HK1237119B - Laminated ceramic capacitor - Google Patents
Laminated ceramic capacitorInfo
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- HK1237119B HK1237119B HK17110965.1A HK17110965A HK1237119B HK 1237119 B HK1237119 B HK 1237119B HK 17110965 A HK17110965 A HK 17110965A HK 1237119 B HK1237119 B HK 1237119B
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Description
技术领域Technical Field
本发明涉及在电容器主体的相对的端部分别设置有大致L字形状的外部电极的层叠陶瓷电容器。The present invention relates to a multilayer ceramic capacitor having substantially L-shaped external electrodes provided at opposing end portions of a capacitor body.
背景技术Background Art
作为在层叠陶瓷电容器的相对的端部分别设置的外部电极的形态,已知有具有沿着电容器主体的长度方向一个面的部分和沿着高度方向一个面的部分的大致L字形状的外部电极(参照后述专利文献1)。后述专利文献1所公开的层叠陶瓷电容器(以下称为现有的层叠陶瓷电容器)包括:电容器主体,其具有在长度方向上相对的第1面和第2面、在宽度方向上相对的第3面和第4面以及在高度方向上相对的第5面和第6面;大致L字形状的第1外部电极,其具有沿着电容器主体的第1面的第1部分和沿着第5面的第2部分;和大致L字形状的第2外部电极,其具有沿着电容器主体的第2面的第1部分和沿着第5面的第2部分。在电容器主体中,内置有由多个第1内部电极层和多个第2内部电极层隔着电介质层层叠而成的电容部。多个第1内部电极层各自的端缘与第1外部电极的第1部分连接。另外,多个第2内部电极层各自的端缘与第2外部电极的第1部分连接。As a form of external electrodes provided at opposite ends of a multilayer ceramic capacitor, there is known a generally L-shaped external electrode having a portion along one surface in the length direction of the capacitor body and a portion along one surface in the height direction (see Patent Document 1 mentioned below). The multilayer ceramic capacitor disclosed in Patent Document 1 mentioned below (hereinafter referred to as the conventional multilayer ceramic capacitor) includes: a capacitor body having a first surface and a second surface opposite to each other in the length direction, a third surface and a fourth surface opposite to each other in the width direction, and a fifth surface and a sixth surface opposite to each other in the height direction; a generally L-shaped first external electrode having a first portion along the first surface of the capacitor body and a second portion along the fifth surface; and a generally L-shaped second external electrode having a first portion along the second surface of the capacitor body and a second portion along the fifth surface. A capacitor portion formed by stacking a plurality of first internal electrode layers and a plurality of second internal electrode layers with a dielectric layer interposed therebetween is built into the capacitor body. The end edges of the plurality of first internal electrode layers are connected to the first portion of the first external electrode. Furthermore, the end edges of the plurality of second internal electrode layers are connected to the first portion of the second external electrode.
现有的层叠陶瓷电容器中,第1外部电极和第2外部电极分别为不具有沿着电容器主体的第6面的部分、沿着第3面的部分和沿着第4面的部分的大致L字形状。因此,与使用了具有沿着第6面的部分的U字状的外部电极的同一外形尺寸(长度、宽度和高度)的层叠陶瓷电容器相比,能够将电容器主体的高度方向尺寸设计成增大与沿着第6面的部分的厚度相应的量。另外,与使用了具有沿着第6面的部分、沿着第3面的部分和沿着第4面的部分的有底4角筒状的外部电极的同一外形尺寸的层叠陶瓷电容器相比,能够将电容器主体的高度方向尺寸和宽度方向尺寸设计成分别增大与沿着第6面的部分、沿着第3面的部分和沿着第4面的部分各自的厚度相应的量。即,基于电容器主体的尺寸扩大来实现内部电极层的数量的增加和内部电极层的面积的增加,因此,能够对电容增加有贡献。In conventional multilayer ceramic capacitors, the first and second external electrodes are each substantially L-shaped, lacking a portion along the sixth surface of the capacitor body, a portion along the third surface, or a portion along the fourth surface. Therefore, compared to a multilayer ceramic capacitor of the same external dimensions (length, width, and height) using a U-shaped external electrode having a portion along the sixth surface, the height dimension of the capacitor body can be designed to be larger by an amount corresponding to the thickness of the portion along the sixth surface. Furthermore, compared to a multilayer ceramic capacitor of the same external dimensions using a bottomed, rectangular cylindrical external electrode having a portion along the sixth surface, a portion along the third surface, and a portion along the fourth surface, the height and width dimensions of the capacitor body can be designed to be larger by an amount corresponding to the thickness of the portion along the sixth surface, the portion along the third surface, and the portion along the fourth surface, respectively. In other words, the increase in the number and area of the internal electrode layers due to the increased size of the capacitor body can contribute to an increase in capacitance.
关于在上文中所记载的电容增加,尝试了作为电容器主体的除了第1内部电极层和第2内部电极层之外的部分的材料,使用相对介电常数高的高介电常数类电介质陶瓷,但是,使用高介电常数类电介质陶瓷时,层叠陶瓷电容器自身的DC偏压特性恶化,施加了比额定电压高的直流电压时的有效电容大幅降低。Regarding the increase in capacitance described above, attempts were made to use high-dielectric-constant dielectric ceramics with a high relative dielectric constant as the material for the capacitor body, excluding the first and second internal electrode layers. However, the use of high-dielectric-constant dielectric ceramics deteriorated the DC bias characteristics of the multilayer ceramic capacitor itself, significantly reducing the effective capacitance when a DC voltage higher than the rated voltage was applied.
现有技术文献Prior art literature
专利文献Patent Literature
专利文献1:日本特开2015-228481号公报Patent Document 1: Japanese Patent Application Laid-Open No. 2015-228481
发明内容Summary of the Invention
发明想要解决的技术问题The technical problem that the invention aims to solve
本发明的课题在于提供一种层叠陶瓷电容器,其不损害电容增加的好处,而且在为了进一步增加电容使用了高介电常数类电介质陶瓷的情况下也能够抑制DC偏压特性恶化。An object of the present invention is to provide a multilayer ceramic capacitor that does not compromise the benefit of increased capacitance and can suppress deterioration of DC bias characteristics even when a high-dielectric-constant dielectric ceramic is used to further increase capacitance.
