HRP20120668T1 - Method and device for discontinuous hydrolysis of organic substrates - Google Patents

Method and device for discontinuous hydrolysis of organic substrates Download PDF

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Publication number
HRP20120668T1
HRP20120668T1 HRP20120668AT HRP20120668T HRP20120668T1 HR P20120668 T1 HRP20120668 T1 HR P20120668T1 HR P20120668A T HRP20120668A T HR P20120668AT HR P20120668 T HRP20120668 T HR P20120668T HR P20120668 T1 HRP20120668 T1 HR P20120668T1
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Croatia
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substrate
hydrolyzer
pressure
tank
hydrolysis
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HRP20120668AT
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Croatian (hr)
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Dauser Hermann
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Biogas Systems Gmbh
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Publication of HRP20120668T1 publication Critical patent/HRP20120668T1/en

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C1/00Pretreatment of the finely-divided materials before digesting
    • D21C1/02Pretreatment of the finely-divided materials before digesting with water or steam
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00Means for pre-treatment of biological substances
    • C12M45/02Means for pre-treatment of biological substances by mechanical forces; Stirring; Trituration; Comminuting
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00Means for pre-treatment of biological substances
    • C12M45/06Means for pre-treatment of biological substances by chemical means or hydrolysis
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00Means for pre-treatment of biological substances
    • C12M45/20Heating; Cooling
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/04Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Zoology (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Biomedical Technology (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Sustainable Development (AREA)
  • Microbiology (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)

Abstract

Naprava za diskontinuiranu hidrolizu organskih supstrata, posebno energetskih uroda, kao i biljnog ili ·ivotinjskog otpada, koja obuhvaća pred-prilagodni spremnik (1) za prihvaćanje krutih i/ili tekućih organskih tvari, i snabdjevni uređaj (15) za punjenje hidrolizatora (8) supstratima iz spomenutog pred-prilagodnog spremnika (1), te nadalje otpustni uređaj (20) s ekspanzijskim spremnikom (12) za otpu®tanje tlaka supstrata nakon obrade u spomenutom hidrolizatoru (8), naznačena time, da otpustni uređaj (20) sadr·i odvajač pare (10) namje®ten prethodno od ekspanzijskog spremnika (12) i ni·e u poretku od tlačnog ®tita (9), gdje je postavljen uređaj za izravno izlaganje uvedenih organskih supstrata pregrijanom parom iz spomenutog odvajača pare (10). Patent sadr·i jo® 15 patentnih zahtjeva.Device for discontinuous hydrolysis of organic substrates, especially energy crops, as well as vegetable or animal waste, comprising a pre-adaptation tank (1) for receiving solid and / or liquid organic substances, and a supply device (15) for filling hydrolyzers (8) substrates from said pre-adaptation tank (1), and further a discharge device (20) with an expansion tank (12) for releasing the pressure of the substrate after treatment in said hydrolyzer (8), characterized in that the discharge device (20) comprises and a steam separator (10) arranged previously from the expansion tank (12) and lower in order from the pressure shield (9), where a device for direct exposure of the introduced organic substrates to superheated steam from said steam separator (10) is arranged. The patent contains 15 more patent claims.

Claims (16)

