HRP921490A2 - Dry cold process for making foundry dusts into briquettes - Google Patents
Dry cold process for making foundry dusts into briquettes Download PDFInfo
- Publication number
- HRP921490A2 HRP921490A2 HR921490A HRP921490A HRP921490A2 HR P921490 A2 HRP921490 A2 HR P921490A2 HR 921490 A HR921490 A HR 921490A HR P921490 A HRP921490 A HR P921490A HR P921490 A2 HRP921490 A2 HR P921490A2
- Authority
- HR
- Croatia
- Prior art keywords
- dust
- weight
- briquettes
- parts
- limestone
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 30
- 239000000428 dust Substances 0.000 claims description 37
- 229910000831 Steel Inorganic materials 0.000 claims description 11
- 239000010959 steel Substances 0.000 claims description 11
- 235000019738 Limestone Nutrition 0.000 claims description 10
- 238000007664 blowing Methods 0.000 claims description 10
- 239000006028 limestone Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 7
- 229910001570 bauxite Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000010459 dolomite Substances 0.000 claims description 3
- 229910000514 dolomite Inorganic materials 0.000 claims description 3
- 239000010450 olivine Substances 0.000 claims description 3
- 229910052609 olivine Inorganic materials 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910000976 Electrical steel Inorganic materials 0.000 description 3
- 239000011398 Portland cement Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- -1 dunite Substances 0.000 description 3
- 238000010310 metallurgical process Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y15/00—Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Description
Područje tehniku u koju spada izum The technical field to which the invention belongs
Izum se odnosi na postupak za hladno briketiranje topioničkih prašina i pripada području ljevanja. The invention relates to a process for cold briquetting of smelter dusts and belongs to the field of casting.
Tehnički problem Technical problem
Tehnički problem koji se rješava opisanim izumom sadržan je u narednome: kako ostvariti postupak za hladno briketiranje prašina lijeva s kojim će biti odstranjeni nedostatci do sada poznatih postupaka a s kojim će ponovno biti moguće ponovno upotrijebiti u konvertorima, primjerice za ovu prigodu, čeličnu prašinu? The technical problem that is solved by the described invention is contained in the following: how to implement a process for cold briquetting of cast iron dust that will eliminate the shortcomings of the hitherto known processes and with which it will be possible to reuse steel dust in converters, for example for this occasion?
Stanje tehnike State of the art
Prigodom niza metalurških postupaka u topionicama stvara se metalna prašina. Tako se, na primjer, prigodom izrade čelika poznatim postupkom upuhavanja kisika, nastaje odgovarajuća čelična prašina a koja se skuplja prikladnim filterima. Prašina imade visoki sadržaj metala a pri čemu, u zavisnosti od postupka, stoji na raspolaganju željezo u obliku metala ili oksida. During a series of metallurgical processes in smelters, metal dust is created. Thus, for example, during the production of steel by the well-known process of oxygen blowing, appropriate steel dust is created, which is collected by suitable filters. The dust has a high metal content and, depending on the process, iron is available in the form of metal or oxide.
Prerada takove vrste prašine uvijek predstavlja poteškoću glede zaštite okoliša i tome pripadajućih troškova. Za ponovno korištenje prašine odgovara njezin visoki sadržaj metala i tako nije propušten pokus da se ta prašina ponovno vrati u postupak izradbe čelika. The processing of this type of dust always presents a difficulty in terms of environmental protection and associated costs. Its high metal content is suitable for the reuse of dust, and thus the attempt to return this dust to the steelmaking process was not missed.
Prašine s visokim sadržajem metala, a poglavito dijelova pirofornog željeza, briketiraju se uz pomoć postupka toplog briketiranja i vraćaju u konvertor. Poznate su i metode upuhavanja prašine u konvertore kao i postupak granuliranja uz dodatak vezivnog materijala. Pri spomenutim metodama u konvertor dospijevaju materijali koji nisu podobni za metalurški proces. Tako postupak US-A 833 630 opisuje briketrianje lomljivih rudača, pri čemu se dodatak posebnog vapnenca u smjesi s magnezijem i portland cementom pokazao kao značajan jer se na drugi način ne može polučiti dovoljna čvrstoća briketa od rudače. Vlaga koja se nalazi u rudači od 18 do 20 % od posebnog je značaja za hidrauličku reakciju s vezivnim sredstvom portland cementa. Pri ovom poznatom postupku briketiranja, zahtijevana čvrstoća briketa rudače postignuta je pomoću reakcije portland cementa. Dusts with a high metal content, mainly parts of pyrophoric iron, are briquetted with the help of the hot briquetting process and returned to the converter. Methods of blowing dust into converters as well as the granulation process with the addition of binding material are also known. With the mentioned methods, materials that are not suitable for the metallurgical process reach the converter. Thus, the process of US-A 833 630 describes the briquetting of brittle ores, whereby the addition of special limestone in a mixture with magnesium and portland cement proved to be significant, because sufficient strength of the ore briquettes cannot be obtained in any other way. The moisture found in the ore from 18 to 20% is of particular importance for the hydraulic reaction with the Portland cement binder. In this known briquetting process, the required strength of the ore briquettes was achieved using the Portland cement reaction.
