HRP20030605A2 - Agent, appliance and process for removing scale - Google Patents
Agent, appliance and process for removing scale Download PDFInfo
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- HRP20030605A2 HRP20030605A2 HR20030605A HRP20030605A HRP20030605A2 HR P20030605 A2 HRP20030605 A2 HR P20030605A2 HR 20030605 A HR20030605 A HR 20030605A HR P20030605 A HRP20030605 A HR P20030605A HR P20030605 A2 HRP20030605 A2 HR P20030605A2
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- active agent
- procedure
- removing limescale
- limescale
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- 238000000034 method Methods 0.000 title claims description 20
- 230000008569 process Effects 0.000 title claims description 6
- 239000013543 active substance Substances 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- 239000005060 rubber Substances 0.000 claims description 4
- 229910001369 Brass Inorganic materials 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000010951 brass Substances 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 231100000252 nontoxic Toxicity 0.000 claims description 3
- 230000003000 nontoxic effect Effects 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 235000015114 espresso Nutrition 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 231100000404 nontoxic agent Toxicity 0.000 description 3
- 206010029412 Nightmare Diseases 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000003440 toxic substance Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
- C02F5/145—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus combined with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/683—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
- C02F5/125—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen combined with inorganic substances
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28G—CLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
- F28G9/00—Cleaning by flushing or washing, e.g. with chemical solvents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Description
Područje na koje se izum odnosi The field to which the invention relates
Izum spada u područje kemijskih sredstava, uređaja i postupaka s ciljem uklanjanja sloja vodenog kamenca, nataloženog u uređajima s izmjenjivačima topline. The invention belongs to the field of chemical means, devices and procedures with the aim of removing a layer of scale deposited in devices with heat exchangers.
Prema Međunarodnoj klasifikaciji patenata izum može biti klasificiran u: According to the International Classification of Patents, an invention can be classified into:
F28G9/00 Čišćenje unutarnjih ili vanjskih površina vodova za izmjenu ili prijenos topline, npr. vodocijevi kotlova. Čišćenje ispiranjem ili pranjem, npr. kemijskim otopinama F28G9/00 Cleaning of internal or external surfaces of heat exchange or transfer lines, eg boiler water pipes. Cleaning by rinsing or washing, eg with chemical solutions
C02F5/00 Omekšavanje vode; Sprečavanje stvaranja kotlovskog kamenca; Dodavanje vodi tvari koje sprečavaju stvaranje kamenca ili za njegovo uklanjanje C02F5/00 Water softening; Preventing the formation of boiler scale; Adding substances to the water that prevent the formation of scale or to remove it
Tehnički problem Technical problem
Opće poznato je da pri miješanju tople i hladne vode, dolazi do ubrzanog nastajanja i taloženja vodenog kamenca, temeljnog i najtvrdokornijeg problema u svim izmjenjivačima topline. Temeljni parametri tehničkog problema koji rješava opisani izum su: It is common knowledge that when mixing hot and cold water, there is an accelerated formation and deposition of scale, the fundamental and most stubborn problem in all heat exchangers. The basic parameters of the technical problem solved by the described invention are:
aktivno sredstvo koje učinkovito otapa vodeni kamenac, nije otrovno, nije agresivno prema tretiranim materijalima (metalima, plastici, gumi, …) i ne zagađuje okoliš, an active agent that effectively dissolves limescale, is non-toxic, non-aggressive towards treated materials (metals, plastics, rubber, ...) and does not pollute the environment,
uređaj koji svojom mobilnošću, te fleksibilnim crijevima varijabilne duljine i "klik" priključcima omogućava jednostavan i brz priključak na praktički svaki uređaj s izmjenjivačem topline, bez potrebe za premještanjem i/ili rastavljanjem tretiranog uređaja, a device that, with its mobility, flexible hoses of variable length and "click" connections, enables a simple and quick connection to practically any device with a heat exchanger, without the need to move and/or disassemble the treated device,
postupak koji osigurava maksimalnu funkcionalnost i produljuje životni vijek uređaja s izmjenjivačima topline, provediv je u svim uvjetima, ne predstavlja bilo kakvu opasnost za osoblje i ekološki je prihvatljiv. a procedure that ensures maximum functionality and extends the life of devices with heat exchangers, is applicable in all conditions, does not pose any danger to personnel and is environmentally friendly.