1. Naprava za diskontinuiranu hidrolizu organskih supstrata, posebno energetskih uroda, kao i biljnog ili životinjskog otpada, koja obuhvaća pred-prilagodni spremnik (1) za prihvaćanje krutih i/ili tekućih organskih tvari, i snabdjevni uređaj (15) za punjenje hidrolizatora (8) supstratima iz spomenutog pred-prilagodnog spremnika (1), te nadalje otpustni uređaj (20) s ekspanzijskim spremnikom (12) za otpuštanje tlaka supstrata nakon obrade u spomenutom hidrolizatoru (8), naznačena time, da otpustni uređaj (20) sadrži odvajač pare (10) namješten prethodno od ekspanzijskog spremnika (12) i niže u poretku od tlačnog štita (9), gdje je postavljen uređaj za izravno izlaganje uvedenih organskih supstrata pregrijanom parom iz spomenutog odvajača pare (10).1. Device for discontinuous hydrolysis of organic substrates, esp energy crops, as well as plant or animal waste, which includes a pre-adapted container (1) for accepting solid and/or liquid organic substances, and a supply device (15) for filling the hydrolyzer (8) with substrates from the aforementioned pre-adapted container (1) ), and further a release device (20) with an expansion tank (12) for releasing the pressure of the substrate after processing in the aforementioned hydrolyzer (8), characterized by the fact that the release device (20) contains a steam separator (10) arranged in advance of the expansion tank (12) ) and lower in order than the pressure shield (9), where a device is placed for direct exposure of introduced organic substrates to superheated steam from the mentioned steam separator (10). 2. Naprava prema zahtjevu 1, naznačena time, da je odvajač pare (10) oblikovan kao ciklon (10) i opskrbljava jedinicu distribucije pare (3), na primjer brizgalicu, koja je smještena izravno u pred-prilagodnom spremniku (1) za organske supstrate. 2. Device according to claim 1, characterized in that the steam separator (10) is shaped like a cyclone (10) and supplies a steam distribution unit (3), for example a sprayer, which is placed directly in a pre-adapted container (1) for organic substrates. 3. Naprava prema zahtjevu 1 ili 2, naznačena time, da ekspanzijska cijev (11) koja izlazi iz odvajača pare (10) prolazi kroz pred-prilagodni spremnik (1) i konstruirana je tako da prenosi izmjenu kontaktne otpadne topline u sadržaj spomenutog pred-prilagodnog spremnika (1). 3. The device according to claim 1 or 2, characterized by the fact that the expansion pipe (11) coming out of the steam separator (10) passes through the pre-adaptive tank (1) and is designed to transfer contact waste heat exchange into the contents of said pre- of the adapter tank (1). 4. Naprava prema zahtjevu 3, naznačena time, da je odvajač pare (10) postavljen izravno iznad pred-prilagodnog spremnika (1) i time da se ekspanzijska cijev (11) proteže uglavnom vertikalno unutar pred-prilagodnog spremnika (1) te ima pribiližan volumen jedne istisnute hrpe iz hidrolizatora (8). 4. Device according to claim 3, characterized in that the vapor separator (10) is placed directly above the pre-adaptive container (1) and in that the expansion pipe (11) extends mostly vertically inside the pre-adaptive container (1) and has an approximate the volume of one extruded pile from the hydrolyzer (8). 5. Naprava prema zahtjevu 1 ili 2, naznačena time, da se ekspanzijska cijev (11) koja izlazi iz odvajača pare (10) izravno ulijeva u ekspanzijski spremnik (12). 5. Device according to claim 1 or 2, characterized in that the expansion pipe (11) coming out of the steam separator (10) is directly poured into the expansion tank (12). 6. Naprava prema bilo kojem zahtjevu 1 do 5, naznačena time, da je pred-prilagodni spremnik (1) opskrbljen miješalicom (2). 6. Device according to any one of claims 1 to 5, characterized in that the pre-adaptive container (1) is provided with a mixer (2). 7. Naprava prema bilo kojem zahtjevu 1 do 6, naznačena time, da snabdjevni uređaj (15) za punjenje hidrolizatora (8) ima tlačnu posudu (5), postavljenu uz snabdjevnu liniju s ventilskim upravljanjem (14) prema hidrolizatoru (8) i dodatnu spojnu liniju s ventilskim upravljanjem (7) za određivanje ravnoteže temperature i tlaka s hidrolizatorom (8).7. Device according to any of claims 1 to 6, characterized in that the supply device (15) for filling the hydrolyzer (8) has a pressure vessel (5), placed along the supply line with valve control (14) towards the hydrolyzer (8) and an additional connection line with valve control (7) for determining the balance of temperature and pressure with the hydrolyzer (8). 8. Naprava prema zahtjevu 7, naznačena time, da je tlačna posuda (5) snabdjevnog uređaja (15) opremljena sklopom sita (6) koja služe za odvajanje vode iz uvedenog supstrata iz pred-prilagodnog spremnika (1).8. Device according to claim 7, characterized in that the pressure vessel (5) of the supply device (15) is equipped with a sieve assembly (6) that serves to separate water from the introduced substrate from the pre-adaptive container (1). 