HRP20201166T1 - Procesi desorpcije co2 poboljšani enzimom - Google Patents
Procesi desorpcije co2 poboljšani enzimom Download PDFInfo
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- HRP20201166T1 HRP20201166T1 HRP20201166TT HRP20201166T HRP20201166T1 HR P20201166 T1 HRP20201166 T1 HR P20201166T1 HR P20201166T T HRP20201166T T HR P20201166TT HR P20201166 T HRP20201166 T HR P20201166T HR P20201166 T1 HRP20201166 T1 HR P20201166T1
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- Prior art keywords
- ion
- rich solution
- carbonic anhydrase
- bicarbonate ions
- solution
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- 238000000034 method Methods 0.000 title claims 16
- 238000003795 desorption Methods 0.000 title claims 11
- 102000004190 Enzymes Human genes 0.000 title claims 4
- 108090000790 Enzymes Proteins 0.000 title claims 4
- 239000000243 solution Substances 0.000 claims 20
- 150000002500 ions Chemical class 0.000 claims 19
- 102000003846 Carbonic anhydrases Human genes 0.000 claims 10
- 108090000209 Carbonic anhydrases Proteins 0.000 claims 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 8
- 150000001875 compounds Chemical class 0.000 claims 6
- 239000002245 particle Substances 0.000 claims 6
- 238000006243 chemical reaction Methods 0.000 claims 4
- 230000001276 controlling effect Effects 0.000 claims 4
- 238000004925 denaturation Methods 0.000 claims 4
- 230000036425 denaturation Effects 0.000 claims 4
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims 2
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 2
- 239000002244 precipitate Substances 0.000 claims 2
- 238000000518 rheometry Methods 0.000 claims 2
- 150000003512 tertiary amines Chemical class 0.000 claims 2
- 125000001302 tertiary amino group Chemical group 0.000 claims 2
- PAZJPZXNSAMZCX-UHFFFAOYSA-N 2-[butan-2-yl(methyl)amino]acetic acid Chemical group CCC(C)N(C)CC(O)=O PAZJPZXNSAMZCX-UHFFFAOYSA-N 0.000 claims 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 1
- 239000004471 Glycine Substances 0.000 claims 1
- SGXDXUYKISDCAZ-UHFFFAOYSA-N N,N-diethylglycine Chemical group CCN(CC)CC(O)=O SGXDXUYKISDCAZ-UHFFFAOYSA-N 0.000 claims 1
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical group CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- 239000007983 Tris buffer Substances 0.000 claims 1
- 229940024606 amino acid Drugs 0.000 claims 1
- 235000001014 amino acid Nutrition 0.000 claims 1
- 150000001413 amino acids Chemical class 0.000 claims 1
- -1 butyl glycine Chemical group 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 108700003601 dimethylglycine Chemical group 0.000 claims 1
- 238000004090 dissolution Methods 0.000 claims 1
- 230000002255 enzymatic effect Effects 0.000 claims 1
- 239000006249 magnetic particle Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 150000004885 piperazines Chemical class 0.000 claims 1
- 229910052700 potassium Chemical group 0.000 claims 1
- 239000011591 potassium Chemical group 0.000 claims 1
- 229910000027 potassium carbonate Inorganic materials 0.000 claims 1
- 230000001737 promoting effect Effects 0.000 claims 1
- 230000008929 regeneration Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 159000000000 sodium salts Chemical group 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 229940066771 systemic antihistamines piperazine derivative Drugs 0.000 claims 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/84—Biological processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12F—RECOVERY OF BY-PRODUCTS OF FERMENTED SOLUTIONS; DENATURED ALCOHOL; PREPARATION THEREOF
- C12F3/00—Recovery of by-products
- C12F3/02—Recovery of by-products of carbon dioxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/306—Alkali metal compounds of potassium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/606—Carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/10—Inorganic absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/10—Inorganic absorbents
- B01D2252/102—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/202—Alcohols or their derivatives
- B01D2252/2023—Glycols, diols or their derivatives
- B01D2252/2026—Polyethylene glycol, ethers or esters thereof, e.g. Selexol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20436—Cyclic amines
- B01D2252/20442—Cyclic amines containing a piperidine-ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20436—Cyclic amines
- B01D2252/20447—Cyclic amines containing a piperazine-ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20478—Alkanolamines
- B01D2252/20484—Alkanolamines with one hydroxyl group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20478—Alkanolamines