Stanje tehnike State of the art
Kao najučestaliji problem, vodeni kamenac predstavlja i noćnu i dnevnu moru svih servisa koji se bave uklanjanjem istog. Jedan od najrasprostranjenijih servisa koji ima svakodnevni doticaj s problematikom uklanjanja vodenog kamenca, a koji će biti uzet kao vrlo relevantan primjer, je servis espresso automata. Svi primjeri i vrijednosti podataka odnose se na ispitivanja i istraživanja u servisima espresso aparata, kako samostalnih tako i servisa integriranih u sustave pržionica kave. As the most common problem, limescale is both a nightmare and a nightmare for all services that deal with its removal. One of the most widespread services that has daily contact with the problem of water scale removal, and which will be taken as a very relevant example, is the espresso machine service. All examples and data values refer to tests and research in espresso machine services, both stand-alone and services integrated into coffee roaster systems.
Sloj kamenca od samo 0.1 mm, budući da djeluje kao vrlo efikasan toplinski izolator, snižava temperaturu medija koji je potrebno zagrijati na određenu temperaturu preko 25%. Posljedica navedenog je da dolazi do nepotrebnog povećanja potrošnje električne energije, uslijed gubitaka za zagrijavanje sloja kamenca. Pored povećanja troškova za potrošenu električnu energiju, negativne posljedice su smanjenje životne dobi grijača zbog produljenja vremena uključenosti i produljenje vremena potrebnog da medij, npr. voda, u automatima i napravama koje koriste izmjenjivač topline, dosegne potrebnu temperaturu. Navedeni sloj vodenog kamenca debljine 0.1 mm može se, npr. u espresso automatima, nataložiti za približno 60 dana. A layer of scale of only 0.1 mm, since it acts as a very efficient heat insulator, lowers the temperature of the medium that needs to be heated to a certain temperature by over 25%. The consequence of the above is that there is an unnecessary increase in electricity consumption, due to losses for heating the layer of scale. In addition to the increase in costs for the consumed electricity, the negative consequences are the reduction of the life of the heater due to the extension of the on time and the extension of the time required for the medium, for example water, in machines and devices that use a heat exchanger, to reach the required temperature. The aforementioned layer of water scale with a thickness of 0.1 mm can, for example, be deposited in espresso machines in approximately 60 days.
Tradicionalni postupak uklanjanja vodenog kamenca je trajan, složen i mukotrpan posao, jer se espresso automat prvo rastavlja. Potom se pojedini dijelovi uranjaju u kisele kupelji (sa solnom kiselinom kao temeljnom komponentom), koje i samim svojim isparavanjem nagrizaju kako materijale u blizini tako i dišne organe djelatnika. Taj problem se dosad rješavao odvojenim, posebno ventiliranim prostorijama namijenjenim isključivo za opasne i agresivne otopine. The traditional descaling process is a long, complex and painstaking job, because the espresso machine is first disassembled. Then individual parts are immersed in acid baths (with hydrochloric acid as a basic component), which by their very evaporation corrode both the materials in the vicinity and the respiratory organs of the workers. Until now, this problem was solved by separate, specially ventilated rooms intended exclusively for dangerous and aggressive solutions.
Povećanom brigom za zdravstveno stanje svojih djelatnika na prostorima EU zabranjuju se opasne i otrovne tvari u zatvorenim prostorima, pa ponestaje rješenja kako ukloniti vodeni kamenac bez otrovnih otopina visoke koncentracije. Prilikom uklanjanja kamenca, naročito debljih slojeva i/ili sa teže pristupačnih mjesta, takva agresivna otopina ujedno nagriza i oštećuje i materijale od kojih su načinjeni tretirani elementi (spremnici, cijevi, ventili, grijači, …). Zbog toga serviser mora prvo dobro isprati, potom provjeriti i tek tada ponovo montirati tretirane elemente. Tek kada je espresso automat kompletno složen i ponovo stavljen u funkciju, moguće je provjeriti da li su u potpunosti uklonjena sva štetna i otrovna sredstva. U slučaju da nisu postupak se ponavlja. Due to increased concern for the health of its employees in the EU, dangerous and toxic substances are prohibited in closed spaces, so there is a lack of solutions to remove limescale without high-concentration toxic solutions. When removing limescale, especially thicker layers and/or from hard-to-reach places, such an aggressive solution corrodes and damages the materials from which the treated elements are made (tanks, pipes, valves, heaters, etc.). For this reason, the service technician must first rinse thoroughly, then check and only then reassemble the treated elements. Only when the espresso machine is completely assembled and put back into operation, it is possible to check whether all harmful and toxic agents have been completely removed. If they are not, the procedure is repeated.