Sličan poistupak opisan je u DE-B 1 142 442. Kod ovog spisa postupak je u briketiranju finih rudača. Za briketrianje finih rudača upotrijebljeni temeljni dodatni materijal, posebice magnezijev hidrat i / ili kalcijev hidrat, predstavlja vezivno sredstvo, koje reagira s ugljičnim dioksidom iz zraka u karbonat i na taj način osigurava zahtijevanu čvrstoću briketa. A similar procedure is described in DE-B 1 142 442. In this document, the procedure is in the briquetting of fine ores. For the briquetting of fine ores, the basic additional material used, especially magnesium hydrate and/or calcium hydrate, is a binding agent, which reacts with carbon dioxide from the air into carbonate and thus ensures the required strength of the briquettes.
Također i pri drugim metalurškim postupcima, prigodom proizvodnje elektro čelika ili u industriji aluminija, dobiva se prašina, topionička, koja zahtjeva odvod odnosno, po mogućnosti, povratak u postupak. Also during other metallurgical processes, during the production of electrical steel or in the aluminum industry, smelting dust is obtained, which requires removal or, if possible, return to the process.
Opis rješenja tehničkog problema Description of the solution to the technical problem
Tehnički je problem riješen ovim izumom na taj način, što se prašina pri tlakovima preko 10.000 bara pri normalnoj temperaturi od 30° C zajedno s kalcijem, dolomitom, magnezijem, dunitom, olivinom ili boksitom u izgorjelom ili neizgorjelom obliku uvijek sami za sebe ili u međusobnoj smjesi briketiraju u brikete koji se praše i koji su podobni za transport. The technical problem was solved by this invention in such a way that the dust at pressures over 10,000 bar at a normal temperature of 30° C together with calcium, dolomite, magnesium, dunite, olivine or bauxite in burned or unburned form always by themselves or in mutual the mixture is briquetted into briquettes that are pulverized and suitable for transport.
Uz pomoć postupka sukladno izumu mogu se topioničke prašine, posebice prašine za upuhavanje, pri normalnoj temperaturi od 20° C uz primjenu visokih tlakova od preko 10.000 bara, dodavanjem bazičnih dodataka prevesti u brikete podobne za transport. Ovi se briketi mogu u obliku koji ne zagađuje okoliš ponovno dovesti u postupak dobivanja čelika a uz iskorištavanje materijala koji oni sadržavaju. Postupak sukladno izumu i to suhog briketiranja rješava istodobno s odvodom prašine iz topionica do sada nerazlučive probleme zaštite okoliša. Kao posebna prednost iskazalo se pri tome, da se kod izvođenja postupka sukladno izumu ne opterećuje okružje putem štetnih čimbenika od otpadnih plinova organskih ili neorganskih vezivnih sredstava. With the help of the process according to the invention, smelter dust, especially blowing dust, at a normal temperature of 20°C with the application of high pressures of over 10,000 bar, can be converted into transportable briquettes by adding basic additives. These briquettes can be brought back into the process of obtaining steel in a form that does not pollute the environment, while utilizing the material they contain. The process according to the invention, that of dry briquetting, simultaneously with the removal of dust from smelters, solves hitherto indistinguishable problems of environmental protection. As a special advantage, the fact that the process according to the invention is carried out does not burden the environment through harmful factors from the waste gases of organic or inorganic binders.
Kao dodatni materijal postupka za briketiranje prema postupku, koji s jedne strane omogućavaju briketiranje topioničke prasne, posebno prašine od upuhavanja, a s druge strane pozitivno utječu na svježi postupak uvode se vapnenac, dolomit, magnezit, dunit, olivin, boksit u izgorjelom ili neizgorjelom obliku, uvijek sam ili u smjesama. Posebne prednosti iskazuju se, a prigodom izvođenja postupka sukladno izumu, time što se prašini od upuhavanja dodaje 50 težinskih dijelova vapnenca na svakih 100 težinskih dijelova prašine i ova se smjesa podvrgava hladnom briketiranju pomoću tijeskova visokog tlaka. Limestone, dolomite, magnesite, dunite, olivine, bauxite in burnt or unburnt form are introduced as an additional material of the briquetting process according to the procedure, which on the one hand enables the briquetting of smelter dust, especially blowing dust, and on the other hand positively affects the fresh process. always alone or in mixtures. Special advantages are shown, when carrying out the process according to the invention, by adding 50 parts by weight of limestone to the dust from blowing for every 100 parts by weight of dust and this mixture is subjected to cold briquetting using high pressure presses.
Prema daljnjem obliku izvođenja izuma može se čeličnoj prašini od upuhavanja dodati 40 težinskih dijelova pečenog vapnenaca, 5 težinskih dijelova sinterdunita i 5 težinskih dijelova pečenog boksita i to na svakih 100 težinskih dijelova prašine. According to a further embodiment of the invention, 40 parts by weight of calcined limestone, 5 parts by weight of sinterdunite and 5 parts by weight of calcined bauxite can be added to the steel dust from blowing, for every 100 parts by weight of dust.
