GR1009990B - Climate change protection system with power generating units of negative carbon emissions - Google Patents

Abstract

The invention relates to a Biomass Cracking-Carbonization System collaborating with Power Generation Systems, which carbonization system is characterized by the fact that power plants consume -instead of mineral fuels- volatile biomass cleaned from components which are harmful to boilers and gas turbines, without Carbon Dioxide emissions and with parallel retension over double the atmospheric carbon dioxide in the form of pyrolytic activated carbon which is available as an excellent soil enhancer in agriculture, where it dramatically increases the agricultural production in the perpetual, while contributing to the complete decarbonization of the transport means via the methanization of the natural gas and the production of virtual green biofuels for land, sea and air transport.

Description

SYSTEM OF PROTECTION AGAINST CLIMATE CHANGE WITH NEGATIVE CARBON DIOXIDE EMISSION ELECTRICITY UNITS

GENERALLY

Planet Earth or more precisely the Spaceship GAIA, in which we are all on board, is in danger of total destruction of Civilization and the Biosphere, as we know it today, through the destructive invasion of the worst and most dangerous enemy of the Human Race, which we wrongly call Climate Change , a very painless and complacent name for such a monstrous criminal, who threatens to obliterate-murder the Human Race, the Biosphere and Civilization as we know it today, if we do not all join the battle against him, since "In the Spaceship GAIA there are no Passengers. We are all Crew" ("There are no passengers on Spaceship Earth. We are all crew") Marshall McLuhan, Biography [3].

According to a Secret US Army Report [1], [2] which was leaked and published by The OBSERVER newspaper in London and which has also been captured in a Hollywood Science Film (funded by the US Army to awaken the Public Opinion), where the catastrophic effects of Climate Change are popularized according to the controversial US Army Study, Titled "The Day After Tomorrow" [4], i.e. an Ice Age, where Climate Change is predicted to wipe out-kill more than half of the Earth's Population, more than three and a half billion people, while those who survive, if they survive, will have returned to the Stone Age and even an Ice Age for the next 2,000-3,000 years, where the Pandemic of Corona Virus COVID 19 will look like a simple cold, but maybe the Corona Virus will act as a spark of awakening of the Universal Consciousness, in front of the Maximum Dangers from the monstrous Mega-Criminal we misnamed Climate Change,

The proper name of this Mega-Criminal should be (E)Climate Change, which the current state of technology apparently avoids uttering, so as not to panic Doomed Humanity, since it has failed to develop Weapons suitable to deal with it and is content half-measures, such as exhortations to reduce CO2 emissions to zero by 2050, which not only will not be effective but are not even followed, despite the (delayed) signing of the UN COP21 in Paris in December 2015 ,

Where on the one hand the USA has declared that it is disengaged from it and on the other the inexorable need for energy undermines it more, with the Chinese promising to slow down the rate of construction of new Coal Power Plants, but still to implement some 300GW of new Carbon Units by 2030, before they stop and the rest of the Developing World follows them at about half the speed for another 150GW of Carbon Units by 2030 (i.e. more than the total of US and European Union Carbon Units combined today), where with such strategies cannot defeat (Ec)Climate Change, which is already here.

Even worse the overall increase in Atmospheric Carbon Dioxide instead of slowing down is instead accelerating, with an increase in 2018-19 of around 3.0ppm/Year, when the average of the last twenty years was below 2.5ppm/Year, and is getting worse. , especially after the nightmarish forest fires on a planetary scale, with the latest example being the nightmarish satellite images of Australia burning from end to end [5], plus the Amazon [6], Siberia, California, Canada, China, etc., which alone account for approximately half of the Planet's Carbon Dioxide emissions.

The latest Manifesto (11.05.2019) by more than 11,200 Environmental and Energy Scientists from 153 countries, including Greece [7], [8], declares that we no longer have just Climate Change but a Climate Change Urgency ("Climate Change Emergency"), where Climate Change is already here, and that we do not "take" time to wait to react until 2050, it will probably be too late and of no return, we must react and fight it now , yesterday! "We are the First Generation to experience Climate Change and the Last to take Action to deal with it" (Cry of Agony at the WWF Annual Report on 30.10.2018) [9].

The latest Studies from the most authoritative Internationally Recognized Research Bodies and the UN [10], [11], [12], point out that the goal of 2.0°C as an upper limit for global warming is no longer enough, but we need a new target of 1.5°C so that we have a better chance that Climate Change will not become irreversible and that for this purpose it is not enough to get Carbon Dioxide emissions to zero by 2050, but we also need to reduce the volume of Carbon Dioxide that has been trapped in the Atmosphere, where Carbon Dioxide survives for over a thousand years, that is to develop Carbon Dioxide Negative Emission Power Plants, or as the proposed with the present invention are called CO2 Negative Emission Units, for sequestering as much Atmospheric Carbon Dioxide as possible and as quickly as possible,

Whereas with the best version of the UN's 1.5°C Scenario we will achieve zero Carbon Dioxide emissions in 2050, since in the meantime an additional 1500 Gigatons of Carbon Dioxide will have accumulated in the atmosphere (based on 2015), so that we have 80% chance that Climate Change will not become Irreversible and (Ex)Climate Change (with a 20% chance that it will become Irreversible and (Ex)Climate Change, with all that this entails for Human Lives, the Biosphere and Culture as we know it today)

In contrast to the implementation of CO2 Negative Emission Units, which can profitably modify the existing Coal and Natural Gas Power Plants in operation today into CO2 Negative Emission Units, so that in 2050 instead of increasing the accumulated Carbon Dioxide in the atmosphere by 1500 Gigatons (based on 2015 or 1430 Gigatons based on 2020 with all the allowable margins due to the recession due to the Corona Virus), instead we will have a reduction in the amount of Carbon Dioxide accumulated in the Atmosphere due to the operation of the CO2 Negative Emission Units with absorption of 1430 Gigatons of Carbon Dioxide from the Atmosphere, so the increase of Carbon Dioxide in the Atmosphere compared to 2020 will be zero [13], with an incomparably better chance that (E)Climate Change will be defeated and will not become Irreversible, with astronomical business profit for the International Business Community plus the unimaginably great value the of rescuing the victims of (Ex)Climate Change and Civilization as we know it today.

At the same time, among other things, it is recommended that we must protect the Forests from Fires and carry out Extensive Reforestation, with more than 30 Billion New Trees required, but with a noticeable effect in 30-40 years after planting (perhaps too late then!). with Australia's first announcement of 1.0 Billion Trees (very few but a start), as opposed to CO2 Negative Emission Units, which protect Forests directly by clearing them of Residual Biomass and Dry Trees (which convert profitably into Volatile Biomass for Power Generation and Pyrolytic Activated Carbon) and realize the required Billions of New Trees also profitably, as Fruit Trees, where with their rampant growth through Pyrolytic Activated Carbon as a Soil Improver, they bring greater results, in half the time and with spectacular gains for the international economy,

At the same time, a corresponding change in human behavior is recommended in the consumption of energy from the use of the means of transport, which currently consume over 60% of global oil production, where the current level of technology shows half measures, such as the Electric Car, which then only is neutral in terms of Carbon Dioxide emissions, if the electricity consumed is 100% from RES, otherwise it is highly polluting, or very expensive solutions for Shipping and Aviation with Green Biofuels, where all proposed solutions at best do not emit no or a reduced percentage of Carbon Dioxide, but not the desired and absolutely necessary Negative Carbon Dioxide Emissions,

Unlike CO2 Negative Emission Units, which provide direct, economically competitive and environmentally beneficial solutions, as mentioned below, both for the Green CNG Automotive sector, as well as for the Shipping, Aviation and other Land or other Means of Transport with the Green Virtual Biofuels, as below, which arise as inexpensive by-products of Power Generation with Clean Volatile Biomass and Negative Carbon Dioxide Emissions and which not only do not emit Carbon Dioxide into the Atmosphere, but on the contrary absorb Dioxide of Carbon from the Atmosphere, benefiting the Environment and saving the existing infrastructure in the Means of Transport, which with minimal or no conversions can now operate with Negative Carbon Dioxide Emissions, In addition, the current level of technology recommends a shift to Clean Energy Sources , such as RES (clean but insufficient in order to cover the Load Curve and the Strategic Reserve of 90 days of Coal, in times of crisis or prolonged winter), with the parallel abolition and early decommissioning of the entire existing giant infrastructure in Power Plants from fossil fuels, over 5,000GW on a planetary scale, with incalculable damage to the shares of the Companies that operate such Units, loss of millions of jobs, risk of instability of the Grid for operation only with RES, very expensive and uncertain solutions to cover the gap, such as Hydrogen, Batteries, Nuclear Energy, etc.,

Where, on the contrary, the CO2 Negative Emissions Units of the present invention come to cover the above deficiencies and uncertainties by saving the Existing or New Fossil Fuel Power Generation Units, which with minimal or no conversions are transformed into green CO2 Negative Emissions Units, which operate not only without Carbon Dioxide Emissions, but on the contrary, with a Commitment of up to twice as much Atmospheric Carbon Dioxide, i.e. with the sought-after large Negative Carbon Dioxide Emissions, the creation of millions of jobs, an upgrade in the value of the shares of the Companies that operate Fossil Fuel Units transformed into Units of Negative CO2 Emissions, creation of Green Fuels for Transportation, Over-doubling of Agricultural Production by using the produced Pyrolytic Activated Carbon as a Soil Improver and many more, as below,

And most importantly, CO2 Negative Emission Unit Technology transforms the operation of Existing Fossil Fuel Units from harmful to extremely profitable, with a number of parallel beneficial effects as above and not only, where it thus supplies us not only with the Weapons we lack for the battle against on Climate Change, but also the Weapons against the Global Economic Recession due to Corona and much more, i.e. on the one hand the Heavy Artillery to Fight Climate Change and on the other hand a Source of Great Prosperity and Wealth from the very Weapons of Fighting Climate Change, an investment that is, which we are offered to implement, even if we did not have the War of Existence Against Climate Change, simply because it dramatically improves the level of Prosperity and Wealth of Human Society and protects the Biosphere on a planetary level.

B. THE KNOWLEDGE FIELD TODAY

Carbon dioxide capture technology has made significant progress in other applications such as ammonia and fertilizer production, as well as applications where the produced carbon dioxide is sold as a commercial product for various industrial uses. However, for the application in Coal-fired Power Plants, an even greater reduction is needed both in the investment cost of carbon dioxide capture (Capex) and in the burden of the cost of the produced kilowatt-hour, so that its application becomes competitive and sustainable, as well as for the possibility of alternative storage of carbon dioxide, when it is not used as a commercial product, while the technology for sustainable Negative Carbon Dioxide Emissions is completely lacking.

Internationally there is an impressive output of Patents and Papers where proposals are made for the solution of the problems presented below, but despite research and demonstration projects, it has not been possible to date to demonstrate any technology that is technically and economically viable, for dealing with them. In the European Union, it is planned to increase the carbon dioxide tax from the current levels of €25/Ton.CO2 to €30-35/Ton.CO2, the imposition of which will strengthen the sustainability of carbon dioxide capture and storage systems, but does not solve the problems presented below.

Where the current state of the art, despite the support, the great funding and the efforts to date, is not able to present a technically and economically viable technology for a perspective of Protection and Rescue of the Biosphere through the absolutely necessary Negative Carbon Dioxide Emissions and which, on the contrary, can be offered by the technology of the CO2 Negative Emissions Units or Carbon Dioxide Negative Emissions Power Generation Units of the present invention,

Where with the production of Clean Volatile Biomass in combination with Pyrolytic Activated Carbon, which are co-produced in Innovative Pressurized Pyrolysis-Carbonization Units, in collaboration with Modified New or Existing Units with Negative CO2 Emissions, the requested environmental, i.e. Power Generation Units, which instead of emitting Carbon Dioxide into the Atmosphere, on the contrary, they absorb from the Atmosphere up to more than twice the amount of Atmospheric Carbon Dioxide in relation to the Carbon Dioxide Emissions from corresponding Fossil Fuel Units, through the concurrently produced Pyrolytic Activated Carbon, which is at the same time an excellent Soil improver, which remains permanently in the soil for hundreds or even thousands of years and doubles agricultural production in perpetuity,

Already the European Investment Bank, the financing arm of the European Union, announced in mid-2019 that it will stop financing projects linked to fossil fuels from 2021, even for Natural Gas, which was considered the transition fuel to the era of clean fuels and it was going to cover the Load Curve so that there is grid stability due to the nature of RES, which is stochastic size and does not guarantee the coverage of the Load Curve, at night or when the Sun is not enough (PV) or when not the Wind is blowing (Aeolica), which shows recognition of the criticality of the present juncture,

In addition, a very important parameter, which is introduced with the CO2 Negative Emission Units proposed in the present invention, is the survival and continued operation of the existing gigantic infrastructure of Coal and Natural Gas Power Plants (PA), where with a small modification according to present invention are converted into CO2 Negative Emission Units, which not only do not emit Carbon Dioxide into the Atmosphere, but on the contrary they are turned into Green Giants Defenders of the Environment and the Biosphere and Warriors against (E)Climate Change, which absorb and bind up to and more than twice the amount of Atmospheric Carbon Dioxide, where they will thus constitute the Heavy Artillery in the battle against (E)Climate Change, cleaning up the environment and decisively contributing to the achievement of the new UN goal of reducing global warming below 1.5°C until 2050.

Where the amount of atmospheric carbon dioxide, which has already accumulated in the atmosphere, is estimated at 3500 Gigatons (2015) while the maximum amount allowed, so that Climate Change does not become irreversible according to COP21 in Paris in 2015 is 5000 Gigatons, that is, a maximum of 1500 Gigatons is allowed to be emitted in the 35 years until 2050 (based on 2015) or 1430 Gigatons based on 2020, because despite UN admonitions, carbon dioxide emissions are still increasing at an alarming rate of over 3 ,0ppm/Year, where the concentration of carbon dioxide in the Atmosphere is dangerously close to the limit, after which Climate Change can become Irreversible,

Where, on the contrary, if the Existing Coal and Natural Gas Power Plants are Modified, according to the Technology of the Present Invention into CO2 Negative Emission Units for operation with Clean Biomass Volatiles and Pyrolytic Activated Carbon production with up to twice the Negative Carbon Dioxide Emissions as above, of all the currently operating Coal and Natural Gas Power Plants, the upward trajectory of Carbon Dioxide emissions in the Atmosphere on a planetary scale can be reversed and even turned into a corresponding downward trajectory, with the result that instead of an increase of 1500 Gigatons of Carbon Dioxide up to in 2050, as long as the safety margin given by the UN in 2015, to have a zero increase or even a decrease in the concentration of Carbon Dioxide in the Atmosphere, resulting in a much better chance that (E)Climate Change will not become Irreversible [ 13],

To date, the main effort to zero out carbon dioxide emissions in power plants from coal and fossil fuels, concerns the attempt to capture the released carbon dioxide from the exhaust gases of the respective power plants by sprinkling with an ammonia solution and then compressing and channeling it under pressure with piping networks for permanent storage in underground geological formations. But despite the funding and demonstration projects that have been implemented, the corresponding effort has not succeeded in developing carbon dioxide capture technologies that are economically and environmentally sustainable to provide clean electricity generation from coal and are still at the research and development stage. development,

Where, in addition, these technologies simply seek to reduce or even zero the emissions of Carbon Dioxide, although it is necessary not only to reduce the emissions of carbon dioxide from the various sources of its emission, but also to reduce the carbon dioxide of the atmosphere (negative emissions CO2), where carbon dioxide survives for over a thousand years, and where no viable carbon-negative technology for power plants has been proposed or demonstrated to date.

Also regarding the new UN 1.5°C global warming limit for 2050, it is worth noting that sequestration and reduction of Atmospheric Carbon Dioxide with large-scale Negative Carbon Dioxide Emissions will contribute decisively to achieving this goal and for an additional reason, because the proposed modifications to the Existing Power Plants to convert them into CO2 Negative Emission Units, imply on the one hand minimal modifications to the Existing Power Plants and on the other hand an excellent business profit, on the basis of which they can be undertaken by the Global Business Community and be implemented 10-15 years earlier than the UN's 2050 goal, where such a gain of time can be the Regulating Factor that will weigh on the sensitive Environmental Scales of the Planet, so that it turns towards salvation instead of the destruction of Climate Change. C02 Negative Emission Units will thus be the Vaccine against the destructive Climate Change Virus.

C. PRIOR ART ADVANTAGES OF THE PRESENT INVENTION

The main Advantages of the Present Invention with respect to the Current State of the Art, are listed below in comparison with the treatment of the hot Problems in the field of Energy, the danger of Climate Change and the degradation of the Environment, in the most critical period for the future of Civilization to the Planet, which is facing a unique challenge in its history due to Climate Change, which may even mean the end of Civilization as we know it today, as pointed out by all International Research Organizations and the UN, including:

"We are the first generation to know that we are destroying our planet and the last that can do something about it" WWF points out in its Annual Report on 30.10.2018 [9], while recently (11.05.2019) the Declaration was published by more by 11,250 scientists from 153 countries, including Greece, who co-sign the Declaration, with which they warn that there is now, not just Climate Change, but a Climate Emergency [7], [8], where they reason, along with the UN's 2018 IPCC, of "untold human suffering" that will become inevitable unless a radical and lasting shift in human activities, which burden the climate and raise temperatures through "greenhouse gas" emissions, is made immediately ” and where perhaps the most successful exhortation to enlist in the fight against the threat of Climate Change belongs to the well-known Canadian Sociologist Marshall McLuhan, who proclaimed that “In the spaceship GAIA d there are no Passengers. We are all Crew" ("There are no passengers on Spaceship Earth. We are all crew") Marshall McLuhan, Biography [3]. Where addressing the risk of Climate Change, in addition to reducing Carbon Dioxide emissions to zero by 2050, requires, according to authoritative International Research Bodies, State Research Centers and the UN IPCC ([10], [11], [12]) the capture and permanent storage of even greater amounts of Atmospheric Carbon Dioxide or otherwise Negative Carbon Dioxide Emissions, in order to achieve the new UN target of global warming below 1.5°C, so that we can hope a better chance that Climate Change will not become irreversible;

Where to achieve this new UN target the following are the Advantages of the CO2 Negative Emission Units of the Present Invention, which result from the combination of an innovative Pressure Cracking Unit in cooperation with Modified Power Generation Systems (AEi), which enable Power Generation not only with Zero Carbon Dioxide Emissions but contrary to the very large-scale production of Negative Carbon Dioxide Emissions with a parallel dramatic increase in Agricultural Production through the use of the parallel produced Pyrolytic Activated Carbon as an excellent Soil Improver in crops and where the advantages of the Units Negative CO2 Emissions of the Present Invention compared to the Current State of the Art, which also provide a Solution to the existing Problems, are indicative, among others, of the following:

1) They include the Pyrolysis-Carbonation Unit (A.4.1O) which is characterized by the fact that in collaboration with the Carbon Dioxide Emissions Power Generation Systems (A.E.i) it provides Technically and Economically Sustainable Solutions to the main problems that are related with the Production of Energy, in the Degradation of the Environment and in dealing with the Risk of Climate Change, which cannot be solved by the current state of the art, where through the Pyrolysis-Carbonation Units (A.4.1D) they are briefly characterized by, among other things, that:

2) Produce Biomass Pyrolytic Volatiles (009) free from almost 100% of their Harmful Components (A.10.1) for the Boilers (012) of the Steam Electric Units (A.5.1) and for the Gas Turbines (A.6.1A) of the Units Single or Combined Cycle Power Generation (A.6.1') or (A.6.1) in Power Generation Systems (A.E.i), where i= 1 to 5 characterizes the respective versions of the Power Generation Systems of the CO2 Negative Emission Units as described below ,

3) The CO2 Negative Emissions Units with the cooperating Power Generation Systems (A.E.i) not only do not emit Carbon Dioxide but on the contrary operate with the capture of up to twice as much Atmospheric Carbon Dioxide or with Negative Carbon Dioxide Emissions,

4) They save from obsolescence and early decommissioning more than 5000GW of Fossil Fuel Power Plants, which with a small modification are converted into cooperating C02 Negative Emission Units (A.E.i),

5) C02 Negative Emission Units on the one hand avoid Carbon Dioxide Emission Rights Purchase Fees and on the other hand ensure an even larger Credit due to the corresponding higher Negative Carbon Dioxide Emissions,

6) Where the Pyrolysis-Carbonation Units (A.4.10) simultaneously produce Pyrolytic Activated Carbon (008A) and (008B), which is characterized by the fact that it constitutes the Negative Emissions of Carbon Dioxide and, on the other hand, constitutes the filter that retains all harmful components (A.10.1) of Volatile Biomass (009) and makes them suitable for Boilers (012) and Gas Turbines (A.6.1A),

7) Also that Pyrolytic Activated Carbon (008A) and (008B), instead of being buried at high cost in underground geological formations, is instead sold at a profit to agriculture as a permanent Soil Improver that more than doubles agricultural production, where it remains unchanged in the soil for hundreds or even thousands of years and increases agricultural production in perpetuity,

8) Where the CO2 Negative Emission Units in collaboration with the Pyrolysis-Carbonation Units (A.4.10) and the Carbon Dioxide Negative Emission Power Generation Systems (A.E.i), ensure the Coverage of the Load Curve and the 90 Day Strategic Reserve in Extreme periods Weather Phenomena or other Crises, due to long-term storage of Biomass,

9) They reduce the risk of Fires by cleaning the Forests from the Residual Fine Biomass (A.2.1), which through the Pyrolysis-Carbonization Units they transform together with the Woody Biomass (A.2.2) of the Dry or Burnt Trees into Pure Volatile Biomass and Pyrolytic Activated Carbon (008A) and (008B),

