HRP20170716T1 - Pet posude s poboljšanim termalnim svojstvima - Google Patents
Pet posude s poboljšanim termalnim svojstvima Download PDFInfo
- Publication number
- HRP20170716T1 HRP20170716T1 HRP20170716TT HRP20170716T HRP20170716T1 HR P20170716 T1 HRP20170716 T1 HR P20170716T1 HR P20170716T T HRP20170716T T HR P20170716TT HR P20170716 T HRP20170716 T HR P20170716T HR P20170716 T1 HRP20170716 T1 HR P20170716T1
- Authority
- HR
- Croatia
- Prior art keywords
- temperature
- pet container
- glass transition
- endothermic glass
- endothermic
- Prior art date
Links
- 230000009477 glass transition Effects 0.000 claims 13
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000009928 pasteurization Methods 0.000 claims 1
- 238000000957 temperature-modulated differential scanning calorimetry Methods 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/06—Injection blow-moulding
- B29C49/061—Injection blow-moulding with parison holding means displaceable between injection and blow stations
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/0005—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor characterised by the material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/08—Biaxial stretching during blow-moulding
- B29C49/16—Biaxial stretching during blow-moulding using pressure difference for pre-stretching, e.g. pre-blowing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/18—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using several blowing steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C49/4823—Moulds with incorporated heating or cooling means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/6472—Heating or cooling preforms, parisons or blown articles in several stages
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
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- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
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- B65D1/14—Cans, casks, barrels, or drums characterised by shape
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C2049/023—Combined blow-moulding and manufacture of the preform or the parison using inherent heat of the preform, i.e. 1 step blow moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C49/4823—Moulds with incorporated heating or cooling means
- B29C2049/4838—Moulds with incorporated heating or cooling means for heating moulds or mould parts
- B29C2049/4846—Moulds with incorporated heating or cooling means for heating moulds or mould parts in different areas of the mould at different temperatures, e.g. neck, shoulder or bottom
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
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- B29C49/78—Measuring, controlling or regulating
- B29C49/786—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/0715—Preforms or parisons characterised by their configuration the preform having one end closed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B29C49/08—Biaxial stretching during blow-moulding
- B29C49/10—Biaxial stretching during blow-moulding using mechanical means for prestretching
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/6604—Thermal conditioning of the blown article
- B29C49/6605—Heating the article, e.g. for hot fill
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/003—PET, i.e. poylethylene terephthalate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/004—Semi-crystalline
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29L2031/7158—Bottles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/1359—Three or more layers [continuous layer]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Food Science & Technology (AREA)
- Composite Materials (AREA)
- Chemical & Material Sciences (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Wrappers (AREA)
Claims (15)
1. PET posuda oblikovana puhanjem koja sadrži zid koji ima gustoću između 1.370 g/cc i 1.385 g/cc, toplinom induciranu kristalnost, rigidnu amorfnu fazu i mobilnu amorfnu fazu, PET posuda, kada je napunjena tekućinom koja ima temperaturu od 100° C. do 132° C., neće doživjeti pomjenu zapremine veću od 3%; naznačeno time da
• toplinom inducirana kristalnost je od 16% do 24%,
• rigidna amorfna faza je od 55% do 70%,
• mobilna amorfna faza je od 19% do 22%, i
• zid posude ima sadržaj vlage od 1850 ppm do 1930 ppm kada je izložen ambijentalnim uvjetima tijekom 4 dana.
2. PET posuda iz patentnog zahtjeva 1 gdje PET posuda ima toplinom induciranu kristalnost od oko 20%, rigidnu amorfnu fazu oko 60% i mobilnu amorfnu fazu oko 20%.
3. PET posuda iz patentnog zahtjeva 1 ili 2 gdje je gustoća zida između 1.370 g/cc i 1.375 g/cc.
4. PET posuda iz patentnog zahtjeva 1 ili 2 gdje je gustoća zida veća od 1.375 g/cc, poželjno oko 1.385 g/cc.
5. PET posuda iz patentnog zahtjeva 1 gdje sadržaj vlage zida je od 1780 ppm do 1980 ppm kada je izložena relativnoj vlažnosti od 100% na 96° C.
6. PET posuda iz patentnog zahtjeva 1 ili 5 gdje je posuda optički prozirna.
7. PET posuda iz patentnog zahtjeva 1 gdje je promjena zapremine manja od 2%; poželjno promjena zapremine je manja od 1%.