用于解决技术问题的技术方案Technical solutions to technical problems
为了解决上述课题,本发明的层叠陶瓷电容器,其特征在于,包括:(1)电容器主体,包括:在长度方向上相对的第1面和第2面;在宽度方向上相对的第3面和第4面;和在高度方向上相对的第5面和第6面,并且内置有多个第1内部电极层和多个第2内部电极层隔着电介质层层叠的电容部;(2)第1外部电极,其具有沿着上述电容器主体的上述第1面的第1部分和沿着上述第5面的第2部分,在上述第1外部电极的上述第1部分连接着上述多个第1内部电极层各自的端缘;和(3)第2外部电极,其具有沿着上述电容器主体的上述第2面的第1部分和沿着上述第5面的第2部分,在上述第2外部电极的上述第1部分连接着上述多个第2内部电极层各自的端缘,上述电容器主体的上述第1面为凹面形状,上述第1外部电极的上述第1部分与上述电容器主体的上述第1面相接,上述电容器主体的上述第2面为凹面形状,上述第2外部电极的上述第1部分与上述电容器主体的上述第2面相接。In order to solve the above-mentioned problems, the multilayer ceramic capacitor of the present invention is characterized in that it comprises: (1) a capacitor body comprising: a first surface and a second surface opposite to each other in the length direction; a third surface and a fourth surface opposite to each other in the width direction; and a fifth surface and a sixth surface opposite to each other in the height direction, and having a built-in capacitor portion in which a plurality of first internal electrode layers and a plurality of second internal electrode layers are stacked with dielectric layers therebetween; (2) a first external electrode having a first portion along the first surface of the capacitor body and a second portion along the fifth surface, the first portion of the first external electrode being connected to the plurality of first internal electrode layers and the second internal electrode layers. and (3) a second external electrode having a first portion along the second surface of the capacitor body and a second portion along the fifth surface, wherein the first portion of the second external electrode is connected to the end edges of the plurality of second internal electrode layers, the first surface of the capacitor body is concave, the first portion of the first external electrode is in contact with the first surface of the capacitor body, the second surface of the capacitor body is concave, and the first portion of the second external electrode is in contact with the second surface of the capacitor body.
发明效果Effects of the Invention
根据本发明,能够提供一种层叠陶瓷电容器,其不损害电容增加的好处而且在为了进一步增加电容而使用了高介电常数类电介质陶瓷的情况下也能够抑制DC偏压特性恶化。According to the present invention, a multilayer ceramic capacitor can be provided that does not lose the advantage of increased capacitance and can suppress deterioration of DC bias characteristics even when a high-dielectric-constant dielectric ceramic is used to further increase capacitance.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是从电容器主体的第6面f6一侧观看使用了本发明的层叠陶瓷电容器的图。FIG1 is a diagram showing a multilayer ceramic capacitor according to the present invention as viewed from the sixth surface f6 of the capacitor body.
图2是沿着图1的S1-S1线的截面图。FIG. 2 is a cross-sectional view taken along line S1 - S1 in FIG. 1 .
图3是沿着图1的S2-S2线的截面图。FIG3 is a cross-sectional view taken along line S2 - S2 of FIG1 .
图4是表示评价用试样的条件和特性的图。FIG. 4 is a diagram showing conditions and characteristics of evaluation samples.
附图标记说明Description of Reference Numerals
10…层叠陶瓷电容器;11…电容器主体;f1…电容器主体的凹面形状的第1面;f2…电容器主体的凹面形状的第2面;Dmax…电容器主体的凹面形状的第1面和凹面形状的第2面之间的最大长度方向尺寸;Dmin…电容器主体的凹面形状的第1面和凹面形状的第2面之间的最小长度方向尺寸;f3…电容器主体的平面形状的第3面;f4…电容器主体的平面形状的第4面;f5…电容器主体的平面形状的第5面、f6…电容器主体的平面形状的第6面;12…第1外部电极;12a…第1外部电极的第1部分;12b…第1外部电极的第2部分;13…第2外部电极;13a…第2外部电极的第1部分;13b…第2外部电极的第2部分。10…multilayer ceramic capacitor; 11…capacitor body; f1…first surface of the concave shape of the capacitor body; f2…second surface of the concave shape of the capacitor body; Dmax…maximum lengthwise dimension between the first surface of the concave shape and the second surface of the concave shape of the capacitor body; Dmin…minimum lengthwise dimension between the first surface of the concave shape and the second surface of the concave shape of the capacitor body; f3…third surface of the planar shape of the capacitor body; f4…fourth surface of the planar shape of the capacitor body; f5…fifth surface of the planar shape of the capacitor body, f6…sixth surface of the planar shape of the capacitor body; 12…first external electrode; 12a…first portion of the first external electrode; 12b…second portion of the first external electrode; 13…second external electrode; 13a…first portion of the second external electrode; 13b…second portion of the second external electrode.
具体实施方式DETAILED DESCRIPTION
首先,使用图1~图3对使用本发明的层叠陶瓷电容器10的构造进行说明。First, the structure of a multilayer ceramic capacitor 10 according to the present invention will be described using FIG. 1 to FIG. 3 .
层叠陶瓷电容器10的尺寸由长度L和宽度W以及高度H规定。该层叠陶瓷电容器10包括大致长方体形状的电容器主体11、大致L字形状的第1外部电极12和大致L字形状的第2外部电极13。The dimensions of the multilayer ceramic capacitor 10 are defined by a length L, a width W, and a height H. The multilayer ceramic capacitor 10 includes a substantially rectangular parallelepiped capacitor body 11 , a substantially L-shaped first external electrode 12 , and a substantially L-shaped second external electrode 13 .