10) C02 Negative Emissions Units with Carbon Dioxide Emissions Negative Power Generation Systems (A.E.i), enable Virtual Methanation of Volatile Biomass (009) to Green CNG (010E) for Cars, the combustion of which produces Negative Dioxide Emissions of Coal, through the cooperation of the CO2 Negative Emissions Units with Natural Gas and CNG Distribution Companies of the DEPA type,

11) CO2 Negative Emissions Units with Carbon Dioxide Emissions Negative Power Generation Systems (A.E.i), enable the production of Virtual Green Biofuels (010H) for Shipping through the participation of Ship Owners as Strategic Investors in Investments for CO2 Negative Emissions Units ,

12) Likewise to produce the Virtual Green Biofuels (010Z) and (010M) for Air Transport and other Means of Transport through participation of their Owners or Refinery Suppliers of Green Biofuels (010Z) and (010M) as Strategic Investors for Negative Emission Units CO2 as above,

13) Also in cooperation with the Carbon Dioxide Emissions (A.E.i) Power Generation Systems, replace the planned new Carbon Units in China and the Developing World with economically competitive CO2 Negative Emissions Units,

14) Ensure the survival of Natural Gas and part of Petroleum as Green CNG (010E) and Green Biofuels (010H), (010Z) and (010M) with Negative CO2 Emissions, and beyond 2050, where based on UN COP21 had to be zeroed out,

15) Through the participation of Shipowners and other Owners of Means of Transport as Strategic Investors as above they secure Funds for the necessary investments to convert Existing or New Fossil Fuel Units into CO2 Negative Emission Units (A.E.I),

16) Also, the CO2 Negative Emissions Units are characterized by the fact that in the innovative Pyrolysis-Carbonization Unit (A.4.10) the Pyrolysis-Carbonization is carried out under pressure, indicatively above 20Bar, which is created by the released Biomass Volatiles (009), as below , among other things, the following additional important advantages arise for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), in addition to what is summarized above, i.e. they are additionally characterized by the fact that

17) The CO2 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonation Units (A.4.10) are characterized by the fact that in Pyrolysis-Carbonization under a pressure of 20-40 atmospheres, the required Pyrolysis-Carbonization thermal energy is reduced vertically, which under conditions of more than 20 atmospheres becomes negative [14] (Figure 1 and Table 2], i.e. the Pyrolysis-Carbonization reaction becomes exothermic, where instead of consuming energy in the form of heat, it instead gives off heat to the innovative Pyrolysis-Carbonization Units ( A.4.10) and thus improves the overall degree of power generation efficiency, indicatively by 2-4%, in contrast to pyrolysis with the current state of the art where a significant amount of energy is consumed for the pyrolysis process with a corresponding deterioration of the degree of efficiency of the respective power generation,

18) Where the CO2 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonization Units (A.4.10) are also characterized by the fact that because the Dry Biomass Pyrolysis-Carbonization is carried out under pressure, indicatively above 20Bar, which is created by the released Volatiles Biomass, the Thermal Power of the Pyrolysis-Carbonization Units is multiplied, because the released Biomass Volatiles, which create the overpressure, precisely because of the overpressure, better conduct the pyrolysis heat from and to the casing of the Pyrolysis Subchamber inside it to and from the pyrolyzed Biomass , which is additionally stirred back and forth by the operation of the System of Screws or Dual Direction Propellers, so on the one hand the Thermal Power of the Unit increases and on the other hand the necessary pyrolysis time is reduced,

19) Where the CO2 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonation Units (A.4.10) are also characterized by the fact that due to the pyrolysis under pressure, of the order of more than 20Bar, the production of high quality Pyrolytic Activated Carbon (008A) is simultaneously increased ) and (008B) in a quantity up to and above 50% in relation to the corresponding pyrolysis production under atmospheric pressure [14] (Table 2], i.e. the production of Pyrolytic Activated Carbon (008A) and (008B) reaches indicatively up to and above 40% of the weight of the Dry Biomass (A.2.2A) and (A.2.1A) from which it is derived, compared to 20-27% of the weight of the Dry Biomass for pyrolysis under atmospheric pressure with the present state of the art,

20) Where the C02 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonization Units (A.4.10) are also characterized by the fact that because the Pyrolysis Subchamber (002Ao) of the innovative Pyrolysis-Carbonization Units (A.4.10) with the pressurized operation remains closed for a comparatively long time, compared to the time of simple passage of Biomass Volatiles (009) through the mass of Pyrolytic Activated Carbon (008A) and (008B) under atmospheric pressure, this has the effect that the Biomass Volatiles produced (009) to come into prolonged and pressurized contact with the produced Pyrolytic Activated Carbon (008A) and (008B), in which case an almost complete purification of close to 100% of the produced Volatile Biomass (009) from their Harmful Components occurs (A.10.1 ) (i.e. from Potassium, Sodium, Chlorine, Nitrogen, Sulfur, etc.), which are absorbed and retained by the huge mass of continuously stirred Pyrolytic Activated Carbon (008A) and (008B) and they thus represent the safe use of Cleaned Volatile Biomass (009) for Power Generation, in contrast to the current state of the art pyrolysis under atmospheric pressure, where the purification of Volatile Biomass (009) from their Harmful Components (A.10.1) is incomplete and make them unsuitable for combustion in the Boilers (012) of the Steam Electric Units or in the Gas Turbines (A.6.1A) of the Combined Cycle Units (A.6.1), as also analyzed below,

21) Where the CO2 Negative Emission Units with the innovative Pressurized Pyrolysis-Carbonization Units (A.4.10) are also characterized by the fact that in many applications and types of Biomass this First Passage of Volatile Biomass (009) through the mass of Pyrolytic Active Coal (008A) and (008B) and under the applied overpressure, it is enough for a very satisfactory purification of the Volatile Biomass (009), for the protection of the Boiler (012) or the Gas Turbine (A.6.1A) of the respective Power Generation Units , so either the additional Volatile Biomass Purification Passage through additional Spare Pairs of Subchambers complete with Pyrolytic Activated Carbon becomes unnecessary, or the number of required Multiple Volatile Biomass Purification Passages is drastically reduced to achieve the desired level of Purification as above, so that completely safe Pure or Mixed Combustion of Volatile Biomass (009) inside the Boilers or inside the Gas Turbines of the Modified Units of Negative CO2 Emissions,

22) Where the Combined Cycle CO2 Negative Emissions Units with the innovative Pressurized Coking-Carbonization Units (A.4.10), which feed Biomass Volatiles to the Power Generation Gas Turbine, are also characterized by the fact that due to the production of the Biomass Volatiles under pressure, indicatively above 20Bar, these can be fed directly to the Combustion Chamber of the Gas Turbine of the Combined Cycle Units (A.6.1) of the Systems (A.E.i) of the CO2 Negative Emission Units, in which case the Compressor (A.6.1H) of the Volatile Biomass, with a corresponding improvement in the degree of efficiency, otherwise as analyzed in the Power Generation System (A.E.3) below, in contrast to the pyrolysis with the present state of the art under atmospheric pressure, where the Volatile Biomass even when cleaned from the Their Harmful Components (A.10.1), need the Compressor (A.6.1H) for compression to a pressure above 20Bar to enter the Combustion Chamber of the Gas Turbine (A.6.1A), resulting in a deterioration in the degree of performance,

23) Where the Combined Cycle CO2 Negative Emissions Units with the innovative Pressurized Cracking-Carbonization Units (A.4.10) and the cooperation with the CO2 Negative Emissions Unit Gas Turbine Power Generation Unit are also characterized by the fact that because the cracking-carbonization reaction takes place under pressure exothermic, where instead of consuming energy in the form of heat, it instead gives off heat to the Exhaust Gas Boiler (012B) of the cooperating Combined Cycle Unit (A.6.1), so the Post-Combustion Chamber (A.6.1E), which is necessary when Pyrolysis-Carbonization takes place under atmospheric pressure, otherwise as analyzed in the Power Generation System (A.E.3) below,

24) Where the over-increased Plant Production due to the use of Pyrolytic Activated Carbon (008A) and (008B) as an Improving Soil of the CO2 Negative Emission Units with the innovative Pyrolysis-Carbonation Units (A.4.10) and the corresponding increased Production of Woody Biomass (A. 2.2) increases the capture of Atmospheric Carbon Dioxide, which is even much greater over time in size than the Negative Carbon Dioxide Emissions of Power Generation Systems (A.E.i)

D. DESIGNS

- Drawing No. 1 shows the General Layout in Plan of the Atmospheric Carbon Dioxide Sequestration System by Pyrolysis-Carbonization of Biomass, consisting of a number of Pairs of Pyrolysis-Carbonization Chambers (001A) and Subchambers (002A) with their Peripherals, in collaboration with Modified Steam Power Plant for Combustion of Volatile Biomass.

- Drawing No. 2 shows the General Plan Layout of the Atmospheric Carbon Dioxide Sequestration System by Pyrolysis-Carbonization of Biomass, consisting of a number of Pairs of Pyrolysis-Carbonization Chambers (001A) and Subchambers (002A) with their Peripherals, in collaboration with Modified Combined Cycle Power Plant for Combustion of Volatile Biomass.

- Drawing No. 3 shows in Side View the General Layout on three levels of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.10 and A.4.1A with Ball Valves (039), (040) in a row indicative of the Fixed Tubular Subchambers (002АOA) , (002AO), (002AOB) and (002AAA), (002AA), (002AAB),

- Drawing No. 4 shows in Section and Side View the construction of the Drying-Preheating Sub-Unit A.4.1OA, A.4.1AA, A.E.1.3AA versions of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.10 and A. 4.1A with Ball Valves in series on Fixed Tubular Subchambers (002AOA) or (002AAA),

Drawing No. 5 shows in Section and Side View the construction of the Pyrolysis-Carbonization Sub-Unit A.4.10, A.4.1A, A.E.1.4A of the versions of the Innovative Drying-Pyrolysis-Carbonization Unit A.4.10 and A.4.1A with Ball Valves in series on Fixed Tubular Subchambers (002Ao) or (002AA),

- Drawing No. 6 shows in Section and Side View the construction of the Cooling-Heat Exchange Sub-Unit A.4.10B, A.4.1AB, A.E.1.4AB versions of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.10 and A .4.1A with Ball Valves in series on Fixed Tubular Subchambers (002AOB) or (002AAB),

- Drawing No. 7 shows in Section and Side View the construction of the Drying-Preheating Sub-Units A.4.1AAAA, Pyrolysis-Carbonization A.4.1AAA and Cooling-Heat Exchange A.4.1AAAB of the Edition of the Composite Innovative Drying-Cyrolysis-Carbonization Unit A .4.1H with Ball Valves in series in the three phases of Sub-Units resulting from alternating Isolation Valves and Air Ducts, with Side Valves (039), (040) and (034), (017) and (021) indicatively in the Fixed Tubular Hypothalamus (002AAAA), (002AAA) and (002AAAB),

- Drawing No. 8 shows in Section and Side View Detail A1 of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.10, A.4.1A, A.4.1H with Spherical Valves in a row indicative of the Fixed Tubular Subchambers (002Ao), (002AA ), (002AH),

- Drawing No.9 shows in Section A-A' the construction of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.1A with Spherical Valves in a row indicative of the Fixed Tubular Subchambers (002AAA), (002AA), (002AAB),

- Drawing No. 10 shows in Section B-B' the construction of the Support Scaffolds of the Innovative Drying - Pyrolysis - Carbonization Units A.4.10, A.4.1A, A.4.1E, A.4.1H in the versions with Spherical or Side Valves indicative in Fixed or Rotating Tubular Hypochambers (002Ao), (002AA), (002AE) and (002AH),

- Drawing No. 11 shows the Interconnection Connection of the Cooling-Heat Exchange Subchambers (002AAB), (002AEB) and (002AEB) and the Subchambers (002A'AB), (002A'EB) and (002A'HB) or (002A"AB) ), (002A"EB) and (002A"HB) Cooling-Heat Exchange through the Four-Way Valve (015X) or (015'X),

Drawing No. 12 shows in Side View the General Layout on one level of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.10, A.4.1A and A.4.1E with Lateral Valves (039), (040) and (034), ( 017) and (021) indicative of Fixed or Rotating Tubular Subchambers (002Ao), (002AA) and (002AE)

Drawing No. 13 shows in Section and Side View the construction of the Drying-Preheating Sub-Unit A.4.1OAand A.4.1AA of the versions of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.10 and A.4.1A with Lateral Valves (039), (040) and (034), (017) and (021) in the Fixed Tubular Subchambers (002AOA) and (002AAA),

Drawing No. 14 shows in Section and Side View the construction of the Pyrolysis - Carbonization Sub-Unit A.4.10 and A.4.1A versions of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.10 and A.4.1A with Lateral Valves (039), (040) and (034), (017) and (021) in Fixed Tubular Subchambers (002Ao) and (002AA),

- Drawing No. 15 shows in Section and Side View the construction of the Cooling-Heat Exchange Sub-Unit A.4.10B and A.4.1AB versions of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.10 and A.4.1A with Lateral Valves (039 ), (040) and (034), (017) and (021) in Fixed Tubular Subchambers (002AOB) and (002AAB),

- Drawing No. 16 shows in Section and Side View the construction of the Drying-Preheating Sub-Units A.4.1AAAA, Pyrolysis-Carbonization A.4.1AAA and Cooling-Heat Exchange A.4.1AAAB of the Edition of the Composite Innovative Drying-Cyrolysis-Carbonization Unit A .4.1H in the three phases of Sub-Units resulting from alternating the Isolation Valves and the Air Ducts, with Side Valves (039), (040) and (034), (017) and (021) indicatively in the Fixed Tubular Subchambers (002AAAA) , (002AAA) and (002AAAB),

- Drawing No. 17 shows in Section and Side View Detail A2 of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.1E with Lateral Valves (039), (040) and (034), (017) and (021) indicatively at the Extreme Fixed Part (002AAA), (002AA) and (002AAB) of the Rotating Tubular Subchambers (002AEA), (002AE) and (002AEB),

Drawing No. 18 shows in Section and Side View the construction of the Drying-Preheating Sub-Unit A.4.1E of the Edition of the Innovative Drying-Cryping-Carbonization Unit A.4.1E with Lateral Valves (039), (040) and (034), (017) and (021) in the Rotating Tubular Hypochambers (002AEA),

- Drawing No. 19 shows in Section and Side View the construction of the Pyrolysis-Carbonization Sub-Unit A.4.1E Edition of the Innovative Drying-Pyrolysis-Carbonization Unit A.4.1E with Lateral Valves (039), (040) and (034) , (017) and (021) in the Rotating Tubular Hypothalamus (002AE),

- Drawing No. 20 shows in Section and Side View the construction of the Cooling-Heat Exchange Sub-Unit A.4.1EB of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.1E with Lateral Valves (039), (040) and (034 ), (017) and (021) in the Rotating Tubular Hypochambers (002AEB),

- Drawing No. 21 shows in Section and Side View the construction of the Drying-Preheating Sub-Units A.4.1AEEA, Pyrolysis-Carbonization A.4.1AEE and Heat Exchange Cooling A.4.1AEEB of the Edition of the Composite Innovative Drying-Cyrolysis-Carbonization Unit A.4.1 AE in the three phases of Sub-Units resulting from alternating the Isolation Valves and the corresponding Air Ducts, with Lateral Valves (039), (040) and (034), (017) and (021) indicative of the Extreme Fixed Part (002AAAA), (002AAA) and (002AAAB) of the Rotating Tubular Subchambers (002AEEA), (002AEE) and (002AEEB),

- Drawing No. 22 shows in Section and Side View Detail A3 of the Innovative Drying - Pyrolysis - Carbonization Unit A.4.1E with Lateral Valves (039), (040) and (034), (017) and (021) indicatively at the Extreme Fixed Part (002AAA), (002AA) and (002AAB) of the Rotating Tubular Subchambers (002AEA), (002AE) and (002AEB),

- Drawing No. 23 shows the projected Evolution Curve of the Concentration of Emitted Carbon Dioxide in the Atmosphere without the CO2 Negative Emission Units, in comparison with the predicted Evolution Curve with the Negative Carbon Dioxide Emissions Scenario based on the Current CO2 Negative Emission Units Technology Invention.

E.1. DESCRIPTION OF THE SYSTEM OF PROTECTION AGAINST CLIMATE CHANGE WITH NEGATIVE CARBON DIOXIDE EMISSIONS POWER PLANTS

The Present Invention is characterized by the fact that it consists of a Power Generation System (A.E.i), CO2 Negative Emission Units, where i = 1 to 5, is the index of Alternative Versions of the Power Generation System (A.E.i), the which consists of a Combination of an Innovative Pressurized Pyrolysis-Carbonization Unit (A.4.10) or (A.4.1A) or (A.4.1E) or (A.4.1H) or also under atmospheric pressure (A.4.1' 0) or (A.4.1A) or (A.4.1E) or (A.4.1H), Biomass (A.2.2) and (A.2.1), for the production on the one hand of pure Volatile Biomass (009) for Power Generation, in combination with either a Modified Steam Electric Power Generation Unit (A.5.1) with Pure or Mixed Combustion of Volatile Biomass (009) with Mineral Fuels, indicative of Coal (009A), or with a Modified Simple or Combined Cycle Power Generation Unit (A. 6.1') or (A.6.1) with Pure or Mixed Combustion of Volatile Biomass (009) with Liquid or Gaseous Mineral Fuels, indicatively with Natural Gas (NG) (009B), and on the other hand, in parallel for par treatment of large quantities of Pyrolytic Activated Carbon (008A) and (008B), which constitutes Atmospheric Carbon Dioxide Sequestration, i.e. Negative Carbon Dioxide Emissions, so the Power Generation Units (A.E.I) in combination with the Innovative Pyrolysis Unit- Carbonization as above, are characterized by producing Electricity not only without Carbon Dioxide Emissions, but with Negative Carbon Dioxide Emissions, up to twice as much compared to the Carbon Dioxide emissions from an equivalent Fossil Fuel Power Plant, and where Pyrolytic Activated Carbon (008A) and (008B) is also characterized by the fact that it is intended for permanent storage, indicatively as an excellent Soil Improver in Agriculture, where it more than doubles agricultural production, where the above Negative Emission Units Power Generation System (A.E.I) CO2 is characterized by the fact that it consists of the following Components and Alternative Versions of the Innovative Pyrolysis-Carbonization Unit (A.4.10) and the Power Generation System (A.E.i), namely:

A. Alternative Versions of the Innovative Pyrolysis-Carbonization Unit (A.4.10)

A.0. Pyrolysis-Carbonization Unit (A.4.10) of Biomass Under Pressure, General Form with Fixed or Rotating Chambers and Subchambers

A'1. Pyrolysis-Carbonization Unit (A.4.1A) of Biomass Under Pressure, One Pass Cleaning of Volatile Biomass, with Fixed Chambers and Subchambers

A'2. Pyrolysis-Carbonization Unit (A.4.1E) of Biomass Under Pressure, One Pass Volatile Purification, with Fixed Chambers and Rotating Subchambers

A.3. Pyrolysis-Carbonization Unit (A.4.1H) = (A.4.1HA) or (A.4.1HE) of Biomass Under Pressure, One Pass, Integration into a Complex Pair of Pyrolysis-Carbonization Chambers and Subchambers,

A.4. Pyrolysis-Carbonization Unit (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) of Biomass, Under Atmospheric Pressure, Multiple Purification Passages of Volatile Biomass,

B. CQ2 Negative Emission Unit (A.E.i) Electronic Counterfeiting Systems

B.1. The Power Generation System (A.E.1) as a Unit Combination (A.5.1) with a Pyrolysis-Carbonation Unit (A.4.10) or (A.4.1A) Under Pressure 20-40Bar of a Cleaning Diode,

B 2. The Power Generation System (A.E.2) as a Unit Combination (A.5.1) with a Pyrolysis-Carbonization Unit (A.4.10) or (A.4.1E) Under Pressure 20-40Bar of a Cleaning Diode,

B.3. The Power Generation System (A.E.3) as a Unit Combination (A.6.1) or (A.6.C) with a Pyrolysis-Carbonization Unit (A.4.10) or (A.4.1A) or (A.4.1E) Under Pressure, One Pass Cleaning,

B.4. The Power Generation System (A.E.4) Unit Combination (A.5.1) or (A.6.1) or A.6.1') with Pyrolysis-Carbonation Unit (A.4.10) or (A.4.1H) Under Pressure 20- 40Bar of a Cleaning Diode

B.5. The Power Generation System (A.E.5) Unit Combination (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1A) or ( A.4.1E) or (A.4.1H), Atmospheric Pressure,

Namely:

A. Alternative Versions of the Innovative Pyrolysis-Carbonization Unit (A.4.10).

then a Pyrolysis-Carbonization Unit (A.4.10), which is characterized by the fact that it consists of an Innovative Pyrolysis-Carbonization Unit (A.4.10) of General Form, Under Pressure, Biomass (A.2.2A) and (A.2.1A ), for the production of Clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), which is promoted for use indicatively as a Soil Improver in Agriculture, which is characterized by being carried out under Pressure, indicatively 20- 40Bar, in Fixed or Rotating Chambers (001AOA), (001Ao) and (001AOB) and Subchambers (002AOA), (002AO) and (002AOB) of Pyrolysis-Carbonation, indicatively with Internal Filling System, Forward-Rear Agitation and Discharge of Biomass and of Pyrolytic Activated Carbon through Screws or Double-Directional Propellers (041OA) or (041'OA), in which case very significant advantages arise both for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), as well as and for the Electricity Generation System (A.E.I), such as detailed in the Detailed Description below,

A.0. Pyrolysis-Carbonization Unit (A.4.10) of Pressurized Biomass, General Form with Fixed or Rotating Chambers and Subchambers.