9. Naprava prema zahtjevu 8, naznačena time, da je za dobiveni tekući supstrat u sklopu sita (6) postavljena recirkulacijska linija (16) koja vodi prema pred-prilagodnom spremniku (1), kada izlazi iz sklopa sita (6) u tlačnoj posudi (5).9. Device according to claim 8, indicated by the fact that a recirculation line (16) is installed for the obtained liquid substrate in the screen assembly (6) which leads to the pre-adjusted tank (1) when it exits the screen assembly (6) in the pressure vessel (5). 10. Naprava prema zahtjevu 9, naznačena time, da recirkulacijska linija (16) prolazi kroz izmjenjivač topline (13) ugrađen u ekspanzijskom spremniku (12).10. Device according to claim 9, characterized in that the recirculation line (16) passes through the heat exchanger (13) installed in the expansion tank (12). 11. Naprava prema zahtjevu 7, naznačena time, da je snabdjevni uređaj (15) opremljen vijčanim transporterom (22) koji se proteže unutar pred-prilagodnog spremnika (1) za prijevoz površinskog plivajućeg sanduka (21) s krutim, vlaknastim komponentama poželjno biljnog otpada koji pliva na površini spremnika.11. Device according to claim 7, characterized in that the supply device (15) is equipped with a screw conveyor (22) that extends inside the pre-adaptive container (1) for the transport of surface floating crate (21) with rigid, fibrous components, preferably plant waste which floats on the surface of the tank. 12. Naprava prema zahtjevu 11, naznačena time, da vijčani transporter (22) ima sklop sita (18) za pred-izvlačenje vode iz prevezenog supstrata.12. Device according to claim 11, characterized in that the screw conveyor (22) has a sieve assembly (18) for pre-extraction of water from the transported substrate. 13. Naprava prema bilo kojem zahtjevu 1 do 12, naznačena time, da je naprava dio postorojenja za bioplin sa zajedničkom toplinskom i pogonskom centralom, gdje je pribavljeno sredstvo (17) za opskrbu vrućim ispušnim plinom iz zajedničke toplinske i pogonske centrale za grijanje hidrolizatora (8).13. A device according to any of claims 1 to 12, characterized in that the device is part of a biogas plant with a common heat and power plant, where a means (17) is provided for supplying hot exhaust gas from a common heat and power plant for heating the hydrolyzer ( 8). 14. Postupak za diskontinuiranu hidrolizu organskih supstrata, posebno energetskih uroda, kao i biljnog i životinjskog otpada, pomoću termalno-tlačne hidrolize (eksplozije pare), naznačen time, da se pregrijana para iz supstrata koji su obrađeni termalno-tlačnom hidrolizom, razdvaja otpuštanjem tlaka odmah nakon izlaska dijela supstrata iz hidrolizatora te se upotrebljava za grijanje uvedenog organskog supstrata u procesu hidrolize, pri čemu se pregrijana para upuhuje izravno u smjesu organskog supstrata.14. Process for discontinuous hydrolysis of organic substrates, especially energy crops, as well as plant and animal waste, using thermal-pressure hydrolysis (steam explosion), characterized by the fact that superheated steam from substrates treated by thermal-pressure hydrolysis is separated by pressure release immediately after part of the substrate exits the hydrolyzer and is used to heat the introduced organic substrate in the hydrolysis process, whereby superheated steam is blown directly into the organic substrate mixture. 15. Postupak prema zahtjevu 14, naznačen time, da se uvedena pregrijana para upotrebljava za izdvajanje krutih, vlaknastih komponenata od poželjno biljnog otpada na takav način da one tvore površinski plivajući sanduk.15. The method according to claim 14, characterized in that the introduced superheated steam is used to separate solid, fibrous components from preferably plant waste in such a way that they form a surface floating box. 16. Postupak prema zahtjevu 14 ili 15, naznačen time, da se voda odstranjuje iz smjese organskog supstrata prije dostavljanja supstrata u proces termalno-tlačne hidrolize, tako da se samo manje količine supstrata trebaju zagrijavati na temperaturu koja je potrebna za termalno-tlačnu hidrolizu.16. The method according to claim 14 or 15, characterized in that water is removed from the organic substrate mixture before delivering the substrate to the thermal-pressure hydrolysis process, so that only small amounts of the substrate need to be heated to the temperature required for thermal-pressure hydrolysis.
HRP20120668AT 2008-10-16 2012-08-17 Method and device for discontinuous hydrolysis of organic substrates HRP20120668T1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT0162708A AT507469B1 (en) 2008-10-16 2008-10-16 DEVICE FOR CONTINUOUS OR DISCONTINUOUS HYDROLYSIS OF ORGANIC SUBSTRATES