电容器主体11包括:在长度方向上相对的第1面f1和第2面f2;在宽度方向上相对的第3面f3和第4面f4;和在高度方向上相对的第5面f5和第6面f6。另外,在电容器主体11中内置有由多个第1内部电极层14和多个第2内部电极层15隔着电介质层16交替层叠而成的电容部(附图标记省略),该电容部的宽度方向两侧和高度方向两侧被由电介质形成的边缘部(附图标记省略)覆盖。即,各第1内部电极层14的轮廓和各第2内部电极层15的轮廓为矩形,各第1内部电极层14的轮廓尺寸和厚度与各第2内部电极层15的轮廓尺寸和厚度大致相同,各电介质层16的厚度大致相同。The capacitor body 11 includes: a first surface f1 and a second surface f2 that are opposite to each other in the length direction; a third surface f3 and a fourth surface f4 that are opposite to each other in the width direction; and a fifth surface f5 and a sixth surface f6 that are opposite to each other in the height direction. Furthermore, a capacitor portion (reference numerals omitted) is built into the capacitor body 11 and is formed by alternating stacking of a plurality of first internal electrode layers 14 and a plurality of second internal electrode layers 15 with dielectric layers 16 interposed therebetween. Both sides of the width direction and both sides of the height direction of the capacitor portion are covered by edge portions (reference numerals omitted) formed by dielectrics. Specifically, the outline of each first internal electrode layer 14 and the outline of each second internal electrode layer 15 are rectangular, the outline size and thickness of each first internal electrode layer 14 are substantially the same as the outline size and thickness of each second internal electrode layer 15, and the thickness of each dielectric layer 16 is substantially the same.
各第1内部电极层14的长度方向一端部(图2的左端部)为引出部14a,各引出部14a的端缘被引出到电容器主体11的第1面f1,各端缘与第1外部电极12的第1部分12a连接。另外,各第2内部电极层15的长度方向一端部(图2的右端部)为引出部15a,各引出部15a的端缘被引出到电容器主体11的第2面f2,各端缘与第2外部电极13的第1部分13a连接。One end portion in the longitudinal direction of each first internal electrode layer 14 (the left end portion in FIG. 2 ) forms a lead portion 14a. The end edge of each lead portion 14a is led to the first surface f1 of the capacitor body 11, and each end edge is connected to the first portion 12a of the first external electrode 12. Furthermore, one end portion in the longitudinal direction of each second internal electrode layer 15 (the right end portion in FIG. 2 ) forms a lead portion 15a. The end edge of each lead portion 15a is led to the second surface f2 of the capacitor body 11, and each end edge is connected to the first portion 13a of the second external electrode 13.
电容器主体11的第3面f3、第4面f4、第5面f5和第6面f6分别为大致平坦的平面形状,但是第1面f1和第2面f2分别为具有深度的凹面形状。该“凹面形状”是指向中央或者中央附近去深度增加的形状,面本身可以是凹凸不平的也可以是平滑的。图2中的Dmax和Dmin是替代规定“凹面形状”的规格的尺寸,Dmax表示凹面形状的第1面f1与凹面形状的第2面f2之间的最大长度方向尺寸(长度方向最大尺寸)、具体而言在第1面f1的边与第2面f2的边之间呈现的最大的长度方向尺寸,Dmin表示在凹面形状的第1面f1与凹面形状的第2面f2之间的最小长度方向尺寸(长度方向最小尺寸),具体而言表示在第1面f1的最深部与第2面f2的最深部之间呈现的最小的长度方向尺寸。此外,优选凹面形状的第1面f1的最大深度与凹面形状的第2面f2的最大深度大致相同,但是并不一定为大致相同。另外,优选凹面形状的第1面f1的规格与凹面形状的第2面f2的规格大致相同,但是并不一定为大致相同。The third surface f3, the fourth surface f4, the fifth surface f5, and the sixth surface f6 of the capacitor body 11 are respectively substantially flat plane shapes, but the first surface f1 and the second surface f2 are respectively concave shapes with depth. This "concave shape" is a shape with increasing depth toward the center or near the center, and the surface itself can be uneven or smooth. Dmax and Dmin in Figure 2 are dimensions that replace the specifications for the "concave shape". Dmax represents the maximum length direction dimension (maximum length direction dimension) between the first surface f1 of the concave shape and the second surface f2 of the concave shape, specifically the maximum length direction dimension presented between the edge of the first surface f1 and the edge of the second surface f2. Dmin represents the minimum length direction dimension (minimum length direction dimension) between the first surface f1 of the concave shape and the second surface f2 of the concave shape, specifically the minimum length direction dimension presented between the deepest part of the first surface f1 and the deepest part of the second surface f2. In addition, it is preferred that the maximum depth of the first surface f1 of the concave shape is approximately the same as the maximum depth of the second surface f2 of the concave shape, but they are not necessarily approximately the same. In addition, it is preferred that the specifications of the first surface f1 of the concave shape are approximately the same as the specifications of the second surface f2 of the concave shape, but they are not necessarily approximately the same.
第1外部电极12为具有沿着电容器主体11的凹面形状的第1面f1的第1部分12a和沿着平面形状的第5面f5的第2部分12b的大致L字形状,第1部分12a与凹面形状的第1面f1紧贴,第2部分12b与平面形状的第5面f5紧贴。另外,第2外部电极13为具有沿着电容器主体11的凹面形状的第2面f2的第1部分13a和沿着平面形状的第5面f5的第2部分13b的大致L字形状,第1部分13a与凹面形状的第2面f2紧贴,第2部分13b与平面形状的第5面f5紧贴。The first external electrode 12 has a generally L-shaped structure, comprising a first portion 12a extending along the concave first surface f1 of the capacitor body 11, and a second portion 12b extending along the planar fifth surface f5. The first portion 12a is in close contact with the concave first surface f1, while the second portion 12b is in close contact with the planar fifth surface f5. Furthermore, the second external electrode 13 has a generally L-shaped structure, comprising a first portion 13a extending along the concave second surface f2 of the capacitor body 11, and a second portion 13b extending along the planar fifth surface f5. The first portion 13a is in close contact with the concave second surface f2, while the second portion 13b is in close contact with the planar fifth surface f5.