then Pyrolysis-Carbonization Unit (A.4.10), which is characterized by the fact that it is the general form of Pressure Pyrolysis-Carbonization Unit, which includes all the variants of implementation of the pyrolysis-carbonization principle under pressure, in contrast to the current level of the technique where the pyrolysis is carried out under atmospheric pressure, with indicative variations as below, where on the one hand it produces Biomass Pyrolytic Volatiles (009) free up to almost 100% of their Harmful Components (A.10.1) for Boilers (012) of Steam Electric Units ( A.5.1) and for Gas Turbines (A.6.1A) of Single or Combined Cycle Power Generation Units (A.6.1) or (A.6.1) in Power Generation Systems (A.E.I), as below, where the net Volatile Biomass (009) are indicatively intended for Electricity Generation not only without Carbon Dioxide Emissions but on the contrary with sequestration and permanent storage in the ground of up to more than twice the amount of atmospheric Carbon Dioxide, i.e. with Negative Carbon Dioxide Emissions, in relation to the corresponding Carbon Dioxide emissions of corresponding Power Generation Systems with fossil fuels, and on the other hand it simultaneously produces Pyrolytically Activated Carbon (008A) and (008B), which constitutes the sequestration of atmospheric Carbon Dioxide which is promoted for use indicatively as a Soil Improver in Agriculture, where it more than doubles agricultural production, and where it is combined as all indicative variations thereof as below,

A'1. Pyrolysis-Carbonization Unit (A.4.1A) of Biomass Under Pressure. A Purification Diode of Volatile Biomass, with Fixed Chambers and Subchambers,

then a Pyrolysis-Carbonization Unit (A.4.1A), which is characterized by the fact that it consists of an innovative Biomass Pyrolysis-Carbonization Unit (A.4.1A) (A.2.2) and (A.2.1) for the production of Clean of Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), which is promoted for use indicatively as a Soil Improver in Agriculture, which is characterized by being carried out under Pressure, indicatively 20-40Bar, inside Stable Chambers ( 001AAA), (001AA) and (001AAB) and Subchambers (002AAA), (002AA) and (002AAB) Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange respectively, with Internal Filling System, Forward-Rear Agitation and Discharge of Biomass and of the Pyrolytic Activated Carbon through the Double Directional Screw (041A), in which case very significant advantages arise both for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.i ), as analyzed in n Detailed Description below,

A'2. Pyrolysis-Carbonization Unit (A.4.1E) of Pressurized Biomass, One Pass Volatile Purification, with Fixed Chambers and Rotating Subchambers,

then a Pyrolysis-Carbonization Unit (A.4.1E), which is characterized by the fact that it consists of an innovative Biomass Pyrolysis-Carbonization Unit (A.4.1E) (A.2.2) and (A.2.1) for the production of Clean of Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), as above, which is characterized by the fact that it is also carried out under Pressure, indicatively 20-40Bar, in Fixed Chambers (001AEA), (001AE) and ( 001AEB) and Rotating Subchambers (002AEA), (002AE) and (002AEB), Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange respectively, with an Internal System of Filling, Stirring Back and forth and Evacuating Biomass and Pyrolytic Activated Carbon through of the Internal Helical Ring (041'A), in which case very important advantages also arise both for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.i), such as detailed in the Detailed Description below ro

A.3. Pyrolysis-Carbonization Unit (A.4.1H) = (A.4.1HA) or (A.4.1HE) of Biomass, Under Pressure, One Pass, Integration in a Complex Pair of Chambers and Subchambers Pyrolysis-Blooming,

then Pyrolysis-Carbonization Unit (A.4.1HA) or (A.4.1HE), which is characterized by the fact that instead of three separate pairs of Chambers and Subchambers (001AAA) - (002AAA), (001AA) - (002AA) and (001AAB) - (002AAB) or (001AEA) -(002AEA), (001AE) - (002AE) and (001AEB) - (002AEB) Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange respectively, the merger of the three of separate pairs of Chambers and Subchambers as above in a Composite Pair of Chambers and Subchambers (001AA) - (002AA) or (001AE) - (002AE) which is characterized by the fact that it begins its operation as a pair of Chambers and Subchambers (001AAAA) -(002AAAAA ) or (001AEEA) - (002AEEA) Drying-Preheating of Biomass (A.2.2) and (A.2.1) and then after the end of the Drying-Preheating process by changing Air Duct (022) to Air Ducts (010) and ( 015)-(015A) is converted into a pair of Chambers and Subchambers (001AAA) - (002AAA) or (001AEE) - (002AEE) of Pyrolysis-Carbonization and in continuously after the end of the Pyrolysis-Carbonation process by switching Air Ducts (010) and (015)-(015A) to Air Duct (019) turns into a pair of Chambers and Subchambers (001АААБ) - (002АААБ) or (001ААЕБ) - (002ААЕБ ) Cooling-Heat Exchange of the produced Pyrolytic Activated Carbon (008A) and (008B), as analyzed in the Detailed Description below,

A.4. Biomass Pyrolysis-Blooming Unit (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1HA) or (A.4.1HE) Under Atmospheric Pressure, Multiple Purification Passages Volatile Biomass,

then Pyrolysis-Carbonization Unit (A.4.1'0) or (A.4.1Α) or (A.4.1Ε) or (A.4.1ΕΑ) or (A.4.1ΕΕ) respectively, where each is characterized by operating under Atmospheric Pressure otherwise like the corresponding Pyrolysis-Carbonization Unit under Pressure above, which is characterized by the fact that for the production of Clean Volatile Biomass (009) on the one hand, it needs the Double, Triple or Multiple Diode of Volatile Biomass through the Pyrolytic Activated Carbon of the respective Reserve Subchambers (002A'AB) or (002E'EB) or (002AA'AB) or (002EA'EB) and on the other hand that the Single or Combined Cycle Power Generation Unit (A.6.1) or (A. 6.1) needs a small modification to convert it into Pure or Mixed Combustion of Volatile Biomass (009), which consists in the addition of the Compressor (A.6.1Z) as well as the Post-Combustion Chamber (A.6.1E), as analyzed in the Detail Description below,

B. CO2 Negative Emission Unit Power Generation Systems (A.E.i)

B.1. The Power Generation System (A.E.1) as a Unit Combination (A.5.1) with a Pyrolysis-Carbonization Unit (A.4.1A) under 20-40Bar Pressure of a Cleaning Diode.

then a Power Generation System (PPS), which is characterized by the fact that it consists of a combination of a Modified Steam Power Unit (A.5.1) with Pure or Mixed Combustion of Volatile Biomass (009) with Fossil Fuels, indicatively Coal (009A) and an innovative Pyrolysis-Carbonization Unit (A.4.1A) of Biomass (A.2.2) and (A.2.1) for the production of Clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B) , which is promoted for use indicatively as a Soil Improver in Agriculture, which is characterized by the fact that the Pyrolysis-Carbonization of Biomass (A.2.2) and (A.2.1) is carried out under Pressure, indicatively 20-40Bar, inside Stable Chambers ( 001АAA), (001АА) and (001АAB) and Fixed Subchambers (002ААА), (002ААA) and (002АAB) of Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange respectively, which are created by the released Biomass Volatiles (009), so significant advantages arise both for s all of the Pyrolysis-Carbonization process as well as the Power Generation, as analyzed in the Detailed Description below,

B 2. The Power Generation System (A.E.2) as a Unit Combination (A.5.1) with a Pyrolysis-Carbonization Unit (A.4.1E) Under 20-40Bar Pressure. A Purification Diode.

then Power Generation System (A.E.2), like the Power Generation System (A.E.1) above, which is however characterized by the fact that it consists of a combination of a Modified Steam Electric Power Generation Unit (A.5.1) as above and of an innovative Pyrolysis-Carbonization Unit (A.4.1E) of Biomass (A.2.2) and (A.2.1) for the production of Clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), as above, which is characterized by the fact that it is also carried out under Pressure, indicatively 20-40Bar, inside Fixed Chambers (001AEA), (001AE) and (001AEB) and Rotating Subchambers (002AEA), (002AE) and (002AEB) Drying-Preheating, Pyrolysis -Carbonization and Cooling-Heat Exchange respectively, in which case there are also very important advantages both for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.2 ), as detailed in the Detailed Description below,

B.3. The Power Generation System (A.E.3) as a Unit Combination (A.6.1) or (A.6.1') with a Pyrolysis-Carbonization Unit (A.4.1A) or (A.4.1E) Under Pressure. One Pass Purification,

then Power Generation System (A.E.3), like the Power Generation System (A.E.1) and (A.E.2) above, which is however characterized by the fact that it consists of a combination of a Modified Power Generation Unit of Simple or Combined Cycle (A.6.1') or (A.6.1) with Pure or Mixed Combustion of Volatile Biomass (009) with Fossil Fuels, indicative of PA (009B) and an innovative Pyrolysis-Carbonization Unit (A.4.1A) or (A .4.1E) Under Pressure, indicatively 20-40Bar, for the production of Clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), in which case multiple advantages arise both for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1) as well as the Power Generation, as analyzed in the Detailed Description below,

B.4. The Power Generation System (A.E.4) Unit Combination (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1HA) or (A.4.1HE) Under Pressure 20 -40Bar of One Cleaning Diode

then Power Generation System (A.E.4), like the Power Generation System (A.E.1), (A.E.2) and (A.E.3) above, which is however characterized by the fact that it consists of a combination of a Modified Steam Electric Power Generation Unit (A.5.1) or a Modified Single or Combined Cycle Power Generation Unit (A.6.1') or (A.6.1) respectively and an innovative Pyrolysis-Carbonation Unit (A.4.1HA) or (A.4.1HE) Under Pressure, indicatively 20-40Bar, for the production of Clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), in which case multiple advantages arise both for the entire Pyrolysis-Carbonization process of Biomass (A.2.2) and (A.2.1) as well as of Power Generation, as analyzed in the Detailed Description below,

B.5. The Power Generation System (A.E.5) Combining a Unit (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1A) or ( A.4.1E) or (A.4.1HA) or (A.4.1HE) of Atmospheric Pressure.

then Power Generation System (A.E.5), such as the Power Generation System (A.E.1), (A.E.2), (A.E.3) and (A.E.4) above, the which is characterized by the fact that it consists of a combination of a Modified Steam Electric Power Generation Unit (A.5.1) or a Modified Simple or Combined Cycle Power Generation Unit (A.6.1') or (A.6.1) respectively and an innovative Pyrolysis Unit- Carbonation (A.4.1'0) or (A.4.1Α) or (A.4.1E) or (A.4.1ΑΑ) or (A.4.1Ε) Biomass (A.2.2) and (A.2.1) Atmospheric Pressure , which is characterized by the fact that the production of Clean Volatile Biomass (009) on the one hand requires the Double, Triple or Multiple Diode of Volatile Biomass through the Pyrolytic Activated Carbon of the respective Reserve Subchambers (002A'AB) P (002A'EB) or (002AA'AB) or (002AE'EB) respectively and on the other hand that the Single or Combined Cycle Power Generation Unit (A.6.1') or (A.6.1) needs a small modification to convert it into Pure or Mixed Combustion P of Biomass (009), which consists in the addition of the Compressor (A.6.1Z) as well as the Post-combustion Chamber (A.6.1E), as analyzed in the Detailed Description below,

E.2. DETAILED DESCRIPTION OF THE SYSTEM OF PROTECTION AGAINST CLIMATE CHANGE WITH NEGATIVE CARBON DIOXIDE EMISSIONS ELECTRICITY GENERATING UNITS

The Present Invention is characterized by the fact that it consists of the CO2 Negative Emission Units, i.e. a Power Generation System (A.E.i), where i = 1 to 5, is the index of the Alternative Versions of the Power Generation System (A.E.i) , which consists of a Combination of an Innovative Pressurized Coking-Cryzing Unit (A.4.10) or (A.4.1A) or (A.4.1E) or (A.4.1HA) or (A.4.1HE) or and under atmospheric pressure (A.4.1D) or (A.4.1A) or (A.4.1E) or (A.4.1HA) or (A.4.1HE) Biomass (A.2.2) and (A.2.1) , for the production on the one hand of pure Volatile Biomass (009) for Electricity Generation, in combination with either a Modified Steam Electric Power Generation Unit (A.5.1) with Pure or Mixed Combustion of Volatile Biomass (009) with Fossil Fuels, indicatively Coal (009A) , either with a Modified Single or Combined Cycle Power Generation Unit (A.6.1') or (A.6.1) with Pure or Mixed Combustion of Volatile Biomass (009) with Liquid or Gaseous Fossil Fuels, indicatively with Natural Gas (NG) (009B) , and on the other hand, in parallel, for the production of large quantities of Pyrolytic Activated Carbon (008A) and (008B), which constitutes Atmospheric Carbon Dioxide Sequestration, i.e. Negative Carbon Dioxide Emissions, so the Power Generation Units (A.E.i) in combination with the Innovative Pyrolysis-Coking Unit as above, are characterized by producing Electricity not only without Carbon Dioxide Emissions, but with Negative Carbon Dioxide Emissions, up to more than twice the amount compared to the Carbon Dioxide emissions from an equivalent Power Generation Unit with Fossil Fuels, and where Pyrolytic Activated Carbon (008A) and (008B) is also characterized by being intended for permanent storage, indicatively as an excellent Soil Improver in Agriculture, where it more than doubles agricultural production, where the above Power Generation System (A.E .i) is characterized by the fact that it consists of the following Components and Alternatives Versions of the Innovative Pyrolysis-Coking Unit and the Power Generation System (PGE), which are described in detail below, namely:

A. Alternative Versions of the Innovative Pyrolysis-Carbonization Unit (A.4.10)

A.0. Pyrolysis-Carbonization Unit (A.4.10) of Biomass Under Pressure, Generalized Form, with Fixed or Rotating Chambers and Subchambers

A'1. Biomass Pyrolysis-Carbonization Unit (A.4.1A) of Pressurized Biomass, One Diode Purification of Volatile Biomass, with Fixed Chambers and Subchambers

A'2. Pyrolysis-Carbonization Unit (A.4.1E) of Biomass Under Pressure, One Diode Volatiles Purification, with Fixed Chambers and Rotating Subchambers

A.3. Pyrolysis-Carbonization Unit (A.4.1HA) or (A.4.1HA) of Biomass Under Pressure, One Pass, Integration into a Complex Pair of Pyrolysis-Carbonization Chambers and Subchambers,

A.4. Pyrolysis-Carbonization Unit (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1ΑΑ) or (A.4.1ΕΕ) of Biomass, Under Atmospheric Pressure, Multiple Purification Passages Volatile Biomass

B. Power Generation Systems of Negative CO2 Emission Units (A.E.i)

B.1. The Power Generation System (A.E.I) as a Unit Combination (A.5.1) with a Pyrolysis-Carbonation Unit (A.4.1A) Under a Pressure of 20-40Bar One Purification Diode,

B 2. The Power Generation System (A.E.2) as a Unit Combination (A.5.1) with a Pyrolysis-Carbonization Unit (A.4.1E) Under 20-40Bar Pressure of One Purification Diode,

B.3. The Power Generation System (A.E.3) as a Combination of Unit (A.6.1) or (A.6.C) with a Pyrolysis-Carbonation Unit (A.4.1A) or (A.4.1E) Under Pressure, One Purification Diode ,

B.4. The Power Generation System (A.E.4) Unit Combination (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1HA) or (A.4.1HA) Under Pressure 20 -40Bar of One Cleaning Diode

B.5. The Power Generation System (A.E.5) Unit Combination (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1'0) or (A.4.1A) or ( A.4.1E) or (A.4.1HA) or (A.4.1HE) Atmospheric Pressure,

Namely:

A. Alternative Versions of the Innovative Pyrolysis-Carbonization Unit

A.0. Pyrolysis-Carbonization Unit (A.4.10) of Biomass. Under pressure. General Form, with Fixed or Rotating Chambers and Subchambers.

then Pyrolysis-Carbonization Unit (A.4.10), which is characterized by the fact that it consists of an Innovative Pyrolysis-Carbonization Unit (A.4.10) Under Pressure, General Form, Biomass (A.2.2) and (A.2.1), for the production of Clean Volatile Biomass (009) free from almost 100% of their Harmful Components (A.10.1) for the Boilers (012) of the Steam Electric Units (A.5.1) and for the Gas Turbines (A.6.1A) of of Single or Combined Cycle Power Generation Units (A.6.1') or (A.6.1) in Power Generation Systems (A.E.I), as below, where the clean Biomass Volatiles (009) are indicatively intended for Power Generation not only without Dioxide Emissions Coal, but on the contrary, with sequestration and permanent storage in the ground of up to twice as much atmospheric Carbon Dioxide, i.e. with Negative Carbon Dioxide Emissions, in relation to the corresponding Carbon Dioxide emissions of corresponding Power Generation Systems with fossil fuels, and on the other hand y simultaneously produces Pyrolytic Activated Carbon (008A) and (008B), which is the sequestration of atmospheric Carbon Dioxide which is promoted for use indicatively as a Soil Improver in Agriculture, where it more than doubles agricultural production,

Where the Pyrolysis-Carbonization Unit (A.4.10) is characterized by the fact that Biomass Pyrolysis-Carbonization is carried out under Pressure, indicatively 20-40Bar, in Fixed or Rotating Chambers and Subchambers, Drying-Preheating, where it is carried out not only without consuming thermal of energy, but on the contrary, it is carried out with the production of thermal energy, so it also increases the degree of efficiency of the cooperating Power Generation System,

Where the Pyrolysis-Carbonation Unit (A.4.10) is also characterized by the fact that, in cooperation with the Carbon Dioxide Emissions (A.E.i) Power Generation Systems, it provides Technically and Economically Sustainable Solutions to the main Problems related to Energy Production through Negative Carbon Dioxide Emissions, in the Degradation of the Environment and in dealing with the Risk of Climate Change, which the current state of the art cannot solve, as well as by producing very important advantages both for the entire Pyrolysis-Carbonization process of Biomass (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.I), as analyzed in Chapter C "Advantages of the Present Invention in terms of the state of the art" above,

In contrast to the current state of the art where the pyrolysis is carried out under atmospheric pressure with the consumption of external thermal energy, in which case it also worsens the degree of efficiency of the cooperating Power Generation System, and does not present the significant advantages of Pressure Pyrolysis-Carbonization, as detailed above ,

Where the innovative Pyrolysis-Carbonization Unit (A.4.10) of General Form is characterized by the fact that it consists indicatively of the following three collaborating Components, namely:

- The Drying-Preheating Subunit (A.4.1OA), consisting of the Pairs of Drying-Preheating Chambers and Subchambers (001AOA)-(002AOA),

- The Pyrolysis-Carbonization Subunit (A.4.1O), consisting of the Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001Ao) - (002Ao),

- The Cooling-Heat Exchange Subunit (A.4.1ОБ), consisting of the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001AOB)-(002AOB),

as described below, namely:

The Drying-Preheating Subunit (A.4.1OA), which is characterized by:

Where the Drying-Preheating Subunit (A.4.1OA) is also characterized by the fact that it consists of the pairs of Chambers and Subchambers Drying-Preheating (001АOA)-(002АOA) of Biomass (A.2.2) and (A.2.1), with fixed or rotating cylindrical Drying-Preheating Chambers and Subchambers, horizontal, inclined or vertical or of any other form, respectively,

Where the Drying-Preheating Subunit (A.4.1OA) is characterized by the fact that it consists of the Pairs of Drying-Preheating Chambers and Subchambers (001АОА)-(002АОА), which are fed with the Biomass of the Initial Semi-Outdoor Pre-Drying (A.2.0) through of the Loading-Unloading System (A.7.1), through the Double Isolation Valves (039A), where after Drying-Preheating they supply the Dry and Preheated Biomass (A.2.2A) and (A.2.1A) to the Pyrolysis Subunit- Carbonization (A.4.1O), which consists of the Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001АО) - (002АО) through the Double Isolation Valves (040А)-(039), where this one after the Pyrolysis-Carbonization supplies with the produced Pyrolytic Activated Carbon (008A) and (008B) the Cooling-Heat Exchange Subunit (A.4.10B), which consists of the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АОБ) - (002АОБ) through the Double Isolation Valves (040)-(039B) and where from the Cooling-Heat Exchange Subunit modality (A.4.10B), after the Cooling of the Pyrolytic Activated Carbon (008A) and (008B) through the Heat Exchange with the Preheating of the Feed Water (012A) of the Boiler (012) of the Steam Unit (A.5.1) or Boiler (012B) of the Combined Cycle Unit (A.6.1), the Pyrolytic Activated Carbon (008A) and (008B) exits through the Double Isolation Valves (040B) and is promoted for preparation as a Soil Improver,

Where the Drying-Preheating Subunit (A.4.1OA) is characterized by the fact that it consists of the Pairs of Drying-Preheating Chambers and Subchambers (001АOA)-(002АOA), and then as in Claim 6 it is part of the Drying-Preheating Subsystem (A .E.1.3O), which is characterized by the fact that it is a constituent element of the Power Generation Systems (A.E.i), where i = 1 to 5 is the Emissions Index of the Power Generation Units with Negative Carbon Dioxide Emissions, which are implemented through the clean Volatile Biomass (009) which are produced by the innovative Pyrolysis Unit (A.4.10) of General Form, of which the Drying-Preheating Subunit (A.4.1OA) is a part,

Where the Drying-Preheating Subunit (A.4.1OA) is characterized by having a Second Stage Drying (A.3.1) with the available Hot Exhaust Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012 ) of the cooperating Steam Electric Unit (A.5.1) or from the entrance of the Chimney (A.1.5) of the Boiler (012B) of the cooperating Combined Cycle Unit (A.6.1), which remove the last 20% of the moisture and perform corresponding preheating of Dry Biomass (A.2.2A) and (A.2.1A), where there is a significant overall improvement in the degree of efficiency of the corresponding Power Generation System (A.E.I) on average indicatively more than 10%, in contrast to degree of efficiency of power generation through conventional coking pyrolysis, which is lower than the Electricity Generation System (A.E.i),