- B01D2252/20489—Alkanolamines with two or more hydroxyl groups
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20494—Amino acids, their salts or derivatives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/60—Additives
- B01D2252/602—Activators, promoting agents, catalytic agents or enzymes
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- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/22—Carbon dioxide
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2256/24—Hydrocarbons
- B01D2256/245—Methane
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- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
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- Apparatus Associated With Microorganisms And Enzymes (AREA)
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Claims (14)
1. Enzimom katalizirani proces desorpcije za oslobađanje CO2plina iz otopine bogate ionima koja sadrži bikarbonatne ione, naznačen time, što uključuje:
pružanje karbonske anhidraze ili njenih varijanti ili analoga u otopini bogatoj ionima tako da u desorpcijskoj jedinici karbonska anhidraza ili njene varijante ili analozi mogu proticati sa otopinom bogatom ionima promovirajući konverziju bikarbonatnih iona u CO2plin i generirajući ionski osiromašenu otopinu;
kontroliranje početne koncentracije bikarbonatnih iona u otopini bogatoj ionima na nivou ispod praga denaturacije da bi se izbjegla ili umanjila denaturacija karbonske anhidraze u desorpcijskoj jedinici;
kontroliranje temperature otopine bogate ionima na nivou ispod praga temperature denaturacije enzima da bi se izbjegla denaturacija karbonske anhidraze u desorpcijskoj jedinici; i
oslobađanje CO2plina i ionski osiromašene otopine iz desorpcijske jedinice;
pri čemu otopina bogata ionima uključuje najmanje jedan spoj odabran između sljedećih: tercijarni amini, tercijarni alkanolamini, tercijarne amino-kiseline, karbonati, 2-amino-2-metil-1-propanol (AMP), 2-amino-2-hidroksimetil-1,3-propandiol (TRIS), i derivati piperidina ili piperazina koji su supstituirani najmanje jednom alkanol grupom; i
pri čemu je karbonska anhidraza osigurana u količini dovoljnoj da omogući smanjenje regeneracijske energije od 10% do 60% u usporedbi sa uporabom karbamat-formirajuće otopine.
2. Proces iz patentnog zahtjeva 1, naznačen time, što uključuje reguliranje koncentracije karbonske anhidraze u otopini bogatoj ionima dodavanjem količine karbonske anhidraze prije uvođenja otopine bogate ionima u desorpcijsku jedinicu.
3. Proces iz patentnih zahtjeva 1 ili 2, naznačen time, što se konverzija bikarbonatnih iona u CO2 plin odvija pod uvjetima koji promoviraju formiranje mjehurića CO2 u otopini bogatoj ionima.
4. Proces iz bilo kojeg od patentnih zahtjeva 1 do 3, naznačen time, što uključuje kontroliranje reologije otopine bogate ionima, za promociju formiranja i oslobađanja mjehurića CO2 iz otopine bogate ionima, pri čemu se reologija poželjno kontrolira upravljanjem početnom koncentracijom bikarbonatnih iona u otopini bogatoj ionima i početnom temperaturom otopine bogate ionima.
5. Proces iz bilo kojeg od patentnih zahtjeva 1 do 4, naznačen time, što je otopina bogata ionima u formi guste suspenzije koja sadrži raspršene precipitate, pri čemu proces uključuje promociju rastvaranja raspršenih precipitata tokom konverzije bikarbonatnih iona u CO2plin, čime se formiraju dodatni bikarbonatni ioni za enzimsku konverziju u CO2 plin.
6. Proces iz bilo kojeg od patentnih zahtjeva 1 do 5, naznačen time, što uključuje upravljanje koncentracijom karbonske anhidraze u desorpcijskoj jedinici u skladu sa koncentracijom bikarbonatnih iona i temperaturom otopine bogate ionima, sa ciljem povećanja stope desorpcije.
7. Proces iz bilo kojeg od patentnih zahtjeva 1 do 6, naznačen time, što je karbonska anhidraza dana slobodna u otopini, udružena sa česticama, imobilizirana na površini čvrstih ili poroznih čestica, imobilizirana unutar poroznih čestica, "zarobljena" česticama, u formi unakrsno povezanih enzimskih agregata (CLEA), u formi unakrsno povezanih enzimskih kristala (CLEC), ili podržana magnetnim česticama, ili kombinacija toga.
8. Proces iz bilo kojeg od patentnih zahtjeva 1 do 6, naznačen time, što je karbonska anhidraza dana udružena sa česticama, pri čemu čestice imaju veličinu i gustoću koje ih čine pogodnim za miješanje unutar otopine bogate ionima, formiranjem mjehurića CO2.
9. Proces iz bilo kojeg od patentnih zahtjeva 1 do 8, naznačen time, što se najmanje jedan spoj bira između N-metildietanolamina (MDEA), dimetilmonoetanolamina (DMMEA), dietilmonoetanolamina (DEMEA), triizopropanolamina (TIPA), trietanolamina, i između kalij karbonata i natrij karbonata.