Izlaganje suštine izuma Presentation of the essence of the invention
Ovaj izum odnosi se na sredstvo, uređaj i postupak za uklanjanje sloja nataloženog vodenog kamenca koristeći aktivno, manje agresivno kemijsko sredstvo, povišeni tlak, povišenu temperaturu i veliki broj izmjena aktivnog sredstva. This invention relates to a means, a device and a method for removing a layer of deposited water scale using an active, less aggressive chemical agent, elevated pressure, elevated temperature and a large number of changes of the active agent.
Primarni cilj izuma je poboljšati i ubrzati postupak uklanjanja vodenog kamenca iz uređaja s izmjenjivačima topline bilo kojeg oblika i namjene, bez opasnosti za zdravlje djelatnika i s minimalnim štetnim utjecajem na okoliš. The primary goal of the invention is to improve and speed up the process of removing limescale from devices with heat exchangers of any shape and purpose, without endangering the health of employees and with minimal harmful impact on the environment.
Sekundarni cilj izuma je omogućiti uklanjanje vodenog kamenca iz uređaja s izmjenjivačima topline bez rastavljanja i/ili njihovog premještanja, uz uštedu potrebnog vremena i energije što izravno utječe na smanjenje ukupnih troškova održavanja. The secondary goal of the invention is to enable the removal of limescale from devices with heat exchangers without disassembling and/or moving them, saving the necessary time and energy, which directly affects the reduction of total maintenance costs.
Daljnji ciljevi i prednosti izuma dijelom će biti prikazani i pokazani u opisu kako slijedi, a dijelom kroz primjere i primjenu izuma. Further objects and advantages of the invention will be partly presented and demonstrated in the following description, and partly through examples and application of the invention.
Kratki opis crteža Brief description of the drawing
Slika 1 prikazuje uređaj prema izumu u punom presjeku. Figure 1 shows the device according to the invention in full section.
Slika 2 prikazuje upravljački ormarić sa svim elementima za upravljanje i priključkom za pumpu. Figure 2 shows the control cabinet with all the control elements and the pump connection.
Slika 3 prikazuje dvosmjernu višestupanjsku pumpu s motorom i priključcima za uređaj. Figure 3 shows a two-way multistage pump with motor and device connections.
Na crtežima i u daljem tekstu opisa izuma korišteni su sljedeći pozicijski brojevi: The following position numbers are used in the drawings and in the following text of the description of the invention:
1 ručka uređaja 1 device handle
2 ulaz medija za posredno grijanje (16) 2 media inlet for indirect heating (16)
3 vanjski plašt duplikatora 3 outer shell of the duplicator
4 izlaz aktivnog sredstva (17) na pumpu (31) 4 output of the active agent (17) to the pump (31)
5 grijač 5 heater
6 kotači za transport uređaja 6 wheels for transporting the device
7 matica za sigurno brtvljenje poklopca 7 nuts for secure sealing of the cover
8 poklopac 8 cover
9 ulazni priključak aktivnog sredstva (17) 9 input connection of the active agent (17)
10 upravljački ormarić 10 control cabinet
11 unutarnji plašt duplikatora 11 inner sheath of the duplicator
12 sonda 12 probes
13 ispust aktivnog sredstva (17) 13 release of active agent (17)
14 noga 14 leg
15 ispust medija za posredno grijanje (16) 15 media outlet for indirect heating (16)
16 medij za posredno grijanje (voda) 16 medium for indirect heating (water)
17 aktivno sredstvo 17 active agent
18 tipkalo - start 18 button - start
19 kontrolna lampica uključeno/isključeno 19 control light on/off
20 tipkalo - stop 20 button - stop
21 sigurnosna sklopka 21 safety switch
22 ručka za otvaranje i zatvaranje ormarića 22 handles for opening and closing the cabinet
23 utičnica pumpe (31) 23 pump sockets (31)
24 kontrolna lampica pumpe (31) 24 pump control light (31)
25 kontrolna lampica grijača (5) 25 heater indicator light (5)
26 prekidač pumpe (31) 26 pump switch (31)
27 prekidač grijača (5) 27 heater switch (5)
28 regulacioni termometar 28 regulation thermometer
29 usisni priključak pumpe (31) 29 pump suction port (31)
30 isisni priključak pumpe (31) 30 pump suction port (31)
31 pumpa 31 pumps
32 upravljačko-priključna kutija pumpe (31) 32 pump control and connection box (31)
33 pogonski motor pumpe (31) 33 pump drive motor (31)
Detaljan opis ostvarivanja izuma Detailed description of the realization of the invention
Osnovne komponente uređaja za uklanjanje vodenog kamenca prema izumu su: The basic components of the device for removing limescale according to the invention are:
- duplikator spremnik (sl. 1.) s posrednim grijanjem grijačem (5), - duplicator tank (fig. 1) with indirect heating by heater (5),
- višestupanjska pumpa (31) (sl. 3.), - multistage pump (31) (fig. 3),
- aktivno, manje agresivno, neotrovno sredstvo (17) i - active, less aggressive, non-toxic agent (17) i
- upravljački ormarić (10) (sl. 2). - control cabinet (10) (fig. 2).