另外,第1外部电极12的第1部分12a的厚度比电容器主体11的凹面形状的第1面f1的最大深度大,并且第2外部电极13的第1部分13a的厚度比电容器主体11的凹面形状的第2面f1的最大深度大。因此,在从第6面f6一侧观看电容器主体11时,第1外部电极12的第1部分12a和第2外部电极13的第1部分13a分别从该电容器主体11突出到外侧。此外,优选第1外部电极12的第1部分12a的突出部分的厚度与第2外部电极13的第1部分13a的突出部分的厚度大致相同,但是,并不一定为大致相同。另外,第1外部电极12的第2部分12b的厚度和长度方向尺寸与第2外部电极13的第2部分13b的厚度和长度方向尺寸大致相同。Furthermore, the thickness of the first portion 12a of the first external electrode 12 is greater than the maximum depth of the concave first surface f1 of the capacitor body 11, and the thickness of the first portion 13a of the second external electrode 13 is greater than the maximum depth of the concave second surface f1 of the capacitor body 11. Therefore, when the capacitor body 11 is viewed from the sixth surface f6, the first portion 12a of the first external electrode 12 and the first portion 13a of the second external electrode 13 each protrude outward from the capacitor body 11. While the thickness of the protruding portion of the first portion 12a of the first external electrode 12 and the thickness of the protruding portion of the first portion 13a of the second external electrode 13 are preferably approximately the same, they are not necessarily the same. Furthermore, the thickness and longitudinal dimension of the second portion 12b of the first external electrode 12 are approximately the same as the thickness and longitudinal dimension of the second portion 13b of the second external electrode 13.
虽然省略图示,第1外部电极12具有包括与电容器主体11的凹面形状的第1面f1和平面形状的第5面f5紧贴的基底膜和与该基底膜的外表面紧贴的表面膜的2层构造,或者具有在基底膜和表面膜之间包括至少1个中间膜的多层构造。另外,第2外部电极13具有包括与电容器主体11的凹面形状的第2面f2和平面形状的第5面f5紧贴的基底膜和与该的基底膜的外表面的表面膜的2层构造、或者具有在基底膜和表面膜之间包括至少1个中间膜的多层构造。Although not shown in the figure, the first external electrode 12 has a two-layer structure including a base film that is in close contact with the concave first surface f1 and the flat fifth surface f5 of the capacitor body 11, and a surface film that is in close contact with the outer surface of the base film, or a multilayer structure including at least one intermediate film between the base film and the surface film. Furthermore, the second external electrode 13 has a two-layer structure including a base film that is in close contact with the concave second surface f2 and the flat fifth surface f5 of the capacitor body 11, and a surface film that is in close contact with the outer surface of the base film, or a multilayer structure including at least one intermediate film between the base film and the surface film.
对电容器主体11的材料补充说明,电容器主体11的除了第1内部电极层14和第2内部电极层15之外的部分,优选能够使用以钛酸钡、钛酸锶、钛酸钙、钛酸镁、锆酸钙、锆钛酸钙、锆酸钡、氧化钛等为主成分的高介电常数类电介质陶瓷,更优选能够使用相对介电常数在1000以上的高介电常数类电介质陶瓷。As a supplementary explanation of the material of the capacitor body 11, the portion of the capacitor body 11 other than the first internal electrode layer 14 and the second internal electrode layer 15 can preferably use a high dielectric constant dielectric ceramic whose main components are barium titanate, strontium titanate, calcium titanate, magnesium titanate, calcium zirconate, calcium zirconate titanate, barium zirconate, titanium oxide, etc., and more preferably use a high dielectric constant dielectric ceramic with a relative dielectric constant of 1000 or more.
对各第1内部电极层14的材料和各第2内部电极层15的材料补充说明,各第1内部电极层14和各第2内部电极层15优选能够使用以镍、铜、钯、铂、银、金、它们的合金等为主成分的良导体。To supplementally explain the material of each first internal electrode layer 14 and each second internal electrode layer 15 , each first internal electrode layer 14 and each second internal electrode layer 15 can preferably use a good conductor mainly composed of nickel, copper, palladium, platinum, silver, gold, or alloys thereof.
对第1外部电极12和第2外部电极13各自的基底膜等的材料和作制方法补充说明,第1外部电极12和第2外部电极13各自的基底膜例如由烤膜或者镀膜构成,该基底膜优选能够使用以镍、铜、钯、铂、银、金、它们的合金等为主成分的良导体。表面膜例如由镀膜构成,该表面膜优选能够使用以铜、锡、钯、金、锌、它们的合金等为主成分的良导体。中间膜例如由镀膜构成,该中间膜优选能够使用以铂、钯、金、铜、镍、它们的合金等为主成分的良导体。The materials and manufacturing methods of the base films of the first and second external electrodes 12, 13 are supplementally explained. The base films of the first and second external electrodes 12, 13 are, for example, formed of a baked film or a plated film. A good conductor primarily composed of nickel, copper, palladium, platinum, silver, gold, or alloys thereof can be used for the base films. The surface films are, for example, formed of a plated film. A good conductor primarily composed of copper, tin, palladium, gold, zinc, or alloys thereof can be used for the surface films. The intermediate films are, for example, formed of a plated film. A good conductor primarily composed of platinum, palladium, gold, copper, nickel, or alloys thereof can be used for the intermediate films.
此外,在图1~图3中,描绘了长度L和宽度W以及高度H分别为长度L>宽度W=高度H的层叠陶瓷电容器10,但是,上述长度L、宽度W和高度H的关系除了长度L>宽度W>高度H、长度L>高度H>宽度W之外,也可以为宽度W>长度L=高度H、宽度W>长度L>高度H、宽度W>高度H>长度L。另外,将第1内部电极层14和第2内部电极层15各描绘了7层,并且描绘了13层的电介质层16,但是,上述是图示的情况,第1内部电极层14和第2内部电极层15各自的数量也可以为8层以上(电介质层16的数量为15层以上),也可以为6层以下(电介质层16的数量为11层以下)。1 to 3 illustrate a multilayer ceramic capacitor 10 having a length L, a width W, and a height H, respectively, such that length L > width W = height H. However, the relationship between length L, width W, and height H may be such that width W > length L = height H, width W > length L > height H, or width W > height H > length L, in addition to length L > width W > height H and length L > height H > width W. Furthermore, although the first and second internal electrode layers 14 and 15 are each depicted as having seven layers, and the dielectric layers 16 are depicted as having 13 layers, this is for illustration purposes only. The number of first and second internal electrode layers 14 and 15 may each be 8 or more (the number of dielectric layers 16 may be 15 or more), or 6 or less (the number of dielectric layers 16 may be 11 or less).