8. PET posuda iz patentnog zahtjeva 1 gdje zid, kada je podvrgnut temperaturom moduliranoj diferencijalnoj skenirajućoj kalorimetriji i analiziran u opsegu temperature od 0° C. do 325° C. pri brzini zagrijavanja od 5 °C/min, izlaže temperaturu prvog endotermnog prelaza stakla i temperaturu drugog endotermnog prelaza stakla višu od prve temperature prelaza.
9. PET posuda iz patentnog zahtjeva 8 gdje je temperatura drugog endotermnog prelaza stakla najmanje 20° C. viša nego temperatura prvog endotermnog prelaza stakla.
10. PET posuda iz patentnog zahtjeva 9 gdje je temperatura drugog endotermnog prelaza stakla najmanje 30° C. viša nego temperatura prvog endotermnog prelaza stakla.
11. PET posuda iz patentnog zahtjeva 10 gdje je temperatura drugog endotermnog prelaza stakla najmanje 40° C. viša nego temperatura prvog endotermnog prelaza stakla; poželjno temperatura drugog endotermnog prelaza stakla je najmanje 50° C. viša nego temperatura prvog endotermnog prelaza stakla.
12. PET posuda iz patentnog zahtjeva 8 gdje temperatura drugog endotermnog prelaza stakla ima entalpiju veću od 0.5. J/g.
13. PET posuda iz patentnog zahtjeva 12 gdje temperatura drugog endotermnog prelaza stakla ima entalpiju veću od 1.0. J/g.
14. PET posuda iz patentnog zahtjeva 13 gdje temperatura drugog endotermnog prelaza stakla ima entalpiju veću od 2.0. J/g.
15. PET posuda iz patentnog zahtjeva 1 gdje zid posude ima sadržaj vlage od oko 1780 ppm do oko 1980 ppm kada je izložen uvjetima vrućeg punjenja na oko 96° C. i 100% RH, i/ili uvjetima pasterizacije na 98° C., 100% relativna vlažnost.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201061424558P | 2010-12-17 | 2010-12-17 | |
US13/250,189 US9023446B2 (en) | 2009-09-22 | 2011-09-30 | PET containers with enhanced thermal properties and process for making same |
PCT/US2011/065118 WO2012083002A2 (en) | 2010-12-17 | 2011-12-15 | Pet containers with enhanced thermal properties and process for making same |
EP11805341.2A EP2663498B1 (en) | 2010-12-17 | 2011-12-15 | Pet containers with enhanced thermal properties |
Publications (1)
Publication Number | Publication Date |
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HRP20170716T1 true HRP20170716T1 (hr) | 2017-07-28 |
Family
ID=45446234
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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HRP20170716TT HRP20170716T1 (hr) | 2010-12-17 | 2017-05-15 | Pet posude s poboljšanim termalnim svojstvima |
HRP20180675TT HRP20180675T1 (hr) | 2010-12-17 | 2018-04-27 | Proces za izradu pet posuda sa poboljšanim termalnim svojstvima |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
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HRP20180675TT HRP20180675T1 (hr) | 2010-12-17 | 2018-04-27 | Proces za izradu pet posuda sa poboljšanim termalnim svojstvima |
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US (2) | US9023446B2 (hr) |
EP (2) | EP2663498B1 (hr) |
CN (1) | CN103648747B (hr) |
CA (2) | CA2820952C (hr) |
CY (2) | CY1119085T1 (hr) |
DK (2) | DK2663498T3 (hr) |
ES (2) | ES2670831T3 (hr) |
HR (2) | HRP20170716T1 (hr) |
HU (2) | HUE037925T2 (hr) |
LT (2) | LT2663498T (hr) |
MX (1) | MX349077B (hr) |
PL (2) | PL2663498T3 (hr) |
PT (2) | PT2663498T (hr) |
RS (2) | RS57169B1 (hr) |
SI (2) | SI2663498T1 (hr) |
TR (1) | TR201808732T4 (hr) |
WO (1) | WO2012083002A2 (hr) |
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- 2011-12-15 WO PCT/US2011/065118 patent/WO2012083002A2/en active Application Filing
- 2011-12-15 SI SI201131151A patent/SI2663498T1/sl unknown
- 2011-12-15 PL PL16182977T patent/PL3124203T3/pl unknown
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