HRP20191157T1 - Multistage resid hydrocracking - Google Patents

Multistage resid hydrocracking Download PDF

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Publication number
HRP20191157T1
HRP20191157T1 HRP20191157TT HRP20191157T HRP20191157T1 HR P20191157 T1 HRP20191157 T1 HR P20191157T1 HR P20191157T T HRP20191157T T HR P20191157TT HR P20191157 T HRP20191157 T HR P20191157T HR P20191157 T1 HRP20191157 T1 HR P20191157T1
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Croatia
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fraction
residue
stage
reactor
effluent
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HRP20191157TT
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Croatian (hr)
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Mario C. Baldassari
Ujjal K. Mukherjee
Avinash Gupta
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Lummus Technology Llc
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Publication of HRP20191157T1 publication Critical patent/HRP20191157T1/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • C10G67/0454Solvent desasphalting
    • C10G67/049The hydrotreatment being a hydrocracking
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/003Solvent de-asphalting
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/107Atmospheric residues having a boiling point of at least about 538 °C
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1077Vacuum residues
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/205Metal content
    • C10G2300/206Asphaltenes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/301Boiling range
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/42Hydrogen of special source or of special composition

Claims (15)

1. Postupak za poboljšanje ostatka, naznačen time, da sadržava: hidrokrekiranje ostatka u prvom reakcijskom stupnju (14) da bi se dobio efluent prvog stupnja; hidrokrekiranje deasfaltirane uljne frakcije u drugom reakcijskom stupnju (22) da bi se dobio efluent drugog stupnja; dovođenje efluenta iz prvog stupnja i iz drugog stupnja u sustav za odvajanje (26); frakcioniranje efluenta iz prvog stupnja i efluenta iz drugog stupnja u sustavu za odvajanje (26) da bi dobila najmanje jedna ugljikovodična frakcija destilata i frakcije ugljikovodičnog ostatka; te dovođenje ugljične frakcije ostatka u jedinicu za deasfaltiranje otapalom (32) kako bi se dobila asfaltenska frakcija i deasfaltirana uljna frakcija, pri čemu hidrokrekiranje ostatka obuhvaća: dovođenje vodika i ostatka u prvi reaktor koji sadržava prvi katalizator za hidrokrekiranje; dovođenje u kontakt ostatka i vodika u prisutnosti prvog katalizatora za hidrokrekiranje pod određenim uvjetima temperature i tlaka da bi se razbio barem dio ostatka; vraćanje efluenta iz prvog stupnja iz prvog reaktora; pri čemu hidrokrekiranje deasfaltirane uljne frakcije obuhvaća: dovođenje vodika i deasfaltirane uljne frakcije u drugi reaktor koji sadržava drugi katalizator za hidrokrekiranje; dovođenje deasfaltirane uljne frakcije i vodika u prisutnosti drugog katalizatora za hidrokrekiranje pod određenim uvjetima temperature i tlaka da bi se razbio barem dio deasfaltiranog ulja; te obnavljanje efluenta iz drugog stupnja iz drugog reaktora, i pri čemu frakcioniranje obuhvaća: razdvajanje efluenta prvog i drugog stupnja u visokotlačnom visokotemperaturnom separatoru (40) radi dobivanja proizvoda plinovite faze i proizvoda tekuće faze; odvajanje proizvoda tekuće faze u atmosferskom destilacijskom tornju (54) kako bi se dobila frakcija koja sadržava ugljikovodike koji vriju u nizu atmosferskih destilata i prvu frakciju s dna koja sadržava ugljikovodike s uobičajenim vrelištem od najmanje 340 °C; odvajanje frakcije dna u vakuumskoj destilacijskoj koloni (60) da bi se dobila frakcija koja sadržava ugljikovodike s vrelištem u nizu vakuumskih destilata i drugu frakciju s dna koja sadržava ugljikovodike kojima je temperatura vrenja najmanje 480 °C; i dovođenje druge frakcije s dna u jedinicu za deasfaltiranje otapalom (32) kao ostatak ugljikovodične frakcije.1. A process for improving the residue, characterized in that it contains: hydrocracking the residue in the first reaction stage (14) to obtain the effluent of the first stage; hydrocracking the deasphalted oil fraction in the second reaction stage (22) to obtain the effluent of the second stage; bringing effluent from the first stage and from the second stage into the separation system (26); fractionating the effluent from the first stage and the effluent from the second stage in the separation system (26) to obtain at least one hydrocarbon fraction of the distillate and the hydrocarbon residue fraction; and feeding the carbon fraction of the residue to the solvent deasphalting unit (32) to obtain the asphaltene fraction and the deasphalted oil fraction, wherein the hydrocracking of the residue includes: feeding hydrogen and residue to the first reactor containing the first hydrocracking catalyst; contacting the residue with hydrogen in the presence of a first hydrocracking catalyst under certain conditions of temperature and pressure to crack at least a portion of the residue; return of effluent from the first stage from the first reactor; whereby the hydrocracking of the deasphalted oil fraction includes: feeding hydrogen and the deasphalted oil fraction to a second reactor containing a second hydrocracking catalyst; feeding the deasphalted oil fraction and hydrogen in the presence of a second hydrocracking catalyst under certain conditions of temperature and pressure to crack at least a portion of the deasphalted oil; and recovery of effluent from the second stage from the second reactor, i whereby fractionation includes: separation of the effluent of the first and second stage in a high-pressure, high-temperature separator (40) in order to obtain a product of the gaseous phase and a product of the liquid phase; separating the liquid phase product in an atmospheric distillation tower (54) to obtain a fraction containing hydrocarbons boiling in a series of atmospheric distillates and a first fraction from the bottom containing hydrocarbons with a normal boiling point of at least 340 °C; separating the bottom fraction in a vacuum distillation column (60) to obtain a fraction containing hydrocarbons with a boiling point in a series of vacuum distillates and another fraction from the bottom containing hydrocarbons boiling at least 480 °C; and feeding the second fraction from the bottom to the solvent deasphalting unit (32) as the rest of the hydrocarbon fraction. 2. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da su najmanje jedna radna temperatura i radni tlak u drugom reakcijskom stupnju (22) veći od radne temperature i radnog tlaka prvog reakcijskog stupnja (14).2. The method according to patent claim 1, characterized in that at least one working temperature and working pressure in the second reaction stage (22) are higher than the working temperature and working pressure of the first reaction stage (14). 3. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da se barem dio asfaltena u ostatku hidrokrekira u prvom reakcijskom stupnju (14).3. The method according to patent claim 1, characterized in that at least part of the asphaltene in the residue is hydrocracked in the first reaction stage (14). 4. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da nadalje obuhvaća djelovanje prvog reakcijskog stupnja (14) na temperaturi i tlaku za hidrokrekiranje ostatka pri konverziji od oko 30 % težinskog udjela do oko 75 % težinskog udjela ostatka.4. The method according to patent claim 1, characterized in that it further comprises the operation of the first reaction stage (14) at temperature and pressure for hydrocracking the residue at conversion of about 30% by weight to about 75% by weight of the residue. 5. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da nadalje obuhvaća djelovanje prvog reakcijskog stupnja (14) na temperaturi i tlaku za hidrokrekiranje ostatka uz ukupnu konverziju ostatka od najmanje 60 % težinskog udjela.5. The process according to patent claim 1, characterized in that it further comprises the operation of the first reaction stage (14) at temperature and pressure for hydrocracking the residue with a total conversion of the residue of at least 60% by weight. 6. Postupak u skladu s patentnim zahtjevom 5, naznačen time, da je ukupna konverzija ostatka najmanje 95 % težinskog udjela.6. The process according to claim 5, characterized in that the total conversion of the residue is at least 95% by weight. 7. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da ostatak ugljikovodične frakcije sadržava ugljikovodike s uobičajenim vrelištem od najmanje 340 °C.7. Process according to claim 1, characterized in that the rest of the hydrocarbon fraction contains hydrocarbons with a normal boiling point of at least 340 °C. 8. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da prvi reakcijski stupanj (14) obuhvaća reaktor s jednim vrijućim slojem.8. The method according to claim 1, characterized in that the first reaction stage (14) comprises a reactor with one fluidized bed. 9. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da drugi reakcijski stupanj (22) obuhvaća najmanje jedan od reaktora s vrijućim slojem i reaktora s fiksnim slojem.9. The method according to claim 1, characterized in that the second reaction stage (22) comprises at least one of the fluidized bed reactor and the fixed bed reactor. 10. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da nadalje obuhvaća hlađenje proizvoda plinovite faze radi dobivanja plinovite frakcije koja sadržava vodik i frakcije destilata; i dovođenje frakcije destilata u separaciju proizvoda tekuće faze.10. The method according to patent claim 1, characterized in that it further comprises cooling the gaseous phase product in order to obtain a gaseous fraction containing hydrogen and distillate fractions; and bringing the distillate fraction to the liquid phase product separation. 11. Postupak u skladu s patentnim zahtjevom 10, naznačen time, da nadalje obuhvaća recikliranje barem dijela obnovljenog vodika u barem jednom od prvog reaktora i drugog reaktora.11. The method according to claim 10, further comprising recycling at least part of the recovered hydrogen in at least one of the first reactor and the second reactor. 12. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da nadalje obuhvaća hlađenje druge frakcije s dna izravnom izmjenom topline s najmanje jednim dijelom ostatka i dijelom prve frakcije s dna.12. The method according to claim 1, characterized in that it further comprises cooling the second fraction from the bottom by direct heat exchange with at least one part of the residue and part of the first fraction from the bottom. 13. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da su barem radna temperatura ili radni tlak u drugom reaktoru manji od radne temperature i radnog tlaka prvog reaktora.13. The method according to claim 1, characterized in that at least the operating temperature or operating pressure in the second reactor is lower than the operating temperature and operating pressure of the first reactor. 14. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da ostatak ugljikovodične frakcije sadržava ugljikovodike s uobičajenim vrelištem od najmanje 480 °C.14. The process according to patent claim 1, characterized in that the rest of the hydrocarbon fraction contains hydrocarbons with a normal boiling point of at least 480 °C. 15. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da frakcioniranje obuhvaća dovođenje efluenta iz prvog stupnja i efluenta iz drugog stupnja u zajednički sustav za frakcioniranje.15. The method according to patent claim 1, characterized in that the fractionation comprises bringing the effluent from the first stage and the effluent from the second stage into a common system for fractionation.
HRP20191157TT 2009-06-23 2019-06-27 Multistage resid hydrocracking HRP20191157T1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/490,089 US8287720B2 (en) 2009-06-23 2009-06-23 Multistage resid hydrocracking
EP10726674.4A EP2445993B1 (en) 2009-06-23 2010-06-16 Multistage resid hydrocracking
PCT/US2010/001736 WO2010151300A1 (en) 2009-06-23 2010-06-16 Multistage resid hydrocracking

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KR (2) KR101696017B1 (en)
CN (2) CN102803441B (en)
BR (1) BRPI1015117B1 (en)
CA (1) CA2764971C (en)
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HU (2) HUE053691T2 (en)
MX (1) MX2011013604A (en)
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PL (2) PL2562235T3 (en)
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