In contrast to the current state of the art, where on the one hand the Heat of the Hot Exhaust Gases (A.1.4) is either discarded unused through the Chimneys (A. 1.5) into the environment or expelled through cooling in the Water Washers in the Desulphurization Systems, which are eliminated in the cooperating Power Generation Systems (A.E.i), because the Sulfur Compounds are completely retained by the Pyrolytic Activated Carbon Filter (008A) and (008B),

And where, on the other hand, with the current state of the art, useful heat is consumed by burning part or all of the Fine Biomass (A.2.1) or also part of the Woody Biomass (A.2.2) to evaporate the moisture content resulting in a poor degree of efficiency, where the Fine Biomass Biomass (A.2.1) even when pelletized, is not intended for drying and pyrolysis-carbonization for the production of Fine Granulated Pyrolytic Activated Carbon (008B), but only for combustion and heat production, as above,

In other respects, it is characterized by the fact that it participates in the collaborating Power Generation Systems (A.E.i) of the C02 Negative Emission Units, as above,

The Pyrolysis-Carbonization (A.4.1o) and Cooling-Heat Exchange (A.4. 1OB) Subunits, which are characterized by the fact that:

Where the Pyrolysis-Carbonization Subunit (A.4.1O) is characterized by the fact that it consists of the Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001ΑO)-(002Αο) and the Cooling-Heat Exchange Subunit (A.4.1OB) is characterized by the that it consists of the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001AOB)-(002AOB) respectively, then both are characterized by constituting the Pyrolysis-Carbonation Subsystem (A.E.1.4O), which is characterized by that it is a constituent element of the Power Generation Systems (A.E.i), where i = 1 to 5 is the Emissions Index of Power Generation Units with Negative Carbon Dioxide Emissions, and where the Pyrolysis-Carbonization (A.4.1O) and Cooling-Heat Exchange Subunits (A.4.1OB) are respectively characterized by the fact that they consist of the following, namely:

Where the Cracking-Carbonization (A.4.10) and Cooling-Heat Exchange (A.4.1OB) Subunits, respectively, are characterized by the fact that they consist of Pairs of fixed or rotating Chambers and Subchambers of Cracking-Carbonization (001AO)-(002AO) and Cooling- Heat Exchanger (001AOB)-(002AOB) respectively, with an indicative cylindrical, horizontal or inclined or vertical or other form, where the Pyrolysis-Carbonization of Biomass (A.2.2A) and (A.2.1A) and Cooling takes place -Heat Exchange of Pyrolytic Activated Carbon (008A) and (008B), respectively,

Where the Pyrolysis-Carbonization process inside the Sub-Chambers (002Ao) is carried out under Pressure, indicatively 20-40Bar, while all the other Chambers (001AO), (001AOB) and the Subchamber (002AOB) operate under atmospheric pressure in the Carbonization Pyrolysis Process of One Purification Diode of Volatile Biomass (009), while in the process of multiple Purification of Volatile Biomass (009), then the Cooling-Heat Exchange Subchambers (002AOB) also operate under the same pressure as the Subchambers (002Ao), indicatively 20-40Bar, where produced clean Biomass Volatiles (009) and at the same time Pyrolytic Activated Carbon (008A) and (008B),

Where the Cooling-Heat Exchange Subunit (A.4.1OB) is characterized in that the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АOB)-(002АOB) of the Pyrolytic Activated Carbon (008A) and (008B), cool the superheated Pyrolytic Activated Coal (008A) and (008B) exchanging heat and preheating the Feed Water (012A) of the Boiler (012) or the Exhaust Gas Boiler (012B), thus further improving the degree of efficiency of the cooperating Power Generation System,

Where the Pyrolysis-Carbonization Subunit (A.4.10) is characterized by the fact that Biomass Pyrolysis-Carbonization is carried out under Pressure, indicatively 20-40Bar, inside the Pyrolysis-Carbonization Chambers and Sub-Chambers (001AO)-(002AO) respectively, where it is carried out not only without the consumption of thermal energy, but on the contrary, it is carried out with the production of thermal energy, so it also increases the degree of efficiency of the cooperating Power Generation System, as well as it is carried out with the production of very important advantages both for the whole Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), as well as for the Power Generation System (A.E.I), as analyzed in Chapter C "Advantages of the Present Invention in terms of the state of the art" above,

In contrast to the current state of the art where the pyrolysis is carried out under atmospheric pressure, with the consumption of external thermal energy, so it also worsens the degree of efficiency of the cooperating Power Generation System, and does not present the significant advantages of Pressure Pyrolysis-Carbonization, as detailed above in Chapter C, where it fails to provide the solutions and advantages of Pressurized Coking as above, and leads to obsolescence and premature decommissioning of more than 5,000GW of Fossil Fuel Power Plants, which with little conversion and in combination with innovative Pyrolysis-Carbonization Units (A.4.10) are converted into Power Generation Units with Negative Carbon Dioxide Emissions, with all the advantages as above in Chapter C,

Where the Cooling-Heat Exchange Subunit (A.4.1OB) is characterized in that the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АOB)-(002АOB) of the Pyrolytic Activated Carbon (008A) and (008B) cool the superheated Pyrolytic Activated Coal (008A) and (008B) exchanging heat and preheating the Feed Water (012A) of the Boiler (012) or the Exhaust Gas Boiler (012B), thus further improving the degree of efficiency of the cooperating Power Generation System,

Otherwise, they are characterized by the fact that they participate in the cooperating Power Generation Systems (A.E.I) of the CO2 Negative Emissions Units, as above, Where the Pyrolysis-Carbonization Unit (A.4.10) is also characterized by the fact that the Chambers and Subchambers as above are equipped with a Biomass Single Pass System (A.2.2) and (A.2.1) through the Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange Chambers and Subchambers (001АOA)-(002АOA), (001АО)-( 002АО) and (001АОБ)-(002АОБ) respectively or corresponding Transit with Retention of Biomass (A.2.2) and (A.2.1) within the Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange Chambers and Subchambers (001АOA) -(002ΑOA), (001ΑΑ)-(002ΑΑ) and (001ΑΑΒ)-(002ΑΒΒ) respectively for a longer period of time, statically or with back-and-forth stirring indicatively through appropriate Filling, Back-Back Stirring and Discharge Screw Systems as well as corresponding Isolation Valves,

Where the Pyrolysis-Carbonation Unit (A.4.10) is also characterized by the fact that the Chambers and Subchambers as above are equipped with an appropriate System of Filling, Stirring Forward-Backwards and Evacuating the Biomass and Pyrolytic Activated Carbon indicatively through an Internal System through Screws or Propellers Bidirectional (041OA) or (041'OA), while the process of promoting one direction from the entrance of the Biomass to the exit of the produced Pyrolytic Activated Carbon is included, if the characteristics of the Biomass (A.2.2) and (A. 2.1),

Where the innovative Pyrolysis-Carbonization Unit (A.4.10) of General Form is also characterized by the fact that it has Electrostatic Filters (012E) or Bag Filters (012Z), for the retention of Microparticles from the cooling of the Pyrolytic Activated Carbon (008A) and (008B) in System of Cooling-Heat Exchange Chambers and Subchambers (001AOB)-(002AOB) of Pyrolytic Activated Carbon (008A) and (008B) or the Electrostatic Filters (012'E) or Bag Filters (012'g) for the retention of Microparticles from Drying and Preheating of Biomass (A.2.2A) and (A.2.1A) in the System of Drying-Preheating Chambers and Subchambers (001ΑOA) and (002ΑOA) above,

A'1. Pyrolysis-Carbonization Unit (A.4.1A) of Biomass, Under Pressure. One Diode, then Pyrolysis-Carbonization Unit (A.4.1A), like the Pyrolysis-Carbonization Unit (A.4.10) in Paragraph A.0, which is however characterized by the fact that it consists and functions as follows, that is to say that produces on the one hand clean Volatile Biomass (009), which are intended indicatively for Electricity Generation Without Carbon Dioxide Emissions and on the other hand simultaneously Pyrolytic Activated Carbon (008A) and (008B), which constitutes the sequestration of Atmospheric Carbon Dioxide and is promoted for use indicatively as Soil Improver in Georgia,

Which is characterized by the fact that in collaboration with the Carbon Dioxide Emissions Power Generation Systems (A.E.I) it provides Technically and Economically Viable Solutions to the main problems related to Energy Production with Negative Carbon Dioxide Emissions, the Degradation of Environment and dealing with the Risk of Climate Change, which the current state of the art cannot solve, such as sustainable solutions and advantages 1-23, which are given in detail in Chapter C above,

Where the innovative Pyrolysis-Carbonization Unit (A.4.1A) is characterized by the fact that it consists of the following three collaborating Components, namely:

- The Drying-Preheating Subunit (A.4.1AA), consisting of the Pairs of Drying-Preheating Chambers and Subchambers (001AAA) and (002AAA),

- The Pyrolysis-Carbonization Subunit (A.4.1A), consisting of the Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001AA) and (002AA),

- The Cooling-Heat Exchange Subunit (A.4.1AB), consisting of the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001AAB)-(002AAB),

as described below,

- The Drying-Preheating Subunit (A.4.1AA) which is owned by:

Where the Drying-Preheating Subunit (A.4.1AA) is characterized by the fact that it consists of the Pairs of Drying-Preheating Chambers and Subchambers (001AAA) and (002AAA), then also as part of the Drying-Preheating Subsystem (A.E.1.3А ), which is characterized by the fact that it is a constituent element of the Power Generation Systems (PPP) of the C02 Negative Emission Units, where i = 1 to 5 is the Emissions Index of the Power Generation Units with Negative Carbon Dioxide Emissions, which are implemented through the clean Volatile Biomass (009) which are produced by the innovative Pyrolysis Unit (A.4.1A), of which the Drying-Preheating Subunit (A.4.1aa) is a part,

Where the Drying-Preheating Subunit (A.4.1AA) is characterized by having a Second Stage Drying (A.3.1) with the available Hot Exhaust Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012 ) of the cooperating Steam Electric Unit (A.5.1) or from the entrance of the Chimney (A.1.5) of the Boiler (012B) of the cooperating Combined Cycle Unit (A.6.1), which remove the last 20% of the moisture and perform corresponding preheating of Dry Biomass (A.2.2a) and (A.2.1a), where there is a significant overall improvement in the degree of efficiency of the corresponding Power Generation System (A.E.i) on average indicatively more than 10%, in contrast to degree of efficiency of electricity generation through conventional coal pyrolysis, which is correspondingly lower than the Electricity Generation System (E.E.I),

Where the Drying-Preheating Subunit (A.4.1AA) is characterized by the fact that it consists of the pairs of Drying-Preheating Chambers and Subchambers (001AAA) and (002AAA) respectively of the Biomass (A.2.2) and (A.2.1), where the Drying-Preheating Chamber (001AAA) is characterized by the fact that it is made of a steel plate of an alloy resistant to moderate temperatures, indicative of an alloy of Fe, Ni, Cr for operating temperatures of 250-400°C, with external Insulation (001E) of thick stone wool quilt indicative of 10 centimeters, with an indicative internal diameter of 2.7m, thickness of steel sheet 5mm and length of 12.0m, for atmospheric pressure, for a power of Volatile Biomass indicatively 63MWθ, which is a structural element for the conversion of a 660MW Lignite Unit into a Negative Carbon Dioxide Emissions Unit Carbon, as below,

Where the Drying-Preheating Chamber (001АAA) is also characterized by containing the Drying-Preheating Subchamber (002АAA), which is watertight with respect to the Chamber (001АAA), with an internal diameter indicative of 2.4m, which is also made of sheet steel of an alloy resistant to temperatures of 250-400°C, approximately 5mm thick for atmospheric pressure and with a longer length, approximately 14.0m, because it exits the Chamber (001АAA) by 1.0m on either side for the purpose of integrating the Inlet-Outlet Valves (039A) and (040A) of the Biomass and the Inlet-Outlet Valves (034) and (034') of the Exhaust (A.1.4), as well as the Speed Reducer-Engine-lnverter System (041Z) of the Dual Direction Screw (041A) ), except for the Shell (041k) or (041'k) of the Chamber (001AAA) or the Subchamber (002AAA) respectively, for temperature and maintenance reasons,

Where the Drying-Preheating Subchamber (002АAA) is characterized by being equipped with the Loading Arms (035A) of Biomass (A.2.2) and (A.2.1) and the Unloading Arms (036A) of Dry and Preheated Biomass (A. 2.2A) and (A.2.1A), which belong to the respective Loading-Unloading System (A.7.1), which are equipped with the Double Inlet Flaps (039A) and Outlet (040A), where the Loading Arms (035A ) per Subchamber (002АА), are grouped indicatively by seven in the Collector-Silo (003АА) Loading with Biomass (А.2.2) and (А.2.1) of the Drying-Preheating pairs (001ААА) and (002ААА), where the Biomass (А .2.2) and (A.2.1) is supplied to the Collector-Silo (003AA) from the Central Biomass Silo (004A) through the Feeding Belts (037), of the corresponding Loading-Unloading System (A.7.1), while the Unloading Arms ( 036A) abduct the Dry and Preheated Biomass (A.2.2A) and (A.2.1A), through the Double Outlet-Inlet Flaps (040A)-(039), to Belt Tr of yield (037) of the Subsystem (A.E.1.4) of Pyrolysis-Carbonation Pairs (001AA)-(002Aa),

Where the Drying-Preheating Subchamber (002АAA) is characterized by the fact that it is equipped inside with the Double Directional Screw System (041A) for the Process of Filling, Back-Back Agitation and Discharge of Biomass (A.2.2) and (A. 2.1), which is characterized by the fact that its Shaft (041O) rests on the Bearings (041m) at intervals through the Support Beams (041N) inside the cylindrical Subchamber (002АAA) with a break in the continuity of the Double Directional Screw (041A) in level of the Support Beams (041N) and repeating the sequence immediately after, which is set to rotate and reverse its direction of rotation, through the Speed Reducer-Motor-lnverter System (041Z), placed on the outside of the Shell (041'k) of Subchamber (002AAA), for temperature and maintenance reasons, as below,

Where the pairs of Chambers and Subchambers (001AAA) and (002AAA) are characterized by the fact that they are both connected through the Inlet-Outlet Flaps (034) and (034') to the Air Ducts (022), which through the Depression Fan ( 023) suck up and send part of the hot exhaust gases (A.1.4) of the chimney (A.1.5), as above, with temperatures of 150°-180°C, from the entrance of the Chimney (A.1.5) inside the Drying Chambers and Subchambers (001AAA) and (002AAA), where they carry out the drying and preheating of the Biomass (A.2.2) and (A.2.1), from which they remove the last 20% of moisture remaining and at the same time preheat it at approximately 120°C, while the Exhaust Gases (A.1.4), which after the drying and preheating of the Biomass (A.2.2) and (A.2.1) have undergone a temperature reduction, are led by the Air Ducts (022) to inside the Cooling Tower (018A) of the cooperating Power Plant, where they are emitted into the atmosphere, drifting a upwards from the updraft of the water vapor of the Cooling Tower (018A),

Where the Double Flaps (039A) and (040A) of the Loading (035A) and Unloading (036A) Arms Entry and Exit respectively of the Subchambers (002AAA) handling Biomass (A.2.2) and (A.2.1) for drying, as well as the Double Flaps (034) and (034') of Inlet and Outlet respectively of the Air Ducts (022) are placed on the periphery of the front and rear cylindrical end of the respective cylindrical Chamber (001AAA) the Flaps (034') and of the Subchamber (002Aaa) the rest , where the latter do not prevent the passage of the Shaft (0410) and the Screw (041A), while the corresponding Loading Arms (035A) are indicatively grouped by seven in the upper Inlet Manifolds (003AA), as above,

Where the Drying-Preheating Subunit (A.4.1aa), is also characterized by having the Electrostatic Filters (012'E) or Bag Filters (012'Z), which are placed indicatively in an intermediate position from the Chamber Pairs (001AAA) and (002AAA) Drying-Preheating and the Cooling Tower (A.1.8a), on the Air Duct Circuit (022) which discharges the cold Exhaust Gases (A.1.4) to the Cooling Tower (A.1.8a), which retain the Microparticles (A.2.2') and (A.2.1') of Biomass (A.2.2) and (A.2.1), which are carried away by the stream of Hot Exhaust Gases (A.1.4) as they pass through the Hypothalamus ( 002Aaa) during the Drying - Preheating of Biomass (A.2.2) and (A.2.1), and which are collected and returned to the Drying - Preheating Chain of Biomass (A.2.2) and (A.2.1), so that on the one hand they are avoided material losses and on the one hand not to burden the environment with Microparticles,

Where the innovative Pyrolysis Unit (A.4.1A) through the cooperating Power Generation System (A.E.I), is characterized by the fact that through the Subsystems (A.E.1.1), (A.E.I.2) and (A.E.I.3) frees the Biomass from the high humidity rates either by Natural Drying of the Biomass (A.2.0) in the Semi-Outdoor Storage Subsystem (A.1.2) of the Subsystem (A.E.1.1), or by exploitation of the Heat of the Hot Exhaust Gases (A.1.4) of the Chimneys (A.1.5) of the Boiler (012) of the Units (A.5.1) or of the Chimneys (A.1.5) of the Exhaust Gas Boiler (012B) in the Subsystems (A.E .1.2) and (A.E.1.3), as above,

Where it becomes possible to exploit the very large amounts of heat of the Hot Exhaust Gases (A.1.4) of the Chimneys (A.1.5), of the order of 20-30% of the heat of the respective power generation fuel, which provide their heat for Drying of Biomass (A.2.0), from humidity 30-50% to full drying levels, as well as a corresponding pre-heating at 120°C, with a corresponding very serious improvement of more than 10% of the total degree of efficiency of the cooperating Power Generation System (A.E.i), depending with the percentage of moisture of the corresponding Biomass (A.2.0),

In contrast to the current state of the art, where on the one hand the Heat of the Hot Exhaust Gases (A.1.4) is either discarded unused through the Chimneys (A.1.5) into the environment or expelled through cooling in the Water Washers in the Desulphurization Systems, which are eliminated in the cooperating Power Generation Systems (A.E.i), because the Sulfur Compounds are completely retained by the Pyrolytic Activated Carbon Filter (008A) and (008B), as above,

And on the other hand, useful heat is consumed by burning part or all of the Fine Biomass (A.2.1) or even part of the Woody Biomass (A.2.2) to evaporate the contained moisture resulting in a poor degree of efficiency, where the Fine Biomass (A.2.1) still and when pelletized, it is not intended for drying and pyrolysis carbonization for the production of Fine-grained Activated Carbon (008B), but only for combustion and heat production, as above,

Where alternatively the Drying-Preheating Subunit (A.4.1AA) is characterized by the fact that the Pairs of Drying-Preheating Chambers and Subchambers (001АAA) and (002ААAA) can be manufactured in the same form and dimensions as the Pairs of Pyrolysis-Carbonization Chambers and Subchambers ( 001АА) and (002АА) and with the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АAB) and (002АAB), for reasons of uniformity in their production and in the availability of Spare Parts,

otherwise it is characterized by the fact that it participates in the cooperating Power Generation System (A.E.1) of the corresponding C02 Negative Emissions Unit, as described in Paragraph B.1. "Power Generation System (A.E.1) as a Unit Combination (A.5.1) with a Pyrolysis-Carbonization Unit (A.4.1A) Under 20-40Bar Pressure, One Purification Diode",

The Pyrolysis-Carbonization (A.4.1A) and Cooling-Heat Exchange (A.4.1AB) Subunits. in brief Pyrolysis (A.4.1A,B). which are characterized by the fact that:

- Where the Pyrolysis-Carbonization Subunits (A.4.1A) and Cooling-Heat Exchange (А.4.1AB) are characterized by the fact that they consist of (A.4.1A) Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001AA) and (002AA) and (A.4.1AB) from the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001AAB) and (002AAB) respectively, then the Pyrolysis-Carbonation Subsystem (A.E.1.4A), which is characterized by that it is a component of the Power Generation Systems (A.E.i), where i = 1 to 5 is the Emissions Index of Power Generation Units with Negative Carbon Dioxide Emissions, where the Pyrolysis-Coalization Subsystem (A.E.1.4) is characterized by the fact that consists indicatively of an equal number of Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001AA) and (002AA) with the number of pairs of Drying-Preheating Chambers and Subchambers (001AAA) and (002AAA) and with the number of pairs of Cooling-Heat Exchange Chambers and Subchambers ( 001AAB) and (002AAB) of P Urolytic Activated Carbon (008A) and (008B),

Where the keinotomical Pyrolysis Subunit (A.4.1A,B) is characterized by the fact that the Pyrolysis-Carbonization and Cooling-Heat Exchange processes are respectively carried out in Fixed Chambers (001AA) and (001AAB) and Subchambers (002AA) and (002AAB) of Pyrolysis -Carbonation and Cooling-Heat Exchange, respectively,

Where the Pyrolysis-Carbonization process inside the Subchambers (002AA) is carried out under Pressure, indicatively 20-40Bar, while all the other Chambers (001AA) and (001AAB) and the Subchamber (002AAB) operate under atmospheric pressure in the Single Pass Pyrolysis-Carbonization process Purification of Volatile Biomass (009), while in the process of multiple Purification of Volatile Biomass (009), then the Cooling-Heat Exchange Subchambers (002AAB) also operate under the same pressure as the Subchambers (002AA), indicatively 20-40Bar,

Where the innovative Pyrolysis Sub-Unit (A.4.1A,B) is characterized by the fact that the Pyrolysis-Carbonization and Cooling-Heat Exchange Subchambers (002AA) and (002AAB) respectively, are equipped with the Internal Filling, Forward-Rear Stirring and Discharge System of Biomass and Pyrolytic Activated Carbon through the Dual Directional Screw (041A), as described above, which ensures uniform distribution of heat absorption and heat dissipation in the mass of pyrolyzed Biomass (A.2.2A) and (A.2.1A), as and maximizing the contact of the Volatile Biomass (009) with the stirred mass of the simultaneously produced Pyrolytic Activated Carbon (008A) and (008B), in which case the advantages for the Power Generation System (A.E.i) arise, as detailed above, in Chapter C,