接着,适当引用图1~图3的附图标记,对适用于上述层叠陶瓷电容器10的制法例进行说明。Next, an example of a manufacturing method applicable to the above-mentioned multilayer ceramic capacitor 10 will be described, citing reference numerals in FIG. 1 to FIG. 3 as appropriate.
在制造时,准备含有电介质陶瓷粉末的陶瓷浆料,含有良导体粉末的第1电极膏,和含有良导体粉末并且含有共材(与在陶瓷浆料中所包含的电介质陶瓷粉末相同的电介质陶瓷粉末)的第2电极膏。接着,在载体膜的表面涂敷上述陶瓷浆料并使其干燥,制作第1生片。另外,在第1生片的表面印刷上述第1电极膏并使其干燥,制作作为第1内部电极层14和第2内部电极层15的前体的形成有内部电极图案组的第2生片。During production, a ceramic slurry containing dielectric ceramic powder, a first electrode paste containing good conductor powder, and a second electrode paste containing good conductor powder and a common material (the same dielectric ceramic powder as the dielectric ceramic powder contained in the ceramic slurry) are prepared. The ceramic slurry is then applied to the surface of a carrier film and dried to produce a first green sheet. Separately, the first electrode paste is printed on the surface of the first green sheet and dried to produce a second green sheet with an internal electrode pattern set formed thereon, serving as a precursor for the first and second internal electrode layers 14 and 15.
接着,反复进行叠层热压接的操作直至从第1生片所取出的单位片达到规定个数,制作与高度方向一侧的边缘部对应的部位。另外,反复进行叠层热压接的操作直至从第2生片所取出的单位片(包含内部电极图案组)达到规定个数,制作与电容部对应的部位。并且,反复进行叠层热压接的操作直至从第1生片所取出的单位片达到规定个数,制作与高度方向另一侧的边缘部对应的部位。最后,对所叠层的整体进行正式热压,制作未烧制层叠片。Next, the lamination hot pressing operation is repeated until the number of unit sheets taken out from the first green sheet reaches a predetermined number, and a portion corresponding to the edge portion on one side in the height direction is produced. Furthermore, the lamination hot pressing operation is repeated until the number of unit sheets (including the internal electrode pattern group) taken out from the second green sheet reaches a predetermined number, and a portion corresponding to the capacitor portion is produced. Furthermore, the lamination hot pressing operation is repeated until the number of unit sheets taken out from the first green sheet reaches a predetermined number, and a portion corresponding to the edge portion on the other side in the height direction is produced. Finally, the entire laminate is formally hot pressed to produce an unfired laminate.
接着,将未烧制层叠片按格子状切断,制作未烧制芯片。接着,在未烧制芯片的长度方向两个面分别浸渍上述第2电极膏并使其干燥,并且,在未烧制芯片的高度方向一个面印刷上述第2电极膏并使其干燥,制作与第1外部电极12和第2外部电极13各自的基底膜对应的未烧制基底膜。Next, the unfired laminated sheet is cut into a grid pattern to produce unfired chips. Next, the second electrode paste is impregnated onto both longitudinal surfaces of the unfired chips and dried, and the second electrode paste is printed onto one height surface of the unfired chips and dried, thereby producing unfired base films corresponding to the base films of the first external electrode 12 and the second external electrode 13.
接着,将多个形成了未烧制基底膜的未烧制芯片,在与上述陶瓷浆料中所包含的电介质陶瓷粉末和上述第1电极膏以及上述第2电极膏中所包含的良导体粉末相应的气氛下,并且按温度曲线一并进行烧制(包括脱粘结剂处理和烧制处理),根据需要进行二次烧制(再氧化处理),制作烧制芯片。接着,将多个烧制芯片一并滚筒研磨(抛光),将角和棱线进行倒圆,制作电容器主体11。Next, multiple unfired chips, each having an unfired base film formed thereon, are collectively fired (including a debindering process and firing process) in an atmosphere corresponding to the dielectric ceramic powder contained in the ceramic slurry and the good conductor powder contained in the first and second electrode pastes, according to a temperature profile. A secondary firing (reoxidation process) is performed as needed to produce fired chips. Subsequently, the multiple fired chips are collectively barrel-polished (polished) to round off corners and edges, thereby producing capacitor body 11.
在上述未烧制芯片作制工序中所得到的未烧制芯片的长度方向两个面分别为大致平坦的平面形状,但是,在上述未烧制基底膜作制工序中分别在未烧制芯片的长度方向两个面形成的未烧制基底膜中含有共材,在未烧制芯片的宽度方向两个面和高度方向另一个面没有形成未烧制基底膜。因此,在上述烧制芯片作制工序中,根据未烧制基底膜中所含有的共材的含量,作用将未烧制芯片的长度方向两个面分别向宽度方向内侧压缩的力CF(参照图1)并且作用向高度方向内侧压缩的力CF(参照图2),基于这些压缩力,未烧制芯片的长度方向两个面分别整形为凹面形状。The two longitudinal surfaces of the unfired chip obtained in the above-mentioned unfired chip manufacturing process are respectively substantially flat plane shapes. However, the unfired base film formed on the two longitudinal surfaces of the unfired chip in the above-mentioned unfired base film manufacturing process contains a common material, and no unfired base film is formed on the two width-direction surfaces and the other height-direction surface of the unfired chip. Therefore, in the above-mentioned fired chip manufacturing process, depending on the content of the common material contained in the unfired base film, a force CF is applied to compress the two longitudinal surfaces of the unfired chip inward in the width direction (see FIG. 1 ) and a force CF is applied to compress the two longitudinal surfaces of the unfired chip inward in the height direction (see FIG. 2 ). Based on these compressive forces, the two longitudinal surfaces of the unfired chip are respectively shaped into concave shapes.