Samo pomoću postupka prema izumu postalo je moguće da se naprijed naznačeni problemi riješe sukladno svrsi. Ukoliko se pokuša to, da se čelična prašina od upuhavanja oblikuje na tijeskovima ili tijeskovima za valjanje prstenova u oblik briketa neće se dobiti oblici koji su trajni. Čelična prašina u upuhavanju imade ekstremnu finoću (100 % manja zrna od 20 //m) i tekuća je prašina kao voda, tako da se samo pored ekstremnih tlakova preko 10.000 bara, kao što predviđa ovaj postupak prema izumu, pri normalnoj temperaturi i uz dodatak bazičnih materijala, mogu tiještiti suhim postupkom briketi podobni za transport i koji ne praše. Only by means of the method according to the invention it became possible to solve the above-mentioned problems in accordance with the purpose. If you try to shape the steel dust from blowing on presses or ring presses into briquettes, you will not get shapes that are permanent. The steel dust in blowing has an extreme fineness (100% smaller grains than 20 //m) and is a liquid dust like water, so that only in addition to extreme pressures over 10,000 bar, as foreseen by this process according to the invention, at normal temperature and with the addition basic materials, they can dry briquettes suitable for transport and which do not dust.
Postupak sukladno izumu bit će pobliže pojašnjen u narednim primjerima: The procedure according to the invention will be explained in more detail in the following examples:
Primjer 1: Example 1:
500 tona čelične prašine od upuhivanja iz Ldkonvertora uzima se preko Lurgi uređaja za odprašivanje i uz dodatak od 40 težinskih jedinica pečenog vapnenaca, 6 težinskih jedinica sinterdunita i pet težinskih jedinica pečenog boksita svakom stotom dijelu čelične prašine briketira se pri 12.000 do 15.000 bara u tijeskovima visokog tlaka pri normalnoj temperaturi. 500 tons of steel dust from blowing from the Ldkonvertor is taken through a Lurgi dedusting device and with the addition of 40 weight units of calcined limestone, 6 weight units of sinterdunite and five weight units of baked bauxite to every hundredth part of the steel dust is briquetted at 12,000 to 15,000 bar in high pressure presses. pressure at normal temperature.
Za transport podobni briketi koji ne praše mogu se uobičajenim dozirnim sredstvima ponovno dovoditi LD konvertoru. Briquettes that are suitable for transport and do not dust can be fed back to the LD converter with the usual dosing means.
Primjer 2: Example 2:
100 tona prašine iz aliminijske industrije briketira se uz dodatak 10 težinskih dijelova vapnenaca i pet težinskih dijelova sinterdunita svakom stotom težinskom dijelu prašine, pri normalnoj temperaturi pod tlakom od 10.000 bara. Stvorena prašina u obliku komada dalje se može primijeniti u industriji topljenja. 100 tons of dust from the aluminum industry are briquetted with the addition of 10 parts by weight of limestone and five parts by weight of sinterdunite for every hundred parts by weight of dust, at normal temperature under a pressure of 10,000 bar. The created dust in the form of pieces can further be used in the smelting industry.
Primjer 3: Example 3:
200 tona prašine dobivene iz topionice elektročelika tlači se u brikete sa 10 težinskih dijelova vapnenaca i pet težinskih dijelova sinterdunita na svakih stotinu težinskih dijelova prašine, pri normalnoj temperaturi i pod tlakom od 10.000 bara. Dobiveni briketi, podobni za transport mogu se ponovno dovesti u postupak dobivanja elektročelika ili u postupak obojenih metala - topionica. 200 tons of dust obtained from an electrical steel smelter is pressed into briquettes with 10 parts by weight of limestone and five parts by weight of sinterdunite for every hundred parts by weight of dust, at normal temperature and under a pressure of 10,000 bar. The obtained briquettes, suitable for transport, can be brought back to the process of obtaining electrical steel or to the process of non-ferrous metals - smelters.
Claims (3)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT2041/89A AT393139B (en) | 1989-08-30 | 1989-08-30 | DRY METHOD FOR COLD BRIQUETTING HUT DUST |
YU162490A YU162490A (en) | 1989-08-30 | 1990-08-24 | DRY PROCEDURE FOR COLD BRIQUETTING OF TOPIONIC DUST |
Publications (1)
Publication Number | Publication Date |
---|---|
HRP921490A2 true HRP921490A2 (en) | 1995-06-30 |
Family
ID=25597491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HR921490A HRP921490A2 (en) | 1989-08-30 | 1992-09-25 | Dry cold process for making foundry dusts into briquettes |
Country Status (1)
Country | Link |
---|---|
HR (1) | HRP921490A2 (en) |
-
1992
- 1992-09-25 HR HR921490A patent/HRP921490A2/en not_active Application Discontinuation
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