 | 2018-09-25 | Foamix Pharmaceuticals Ltd | Compositions and methods for treating rosacea and acne. |
-
1971
- 1971-02-04 GB GB393471*[A patent/GB1353381A/en not_active Expired
-
1972
- 1972-01-13 EG EG18/72A patent/EG11027A/en active
- 1972-01-20 DE DE2202535A patent/DE2202535C3/en not_active Expired
- 1972-01-21 IT IT20029/72A patent/IT1030526B/en active
- 1972-01-21 IL IL38606A patent/IL38606A/en unknown
- 1972-01-21 ZA ZA720420A patent/ZA72420B/en unknown
- 1972-01-25 IE IE95/72A patent/IE36193B1/en unknown
- 1972-01-28 DE DE19722203947 patent/DE2203947A1/en active Pending
- 1972-01-31 IT IT20030/72A patent/IT1048888B/en active
- 1972-01-31 CH CH138272A patent/CH549952A/en not_active IP Right Cessation
- 1972-01-31 CA CA133,546A patent/CA1019551A/en not_active Expired
- 1972-01-31 CH CH138372A patent/CH554648A/en not_active IP Right Cessation
- 1972-01-31 CA CA133,545A patent/CA968141A/en not_active Expired
- 1972-02-02 FI FI266/72A patent/FI55329C/en active
- 1972-02-02 BR BR576/72*[A patent/BR7200576D0/en unknown
- 1972-02-02 RO RO7269633A patent/RO67319A/en unknown
- 1972-02-02 LU LU64713D patent/LU64713A1/xx unknown
- 1972-02-03 AU AU38606/72A patent/AU450078B2/en not_active Expired
- 1972-02-03 FR FR7203598A patent/FR2127011B1/fr not_active Expired
- 1972-02-03 FR FR7203597A patent/FR2127010B1/fr not_active Expired
- 1972-02-03 NO NO281/72A patent/NO140089C/en unknown
- 1972-02-03 SE SE7201260A patent/SE402404B/en unknown
- 1972-02-03 TR TR18113A patent/TR18113A/en unknown
- 1972-02-03 DK DK47972AA patent/DK134051B/en not_active IP Right Cessation
- 1972-02-03 HU HUWI207A patent/HU165167B/hu unknown
- 1972-02-03 DD DD160668A patent/DD97824A5/xx unknown
- 1972-02-03 JP JP47012519A patent/JPS5112690B1/ja active Pending
- 1972-02-03 AU AU38605/72A patent/AU457073B2/en not_active Expired
- 1972-02-04 AT AT93272*#A patent/AT335069B/en not_active IP Right Cessation
- 1972-02-04 AR AR240382A patent/AR195787A1/en active
- 1972-02-04 NL NL7201524A patent/NL7201524A/xx unknown
- 1972-02-04 BE BE778951A patent/BE778951A/en unknown
- 1972-02-04 NL NL727201522A patent/NL152244B/en not_active IP Right Cessation
- 1972-02-04 BE BE778950A patent/BE778950A/en not_active IP Right Cessation
-
1974
- 1974-07-24 NO NO742702A patent/NO742702L/en unknown
-
1978
- 1978-08-31 HK HK500/78A patent/HK50078A/en unknown
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