此外,未烧制基底膜中所包含的共材(在此,是与上述陶瓷浆料中所包含的电介质陶瓷粉末相同的电介质陶瓷粉末)产生上述作用,但是,替代上述共材而使用具有与该共材相同程度的热膨胀系数的材料、例如具有与上述陶瓷浆料中所包含的电介质陶瓷粉末相同程度的热膨胀系数的其它种类的电介质陶瓷粉末、具有与上述陶瓷浆料中所包含的电介质陶瓷粉末相同程度的热膨胀系数的玻璃粉末等,也能够进行上述同样的整形。In addition, the common material contained in the unfired base film (here, the same dielectric ceramic powder as the dielectric ceramic powder contained in the above-mentioned ceramic slurry) produces the above-mentioned effect, but the same shaping as above can be achieved by using a material having a thermal expansion coefficient similar to that of the common material instead of the above-mentioned common material, for example, another type of dielectric ceramic powder having a thermal expansion coefficient similar to that of the dielectric ceramic powder contained in the above-mentioned ceramic slurry, or glass powder having a thermal expansion coefficient similar to that of the dielectric ceramic powder contained in the above-mentioned ceramic slurry.
接着,通过电解电镀、无电解电镀等的湿式镀层法,或者溅射、真空蒸镀等的干式镀层法形成覆盖烧制芯片的各基底膜的表面膜、或者中间膜和表面膜,分别制作第1外部电极12和第2外部电极13。Next, a surface film, or an intermediate film and a surface film covering each base film of the fired chip is formed by a wet plating method such as electrolytic plating or electroless plating, or a dry plating method such as sputtering or vacuum evaporation, thereby producing the first external electrode 12 and the second external electrode 13 respectively.
接着,使用图4,对用于评价上述层叠陶瓷电容器10而准备的试样1~12的条件和特性等进行说明。Next, conditions, characteristics, and the like of samples 1 to 12 prepared for evaluating the above-described multilayer ceramic capacitor 10 will be described using FIG. 4 .
各试样1~12是基于上述制法例所制造的样品,各试样1~12的共通条件和不同条件如以下所述。此外,共通条件和不同条件中所记载的数值均是设计上的基准值,不包含制造公差。Samples 1 to 12 were manufactured based on the above-mentioned manufacturing method. The common and different conditions for each of Samples 1 to 12 are as follows. The values listed in the common and different conditions are design reference values and do not include manufacturing tolerances.
<试样1~12的共通条件(引用图1~图3的附图标记)><Common Conditions for Samples 1 to 12 (Referring to Reference Symbols in FIG. 1 to FIG. 3 )>
·额定电压为6.3V,额定电容为2.2μF。The rated voltage is 6.3V and the rated capacitance is 2.2μF.
·长度L为600μm,宽度W为300μm,高度H为300μm。The length L is 600 μm, the width W is 300 μm, and the height H is 300 μm.
·电容器主体11的长度方向尺寸(对应于最大长度方向尺寸Dmax)为520μm,宽度方向尺寸为300μm,高度方向尺寸为275μm。The capacitor body 11 has a longitudinal dimension (corresponding to a maximum longitudinal dimension Dmax) of 520 μm, a width dimension of 300 μm, and a height dimension of 275 μm.
·电容器主体11的除了第1内部电极层14和第2内部电极层15之外的部分的主成分为钛酸钡。The main component of the portion of the capacitor body 11 excluding the first internal electrode layer 14 and the second internal electrode layer 15 is barium titanate.
·第1内部电极层14和第2内部电极层15的主成分为镍,各自的厚度为0.5μm,各自的层数为123层。The main component of the first internal electrode layer 14 and the second internal electrode layer 15 is nickel, the thickness of each is 0.5 μm, and the number of layers is 123.
·电介质层16的厚度为0.5μm,层数为245层。The dielectric layer 16 has a thickness of 0.5 μm and a number of 245 layers.
·电容器主体11的宽度方向边缘部的厚度为20μm,高度方向边缘部的厚度为15μm。The thickness of the capacitor body 11 at the edge portion in the width direction is 20 μm, and the thickness of the edge portion in the height direction is 15 μm.
·第1外部电极12的第1部分12a的突出部分的厚度和第2外部电极13的第1部分13a的突出部分的厚度为40μm,第1外部电极12的第2部分12b的厚度和第2外部电极13的第2部分13b的厚度为25μm。The thickness of the protruding portion of the first portion 12a of the first external electrode 12 and the protruding portion of the first portion 13a of the second external electrode 13 are 40 μm, and the thickness of the second portion 12b of the first external electrode 12 and the second portion 13b of the second external electrode 13 are 25 μm.
·第1外部电极12和第2外部电极13分别为3层构造,基底膜的主成分为铜,中间膜的主成分为镍,表面膜的主成分为锡。The first external electrode 12 and the second external electrode 13 each have a three-layer structure, wherein the main component of the base film is copper, the main component of the intermediate film is nickel, and the main component of the surface film is tin.
<试样1~12的不同条件(引用图1~图3的附图标记)><Different Conditions of Samples 1 to 12 (Referring to Reference Symbols in Figures 1 to 3 )>
·试样1的最小长度方向尺寸Dmin为520μm。The minimum longitudinal dimension Dmin of Sample 1 is 520 μm.
·试样2的最小长度方向尺寸Dmin为515μm。The minimum longitudinal dimension Dmin of Sample 2 was 515 μm.
·试样3的最小长度方向尺寸Dmin为510μm。The minimum longitudinal dimension Dmin of Sample 3 was 510 μm.
·试样4的最小长度方向尺寸Dmin为504μm。The minimum longitudinal dimension Dmin of Sample 4 was 504 μm.