10. Proces iz bilo kojeg od patentnih zahtjeva 1 do 9, naznačen time, što desorpcijska jedinica uključuje veći broj desorpcijskih posuda aranžiranih u nizu ili paralelno.
11. Proces iz bilo kojeg od patentnih zahtjeva 1 do 8, naznačen time, što se najmanje jedan spoj bira između tercijarnih amino-kiselina.
12. Proces iz bilo kojeg od patentnih zahtjeva 1 do 8, naznačen time, što se najmanje jedan spoj bira između N-sekundarnog butil glicina, N-metil N-sekundarnog butil glicina, dietilglicina, i dimetilglicina, i kalijevih ili natrijevih soli amino-kiselina.
13. Proces iz bilo kojeg od patentnih zahtjeva 1 do 8, naznačen time, što se najmanje jedan spoj bira između tercijarnih alkanolamina.
14. Proces iz bilo kojeg od patentnih zahtjeva 1 do 8, naznačen time, što se najmanje jedan spoj bira između tercijarnih amina.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US34486910P | 2010-10-29 | 2010-10-29 | |
PCT/CA2011/001210 WO2012055035A1 (en) | 2010-10-29 | 2011-10-28 | Enzyme enhanced c02 capture and desorption processes |
EP11835402.6A EP2632570B1 (en) | 2010-10-29 | 2011-10-28 | Enzyme enhanced c02 desorption processes |
Publications (1)
Publication Number | Publication Date |
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HRP20201166T1 true HRP20201166T1 (hr) | 2020-11-13 |
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HRP20201166TT HRP20201166T1 (hr) | 2010-10-29 | 2020-07-27 | Procesi desorpcije co2 poboljšani enzimom |
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US (1) | US20130203155A1 (hr) |
EP (1) | EP2632570B1 (hr) |
CA (1) | CA2773724C (hr) |
CY (1) | CY1123155T1 (hr) |
DK (1) | DK2632570T3 (hr) |
ES (1) | ES2808332T3 (hr) |
HR (1) | HRP20201166T1 (hr) |
HU (1) | HUE050812T2 (hr) |
LT (1) | LT2632570T (hr) |
PL (1) | PL2632570T3 (hr) |
PT (1) | PT2632570T (hr) |
RS (1) | RS60589B1 (hr) |
SI (1) | SI2632570T1 (hr) |
WO (1) | WO2012055035A1 (hr) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2010281323B2 (en) | 2009-08-04 | 2015-09-03 | Saipem S.P.A. | Process for co2 capture using carbonates and biocatalysts |
EP2678094A4 (en) * | 2011-02-03 | 2014-12-10 | Co2 Solutions Inc | CO2 TREATMENTS USING ENZYMATIC PARTICLES DIMENSIONED ACCORDING TO THE THICKNESS OF A REACTIVE LIQUID FILM FOR AMPLIFIED CATALYSIS |
CN104602789A (zh) * | 2012-04-24 | 2015-05-06 | 二氧化碳处理公司 | 用碳酸酐酶和用于增强通量比的叔氨基溶剂的co2捕获 |
CA2778095A1 (en) * | 2012-05-17 | 2013-11-17 | Co2 Solutions Inc. | Activity replenishment and in situ activation for enzymatic co2 capture packed reactor |
WO2014005226A1 (en) * | 2012-07-03 | 2014-01-09 | Co2 Solutions Inc. | Bauxite residue neutralisation with enzymatically enhanced gas capture |
US9968885B2 (en) | 2012-10-29 | 2018-05-15 | Co2 Solutions Inc. | Techniques for CO2 capture using sulfurihydrogenibium sp. carbonic anhydrase |
WO2014090328A1 (en) * | 2012-12-14 | 2014-06-19 | Statoil Petroleum As | Absorption/desorption of acidic components such as e.g. co2 by use of at least one catalyst |
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2011
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- 2011-10-28 CA CA2773724A patent/CA2773724C/en active Active
- 2011-10-28 DK DK11835402.6T patent/DK2632570T3/da active
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EP2632570A1 (en) | 2013-09-04 |
RS60589B1 (sr) | 2020-08-31 |
EP2632570A4 (en) | 2014-11-12 |
CA2773724C (en) | 2013-08-20 |
EP2632570B1 (en) | 2020-04-29 |
CY1123155T1 (el) | 2021-10-29 |
US20130203155A1 (en) | 2013-08-08 |
ES2808332T3 (es) | 2021-02-26 |
PL2632570T3 (pl) | 2020-11-16 |
SI2632570T1 (sl) | 2020-09-30 |
HUE050812T2 (hu) | 2021-01-28 |
DK2632570T3 (da) | 2020-07-27 |
PT2632570T (pt) | 2020-07-30 |
CA2773724A1 (en) | 2012-04-29 |
WO2012055035A1 (en) | 2012-05-03 |
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