Where the Pyrolysis Subunit (A.4.1A,B) is also characterized in that the Pyrolysis-Carbonization Chamber (001АА) and the Cooling-Heat Exchange Chamber (001АAB) are made of Fe, Ni, Cr alloy steel plate for operating temperatures of 650-900°C but for atmospheric pressure, with internal lining of Firebricks (001B) and external Insulation (001E) of rockwool quilt approximately 20 cm thick, with an internal diameter of approximately 3.0m, with steel plate thickness of 5.0mm and length also indicative 12.0m for a Volatile Biomass power of 63MWθ, which is a Structural Element for converting a 660MW Coal Unit into a Carbon Dioxide Negative Emission Unit (A.5.1) of the same power with Volatile Biomass combustion (009) as below,

Where the Pyrolysis Subunit (A.4.1A,B) is also characterized by the fact that the Pyrolysis-Carbonation Subchambers (002АА) are made of steel plate of a high-temperature resistant alloy, indicative of Superalloy type Ni, Cr, in percentages of 12-20%, for operating temperatures of the order of 650-900°C [20] and a thickness indicative of 15mm for pressures up to 60Bar, while the Cooling-Heat Exchange Subchambers (002АAB), are made of Fe, Ni, Cr alloy steel plate for operating temperatures of the order of 650 -900°C but for atmospheric pressure, 5.0mm thick and 14m long per Subchamber (002A) or (002AB) for each Pyrolysis Subunit (A.4. 1A,B) indicative of 63MWθ, which is a basic Structural Element for the conversion of a 660MWe Lignite Unit into a Green Unit with Negative Carbon Dioxide Emissions, i.e. Replacement of the 16 Oil Burners of the 660MWe Unit into Volatile Biomass Burners (009) with two Units (A.4.1A) per Burner,

Where the Pyrolysis Subunit (A.4.1A,B) is also characterized by the fact that the level of purification of Volatile Biomass (009) from their Harmful Components (A.10.1) for Pyrolysis under a pressure of 20-40Bar for a simple Purification Diode is already sufficient for the safe operation of the Boiler (012) or the Gas Turbine (A.6.1A), indicatively above 97.5%, in which case a Second Purification Passage of the Volatile Biomass (009) from their Harmful Components can be avoided (A.10.1) or to drastically limit the number of Cleaning Diodes for special cases,

Where the Cracking Sub-Unit (A.4.1AB) is also characterized in that the Cracking-Carbonation Subchamber (002AA) is characterized in that it is watertight with respect to the Chamber (001AA), and where the Subchamber (002AA) due to high operating pressure is constructed with smaller diameter, indicatively 800mm, so inside the Chambers (001AA) and (001AAB) a bundle of 7 parallel Pyrolysis-Carbonization (002AA) and Cooling-Heat Exchange (002AAB) Subchambers is placed, where the former are connected through the Loading-Unloading Arms ( 035) and (036) respectively, on the one hand with the Drying-Preheating Subchambers (002AAA) and on the other hand with the Cooling Subchambers (002AAB) of the superheated Pyrolytic Activated Carbon (008A) and (008b), where the Cooling-Heat Exchange Chambers and Subchambers ( 001AAB) and (002AAB) have the same form as the Pyrolysis Chambers and Subchambers (001AA) and (002AA), connected to them in series through the Loading-Unloading Arms (035) and (036) respectively,

Where alternatively the Pyrolysis Subunit (A.4.1AB) is also characterized by the fact that the extensions of the 7 Unloading Arms (036) of the Pyrolysis Subchambers (002AA), are grouped in the Outlet Collector (003B) from which the outgoing Pyrolytic Activated Carbon (008A) and (008B), is picked up by the Loading Belt (037) and transferred to the Inlet Manifold (003AB) from which the grouped Loading Arms (035B) depart which feed the Subchambers (002AAB) of the Paired Chambers and Cooling-Heat Exchange Subchambers (001AAB) ) and (002AAB) respectively, with the outgoing Pyrolytic Activated Carbon (008A) and (008B) from the Subchambers (002Aa),

Where the ends of the Loading Arms (035) and Unloading (036) carry the Double Flaps (039) and (040) respectively, for the handling of Dry Biomass (A.2.2A) and (A.2.1A) feed and Pyrolytic Active removal Coal (008A) and (008B) from Subchambers (002AA) and (002AAB) without air entering the respective Subchambers (002AA) and (002AAB),

Where the Double Flaps (039) and (040) of the Loading Arms (035) and Unloading (036) Input and Output, respectively, of the Subchambers (002AA) for handling Biomass (A.2.2A) and (A.2.1A) for pyrolysis- carbonation, as well as the Double Flaps (017) and (017A) Inlet and Outlet respectively of the Air Ducts (015) and (015A) are placed on the circumference of the front and rear cylindrical end of the respective Hypochamber (002AA), where they do not prevent the passage of the Shaft (0410) and of the Screw (041A), while the corresponding Loading Arms (035) are either grouped indicatively by seven in the above Inlet Collectors (003AA), as above, or are connected in series with the Unloading Arms (036A) of the Subchambers (002AAA) , in the alternative where Chambers (001AAA) and Subchambers (002AAA) are constructed in the same form as Chambers and Subchambers (001AA) and (002AA) respectively for reasons of uniformity as above,

Where the Pyrolysis Subunit (A.4.1A,B) is also characterized by the fact that the Pyrolysis-Carbonation Chamber (001AA) is fed and heated through the Recirculation Ducts (010) with the Superheated Exhaust Gases (014) from the Hearth (016) of the Boiler (012) and pyrolyzes-carbonizes the contained Biomass (A.2.2A) and (A.2.1A) in the Subchamber (002AA), with the help of the Dual Direction Screw System (041A), which performs the filling process, advancing, stirring and emptying the Subchambers (002AA) with an appropriate procedure as above,

Where the Pyrolysis Subunit (A.4.1A,B) is also characterized in that the Pyrolysis-Carbonization Subchamber (002AA) offers an outlet for the produced Biomass Volatiles (009) through the Volatiles Vents (015) to the Volatiles Outlet Collector (015E). and spare inlet for recirculation of Double Purification from Harmful Components (A.10.1) of the produced Biomass Volatiles (009) through the Volatiles Inlet Collector (015'E) which brings together the Volatiles Recirculation Ducts (015A), where the Collectors (015E) and (015'E) carry the Flight Valves (017) and (017A) respectively,

Where the Pyrolysis Subunit (A.4.1A,B) is also characterized by the fact that the output and possible recirculation of the Volatile Biomass (009) produced from each cylindrical Subchamber (002AA) is through the Volatile Outlet (015) and Inlet (015A) Piping ), which start at the two ends of each cylindrical Subchamber (002AA) immediately through the Intake (039) and Exhaust (040) Flaps, through the Outlet (017) and Inlet (017A) Volatile Valves respectively, which are activated by each Speed Reducer-Motor-lnverter System of Volatile (017Z) and Input (017AZ), which are also located outside the Shell (041'k) of each Subchamber (002AA) for temperature and maintenance reasons, as above,

Where the Volatile Outlet Piping (015) is characterized by being grouped in the Volatile Outlet Manifold (015E) from which the common Volatile Outlet Pipe (015') departs, which via the Four-Way Valve (015X) either goes directly to the Stove (016 ) of the Boiler (012) or in the Combustion Chamber (A.6.1B) of the Gas Turbine (A.6.1A) or is diverted through the Four Way Valve (015x) for an additional Purging Diode through the Volatile Inlet Manifold (015'AE) of the Reserves Subchambers (002A'AB), in which the Volatile Inlet Pipes (015'A) are grouped, which lead the Biomass Volatiles (009) through another set of Backup Subchambers (002A'AB) still filled with Pyrolytic Activated Carbon (008A) and (008B) to a new Volatile Outlet Manifold (015"E) from which the common Volatile Outlet Pipe (015") departs, Where the Cracking Subunit (A.4.1A,B) is also characterized in that the Supply Pipe and Recirculation (010) of Superheated Exhaust Gases (014) from the Stove (016) of the Boiler (012) of the Steam Electric Unit (A.5.1), transports the Superheated Exhaust Gases (014) from the Boiler (012) with temperatures indicatively above 650°C inside the Chambers (001AA) through the Depression Fan ( 028) and the Suction Fan (029), which respectively depress and suck the Superheated Exhaust Gases (014) from the Boiler (012) to the Pyrolysis Chambers (001AA) and recycle them back to the Boiler (012), which heat and pyrolyze the already preheated Dry Biomass (A.2.2A) and (A.2.1A) in the Hypochamber (002AA) and are recycled in the Boiler (012),

Where the Pyrolysis Subunit (A.4.1A B) is also characterized in that the Chambers (001AAB) and Subchambers (002AAB) carry the Preheating Duct (018), which through the Suction Fans (030) and the Isolation Valves (021) , recirculates the Preheating Air (019), which preheats the Feed Water (012A) of the Boiler (012) of the Steam Unit (A.5.1) or the Boiler (012B) of the Combined Cycle Unit (A.6.1) with the extracted heat from the superheated Pyrolytic Activated Carbon (008A) and (008B) to the Subchamber (002AAB), which has been transferred from the Pyrolysis-Carbonization Subchamber (002AA) and after cooling is to be taken out for storage,

Where the Pyrolysis Subunit (A.4.1A b) is also characterized by the fact that internally the process of Filling with Biomass (A.2.2A) and (A.2.1A), Stirring Back and forth of the pyrolyzed Biomass (A.2.2A) and (A.2.1A) and Evacuation of the produced Pyrolytic Activated Carbon (008A) and (008B), characterized by the fact that it is performed by the Dual Direction Screw System (041A), which is characterized by being set to rotate and reverse the direction of its rotation, through the Speed Reducer-Ra-lnverter System (041Z), either for each Subchamber (002 AA) or (002AAB) separately or through the Motion Transmission Chain (041H) for joint movement of all 7 Dual Directional Screws (041A ) for each set of 7 Subchambers (002AA) or (002AAB), of each Chamber (001AA) or (001AAB) respectively,

Where the Double Flaps (039) and (040) entrance - exit and between the Subchambers (002AA) or (002AAB) circulation of Biomass (A.2.2A) and (A.2.1A) for pyrolysis, cooling heat exchange and exit of the Pyrolytic Activated Carbon, respectively, are placed on the circumference of the front or rear cylindrical end of the respective cylindrical Subchamber (002AA) or (002AAB), where they do not prevent the passage of the Shaft (0410) of the Screw (041A), while the corresponding Loading-Unloading Arms (035 ) and (036) are joined in series or grouped by 7 in the Input Collectors (003A) and (003Ab) or Output (003BA) and (003BB) respectively, of each Subchamber (002AA) or (002AAB), as above,

Where the Pyrolysis Subunit (A.4.1A,B) is characterized by the fact that the Loading of Biomass (A.2.2) and (A.2.1) to the Collector-Biomass Inlet Silo (003AA) and the Unloading of the produced Pyrolytic Activated Carbon ( 008A) and (008B) from the Output Collector-Silo (003BB) of the Pyrolytic Activated Carbon (008E) is performed by the Loading - Unloading System (A.7.1), which through the Biomass Feed Belts (037) to the Collector-Silo (003AA) Biomass Inlet and Pyrolytic Activated Carbon Extraction Belts (038) from the Outlet Collector-Silo (003Bb), as well as the Double Valves - Inlet (039A) and Outlet (040B) for Sealing the Subchambers (002AAA) or ( 002AAB) from air inlet, with full automation of the loading-unloading process,

Where the Pyrolysis Subunit (A.4.1A,B) is also characterized by the fact that the number of revolutions of the Dual Directional Screw System (041A) of the Subchambers (002AA) and (002AAB) or of the Backup Subchambers (002AAB) has been adjusted accordingly ) with Pyrolytic Activated Carbon, through the Inverters of the Speed Reducer-Motor-lnverter System (041Z), as above, so as to increase and decrease the speed of filling, stirring back and forth and emptying the Subchambers (002АА) and (002АAB) depending on the type and the characteristics of the Biomass or the apparent volume of the Pyrolytic Activated Carbon (008A) and (008B) for a larger contact surface with the recirculating Biomass Volatiles (009) for their complete purification of their Harmful Components (A.10.1),

Where the Pyrolysis Subunit (A.4.1A B) is also characterized by having Electrostatic Filters (012E) or Bag Filters (012Z), which are placed indicatively on the Air Duct (015') or (015") or (015"') supply of Volatile Biomass (009) for combustion in the Hearth (016) of the Boiler (012) or in the Combustion Chamber (A.6.1E) of the Gas Turbine (A.6.1A) in an intermediate position from the Pairs of Chambers (001AAB) and (002AAB) ) with Pyrolytic Activated Carbon (008A) and (008B) and the Hearth (016) of the Boiler (012) or the Combustion Chamber (A.6.1E) of the Gas Turbine (A.6.1A), which retain the Microparticles (008' A) and (008'B) Pyrolytic Activated Carbon (008A) and (008B), which are carried away by the stream of Volatile Biomass (009) with their Single or Double or Multiple Purification Diode through the Subchambers (002AAB) with Pyrolytic Activated Carbon (008A) and (008B) and which are collected and returned to the mass of Pyrolytic Activated Carbon (008A) and (008B), so as to avoid material and, on the other hand, not to burden the environment with Microparticles (008'A) and (008'B),

Where the innovative Pyrolysis Subunit (A.4.1A,B) is also characterized in that the Pair of Chambers (001АА) and Subchambers (002АА) of Pyrolysis-Carbonization after each filling of the Hypochamber (002АА) from the Hypochamber (002АAA) with dry and preheated Biomass (A.2.2A) and (A.2.1A), the Subchamber (002AA) is sealed through the Isolation Valves (039) and (040), so because the Pyrolysis-Carbonization is carried out under pressure, indicatively 20-40Bar, the which create the emitted Biomass Volatiles (009), as above, is characterized by the fact that, among other things, additional significant advantages arise for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), as analyzed in detail above, in Chapter C

"Advantages of the Present Invention in the Prior Art" as well as in Alternative Version A.0. Pyrolysis-Carbonization Unit (A.4.1Θ) of Biomass Under Pressure, General Form with Fixed or Rotating Chambers and Subchambers, A.2. Pyrolysis-Carbonization Unit under Pressure (A.4.1E) of Biomass (A.2.2) and (A.2.1)

then a Pyrolysis-Carbonization Unit (A.4.1E), which is constructed like the Pyrolysis-Carbonization Unit (A.4.1A) in Paragraph A.1, but is characterized by the fact that instead of Fixed Chambers (001AAA), (001AA) and (001AAB) and Fixed Chambers (002AAA), (002AA) and (002AAB), consists of Fixed Chambers (001AEA), (001Ae) and (001AEB) and Rotating Chambers (002AEAB), (002AE) and (002AEB), with Internal System of Filling, Stirring Forward-Backward and Evacuating the Biomass and Pyrolytic Activated Carbon through the Internal Double Direction Helical Spiral (041'A), which is welded to the inner surface of each Subchamber (002AEA), (002AE) and (002AEB) ,

Where the Dual Direction Helical Spiral (041'A) is characterized by the fact that it performs the process of filling, advancing, stirring and emptying the above Subchambers, through the rotational movement of the above Turning Subchambers, which is done either through seven Internal Speed Reducers (045' ) per Chamber as above, which move the respective Toothed Rotation Rings (043') on the outer surface of the respective Turning Subchambers (002AEA), (002AE) and (002AEB), through the Rolling Bearings (041') of rotation of the Turning Subchambers, where the rotational movement and reversal of the direction of rotation of the Rotating Subchambers as above, is done by coupling the Internal Speed Reducers (045') with the corresponding Speed Reducers-Motor-lnverter Systems (042'), which are outside the Shell (041k ) of each Chamber (001AEA), (001AE) and (001AEB) or of the Shell (041'k) of each Subchamber (002AEA), (002AE) and (002AEB) for thermal reasons operation and maintenance, either in the seven-fold Subchambers (002AE) and (002AEB) through coupling with a common Drive Transmission Chain (041'H) and the seven Toothed Rings of Rotation (043') with an external Speed Reducer-Motor-lnverter System as above ( 042'), which moves all seven Rotating Hypothalamus (002AE) and (002AEB), per each Chamber (001AE) and (001AEB),

Where the respective Loading Arms (035'A) and Unloading (036'B) of Biomass (A.2.2A) and (A.2.1A) and Pyrolytic Activated Carbon (008A) and (008B) and the Double Inlet Flaps ( 039'A), (039') and (039'B) and Extraction (040'A), (040') and (040'B) are placed immediately outside the Sealing Rings of the Inlet-Outlet Rotation (047') and (048') at the front and rear ends of the respective Rotation Cylinder (044') of the Rotating Subchambers (002AEA), (002AE) and (002AEB) respectively, which are characterized by being manufactured indicatively like the Sealing Rings of the Large Diameter Slow-Rotating Pistons Heavy Duty Diesel Engines, which work at even higher temperatures and pressures and additionally reciprocate, unlike Inlet - Outlet Seal Rings (047') and (048'), which simply rotate,

It is also characterized in that the ends of each pair of Chambers (001AEA), (001AE) and (001AEB) and Subchambers (002AEA), (002AE) and (002AEB) take the same form as the ends of the corresponding pairs of Chambers and Subchambers of the Subunit of Pyrolysis (A.4.1AA), on the one hand to facilitate the entry - exit and the filling and emptying operation of Biomass (A.2.2A) and (A.2.1A) and Pyrolytic Activated Carbon (008A) and (00dB) with the help of the Double Directional End Screws (041E), of the same construction as the Double Directional Screw (041A), inside the fixed end parts of the Subchambers (002AEA), (002AE) and (002AEB) and on the other hand for the entry-exit of the corresponding pairs of Air Ducts that enter - exit inside the Rotating Subchambers, as above, where alternatively the continuous function of promoting one direction from the filling of the Biomass (A.2.2) and (A.2.1) to the discharge of the Pyrolytic Activated Carbon (008A ) and (008B ), if the type and requirements of the processed Biomass allow it, otherwise as in the Pyrolysis Subunit (A.4.1AA) above

A.3. Pyrolysis-Carbonization Unit (A.4.1H) of Biomass, Under Pressure. A Passage, Integration into a Complex Pair of Pyrolysis-Carbonization Chambers and Subchambers

then a Pyrolysis-Carbonization Unit (A.4.1H), which is characterized by the fact that it consists of an innovative Pyrolysis-Carbonization Unit (A.4.1H) like the Pyrolysis-Carbonization Units (A.4.1A) and (A.4.1 E) above, which is characterized by the fact that instead of three separate pairs of Chambers and Subchambers (001AAA) - (002AAA), (001AA) - (002AA) and (001AAB) - (002AAB) or (001AEA) - (002AEA) , (001AE) -(002AE) and (001AEB) - (002AEB), Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange respectively, the merging of the respective three separate pairs of Chambers and Subchambers as above into a Composite is also implemented alternatively Pair of Chambers and Subchambers (001AA) - (002AA) or (001AE) -(002AE), which is characterized by gathering on it all the Air Ducts that belonged to each pair of Chambers and Subchambers as above as well as the Biomass Inlet-Outlet (A.2.2) and (A.2.1) and the produced Pyrolytic Activated Carbon (008A) and (008B) respectively,

The Complex Pair of Chambers and Subchambers (001AA) - (002AA) or (001AE) - (002AE) which is characterized by the fact that it begins its operation as a pair of Chambers and Subchambers (001AAAA) - (002AAAA) or (001AEEA) - (002AEEA ) of Biomass Drying-Preheating (A.2.2) and (A.2.1) by activating the Drying-Preheating Duct (022) as well as the Biomass Loading System (A.2.2) and (A.2.1) as above and in after the end of the Drying-Preheating process by alternating the Drying-Preheating Air Duct (022) with the Pyrolysis-Carbonization Air Ducts (010) and (015)-(015A) it is converted into a pair of Chambers and Subchambers (001AAA) - (002AAA) or (001AEE) - (002AEe) of Pyrolysis-Carbonization and then after the end of the Pyrolysis-Carbonization process by switching the Pyrolysis-Carbonization Ducts (010) and (015)-(015A) to the Cooling-Heat Exchange Duct (019) is converted in a pair of Chambers and Subchambers (001AAAB) - (002AAAB) or (001AEEB) - (002AEEB ) Cooling-Heat Exchange of the produced Pyrolytic Activated Carbon (008A) and (008B) with finally activation of the Unloading Subsystem of the produced Pyrolytic Activated Carbon (008A) and (008B), Where it is characterized by the fact that as a result of the implementation of the Composite Pair of Chambers and Subchambers (001AA) - (002AA) or (001AE) - (002AE) as above, the thermal power of the Volatile Biomass produced is reduced to approximately one third of the thermal power of the three dimensionally equivalent independent pairs of Chambers and Subchambers as above, so for the production of equivalent thermal power is multiplied by approximately three times the number of Composite Pairs of Chambers and Subchambers (001AA) - (002AA) or (001AE) - (002AE) as above and where the final choice of one or the other alternative solution will be judged by case from the specific characteristics of each type of Biomass and the remaining techno-economic parameters of each Power Generation System (A. E.i) Negative Carbon Dioxide Emissions, of the Negative CO2 Emission Units, as above,

Otherwise as in Paragraphs A.0, A.1 and A.2 above,

A.4. Pyrolysis-Carbonization Unit (A.4.1'O) or (A.4.1A) or (A.4.1E) or (A.4.1H) of Biomass, Under Atmospheric Pressure, Multiple Purification Passages of Volatile Biomass.

then Pyrolysis Unit (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H), which is characterized by the fact that it consists of an innovative Pyrolysis Unit (A.4.1' 0) or (A.4.1A) or (A.4.1E) or (A.4.1H) such as the Pyrolysis Unit (A.4.10) or (A.4.1A) or (A.4.1E) or (A.4.1E) 4.1H), above, which is however characterized by the fact that it consists of Fixed or Rotating Chambers and Subchambers, which operate with Atmospheric Pressure,