·试样5的最小长度方向尺寸Dmin为499μm。The minimum longitudinal dimension Dmin of Sample 5 was 499 μm.
·试样6的最小长度方向尺寸Dmin为494μm。The minimum longitudinal dimension Dmin of Sample 6 is 494 μm.
·试样7的最小长度方向尺寸Dmin为489μm。The minimum longitudinal dimension Dmin of Sample 7 was 489 μm.
·试样8的最小长度方向尺寸Dmin为484μm。The minimum longitudinal dimension Dmin of Sample 8 was 484 μm.
·试样9的最小长度方向尺寸Dmin为478μm。The minimum longitudinal dimension Dmin of Sample 9 was 478 μm.
·试样10的最小长度方向尺寸Dmin为473μm。The minimum longitudinal dimension Dmin of the sample 10 is 473 μm.
·试样11的最小长度方向尺寸Dmin为468μm。The minimum longitudinal dimension Dmin of the sample 11 was 468 μm.
·试样12的最小长度方向尺寸Dmin为463μm。The minimum longitudinal dimension Dmin of the sample 12 was 463 μm.
·各试样1~12的最小长度方向尺寸Dmin在上述制法例中通过分别使用共材的含量不同的第2电极膏而变化。The minimum longitudinal dimension Dmin of each of the samples 1 to 12 was changed by using the second electrode paste having different contents of the common material in the above-mentioned manufacturing method example.
图4的“Dmin/Dmax”中是按试样1~12的每一个记录了将最小长度方向尺寸Dmin除以最大长度方向尺寸Dmax而得到的数值。图4的“电容降低率(%)”中是按试样1~12的每一个,记录了对于试样1~12的各100个使用安捷伦科技公司的精密LCR测试仪4284A施加比额定电压(6.3V)高的直流电压(7.0V)来测定这时的有效电容,并且将从额定电容减去各100个的有效电容的平均值而得到的值除以额定电容所得的值。另外,图4的“分层产生率(%)”是按试样1~12的每一个记录了利用光学显微鏡观察试样1~12的各100个的截面,在电容器主体内的内部电极层中产生分层的个数。The "Dmin/Dmax" in Figure 4 records the value obtained by dividing the minimum longitudinal dimension Dmin by the maximum longitudinal dimension Dmax for each of Samples 1 to 12. The "Capacitance Reduction Rate (%)" in Figure 4 records the effective capacitance at the time of measuring 100 samples 1 to 12 using Agilent Technologies' precision LCR meter 4284A, applying a DC voltage (7.0V) higher than the rated voltage (6.3V) to each of Samples 1 to 12, and the value obtained by subtracting the average value of the effective capacitance of each 100 samples from the rated capacitance and dividing it by the rated capacitance. In addition, the "Delamination Generation Rate (%)" in Figure 4 records the number of delaminations generated in the internal electrode layer within the capacitor body by observing the cross-section of each of Samples 1 to 12 using an optical microscope for each of Samples 1 to 12.
从图4的“电容降低率(%)”的数值可知,与试样1和2的电容降低率相比,试样3~12的电容降低率较小。另外,从图4的“分层产生率(%)”的数值可知,与试样3~12中的、试样12的分层产生率相比,试样3~11的分层产生率较小。即,对于图4的“电容降低率(%)”的数值考虑了“分层产生率(%)”的数值的情况下,Dmin/Dmax的优选范围在0.90以上0.98以下。As can be seen from the "Capacitance Reduction (%)" values in Figure 4, the capacitance reduction rates of Samples 3 to 12 are smaller than those of Samples 1 and 2. Furthermore, the "Delamination Occurrence (%)" values in Figure 4 show that the delamination occurrence rates of Samples 3 to 11 are smaller than those of Sample 12. In other words, when the "Capacitance Reduction (%)" values in Figure 4 are taken into account, the preferred range of Dmin/Dmax is 0.90 or higher and 0.98 or lower.
接着,对通过上述层叠陶瓷电容器10获得的效果进行说明。Next, the effects obtained by the above-described multilayer ceramic capacitor 10 will be described.
(1)上述层叠陶瓷电容器10中,电容器主体11的第1面f1为凹面形状,第1外部电极12的第1部分12a形成为与凹面形状的第1面f1紧贴,电容器主体11的第2面f2为凹面形状,第2外部电极13的第1部分13a形成为与凹面形状的第2面f2紧贴。即,根据该构成,为了进一步增加电容,在电容器主体11的除了第1内部电极层14和第2内部电极层15之外的部分使用了高介电常数类电介质陶瓷的情况下,也能够抑制层叠陶瓷电容器10自身的DC偏压特性恶化。(1) In the above-described multilayer ceramic capacitor 10, the first surface f1 of the capacitor body 11 is concave, and the first portion 12a of the first external electrode 12 is formed so as to be in close contact with the concave first surface f1. The second surface f2 of the capacitor body 11 is concave, and the first portion 13a of the second external electrode 13 is formed so as to be in close contact with the concave second surface f2. Specifically, according to this configuration, even when a high-dielectric-constant dielectric ceramic is used for portions of the capacitor body 11 other than the first internal electrode layer 14 and the second internal electrode layer 15 in order to further increase capacitance, deterioration in the DC bias characteristics of the multilayer ceramic capacitor 10 itself can be suppressed.