Duplikator spremnik (kotao) izrađen je od nehrđajućeg čeličnog lima s poklopcem (8) za brzo punjenje potrebne količine aktivnog, manje agresivnog, neotrovnog sredstva (17), povišenim, separativnim izlazom (4) i središnjim ispustom (13) u najnižoj točki unutrašnjeg spremnika. The duplicator tank (boiler) is made of stainless steel sheet with a lid (8) for quick filling of the necessary amount of active, less aggressive, non-toxic agent (17), with an elevated, separate outlet (4) and a central outlet (13) at the lowest point of the inner tank .
Integrirani grijač (5) u unutrašnjosti vanjskog spremnika (3) za posredno grijanje aktivnog sredstva (17), te otvor za medij (2) koji posredno grije sadržaj unutarnjeg spremnika (11). Integrated heater (5) in the interior of the outer container (3) for indirect heating of the active agent (17), and an opening for the medium (2) that indirectly heats the contents of the inner container (11).
Višestupanjska pumpa (31) osigurava veći broj izmjena i dinamiku aktivnog sredstva (17), te povišen tlak. Sklopkom na upravljačko-priključnoj kutiji (32) pumpe (31) moguće je mijenjati smjer vrtnje pumpe (31). Time se postiže mogućnost usisavanja aktivne otopine, preko usisnog priključka (29) ili isisavanje preko isisnog priključka (30). The multi-stage pump (31) ensures a greater number of changes and dynamics of the active agent (17), as well as increased pressure. The direction of rotation of the pump (31) can be changed with the switch on the control-connection box (32) of the pump (31). This makes it possible to suck the active solution through the suction port (29) or suction through the suction port (30).
Aktivno, manje agresivno, neotrovno sredstvo (17) spravlja se po vlastitoj formuli, proizašloj iz rezultata vlastitog razvoja i istraživanja. Aktivno sredstvo (17) znatno je manje agresivno prema materijalima standardno korištenim za ovu namjenu (inoxu, bakru, mesingu, čeliku, gumi, plastici, …) od uobičajeno korištenih sredstava, neotrovno je i bezopasno za djelatnike i okolinu, te biorazgradivo i ekološki prihvatljivo. The active, less aggressive, non-toxic agent (17) is made according to its own formula, derived from the results of its own development and research. The active agent (17) is significantly less aggressive towards materials standardly used for this purpose (stainless steel, copper, brass, steel, rubber, plastic, ...) than commonly used agents, it is non-toxic and harmless to employees and the environment, and it is biodegradable and environmentally friendly .
Aktivno sredstvo (17) sastoji se od: The active agent (17) consists of:
- 75%-tne fosforne kiseline u iznosu 10-50% težinskih, preporučljivo 20-40% težinskih, a posebno preporučljivo 30-35% težinskih; - 75% phosphoric acid in the amount of 10-50% by weight, preferably 20-40% by weight, and especially recommended 30-35% by weight;
- 31%-tne solne kiseline u iznosu 5-25% težinskih, preporučljivo 10-20% težinskih, a posebno preporučljivo 12-18% težinskih; - 31% hydrochloric acid in the amount of 5-25% by weight, preferably 10-20% by weight, and especially recommended 12-18% by weight;
- EDTA-e u iznosu 2-5% težinskih, preporučljivo 3-4% težinskih, a posebno preporučljivo 3,4-3,6% težinskih; - EDTA in the amount of 2-5% by weight, recommended 3-4% by weight, and especially recommended 3.4-3.6% by weight;
- glikola 1-5% težinskih; - glycol 1-5% by weight;
- glicerola 1-3% težinskih i - glycerol 1-3% by weight and
- vode 30-65% težinskih. - water 30-65% by weight.