And where the Pyrolysis Units (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) are additionally characterized by the fact that due to possible incomplete cleaning of the Volatile Biomass (009) from the Their Harmful Components (A.10.1) in First Diode, have the possibility to submit the produced Biomass Volatiles (009) to Double, Triple or Multiple Diode through respective Spare Pairs of Chambers and Subchambers with Pyrolytic Activated Carbon (008A) and (008B) , until the purification of the Volatile Biomass (009) reaches the desired purity level, which is safe for the operation of the Boiler (012) or the Gas Turbine (A.6.1A) respectively, otherwise as in the Pyrolysis Units (A .4.10) or (A.4.1A) or (A.4.1E) or (A.4.1H) above,

B.1. The Power Generation System (A.E.1) as a Unit Combination (A.5.1) with a Pyrolysis Unit (A.4.1A) under 20-40Bar Pressure of a Cleaning Diode,

then Power Generation System (A.E.1), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.1.1A) Biomass Storage and Pre-Drying (A.2.0), (A.E. 1.2A) Preparation and First Drying of Biomass (A.2.0), (A.E.1.3A) Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E.1.4A) Pyrolysis- Carbonization of Biomass Under Pressure 20-40Bar, (A.E.1.5A) of the Steam Power Plant (A.5.1) and (A.E.1.7A) Transport and Storage of the produced Pyrolytic Activated Carbon (008A) and (008B) , which are characterized by the fact that they each consist of the following Components, namely:

- The Biomass Storage and Pre-Drying Subsystem (A.E.1.1A) (A.2.0). as received, which is characterized by having Biomass storage (A.2.0) in a Covered Semi-Outdoor Space (A.1.3) with a Transparent Roof (A.1.3A), indicative of transparent Double Wall Plexiglas, for protection from rain and entry of Solar Radiation and ambient air for a First Drying (A.1.2), during the long seasonal storage of Biomass, which is collected on a seasonal basis and stored for up to and over a six-month period, in which case its moisture is reduced indicatively from 40-50% to 30-35%, in contrast to the current state of the art, where no such drying is foreseen with a corresponding deterioration in the degree of performance,

- The Biomass Preparation and First Drying Subsystem (A.E.1.2A) (A.2.0). which is characterized by having the First Drying System (A.2.4), in which a quantity of the stored Biomass (A.2.0) is promoted for First Drying (A.2.4) for the operation of the Steam Electric Unit (A.5.1), indicatively 2-3 days, and then, after the First Drying (A.2.4), promotion to the Milling System (A.2.8) for the division to a small size of Woody Biomass shredding chips (A.2.2) and to the Pelletizing System (A. 2.9) for Pelletization of the Fine Biomass (A.2.1) into pellets of a corresponding size, typically 10-20mm in size, with intermediate storage of the mixture of chips and pellets or possibly only pellets if total Pelletization is selected, of the Ground Woody Biomass (A.2.2) and of the Pelletized Fine Biomass (A.2.1), which constituted the Biomass (A.2.0), in the Biomass Silos (A.2.3), for promotion to the Second Drying System (A.3.1) in the System (A.E.1.3A) , where the First Drying (A.2.4) of the Biomass (A.2.0) takes place in an enclosed thermally insulated Tun Drying el (A.2.7), which contains the Drying Wagons (A.2.5), in which the Biomass (A.2.2) and (A.2.1) are loaded and which are slowly transported inside the Drying Tunnel (A.2.7) through the Conveyor Belt (A.2.6) or by rolling on the Railway Tracks (A.2.6A) and is dried with a part of the Hot Exhaust Gases (A.1.4), taken from the entrance of the Chimney (A.1.5) of the Boiler (012) of the Steam Electric Unit (A.5.1) or from the entrance to the Chimney (A.1.5) of the Exhaust Gas Boiler (012B) of the Combined Cycle Unit (A.6.1), which have a temperature indicatively above 150°-180° C,

Where the Subsystem (A.E.1.2A) is also characterized by the fact that it includes the Exhaust Gas Circulation Duct (032) (A.1.4) of the Chimney (A.1.5) of the Power Generation Unit (A.5.1), for the First Drying (A.2.4) of Biomass (A.2.2) and (A.2.1), the Depression Fan (033), which sucks in and sends part of the Exhaust Gases (A.1.4) of the Chimney (A.1.5) of the Power Plant ( A.5.1), temperature indicative of 180°C, for the First Drying (A.2.4) of Biomass (A.2.2) and (A.2.1), while the corresponding Exhaust Gases (A.1.4) of the Boiler (012) with reduced temperature, due to the First Drying (A.2.4) and pre-heating of the Biomass (A.2.2) and (A.2.1), are transmitted to the Cooling Tower (A.1.8A) for expulsion into the atmosphere, carried away by the ascending stream of water vapor of the Tower of Cooling (A.1.8A), where Drying with Hot Exhaust Gases (A.1.4) lowers the moisture of Biomass (A.2.2) and (A.2.1) indicatively from 30-35% to a level below 20%, in preparation for the Second Drying System s (A.3.1), which takes place in the Subsystem (A.E.1.3A),

Where the Subsystem (A.E.1.2A) is also characterized by the fact that the Biomass (A.2.2) and (A.2.1) after the First Drying System (A.2.4) and its Milling-Pelletization and Storage in Biomass Silos (A.2.3), is promoted to be introduced for the Second Drying Stage (A.3.1) in the Chambers (001AA) and Subchambers (002AA) of the Biomass Drying and Preheating Subsystem (A.E.1.3A) (A.2.2) and (A.2.1), through the Subsystems of the Biomass Feed Belts (037) of the Collector-Silo (003AA) and the Loading Arms (035A) as well as the Double Inlet Flaps (039A) of the Loading-Unloading Systems (A.7.1) , per Chamber (001AA) and Subchamber (002AA) pair, with full automation of the internal continuous process of loading Biomass (A.2.2) and (A.2.1) into the Subchambers (002AA) of the Subsystem (A.E.1.3A) respectively , unlike our previous Application with OBI Number 20190100159, where the loading of Biomass (A.2.2) and (A.2.1) and its transport and import into corresponding Subchambers (002) of the System (A.3) is done with the discontinuous process and use of the abolished Wagons (003),

The Biomass Drying and Preheating Subsystem (A.E.1.3A) (A.2.2) and (A.2.1). then Subsystem (A.E.1.3A) or Drying-Preheating Subunit (A.4.1AA), which is characterized by having Second Stage Drying (A.3.1) with the available Hot Exhaust Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012) of the Steam Unit (A.5.1), which remove the last 20% of the moisture and preheat the Dry Biomass (A.2.2A) and (A.2.1) accordingly A) and where then after heat recovery from the Biomass (A.2.2A) and (A.2.1A) due to drying and pre-heating from the Hot Exhaust Gases (A.1.4), which are thus cooled and transmitted to the Tower of Cooling Tower (A.1.8A) for discharge into the atmosphere, carried away by the updraft of water vapor of the Cooling Tower (A.1.8A), where a significant overall improvement of the efficiency of the System (A.E.1) results on an indicative average more than 10%, in contrast to the degree of efficiency of power generation from conventional pyrolysis-coking, which is correspondingly lower than the System of Power Generation (A.E.1),

otherwise as described in Paragraph A.1 Drying-Preheating Subunit (A.4.1AA) of Pressurized Biomass, Single Pass, above,

- The Subsystem (A.E.1.4A) Pyrolysis-Carbonization of Biomass Under Pressure, then Subsystem (A.E.1. 4A) or Pyrolysis-Carbonization Subunit (A.4.1A,B), which is characterized by the fact that it consists of an innovative Pyrolysis-Carbonization Subunit (A.4.1A,B) of Ground or Pelletized Dry Woody or Fine-Grained Biomass (A.2.2A) and (A.2.1A), consisting of Carbon Pyrolysis Chambers and Subchambers (001AA) - ( 002AA) and Cooling-Heat Exchange (001AAb) -(002AAb) respectively, where the Pelletized Dry Biomass (A.2.2A) and (A.2.1A) is heated indicatively to 550°C and pyrolyzed and then the Pyrolytic Active Coal (008A) and (008B) is cooled and heat exchanged, as detailed in Paragraph A.1 Pyrolysis-Carbonization (A.4.1A) and Cooling-Heat Exchange (A.4.1AB) Subunits of Pressurized Biomass, One Pass, above,

Where the innovative Pyrolysis-Carbonization Subunit (A.4.1A,B) is characterized by the fact that because the Pyrolysis-Carbonization is carried out under pressure, indicatively 20-40Bar, significant additional advantages arise for the entire Biomass Pyrolysis-Carbonization process ( A.2.2) and (A.2.1), as described in detail above in Chapter C "Advantages of the Present Invention in terms of the State of the Art" and in Paragraph A.1 Pyrolysis-Carbonization (A.4.1A) and Cooling-Exchange Subunits of Heat (A.4.1Ab) of Pressurized Biomass, One Pass, above,

Otherwise as described in detail in Paragraph A.1 Pyrolysis-Carbonization (A.4.1A) and Cooling-Heat Exchange (A.4.1AB) Subunits of Biomass Under Pressure, Single Pass, above,

- The Subsystem (A.E.1.5A) of the Modified Steam Electric Power Generation Unit (A.5.1), which is characterized by the fact that the Modified Units (A.5.1) will now operate with Pure or Mixed Combustion of Volatile Biomass (009) and Coal (009A), where the possibility exists, in a first conversion of the Coal Power Plant into a Power Plant (A.5.1) in principle for Mixed Combustion, indicatively with 1/3 Coal (009A) and 2/3 Volatile Biomass (009), to the cost of converting the Coal Steam Electric Power Generation Unit to a Power Generation Unit (A.5.1) is zeroed out, because the Coal Steam Electric Power Generation Units can reduce the load to 1/3 without any conversion and in fact when the combustion in the Hearth (016) of the Boiler (012 ) is supported by the additional Mixed Combustion of 2/3 of Volatile Biomass (009), so the reduced 1/3 of Carbon Dioxide emissions are offset by more than the Negative Carbon Dioxide Emissions aka that correspond to the produced Pyrolytic Activated Carbon (008A) and (008B), so that even with zero conversion costs of the Coal Steam Power Plant, it can not only offset the Carbon Dioxide emissions to zero but convert them by a percentage of 38 -45% in net Negative Carbon Dioxide Emissions,

Where only the innovative Pyrolysis-Carbonization Unit (A.4.1A) with its peripherals remains as an investment for the entire Power Generation System (A.E.1), which as an investment cost is amortized with the net profits of less than two years, while now the Power Generation System (A.E.1) with the Modified Power Generation Unit (A.5.1) is particularly profitable, because on the one hand it avoids the cost of purchasing Carbon Dioxide Emission Rights while on the other hand it secures approximately 40% of this cost as a Credit due of the Production of Negative Carbon Dioxide Emissions, while at the same time it is credited with the sales value of the Pyrolytic Activated Carbon (008A) and (008B) produced as an Improvement Soil for Agriculture, so the result instead of losses turns into a very appreciable profit even for Mixed Combustion as above, while with Pure Combustion, despite the increased investment for the modification of the Boiler (012) for Pure Combustion of Volatile Biomass (009), the profitability increases by at least 40-50% while Negative Carbon Dioxide Emissions more than double,

Where the Subsystem (A.E.1.5A) is characterized by the fact that it consists of a Modified Steam Electric Power Generation Unit (A.5.1) with initial combustion of fossil fuels, indicatively Coal (009A), which has been modified to burn Volatile Gaseous Products ( 009) of the Pyrolysis-Carbonation Unit (A.4.1A) in the Hearth (016) of the Steam Boiler (012), in mixed combustion with Coal (009A) in the proportion that is necessary up to the total zeroing of the use of Coal (009A) and pure combustion of only Volatile Biomass (009), in which case the Carbon Dioxide emissions from the Modified Steam Electric Power Generation Unit (A.5.1) are zeroed out by zeroing the combustion of Coal (009A), because the minimum emission of Carbon Dioxide from the pure combustion of Volatile Biomass (009) does not count as a greenhouse gas, because it comes from Carbon Dioxide which was absorbed from the Atmosphere by plants, while at the same time a Negative Carbon Dioxide Emission is achieved due to the production of Pyrolytic Activated Carbon (008A) and (008B), which is equivalent to seizing 3.667 times heavier Atmospheric Carbon Dioxide and which is promoted for use as a Soil Improver in Agriculture, while at the same time reducing or completely eliminating the operation of the Chimney ( A.1.5) of the Steam Power Generation Unit (A.5.1), which is replaced by the operation of the modified Cooling Tower (A.1.8A), which promotes the reduced temperature Exhaust Gases (A.1.4) into the atmosphere, due to drying and preheating of Biomass (A.2.2) and (A.2.1), with the upward stream of Water Vapor of the Cooling Tower (A.1.8A), as well as the Desulphurization and Denitrification Systems are abolished, because the Sulfur and Nitrogen Compounds are retained by the Filter of Pyrolytic Activated Carbon (008A) and (008B), Coal Mills, Ash and Gypsum Removal Systems from Desulphurization and Waste Treatment Systems from Desulphurisation, Desulphurisation and other waste retained by the Pyrolytic Activated Carbon Filter (008A) and (008B),

- The Subsystem (A.E.1.7A) for the Transport and Storage of Pyrolytic Activated Carbon (008A) and (008B), which is characterized by the fact that it promotes it indicatively either in enrichment and activation units of Pyrolytic Activated Carbon (008A) and (008B) with chemical or organic fertilizers and then promoting it for permanent storage as a Soil Improver in Agriculture, where it remains unchanged for hundreds or even thousands of years, and where by creating and hosting large Colonies of Nitrogen bacteria and other Bacteria in the soil, they bind and assimilate Atmospheric Nitrogen and other Trace Elements that nourish plants, dramatically increases agricultural production by 200% to as much as 900% [15], [16], [17] in perpetuity, either in short-term storage for future use or for other uses, as opposed to the current state of the art, where the reduction of Carbon Dioxide emissions of Fossil Fuel Power Plants is simply foreseen, where it does not foresee negative Carbon Dioxide Emissions, nor production of Pyrolytic Activated Carbon (008A) and (008B),

B.2. The Power Generation System (A.E.2) as a Unit Combination (A.5.1) with a Pyrolysis Unit (A.4.1E) Under Pressure of 20-40Bar One Purification Diode,

then Power Generation System (A.E.2), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.2.1e) Biomass Storage and Pre-Drying (A.2.0), (A.E. 2.2E) Preparation and First Drying of Biomass (A.2.0), (A.E.2.3E) Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E.2.4E) Pyrolysis- Carbonization of Biomass Under Pressure of 20-40Bar and Cooling-Heat Exchange, (A.E.2.5E) of the Steam Power Unit (A.5.1) and (A.E.2.7e) Transport and Storage of the produced Pyrolytic Activated Carbon (008A ) and (008b), which are characterized by the fact that they each consist of the following Components as described below, namely:

- Where Subsystems (A.E.2.1E), (A.E.2.2E), (A.E.2.5E) and (A.E.2.7E, are characterized by being the same as Subsystems (A.E.1.1A), (A .E.1.2A), (A.E.1.5A) and (A.E.1.7 Above in the System (A.E.1),

- The Biomass Drying - Preheating Subsystem (A.E.2.3E) (A.2.2) and (A.2.1). then Subsystem (A.E.2.3E) or Drying - Preheating Subunit (A.4.1EA), which is the same as the Subsystem (A.E.1.3A) above, but is characterized by the fact that instead of the pair with Fixed Chambers and Subchambers (001AAA) and (002AAA) respectively, consists of the pair with Fixed Chambers (001AEA) in conjunction with the Rotating Subchambers (002AEA), otherwise as in the Subsystem (A.E.1.3A) and the Unit of Pyrolysis - Carbonization (A.4.1E) Under Pressure in Paragraph B.1 and A.2 above,

- The Biomass Pyrolysis-Carbonization Subsystem (A.E.2.4E) under 20-40Bar Pressure, then Subsystem (A.E.2.4E) or Pyrolysis-Carbonization Subunit (A.4.1E,B), which is same as the Subsystem (A.E.1.4A) above, but characterized by the fact that instead of the pairs with Fixed Chambers and Subchambers (001AAA)-(002AAA), (001AA)-(002AA) and (001AAB)-(002ААб) ) respectively, consists of the pairs with Fixed Chambers (001AEA), (001AE) and (001AEB) coupled with Rotating Subchambers (002AEA), (002AE) and (002AEB) respectively, otherwise as in Subsystem (A.E .1.4A) and in the Pyrolysis - Carbonization Unit (A.4.1E) Under Pressure in Paragraphs B.1 and A.2 above,

B.3. The Power Generation System (A.E.3) if a Unit Combination (A.6.1) or (A.6.1) with a Pyrolysis-Carbonization Unit (A.4.1A) or (A.4.1E) Under Pressure. A Cleaning Diode. then Power Generation System (A.E.3), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.3.1A) or (A.E.3.1E) Biomass Storage and Pre-Drying (A .2.0), (A.E.3.2A) or (A.E.3.2E) Preparation and First Drying of Biomass (A.2.0), (A.E.3.3A) or (A.E.3.3e) Drying-Preheating of Biomass (A.2.2) and (A.2.1), (A.E.3.4A) or (A.E.3.4E) Pyrolysis-Carbonization and Cooling-Heat Exchange of Biomass Under Pressure 20-40Bar, (A.E.3.6A) or (A.E.3.6e) of the Simple or Combined Cycle Unit (A.6.1) or (A.6.1'), (A.E.3.7A) or (A.E. 3.7E) Transport and Storage of the produced Pyrolytic Activated Carbon (008A) and (008B), which are characterized by the fact that they consist of the following Components as follows, namely:

- Where Subsystems (A.E.3.1A) or (A.E.3.1E). (A.E.3.2A) or (A.E.3.2E). (A.E.3.3A) or (A.E.3.3E) and (A.E.3.7A) or (A.E.3.7E). are characterized by being the same as Subsystems (A.E.I.I.A), (A.E.1.2a), (A.E.1.3A) and (A.E.1.7A) and (A.E .1.1E), (A.E.1.2E), (A.E.1.3E) and (A.E.1.7E) above in System (A.E.1) and (A.E.2),

- The Subsystem (A.E.3.4A) or (A.E.3.4E) Biomass Pyrolysis-Carbonization Under Pressure 20-40Bar, then Subsystem (A.E.3.4A,E) or Pyrolysis-Carbonization Subunit (A.4.1 A,B) or (A.4.1E,B), is characterized by being the same as the Subsystems (A.E.1.4A) and (A.E.2.4e) above, i.e. each as an innovative Pyrolysis Subunit- Carbonization (A.4.1A,B) or (A.4.1E,B) Under Pressure, indicatively 20-40Bar, for the production of pure Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), characterized however, since the Superheated Exhaust Gases (014) for the Pyrolysis-Carbonization in the Subchambers (002AA) and (002AE) are taken from the Gas Turbine outlet (A.6.1A) and after the Pyrolysis-Carbonization are advanced to the Waste Gas Boiler (012B) of Combined Cycle Unit (A.6.1), otherwise as in Subsystem (A.E.1.4A) and (A.E.2.4e) above,

- The Subsystem (A.E.3.6A,E) of the Simple or Combined Cycle Unit (A.6.1) or (A.6.1') hereafter Subsystem (A.E.3.6A,E), is characterized by the fact that it consists of a combination from a Modified Single or Combined Cycle Power Generation Unit (A.6.1') or (A.6.1) with Pure or Mixed Combustion of Volatile Biomass (009) with Fossil Fuels, indicative of PV (009B) and an innovative Pyrolysis-Carbonation Subunit (A. 4.1A,B) or (A.4.1E,B) Under Pressure, indicatively 20-40Bar, for the production of pure Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), in which case the multiple advantages arise both for the entire Pyrolysis-Carbonization process of Biomass (A.2.2) and (A.2.1) as well as for Power Generation, as analyzed in the Detailed Description below,

Otherwise as in Paragraphs B.l, B.2 and A.l, A.2 above,

B.4. The Power Generation System (A.E.4) Combining a Unit (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1HA) or (A.4.1HE) Under Pressure 20 -40Bar of a Cleaning Diode

then Power Generation System (A.E.4), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.4.1H) Biomass Storage and Pre-Drying (A.2.0), (A.E. 4.2H) Preparation and First Drying of Biomass (A.2.0), (A.E.4.3H) Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E.4.4h) Pyrolysis- Carbonization of Biomass Under 20-40Bar Pressure and Cooling-Heat Exchange, (A.E.4.5H) of the Power Generation Unit (A.5.1) or (A.6.1) or A.6.1'), (A.E.4.7H ) of Transport and Storage of the produced Pyrolytic Activated Carbon (008A) and (008B), which are characterized by the fact that they consist of the following Components as described below, namely:

- Where the Subsystems (A.E.4.1H), (A.E.4.2H). (A.E.4.3H) and (A.E.4.7H), are characterized by the fact that they are the same as Subsystems (A.E.1.1A), (A.E.1.2A), (A.E. 1.3A) and (A.E.1.7A) and (A.E.1.1E), (A.E.1.2E), (A.E.1.3E) and (A.E.1.7E) above in System (A.E.1) and (A.E.2),

- The Biomass Pyrolysis-Carbonization Subsystem (A.E.4.4H) Under 20-40Bar Pressure, then Subsystem (A.E.4.4H) or Pyrolysis-Carbonization Subunit (A.4.1H), which is characterized by the that it is the same as the Biomass Pyrolysis-Carbonization Subunit (A.4.1h) of Biomass, Under Pressure, One Pass, Integration into a Composite Pair of Pyrolysis-Carbonization Chambers and Subchambers, otherwise as in Paragraph A.3 above,