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EP (1) EP2177280B1 (en)
AT (1) AT507469B1 (en)
ES (1) ES2388890T3 (en)
HR (1) HRP20120668T1 (en)
PL (1) PL2177280T3 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT509319B1 (en) * 2010-05-25 2011-08-15 Biogas Systems Gmbh METHOD AND DEVICE FOR HYDROLYSIS OF PREFERABLY SOLID, ORGANIC SUBSTRATES
DE102011081286A1 (en) * 2011-08-19 2013-02-21 Peter Rohn Container for the pretreatment of organic substances
DE102011085474A1 (en) * 2011-10-28 2013-05-02 Peter Rohn Process and container for the pretreatment of organic matter in a biogas plant
WO2013163998A1 (en) * 2012-05-03 2013-11-07 Haarslev Industries A/S Method for continuous treatment of biological material
DE102012208649A1 (en) * 2012-05-23 2013-11-28 Thilo Lehmann Device, useful for digestion of lignocellulosic substrates for plant for biogas production, comprises supply unit provided with container for floated substrates, a transport unit, and coupled crusher or squeezer with dewatering device
CA2884720A1 (en) 2012-09-19 2014-03-27 Andritz Inc. Method and apparatus for adding steam for a steam explosion pretreatment process
DE102013101401A1 (en) * 2013-02-13 2014-08-14 Tutech Innovation Gmbh Pretreating horse manure including urine and litter for subsequent fermentation, comprises bringing horse manure with aqueous medium, and circulating a mixture of horse manure and aqueous medium for separation of horse manure and litter
FR3003558B1 (en) * 2013-03-25 2015-04-24 Veolia Water Solutions & Tech METHOD AND DEVICE FOR CONTINUOUS THERMAL HYDROLYSIS
DE102014005270A1 (en) 2014-04-09 2015-10-15 Christine Apelt Method for enabling methane fermentation plants for the material and energetic utilization of lignocellulose-containing biogenic starting materials and arrangement for carrying out the method
ES2538176B1 (en) * 2014-06-11 2015-10-05 Te Consulting House 4 Plus, Sl Procedure and installation for thermal hydrolysis of organic matter with low residence times and without pumps
BR112022010265A2 (en) 2019-11-29 2022-08-16 Leinich Beteiligungen Gmbh METHOD FOR OBTAINING CELLULOSE FIBERS AND PLANT TO PERFORM SUCH METHOD
AT523202B1 (en) * 2019-11-29 2022-10-15 PROCESS AND PLANT FOR PRODUCTION OF CELLULOSE FIBERS

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US6905600B2 (en) 2001-11-16 2005-06-14 Ch2M Hill, Inc. Method and apparatus for the treatment of particulate biodegradable organic waste
CZ17066U1 (en) 2006-07-24 2006-12-12 Coramexport S. R. O. Apparatus for discontinuous and continuous hydrolysis of organic material
US7968760B2 (en) 2007-03-16 2011-06-28 Ch2M Hill, Inc. Treatment of particulate biodegradable organic waste by thermal hydrolysis using condensate recycle
US20080277082A1 (en) * 2007-05-07 2008-11-13 Andritz Inc. High pressure compressor and steam explosion pulping method

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EP2177280B1 (en) 2012-05-30
AT507469A1 (en) 2010-05-15
PL2177280T3 (en) 2012-10-31
EP2177280A2 (en) 2010-04-21
ES2388890T3 (en) 2012-10-19
EP2177280A3 (en) 2011-06-15
AT507469B1 (en) 2010-08-15

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