通过采用上述构成能够抑制DC偏压特性的恶化的事实,根据使用图4在上文所说明的内容更加明确,但是,作为其根据能够推测是以下的内容。例如,在上述制法例的烧制芯片制作工序中,将未烧制芯片的长度方向两个面分别向宽度方向内侧压缩的力CF(参照图1)和向高度方向内侧压缩的力CF(参照图2)在制造后也残留。即,图1~图3所示的层叠陶瓷电容器10中,第1外部电极12和第2外部电极13分别为大致L字形状,所以,能够形成使将电容器主体11的凹面形状的第1面f1和凹面形状的第2面f2分别向宽度方向内侧压缩的力CF(参照图1)和向高度方向内侧压缩的力CF(参照图2)产生作用的状态,因此,认为即使施加比额定电压高的直流电压,高介电常数类电介质陶瓷的相对介电常数也难以发生变化。While the fact that the above-described structure can suppress deterioration of DC bias characteristics is more clearly demonstrated by the description above using FIG4 , the following can be inferred as the basis for this. For example, in the firing chip manufacturing process of the above-described manufacturing method, the force CF (see FIG1 ) that compresses the longitudinal surfaces of the unfired chip inward in the width direction and the force CF (see FIG2 ) that compresses the longitudinal surfaces of the unfired chip inward in the height direction remains after manufacturing. Specifically, in the multilayer ceramic capacitor 10 shown in FIG1 to FIG3 , the first external electrode 12 and the second external electrode 13 are each substantially L-shaped. Therefore, a state is created in which the force CF (see FIG1 ) that compresses the concave first surface f1 and the concave second surface f2 of the capacitor body 11 inward in the width direction and the force CF (see FIG2 ) that compresses the concave first surface f1 and the concave second surface f2 inward in the height direction, respectively, is applied. Therefore, it is believed that the relative dielectric constant of the high-dielectric-constant dielectric ceramic is unlikely to change even when a DC voltage higher than the rated voltage is applied.
(2)上述层叠陶瓷电容器10中,第1外部电极12的第1部分12a的厚度比电容器主体11的凹面形状的第1面f1的最大深度大,并且第2外部电极13的第1部分13a的厚度比电容器主体11的凹面形状的第2面f2的最大深度大。即,根据采用该构成,即使为了进一步增加电容而在电容器主体11的除了第1内部电极层14和第2内部电极层15之外的部分使用高介电常数类电介质陶瓷的情况下,也能够更可靠地抑制层叠陶瓷电容器10自身的DC偏压特性恶化。(2) In the above-described multilayer ceramic capacitor 10, the thickness of the first portion 12a of the first external electrode 12 is greater than the maximum depth of the concave first surface f1 of the capacitor body 11, and the thickness of the first portion 13a of the second external electrode 13 is greater than the maximum depth of the concave second surface f2 of the capacitor body 11. Specifically, by adopting this configuration, even when a high-dielectric-constant dielectric ceramic is used in portions of the capacitor body 11 other than the first internal electrode layer 14 and the second internal electrode layer 15 in order to further increase capacitance, deterioration in the DC bias characteristics of the multilayer ceramic capacitor 10 itself can be more reliably suppressed.
通过采用上述构成能够更可靠地抑制DC偏压特性的恶化的事实,根据使用图4在上文所说明的内容变得明确,但是,作为其根据能够推测是以下的情况。例如,在图1~图3所示的层叠陶瓷电容器10中,形成使将电容器主体11的凹面形状的第1面f1和凹面形状的第2面f2分别向宽度方向内侧压缩的力CF(参照图1)和向高度方向内侧压缩的力CF(参照图2)产生了作用的状态,需要与第1外部电极12的第1部分12a和第2外部电极13的第1部分13a相应的厚度。所以,认为使第1外部电极12的第1部分12a的厚度比电容器主体11的凹面形状的第1面f1的最大深度大,并且使第2外部电极13的第1部分13a的厚度比电容器主体11的凹面形状的第2面f2的最大深度大的情况下,就能够更可靠地维持上述状态。While the fact that the above-described configuration can more reliably suppress deterioration in DC bias characteristics is clear from the above description using FIG4 , the following is presumably the basis for this. For example, in the multilayer ceramic capacitor 10 shown in FIG1 to FIG3 , a state in which a force CF (see FIG1 ) compresses the concave first surface f1 and the concave second surface f2 of the capacitor body 11 inward in the width direction and inward in the height direction, respectively, is exerted. This requires thicknesses corresponding to those of the first portion 12a of the first external electrode 12 and the first portion 13a of the second external electrode 13. Therefore, it is believed that this state can be more reliably maintained if the thickness of the first portion 12a of the first external electrode 12 is greater than the maximum depth of the concave first surface f1 of the capacitor body 11, and the thickness of the first portion 13a of the second external electrode 13 is greater than the maximum depth of the concave second surface f2 of the capacitor body 11.
(3)上述层叠陶瓷电容器10中,电容器主体11的凹面形状的第1面f1和凹面形状的第2面f2之间的最大长度方向尺寸设为Dmax,电容器主体11的凹面形状的第1面f1和凹面形状的第2面f2之间的最小长度方向尺寸设为Dmin时,最大长度方向尺寸Dmax和最小长度方向尺寸Dmin满足0.90≤Dmin/Dmax≤0.98的条件。对于该条件如使用图4在上文所说明的那样,只要满足该条件,即使施加比额定电压高的直流电压也难以产生电容降低,因此能够更可靠地抑制层叠陶瓷电容器10自身的DC偏压特性恶化,并且,能够抑制电容器主体11内的第1内部电极层14和第2内部电极层15各自产生分层的情况,提供高品质的层叠陶瓷电容器10。(3) In the above-described multilayer ceramic capacitor 10, when the maximum longitudinal dimension between the concave first surface f1 and the concave second surface f2 of the capacitor body 11 is Dmax and the minimum longitudinal dimension between the concave first surface f1 and the concave second surface f2 of the capacitor body 11 is Dmin, the maximum longitudinal dimension Dmax and the minimum longitudinal dimension Dmin satisfy the condition of 0.90 ≤ Dmin/Dmax ≤ 0.98. As described above with reference to FIG. 4 , if this condition is satisfied, even when a DC voltage higher than the rated voltage is applied, capacitance reduction is unlikely to occur. Therefore, degradation of the DC bias characteristics of the multilayer ceramic capacitor 10 itself can be more reliably suppressed. Furthermore, delamination of the first internal electrode layer 14 and the second internal electrode layer 15 within the capacitor body 11 can be suppressed, thereby providing a high-quality multilayer ceramic capacitor 10.
Claims (8)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016-035706 | 2016-02-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HK1237119A1 HK1237119A1 (en) | 2018-04-06 |
| HK1237119B true HK1237119B (en) | 2021-04-16 |
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