Upravljački ormarić (10) omogućava i osigurava siguran i bezopasan rad u svim okruženjima, te mogućnost regulacije temperature i tlaka sukladno optimalnim vrijednostima tih parametara u konkretnom slučaju. The control cabinet (10) enables and ensures safe and harmless operation in all environments, as well as the ability to regulate temperature and pressure according to the optimal values of these parameters in the specific case.
Uređaj za uklanjanje vodenog kamenca (sl.1.) radi s: The device for removing limescale (fig. 1.) works with:
- aktivnim sredstvom (17), - active agent (17),
- povišenom temperaturom - optimalno u rasponu 45 - 65°C, - elevated temperature - optimally in the range of 45 - 65°C,
- povišenim tlakom - optimalno u rasponu 2 - 6 bara i - with increased pressure - optimally in the range of 2 - 6 bar i
- velikim brojem izmjena aktivnog sredstva (17). - a large number of changes to the active agent (17).
Uređaj radi s visokom učinkovitošću, kamenac se sa svih mjesta na kojima je nataložen, bez obzira na mjesto i debljinu sloja, otapa i uklanja u vrlo kratkom vremenu, a sve se odvija bez ikakve opasnosti za djelatnike i okoliš. The device works with high efficiency, scale is dissolved and removed in a very short time from all places where it is deposited, regardless of the place and thickness of the layer, and everything takes place without any danger for employees and the environment.
Priključkom uređaja na ulaz izmjenjivača topline, bez potrebe njegovog premještanja i/ili rastavljanja, otopina zagrijana na potrebnu temperaturu prolazi kroz izmjenjivač topline. By connecting the device to the inlet of the heat exchanger, without the need to move and/or disassemble it, the solution heated to the required temperature passes through the heat exchanger.
Kao posljedica kemijskog sastava, tlaka, temperature i velikog broja izmjena uređaj učinkovito i u potpunosti uklanja nataloženi vodeni kamenac. Pravilnim izborom vrste, koncentracije i udjela kvalitetnih inhibitora u aktivnom sredstvu (17) postignuto je da tijekom procesa uklanjanja vodenog kamenca ne dolazi do oštećenja tretiranih površina načinjenih od inoxa, mesinga, bakra, čelika, gume, plastike i sličnih materijala. As a result of the chemical composition, pressure, temperature and a large number of changes, the device effectively and completely removes the deposited limescale. By correctly choosing the type, concentration and proportion of high-quality inhibitors in the active agent (17), it was achieved that during the process of removing limescale there is no damage to treated surfaces made of stainless steel, brass, copper, steel, rubber, plastic and similar materials.
Izlazni priključak izmjenjivača topline spojen na ulazni priključak aktivnog sredstva (17) zatvara sustav cirkulacije. Po potrebi grijačem (5), preko medija za posredno grijanje (16), dogrijava se aktivno sredstvo (17) i pumpom (31) vraća u slijedeći ciklus cirkulacije. Učinkovitost i kvaliteta postupka prema izumu povećavaju se i reverziranjem (promjenom smjera vrtnje) pogonskog motora (33) pumpe (31) tj. promjenom smjera cirkulacije aktivnog sredstva (17). The outlet port of the heat exchanger connected to the inlet port of the active agent (17) closes the circulation system. If necessary, the active agent (17) is reheated by the heater (5), through the medium for indirect heating (16), and returned to the next circulation cycle by the pump (31). The efficiency and quality of the process according to the invention are also increased by reversing (changing the direction of rotation) the drive motor (33) of the pump (31), i.e. by changing the direction of circulation of the active agent (17).
Posebna pažnja poklonjena je upravo sljedećim tehničkim karakteristikama uređaja prema izumu, koje ga čine mnogo naprednijim i savršenijim u odnosu na dosadašnje stanje tehnike: Special attention was given to the following technical characteristics of the device according to the invention, which make it much more advanced and perfect compared to the current state of the art:
- priključci na duplikatoru u "klik" izvedbi omogućuju brzu i sigurnu montažu i demontažu fleksibilnih crijeva na isti i mogućnost redukcije za sve tipove colnog navoja od 1/4" do 3/4", za tretirane objekte, - the connections on the duplicator in the "click" design enable quick and safe mounting and dismounting of flexible hoses on the same and the possibility of reduction for all types of inch thread from 1/4" to 3/4", for treated objects,
- mobilnost uređaja eliminira potrebu za premještanjem tretiranih objekata npr. espresso aparata, - the mobility of the device eliminates the need to move treated objects, e.g. espresso machines,
- fleksibilna crijeva odgovarajuće duljine osiguravaju prilagodljivost svakom položaju objekta za tretiranje, - flexible hoses of appropriate length ensure adaptability to any position of the object to be treated,
- izbor pumpe koja omogućuje radni tlak u rasponu od 2 do 6 bara i protočnim kapacitetom od 25 do 50 l/min. - the choice of a pump that enables a working pressure in the range of 2 to 6 bar and a flow capacity of 25 to 50 l/min.