- The Subsystem (A.E.4.5H) of the Electrical Protection Unit (A.5.1) or (A.6.1) or A.6.1'), hereafter Subsystem (A.E.4.5H), is characterized by the fact that it consists of a combination of a Modified Power Generation Unit (A.5.1) or (A.6.1') or (A.6.1) as in Subsystems (A.E.1.5A) and (A.E.3.5E) and an innovative Pyrolysis Subunit -Carbonization (A.4.1H) Under Pressure, indicatively 20-40Bar, for the production of Clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), so the multiple advantages arise both for the entire process Biomass Pyrolysis-Carbonization (A.2.2) and (A.2.1) as well as Power Generation, as analyzed in the Detailed Description above,

Otherwise as in Paragraphs B.1, B.2, B.3 and A.1, A.3 above,

B.5. The Electroheating System (A.E.5) Combination of Unit (A.5.1) or (A.6.1) or A.6.1') with Pyrolysis-Carbonation Unit (A.4.1'O) or (A.4.1A) or ( A.4.1E) or (A.4.1H) Atmospheric Pressure, then Power Generation System (A.E.5), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.5.1') Storage and Pre-Drying of Biomass (A.2.0), (A.E.5.2') Preparation and First Drying of Biomass (A.2.0), (A.E.5.3') Drying - Preheating of Biomass (A.2.2) and ( A.2.1), (A.E.5.4') Pyrolysis-Carbonization (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) Atmospheric Pressure, (A. E.5.5') of the Power Generation Unit (A.5.1) or (A.6.1) or A.6.1'), (A.E.5.7) Transport and Storage of the produced Pyrolytic Activated Carbon (008A) and (008B), the which are characterized by the fact that they consist of the following Components as described below, namely:

-<'>Where Subsystems (A.E.5.1'), (A.E.5.2'), (A.E.5.3') and (A.E.5.7'), are characterized by being the same as the Subsystems (A.E.1.1A), (A.E.1.2A), (A.E.1.3A) and (A.E.1.7A) above in System (A.E.1),

- The Subsystem (A.E.5.4') with Pyrolysis-Carbonation Subunits (A.4.1'O) or (A.4.1A) or (A.4.1E) or (A.4.1Ο) Atmospheric Pressure, hereinafter Subsystem (A.E.5.4') or Pyrolysis-Carbonization Unit (A.4.1'O) or (A.4.1A) or (A.4.1E) or (A.4.1H), is characterized by being the same as the Pyrolysis-Carbonization Units (A.4.10) or (A.4.1A) or (A.4.1E) or (A.4.1H) Atmospheric Pressure in Paragraph A.4 above,

- The Subsystem (A.E.5.5') of the Electrical Protection Units (A.5.1) or (A.6.1) or A.6.1'). hereinafter Subsystem (A.E.4.5'), characterized by the fact that it consists of a combination of a Modified Power Generation Unit (A.5.1) or (A.6.1') or (A.6.1) as in Subsystems (A.E .1.5A) and (A.E.3.6A) and an innovative Pyrolysis-Carbonization Unit (A.4.1'O) or (A.4.1A) or (A.4.1'E) or (A.4.1'H) Atmospheric Pressure, for the production of clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), in which case the need arises for a Double or Triple or Multiple Purification of Volatile Biomass as in Paragraph A.4 above,

Otherwise as in Paragraphs B.1, B.2, B.3, B.4 and A.1, A.2, A.3 and A.4 above,

REFERENCES

[1] Leaked Pentagon Report Warns Climate Change May Bring Famine, War

[2] Secret Study of the US Army Leaked and published by The OBSERVER in London "An Abrupt Climate Change Scenario and Its Implications for United States National Security"

[3] "There are no passengers on Spaceship Earth. We are all crew" Marshall McLuhan, Biography.

[4] "The Day After Tomorrow" (A Hollywood Movie with financing by the American Army), Available in all Video Shops.

[5] A shocking Picture: Australia in flames from a satellite - An untold catastrophe

[6] The blazes in the Amazon are so big they can be seen from space. One map shows the alarming scale of the fires.

[7] World Alarm: The Planet in Climate Emergency

[8] biz088 (World Scientists' Warning of a Climate Emergency)

[9] "Dramatic Warning from WWF: This is the last Generation which can save the Planet"

[10] Lord Stern: we need negative emissions to avoid 2.0°C warming

[11] Research Funded By Leonardo DiCaprio Foundation Under One Earth Initiative Claims World Can Stay Below 1.5°C With 100% Renewable Energy Achieved By 2050

[12] UN COP21 Agreement in Paris in 2015 on Climate Change

[13] Drawing No 23, where is given graphically that the increase of Carbon Dioxide in the Atmosphere in relation to 2020 will be zero, provided that the Negative C02 Emissions Technology will be adopted by the existing today Fossil-Fuels-Fired Power Plant Units .

[14] ) 076 (The Role of Pressure in the Heat of Pyrolysis of a Lignocellulosic Biomass)

[15] agronomy-03-00404 [The Impact of Biochar Application on Soil Properties and Plant Growth of Pot Grown Lettuce (Lactuca sativa) and Cabbage (Brassica chinensis)] (till 900%).

[16] Terra-preta

[17] 442-311_pdf (Virginia Tech. University)

Claims (10)