- mogućnost višestruke uporabe aktivnog sredstva (17) sve do vrijednosti kiselosti otopine od pH=3,5. - the possibility of multiple use of the active agent (17) up to the acidity of the solution of pH=3.5.
Način primjene izuma Method of application of the invention
Izum predstavlja pouzdan, praktičan, trajan, koristan, ekološki podoban i ekonomski opravdan uređaj. U kombinaciji s aktivnim sredstvom (17) i opisanim postupkom uklanjanja sloja nataloženog vodenog kamenca, predstavlja revolucionarni iskorak u ovom području tehnike, u odnosu na ranije poznata sredstva, uređaje i postupke rješavanja navedenog problema. The invention represents a reliable, practical, durable, useful, environmentally friendly and economically justifiable device. In combination with the active agent (17) and the described procedure for removing the layer of deposited water scale, it represents a revolutionary step forward in this field of technology, in relation to previously known agents, devices and procedures for solving the aforementioned problem.
Mogućnosti primjene vrlo su široke - praktički u svim slučajevima i područjima gdje prisustvo, taloženje i/ili uklanjanje vodenog kamenca predstavlja problem. The application possibilities are very wide - practically in all cases and areas where the presence, deposition and/or removal of water scale is a problem.
Stručnjacima područja i svima koji se bave navedenom problematikom jasno je da je moguće načiniti brojne varijante i modifikacije opisanog sredstva, uređaja i postupka za uklanjanje vodenog kamenca, bez napuštanja duha i opsega izuma. It is clear to experts in the field and to all those who deal with the mentioned problem that it is possible to make numerous variants and modifications of the described agent, device and procedure for removing limescale, without abandoning the spirit and scope of the invention.
Claims (6)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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HR20030605A HRP20030605A2 (en) | 2003-07-25 | 2003-07-25 | Agent, appliance and process for removing scale |
PCT/HR2004/000023 WO2005010454A2 (en) | 2003-07-25 | 2004-07-23 | Cleaning agent, device and process for removing scale |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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HR20030605A HRP20030605A2 (en) | 2003-07-25 | 2003-07-25 | Agent, appliance and process for removing scale |
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HRP20030605A2 true HRP20030605A2 (en) | 2005-04-30 |
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HR20030605A HRP20030605A2 (en) | 2003-07-25 | 2003-07-25 | Agent, appliance and process for removing scale |
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HR (1) | HRP20030605A2 (en) |
WO (1) | WO2005010454A2 (en) |
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GB2436330A (en) * | 2006-03-20 | 2007-09-26 | Christian Jean Gauthier | A cleaning system for an electrode |
CN104595916B (en) * | 2014-11-27 | 2017-01-25 | 中国石油天然气股份有限公司 | Method for cleaning accumulated ash of convection section fin of steam injection boiler |
CN106051799B (en) * | 2016-06-02 | 2018-05-08 | 田新松 | A kind of cleaning method of the efficient scale removal of oil field boiler convection section |
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US2095380A (en) * | 1934-11-21 | 1937-10-12 | Charles N Coryell | Holder for stick materials |
US3350223A (en) * | 1966-05-18 | 1967-10-31 | Jr Robert G Monteath | Plural step method for cleaning the liquid cooling system of an internal combustion engine |
US3951827A (en) * | 1973-12-03 | 1976-04-20 | Borg-Warner Corporation | Composition and method for removing insoluble scale deposits from surfaces |
EP0200776B1 (en) * | 1984-10-26 | 1989-01-18 | UHT, Umwelt- und Hygienetechnik GmbH | Solution process and solvent for hardly soluble carbonates |
DE4432503C2 (en) * | 1994-09-13 | 1998-09-03 | Behr Industrietech Gmbh & Co | Process for cleaning the hollow body of a heat exchanger and device for carrying out the process |
US5607911A (en) * | 1995-01-17 | 1997-03-04 | Levin; Scott | Aqueous compositions with detergent for rust and stain removal |
-
2003
- 2003-07-25 HR HR20030605A patent/HRP20030605A2/en not_active Application Discontinuation
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WO2005010454A2 (en) | 2005-02-03 |
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