A X I O S E I S 1. One Pyrolysis-Carbonization Unit (A.4.10) of Biomass, Under Pressure, of General Form, with Fixed or Rotating Chambers and Subchambers, then Pyrolysis-Carbonization Unit (A.4.10), which is characterized by the fact that it consists of an Innovative Pyrolysis-Carbonization Unit (A.4.10) Under Pressure, General Form, Biomass (A.2.2) and (A.2.1), for the production on the one hand of Clean Volatile Biomass (009) freed up to almost 100% of their Harmful Components (A.10.1) for Boilers (012) of Steam Electric Units (A.5.1) and for Gas Turbines (A.6.1A) of Single or Combined Cycle Power Generation Units (A.6.1') or (A.6.1) in Power Generation Systems (A.E.i), where the clean Biomass Volatiles (009) are indicatively intended for Power Generation with Negative Carbon Dioxide Emissions and on the other hand for the simultaneous production of Pyrolytic Activated Carbon (008A) and (008B), which is the sequestration of atmospheric Carbon Dioxide which is promoted for use indicatively as a Soil Improver in Agriculture, where it more than doubles agricultural production, - Where the Pyrolysis-Carbonization Unit (A.4.10) is characterized by the fact that, in cooperation with the Carbon Dioxide Emissions (A.E.i) Power Generation Systems, it provides Technically and Economically Viable Solutions to the main Problems related to Energy Production through Negative Carbon Dioxide Emissions, in the Degradation of the Environment and in dealing with the Risk of Climate Change, which the current state of the art cannot solve, where the Pyrolysis-Carbonation Unit (A.4.10) is characterized, among other things, by the fact that: - Produces Biomass Pyrolytic Volatiles (009) free from almost 100% of their Harmful Components (A.10.1) for the Boilers (012) of the Steam Electric Units (A.5.1) and for the Gas Turbines (A.6.1A) of the Power Generation Units Single or Combined Cycle (A.6.1') or (A.6.1) in Power Generation Systems (A.E.i), where i= 1 to 5 characterizes the respective versions of the Power Generation Systems as described in Claims 6-10 below, - Where the collaborating Power Generation Systems (A.E.i) not only do not emit Carbon Dioxide but instead operate with sequestration of up to twice as much Atmospheric Carbon Dioxide or with Negative Carbon Dioxide Emissions, Saves more than 5000GW of Fossil Fuel Power Plants from obsolescence and premature decommissioning, which with a small modification are converted into cooperating CO2 Negative Emission Units (A.E.i), - Also from the fact that it simultaneously produces Pyrolytic Activated Carbon (008A) and (008B), which is characterized by the fact that on the one hand it constitutes the Negative Emissions of Carbon Dioxide and on the other hand it constitutes the filter that retains all the harmful components (A.10.1) of of Volatile Biomass (009) and makes them suitable for Boilers (012) and Gas Turbines (A.6.1A), - Also since Pyrolytic Activated Carbon (008A) and (008B) is sold at a profit as a permanent Soil Improver that more than doubles agricultural production, where it remains unchanged in the soil for hundreds or even thousands of years and increases agricultural production in perpetuity, - Also from the fact that in collaboration with the C02 Negative Emissions Units and the Carbon Dioxide Negative Emissions Power Generation Systems (A.E.i), it ensures the Coverage of the Load Curve as well as the 90-Day Strategic Reserve during periods of Extreme Weather or other crises, - Also from the fact that it reduces the risk of Fires by cleaning the Forests from the Residual Fine Biomass (A.2.1) which it transforms together with the Woody Biomass (A.2.2) of Dry or Burnt Trees into Pure Volatile Biomass and Pyrolytic Activated Carbon ( 008A) and (008B), - Also by enabling C02 Negative Emissions Units with Carbon Dioxide Emissions Negative Power Generation Systems (A.E.I), to produce Virtual Methanation of Volatile Biomass (009) to Green CNG (010E) for Cars, the combustion of which produces Negative Carbon Dioxide Emissions, - Also by enabling the C02 Negative Emissions Units with the Carbon Dioxide Emissions Negative Power Generation Systems (A.E.i), to produce Virtual Green Biofuels (010H), (010Z) and (010M) for Shipping , Air Transport and other Means of Transport, - Also from the fact that it ensures the survival of Natural Gas and some of the Petroleum Products as Green CNG (010E) and Green Biofuels (010H), (010Z) and (010M) with Negative CO2 Emissions, and beyond 2050, where based on UN COP21 had to be zeroed out, - Also from the fact that the CO2 Negative Emissions Units are characterized by the fact that in the innovative Pyrolysis-Carbonization Unit (A.4.10) the Pyrolysis-Carbonization is carried out under pressure, indicatively 20-40Bar, which is created by the released Biomass Volatiles (009), among others, the following additional innovative advantages arise for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), in addition to what is claimed in summary above, i.e. they are additionally characterized by the fact that - Where the CO2 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonation Units (A.4.10) are characterized by the fact that in the Pyrolysis-Carbonization under a pressure of 20-40 atmospheres, the Pyrolysis-Carbonization reaction becomes exothermic, where instead to consume energy in the form of heat, on the contrary it delivers heat to the innovative Pyrolysis-Carbonation Units (A.4.10) and thus improves the overall power generation efficiency, indicatively by 2-4%, in contrast to pyrolysis with the current state of the art where it is consumed significant amount of energy for the pyrolysis process with a corresponding deterioration of the degree of efficiency of the corresponding power generation, - Where the CO2 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonization Units (A.4.10) are also characterized by the fact that because the Dry Biomass Pyrolysis-Carbonization is carried out under pressure, indicatively 20-40Bar, which is generated by the released Biomass Volatiles , the Thermal Power of the Pyrolysis-Carbonization Units is multiplied, so on the one hand the Thermal Power of the Unit increases and on the other hand the necessary pyrolysis time decreases, - Where the CO2 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonation Units (A.4.10) are also characterized by the fact that due to the pyrolysis under pressure, of the order of 20-40Bar, the production of high quality Pyrolytic Activated Carbon (008A ) and (008B) in a quantity up to and above 50% in relation to the corresponding pyrolysis production under atmospheric pressure, i.e. the production of Pyrolytic Activated Carbon (008A) and (008B) reaches indicatively up to and above 40% of the weight of the Dry Biomass (A.2.2A) and (A.2.1A) from which it comes, compared to 20-27% of the weight of Dry Biomass for pyrolysis under atmospheric pressure with the present state of the art, - Where the CO2 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonation Units (A.4.10) are also characterized by the fact that the Biomass Volatiles produced (009) come into prolonged and pressurized contact with the Pyrolytic Activated Carbon produced (008A) and (008B), in which case nearly 100% of the Volatile Biomass produced (009) is cleaned of its Harmful Components (A.10.1) (i.e. from Potassium, Sodium, Chlorine, Nitrogen, Sulfur, etc.) and allow thus the safe use of Purified Volatile Biomass (009) for Electricity Generation, in contrast to pyrolysis with the current state of the art under atmospheric pressure, where the purification of Volatile Biomass (009) from its Harmful Components (A.10.1) is incomplete and make them unsuitable for combustion in the Boilers (012) of the Steam Electric Units or in the Gas Turbines (A.6.1A) of the Combined Cycle Units (A.6.1), - Where the CO2 Negative Emissions Units with the innovative Pressurized Pyrolysis-Carbonization Units (A.4.10) are also characterized by the fact that in many applications and types of Biomass this First Passage of Volatile Biomass (009) through the mass of Pyrolytic Activated Carbon (008A) and (008B) and under the applied overpressure, it is sufficient for a very satisfactory purification of the Volatile Biomass (009), for the protection of the Boiler (012) or the Gas Turbine (A.6.1A) of the respective Power Generation Units, so that the Pure and Mixed Combustion of Volatile Biomass (009) in the Boilers or in the Gas Turbines of the Modified CO2 Negative Emissions Power Generation Units is completely safe, - Where the Combined Cycle CO2 Negative Emissions Units with the innovative Pressurized Coking-Carbonization Units (A.4.10), which feed Biomass Volatiles to the Power Generation Gas Turbine, are also characterized by the Biomass Volatile Compressor (A.6.1H) is abolished , with a corresponding improvement in the degree of efficiency, in contrast to pyrolysis with the current state of the art under atmospheric pressure, where Volatile Biomass even when cleaned of their Harmful Components (A.10.1), need the Compressor (A.6.1H) for the compression to a pressure above 20Bar to enter the Combustion Chamber of the Gas Turbine (A.6.1A), resulting in a deterioration of the degree of efficiency, - Where the Combined Cycle CO2 Negative Emissions Units with the innovative Pressurized Coking-Carbonization Units (A.4.10) and the cooperation with the CO2 Negative Emissions Unit Power Generation Gas Turbine, are also characterized by the removal of the Post-Combustion Chamber (A.6.1E ), which is necessary when Pyrolysis-Carbonization takes place under atmospheric pressure, otherwise as analyzed in the Power Generation System (A.E.3) below, Where the innovative Pyrolysis-Carbonization Unit (A.4.10) of General Form is characterized by the fact that it consists indicatively of the following three collaborating Components, namely: - The Drying-Preheating Subunit (A.4.1OA), consisting of the Pairs of Drying-Preheating Chambers and Subchambers (001АОA)-(002АОA), - The Pyrolysis-Carbonization Subunit (A.4.1O), consisting of the Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001AO) - (002AO), - The Cooling-Heat Exchange Subunit (A.4.10B), consisting of the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001AOB)-(002AOB), as described below, The Drying-Preheating Subunit (A.4.1OA), Which is characterized by the fact that it consists of the pairs of Chambers and Subchambers Drying-Preheating (001АОA)-(002АOA) of Biomass (A.2.2) and (A.2.1), with fixed or rotating cylindrical Drying-Preheating Chambers and Subchambers, horizontal, inclined or vertical or of another form, respectively, Where the Drying-Preheating Subunit (A.4.1OA) is characterized by the fact that it consists of the Pairs of Drying-Preheating Chambers and Subchambers (001АOA) -(002AOA), which are fed with the Biomass of the Initial Semi-Outdoor Pre-Drying (A.2.0) through of the Loading-Unloading System (A.7.1), through the Double Isolation Valves (039A), where after Drying-Preheating they supply the Dry and Preheated Biomass (A.2.2A) and (A.2.1A) to the Pyrolysis Subunit- Carbonization (A.4.10), which consists of the Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001ΑO) - (002ΑO) through the Double Isolation Valves (040A)-(039), where after the Pyrolysis-Carbonization it feeds with the produced Pyrolytic Activated Carbon (008A) and (008B) the Cooling-Heat Exchange Subunit (A.4.10B), which consists of the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АОБ) - (002AOB) through the Double Isolation Flaps ( 040)-(039B) and where from the Cooling-Heat Exchange Subunit modality (A.4.1OB), after the Cooling of the Pyrolytic Activated Carbon (008A) and (008B) through the Heat Exchange with the Preheating of the Feed Water (012A) of the Boiler (012) of the Steam Unit (A.5.1) or Boiler (012B) of the Combined Cycle Unit (A.6.1), the Pyrolytic Activated Carbon (008a) and (008B) exits through the Double Isolation Valves (040B) and is promoted for preparation as a Soil Improver, Where the Drying-Preheating Subunit (A.4.1OA) is characterized by the fact that it consists of the Pairs of Drying-Preheating Chambers and Subchambers (001АOA)-(002АОA), and then as in Claim 6 it is part of the Drying-Preheating Subsystem (A .E.1.3O), which is characterized by the fact that it is a component of the Power Generation Systems (A.E.i), where i = 1 to 5 is the Emissions Index of the Power Generation Units with Negative Carbon Dioxide Emissions, which are realized through the clean Volatile Biomass (009) which are produced by the innovative Pyrolysis Unit (A.4.10) of General Form, of which the Drying-Preheating Subunit (A.4.1OA) is a part, Where the Drying-Preheating Subunit (A.4.1OA) is characterized by having a Second Stage Drying (A.3.1) with the available Hot Exhaust Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012 ) of the cooperating Steam Electric Unit (A.5.1) or from the entrance of the Chimney (A.1.5) of the Boiler (012B) of the cooperating Combined Cycle Unit (A.6.1), which remove the last 20% of the moisture and perform corresponding preheating of Dry Biomass (A.2.2A) and (A.2.1A), where there is a significant overall improvement of the degree of efficiency of the corresponding Power Generation System (A.E.i) on average indicatively more than 10%, in contrast to the degree of efficiency of the power generation through conventional pyrolysis of carbonization, which is smaller than the Power Generation System (P.E.i), In contrast to the current state of the art, where on the one hand the Heat of the Hot Exhaust Gases (A.1.4) is either discarded unused through the Chimneys (A.1.5) into the environment or expelled through cooling in the Water Washers in the Desulphurization Systems, which are eliminated in the cooperating Power Generation Systems (A.E.i), because the Sulfur Compounds are completely retained by the Pyrolytic Activated Carbon Filter (008A) and (008B), And where, on the other hand, with the current state of the art, useful heat is consumed by burning part or all of the Fine Biomass (A.2.1) or part of the Woody Biomass (A.2.2) to evaporate the moisture content resulting in a poor degree of efficiency, where the Fine Biomass Biomass (A.2.1) even when pelletized, is not intended for drying and pyrolysis-carbonization for the production of Fine-grained Pyrolytic Activated Carbon (008B), but only for combustion and heat production, as above, It is otherwise characterized by the fact that it participates in the collaborating Power Generation Systems (A.E.i) of the CO2 Negative Emission Units, as above, - The Pyrolysis-Carbonization Subunits (A.4.1O) and Cooling-Heat Exchange (A.4.1OB), Where the Pyrolysis-Carbonization Subunit (A.4.1O) is characterized by the fact that it consists of Pairs of Pyrolysis Chambers and Subchambers- Carbonization (001Ao) - (002Ao) and the Cooling-Heat Exchange Subunit (A.4.1OB) is characterized by the fact that it consists of the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001AOB)-(002AoB) respectively, then both are characterized by the fact that they constitute the Pyrolysis-Coalization Subsystem (A.E.1.4O), which is characterized by the fact that it is a constituent element of the Power Generation Systems (A.E.i), where i = 1 to 5 is the Index of Power Generation Units with Negative Carbon Dioxide Emissions, and where the Pyrolysis-Carbonization (A.4.1O) and Cooling-Heat Exchange (A.4.1OB) Subunits respectively are characterized by being composed of the following, namely: Where the Pyrolysis-Carbonization (A.4.1O) and Cooling-Heat Exchange (Α.4.1OB) Subunits respectively, are characterized by being composed of Pairs of fixed or rotating Pyrolysis-Carbonization Chambers and Subchambers (001АО)-(002АО) and Cooling -Heat Exchange (001AOB)-(002AOB) respectively, with an indicative cylindrical, horizontal or inclined or vertical or other form, where the Pyrolysis-Carbonization of Biomass (A.2.2A) and (A.2.1A) takes place and the Cooling-Heat Exchange of Pyrolytic Activated Carbon (008A) and (008B), respectively, Where the Pyrolysis-Carbonation process inside the Subchambers (002Ao) is carried out under Pressure, indicatively 20-40Bar, while all the remaining Chambers (001Ao), (001AOB) and the Subchamber (002AOB) operate under atmospheric pressure in the Single Pass Pyrolysis-Carbonization process Purification of Volatile Biomass (009), while in the process of multiple Purification of Volatile Biomass (009), then the Cooling-Heat Exchange Subchambers (002AOB) also operate under the same pressure as the Subchambers (002Ao), indicatively 20-40Bar, where clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B) were produced, Where the Cooling-Heat Exchange Subunit (A.4.1OB) is characterized in that the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АOB)-(002АOB) of the Pyrolytic Activated Carbon (008A) and (008B), cool the superheated Pyrolytic Activated Coal (008A) and (008B) exchanging heat and preheating the Feed Water (012A) of the Boiler (012) or the Exhaust Gas Boiler (012B), thus further improving the degree of efficiency of the cooperating Power Generation System, Where the Pyrolysis-Carbonization Subunit (A.4.1O) is characterized by the fact that Biomass Pyrolysis-Carbonization is carried out under Pressure, indicatively 20-40Bar, inside the Pyrolysis-Carbonization Chambers and Subchambers (001AO)-(002AO) respectively, where it is carried out not only without the consumption of thermal energy, but on the contrary it is carried out with the production of thermal energy, so it also increases the degree of efficiency of the cooperating Power Generation System, as well as it is carried out with the production of very important advantages both for the entire Biomass Pyrolysis-Carbonization process (A.2.2 ) and (A.2.1), as well as for the Power Generation System (A.E.i), as detailed above in this Claim 1, In contrast to the current state of the art where the pyrolysis is carried out under atmospheric pressure, with the consumption of external thermal energy, in which case it also worsens the degree of efficiency of the cooperating Power Generation System, and does not present the significant advantages of Pyrolysis-Carbonization Under Pressure, For the rest, they are characterized by the fact that they participate in the cooperating Power Generation Systems (A.E.I) of the Units with Negative CO2 Emissions, as above, Where the Pyrolysis-Carbonization Unit (A.4.10) is also characterized by the fact that the Chambers and Subchambers as above are equipped with a Biomass One Pass System (A.2.2) and (A.2.1) through the Drying-Preheating Chambers and Subchambers , Pyrolysis-Carbonization and Cooling-Heat Exchange (001АOA)-(002АOA), (001АО)-(002АО) and (001АОБ)-(002АОБ) respectively or corresponding Transit with Retention of Biomass (A.2.2) and (A. 2.1) inside the Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange Chambers and Subchambers (001АOA)-(002АOA), (001AO)-(002AO) and (001АОБ)-(002АОБ) respectively for a longer period of time, statically or and with back-and-forth stirring indicatively through suitable Filling Screw Systems, Back-Back Stirring and Discharge as well as corresponding Isolation Valves, Where the Pyrolysis-Carbonation Unit (A.4.10) is also characterized by the fact that the Chambers and Subchambers as above are equipped with an appropriate System of Filling, Agitation Forward-Backward and Evacuation of Biomass and Pyrolytic Activated Carbon indicatively through an Internal System through Screws or Propellers Dual-Directional (041O) or (041'O), where alternatively the continuous one-way promotion function is provided from the filling of the Biomass (A.2.2) and (A.2.1) to the discharge of the Pyrolytic Activated Carbon (008A) and ( 008B), if the type and requirements of the processed Biomass allow it, otherwise as in the Pyrolysis Subunit (A.4.1AA) above Where the innovative Pyrolysis-Carbonation Unit (A.4.10) of General Form is also characterized by the fact that it has Electrostatic Filters (012E) or Bag Filters (012Z), for the retention of Microparticles from the cooling of the Pyrolytic Activated Carbon (008A) and (008B) in System of Cooling-Heat Exchange Chambers and Subchambers (001AOB)-(002AOB) of Pyrolytic Activated Carbon (008A) and (008B) or the Electrostatic Filters (012'E) or Bag Filters (012'Z) for the retention of Microparticles from Drying and Preheating of Biomass (A.2.2A) and (A.2.1A) in the System of Drying-Preheating Chambers and Subchambers (001ΑOA) and (002ΑOA) above, 2. One Pyrolysis-Carbonization Unit (A.4.1A) of Biomass, Under Pressure, One Pass, Next, a Pyrolysis-Carbonization Unit (A.4.1A), like the Pyrolysis-Carbonization Unit (A.4.10) in Claim 1, which is however characterized by the fact that it consists and functions as follows, that is, by producing pure Biomass Volatiles on the one hand (009), which are intended indicatively for Electricity Generation Without Carbon Dioxide Emissions and on the one hand Pyrolytic Activated Carbon (008A) and (008B), which constitutes the sequestration of Atmospheric Carbon Dioxide and is promoted for use indicatively as a Soil Improver in Agriculture, Which is characterized by the fact that, in collaboration with Carbon Dioxide Emissions Power Generation Systems (A.E.I), it provides Technically and Economically Sustainable Solutions to the main problems related to Energy Production with Negative Carbon Dioxide Emissions, the Degradation of Environment and dealing with the Risk of Climate Change, which the current state of the art cannot solve, such as sustainable solutions and advantages, which are claimed in detail in Claim 1 above, Where the innovative Pyrolysis-Carbonation Unit (A.4.1A) is characterized by the fact that it consists of the following three collaborating Components, namely: - The Drying-Preheating Subunit (A.4.1AA), which consists of the Pairs of Chambers and Subchambers Drying-Preheating (001АAA) and (002АAA), - The Pyrolysis-Carbonization Subunit (A.4.1A), consisting of the Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001АА) and (002АА) - The Cooling-Heat Exchange Subunit (A.4.1AB), consisting of the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АAB)-(002АAB), as described below, - The Drying-Preheating Subunit (A.4.1AA), which is characterized by the fact that it consists of the Pairs of Drying-Preheating Chambers and Subchambers (001АAA) and (002АAA), then as part of the Drying-Preheating Subsystem (A. E.1.3A), which is characterized by the fact that it is a constituent element of the Power Generation Systems (P.E.I) of the CO2 Negative Emission Units, where i = 1 to 5 is the Emission Index of the Power Generation Units with Negative CO2 Emissions Coal, which are realized through the clean Volatile Biomass (009) produced by the innovative Pyrolysis Unit (A.4.1A), of which the Drying-Preheating Subunit (A.4.1AA) is a part, Where the Drying-Preheating Subunit (A.4.1AA) is characterized by having a Second Stage Drying (A.3.1) with the available Hot Exhaust Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012 ) of the cooperating Steam Unit (A.5.1) or from the entrance of the Chimney (A.1.5) of the Boiler (012B) as above in Claim 1, Where the Drying-Preheating Subunit (A.4.1AA) is characterized by the fact that it consists of the pairs of Drying-Preheating Chambers and Subchambers (001АAA) and (002АAA) respectively, Biomass (A.2.2) and (A.2.1), The Inlet-Outlet Flaps (039A) and (040A) of the Biomass and the Inlet-Outlet Flaps (034) and (034') of the Exhaust Gases (A.1.4), the Reducer-Motor-lnverter System (041Z), the Screw Bidirectional (041A), the Shell (041k) of the Chamber (001AA), The Loading Arms (035A) of Biomass (A.2.2) and (A.2.1) and the Unloading Arms (036A) of Dry and Preheated Biomass (A.2.2A) and (A.2.1A), the Loading-Unloading System (A.7.1), the Collector-Silo (003AA) Loading with Biomass (A.2.2) and (A.2.1), the Central Biomass Silo (004A), the Feed Belt (037), the Dry and Preheated Biomass (A .2.2A) and (A.2.1A), the Subsystem (A.E.1.4A), The Twin-Directional Screw System (041A), the Shaft (0410), the Bearings (041M), the Support Beams (041A), the Cylindrical Subchamber (002AA), the Gear-Motor-lnverter System (041Z), the Shell (041k), The Inlet-Outlet Flaps (034) and (034'), the Air Ducts (022), the Depression Fan (023), the hot Exhaust Gases (A.1.4), the Chimney (A.1.5), the Cooling Tower (018a) , The Electrostatic Filters (012'E) or Bag Filters (012'g), the Subsystems (A.E.1.1A) and (A.E.1.2A), the cooperating Power Generation System (A.E.i), the Physics Drying of the Biomass (A.2.0), the Semi-Outdoor Storage Subsystem (A.1.2), the Subsystem (A.E.1.1A), the Chimneys (A.1.5) of the Boiler (012) of the Units (A.5.1) or the Chimneys (A.1.5) of the Exhaust Boiler (012B), The improvement of the overall degree of efficiency of the cooperating Power Generation System (A.E.i), depending on the moisture content of the corresponding Biomass (A.2.0), In contrast to the current state of the art, where on the one hand the Heat of the Hot Exhaust Gases (A.1.4) is either discarded unused through the Chimneys (A.1.5) into the environment or expelled through cooling in the Water Washers in the Desulphurization Systems, which are eliminated in the cooperating Power Generation Systems (A.E.I), because the Sulfur Compounds are completely retained by the Pyrolytic Activated Carbon Filter (008A) and (008B), as above, And on the other hand, useful heat is consumed by burning part or all of the Fine Biomass (A.2.1) or even part of the Woody Biomass (A.2.2) to evaporate the contained moisture resulting in a poor degree of efficiency, where the Fine Biomass (A.2.1) still and when pelletized, is not intended for drying and pyrolysis carbonization to produce Fine Grain Activated Carbon (008B), but only for combustion and heat generation, as above, Where alternatively the Drying-Preheating Subunit (A.4.1AA) is characterized by the fact that the Pairs of Drying-Preheating Chambers and Subchambers (001АAA) and (002ААAA) can be manufactured in the same form and dimensions as the Pairs of Pyrolysis-Carbonation Chambers and Subchambers ( 001АА) and (002АА) and with the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АAB) and (002АAB), for reasons of uniformity in their production and in the availability of Spare Parts, otherwise it is characterized by participating in the cooperating Power Generation System (A.E.1) of the CO2 Negative Emission Units, as described in Claim 6 "Power Generation System (A.E.1) as a Unit Combination (A.5.1) with Pyrolysis-Carbonization Unit (A.4.1A) Under 20-40Bar Pressure, One Purification Diode", - The Pyrolysis-Carbonization (A.4.1A) and Cooling-Heat Exchange (А.4.1AB) Sub-Units, which are characterized by the fact that each (A.4.1A) consists of Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001АА ) and (002АА) or (А.4.1AB) from the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АAB) and (002АAB) respectively, then the Pyrolysis-Carbonation Subsystem (A.E.1.4A), which characterized by the fact that it is a constituent element of the Power Generation Systems (A.E.i), where i = 1 to 5 is the Emissions Index of the Power Generation Units with Negative Carbon Dioxide Emissions, where the Subunits (A.4.1A) and ( A.4.1AB) are characterized by the fact that they consist of the following, namely: The clean Biomass Volatiles (009), the Pairs of Pyrolysis-Carbonization Chambers and Subchambers (001АА) and (002АА) and the Pairs of Cooling-Heat Exchange Chambers and Subchambers (001АAB) and (002АAB) of Pyrolytic Activated Carbon (008A) and (008Б) ), Where the Pyrolysis-Carbonization process inside the Subchambers (002АА) is done under Pressure, indicatively 20-40Bar, while all OL remaining Chambers (001АА) and (001АAB) and the Subchamber (002АAB) operate under atmospheric pressure in the Single Pass Pyrolysis-Carbonization process Purification of Volatile Biomass (009), while in the process of multiple Purification of Volatile Biomass (009), then the Cooling-Heat Exchange Subchambers (002АAB) also operate under the same pressure as the Subchambers (002АA), indicatively 20-40Bar, The Pyrolytic Activated Carbon (008A) and (008B) and the additional advantages for the Power Generation System (A.E.I), as claimed above in Claim 1, The Pyrolysis-Carbonization (A.4.1A) and Cooling-Heat Exchange Subunits (A.4.1AB), the Pyrolysis-Carbonization Chamber (001АА), the Cooling-Heat Exchange Chamber (001АAB), the inner lining of Firebricks (001B) , the external Insulation (001E), the high temperature resistant alloy steel sheet, indicative of Superalloy Ni, Cr, in percentages of 12-20%, for operating temperatures of 650-900°C, the Fe, Ni alloy steel sheet, Cr for operating temperatures of 650-900°C but for atmospheric pressure, Volatile Biomass (009), Harmful Components (A.10.1), Purification Diode of Volatile Biomass (009) from their Harmful Components (A.10.1), The bundle of 7 parallel Pyrolysis-Carbonization Subchambers (002АА), the 7 Unloading Arms (036) of the Pyrolysis-Carbonization Subchambers (002АА), which are grouped in the Outlet Manifold (003А), the Inlet Manifold (003AB), the Pyrolysis-Carbonization Subchambers (002АА) and Cooling-Heat Exchange (002АAB), The Recirculation Air Ducts (010), the Superheated Exhaust Gases (014) from the Stove (016) of the Boiler (012), the Dry and Preheated Biomass (A.2.2A) and (A.2.1A), the Aviation Air Ducts (015) , the Volatile Outlet Collector (015E), the spare inlet for the recirculation of Double Cleaning from Harmful Components (A.10.1) of the produced Biomass Volatiles (009) through the Volatile Inlet Collector (015'E), the Volatile Recirculation Ducts (015A) , the Manifolds (015E) and (015'E), the Pilot Valves (017) and (017A) respectively, The Pilot Valves Outlet (017) and Inlet and (017A) respectively, the Shafts (015B), the Speed Reducer-Engine-lnverter System Pilots (015Z), the Shell (041'K) of the Subchamber (002A), The Volatile Exhaust Manifold (015E), the Volatile Exhaust Pipe (015'), the Four-Way Valve (015X), the Hearth (016) of the Boiler (012), the Combustion Chamber (A.6.1B) of the Gas Turbine (A.6.1 A), the Volatile Inlet Manifold (015AE) of the Backup Subchambers (002АB), into which are grouped the Volatile Inlet Piping (015A), the Volatile Outlet Manifold (015'E), the Volatile Outlet Pipe (015"), The Pressure Fan (028), the Suction Fan (029), the Preheating Air Duct (018), the Suction Fans (030), the Isolation Flaps (021), the Preheating Air (019), the Feed Water (012A) of the Boiler (012) of the Steam Electric Unit (A.5.1) or the Boiler (012B) of the Combined Cycle Unit (A.6.1), The Double Direction Screw System (041A), the Reducer-Motor-Inverter System (041z), the Drive Chain (041H), The Inlet Collectors (003A) and (003AB) or Outlet (003A<'>) and (003A'B) respectively, of each Subchamber (002AA) or (002AAB), as above, The Loading - Unloading System (A.7.1), the Biomass Supply Belts (037) to the Biomass Inlet Collector-Silo (003АА) and the Pyrolytic Activated Carbon Discharge Belts (008A)+ (008B) from the Outlet Collector-Silo (003АБ) ), the Double Flaps -Intake (039B) and Exhaust (040B) The Electrostatic Filters (012E) or Bag Filters (012Z), the Air Duct (015") for the supply of Volatile Biomass (009) for combustion in the Hearth (016) of the Boiler (012), or in the Combustion Chamber (A.6.1E) of the Gas Turbine (A.6.1A), Microparticles (008'A) and (008'B) of Pyrolytic Activated Carbon (008A) and (008B), 3. One Pyrolysis-Carbonization Unit (A.4.1E) of Biomass, Under Pressure, One Pass, then a Pyrolysis-Carbonization Unit (A.4.1E), which is manufactured like the Pyrolysis-Carbonization Unit (A.4.1A) in Claim 2, but is characterized by the fact that instead of Fixed Chambers (001АAA), (001АА) and ( 001АAB) and Fixed Chambers (002АAA), (002АA) and (002АAB), consists of Fixed Chambers (001АEA), (001АЕ) and (001АEB) and Rotating Chambers (002АEA), (002АE) and (002АEB), with Internal System Filling, Back-Back Stirring and Evacuation of Biomass and Pyrolytic Activated Carbon through the Dual Direction Internal Helical Coil (041'A), which is welded to the inner surface of each Subchamber (002AEA), (002AE) and (002AEB), The Internal Speed Reducers (045'), the corresponding Toothed Rings of Rotation (043'), the Rolling Bearings (041') of rotation of the Rotating Subchambers, The Speed Reducer-Motor-lnverter Systems (042'), the Shell (041k) of each Chamber (001AEA), (001AE) and (001AEB), the Shell (041'k), the seven-fold Subchambers (002AEEA), (002AEA ) and (002AEB), the Drive Chain (041'H), the Toothed Rings of Rotation (043'), the Speed Reducer-Engine Inverter System (042"), The Loading Arms (035') and Unloading (036') of Biomass (A.2.2A) and (A.2.1A) and Pyrolytic Activated Carbon (008A) and (008B), the Double Inlet Flaps (039') and Extraction (040'), the Sealing Rings of the Inlet-Outlet Rotation (047' and (048'), the front and rear ends of each Rotation Cylinder (044') of the Rotating Subchambers (002AEA), (002AE) and (002AEB ), the Inlet-Outlet Sealing Rings (047') and (048'), The Dual Directional End Screws (041E), the end fixed sections of the Subchambers (002AEA), (002AE) and (002AEB) and the continuous one-way propulsion function from the Biomass filling (A.2.2) and (A.2.1) to the discharge of Pyrolytic Activated Carbon (008A) and (008B), Otherwise as in Claim 1 and 2 above, 4. A Pyrolysis-Carbonization Unit (A.4.1H) = (A.4.1HA) or (A.4.1HE) of Biomass, Under Pressure, One Pass, Integration into a Composite Pair of Pyrolysis-Carbonization Chambers and Subchambers, then a Pyrolysis-Carbonization Unit (A.4.1H), which is characterized by the fact that it consists of an innovative Pyrolysis-Carbonization Unit (A.4.1H) like the Pyrolysis-Carbonization Units (A.4.1A) and (A.4.1 E) above, which is characterized by the fact that instead of three separate pairs of Chambers and Subchambers (001AAA) - (002AAA), (001AA) - (002AA) and (001AAB) - (002AAB) or (001AEA) - (002AEA) , (001AE) -(002Ae) and (001Aev) - (002AEB), Drying-Preheating, Pyrolysis-Carbonization and Cooling-Heat Exchange respectively, the merging of the respective three separate pairs of Chambers and Subchambers as above into a Composite is also implemented alternatively Pair of Chambers and Subchambers (001AA) - (002AA) or (001AE) -(002AE), which is characterized by gathering on it all the Air Ducts that belonged to each pair of Chambers and Subchambers as above as well as the Biomass Inlet-Outlet (A.2.2) and (A.2.1) and the produced Pyrolytic Activated Carbon (008A) and (008B) respectively, Where the Complex Pair of Chambers and Subchambers (001AA) - (002AA) or (001AE) - (002AE) that results is characterized by the fact that it begins its operation as a pair of Chambers and Subchambers (001AAAA) - (002AAAA) or (001AEEA) - ( 002AEEA) Biomass Drying-Preheating (A.2.2) and (A.2.1) with activation of the Drying-Preheating Air Duct (022) as well as the Biomass Loading System (A.2.2) and (A.2.1) as above and then after the end of the Drying-Preheating process by alternating the Drying-Preheating Air Duct (022) with the Pyrolysis-Carbonization Air Ducts (010) and (015)-(015A) it turns into a pair of Chambers and Subchambers (001AAA) - (002AAA) or (001AEe) - (002AEE) Pyrolysis-Carbonization and then after the end of the Pyrolysis-Carbonization process by switching the Pyrolysis-Carbonization Ducts (010) and (015)-(015A) to the Cooling-Heat Exchange Duct (019) becomes a pair of Chambers and Subchambers (001АААБ) - (002АААБ) or (001ААЕБ) - (00 2AEEB) Cooling-Heat Exchange of the produced Pyrolytic Activated Carbon (008A) and (008B) with eventual activation of the Unloading Subsystem of the produced Pyrolytic Activated Carbon (008A) and (008B), Otherwise as in Claims 1, 2 and 3 above, 5. A Pyrolysis-Carbonization Unit (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) of Biomass, Under Atmospheric Pressure, Multiple Purification Passages of Volatile Biomass, then Pyrolysis Unit (A.4.1'0) or (A.4.1'A) or (A.4.1E) or (A.4.1H), which is characterized by the fact that it consists of an innovative Pyrolysis Unit (A.4.1 '0) or (A.4.1A) or (A.4.1E) or (A.4.1H) such as the Pyrolysis Unit (A.4.1Θ) or (A.4.1A) or (A.4.1E) or ( A.4.1H), above, which is characterized by the fact that it consists of Fixed or Rotating Chambers and Subchambers, which operate with Atmospheric Pressure, And where the Pyrolysis Units (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) are additionally characterized by the fact that due to possible incomplete cleaning of the Volatile Biomass (009) from the Their Harmful Components (A.10.1) in First Diode, have the possibility to submit the produced Biomass Volatiles (009) to Double, Triple or Multiple Diode through respective Spare Pairs of Chambers and Subchambers with Pyrolytic Activated Carbon (008A) and (008B) , until the purification of the Volatile Biomass (009) reaches the desired purity level, which is safe for the operation of the Boiler (012) or the Gas Turbine (A.6.1A) respectively, otherwise as in the Pyrolysis Units (A .4.1I) or (A.4.1A) or (A.4.1E) or (A.4.1H) above, Otherwise as in the Pyrolysis Units (A.4.1Θ) or (A.4.1A) or (A.4.1E) or (A.4.1H) in Claims 1, 2, 3 and 4 above, 6. A Power Generation System (A.E.1) as a Unit Combination (A.5.1) with a Pyrolysis Unit (A.4.1A) under 20-40Bar Pressure of a Cleaning Diode, then Power Generation System (A.E.1), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.1.1A) Biomass Storage and Pre-Drying (A.2.0), (A.E. 1.2A) Preparation and First Drying of Biomass (A.2.0), (A.E.1.3A) Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E.1.4A) Pyrolysis- Carbonization of Biomass under 20-40Bar Pressure, (A.E.1.5A) of the Steam Power Plant (A.5.1) and (A.E.1.7A) Transport and Storage of the produced Pyrolytic Activated Carbon (008A) and (008B) , which are characterized by the fact that they each consist of the following Components, namely: - The Biomass Storage and Pre-Drying Subsystem (A.E.1.1A) (A.2.0), which is characterized by having the Biomass (A.2.0), the Covered Semi-Outdoor Space (A.1.3) with a Transparent Roof ( A.1.3A), the First Semi-Outdoor Drying (A.1.2), in which case its humidity is reduced indicatively from 40-50% to 30-35%, in contrast to the current state of the art, where no such Semi-Outdoor Drying with a corresponding deterioration in the degree of performance, - The Subsystem (A.E.1.2A) Preparation and First Drying of Biomass (A.2.0), which is characterized by having the First Drying System (A.2.4), the Milling System (A.2.8), the Pelletizing System (A.2.9), Woody Biomass (A.2.2), Pelletized Fine Biomass (A.2.1), Biomass (A.2.0), Biomass Silos (A.2.3), Second Drying System (A .3.1) in the Subsystem (A.E.1.3A), the Drying Tunnel (A.2.7), the Drying Wagons (A.2.5), the Biomass (A.2.2) and (A.2.1), the Conveyor Belt ( A.2.6) or the Railway Tracks (A.2.6A), the Hot Exhaust Gases (A.1.4), the Chimney (A.1.5) of the Boiler (012) of the Steam Power Unit (A.5.1) or the Chimney (A. 1.5) of the Exhaust Gas Boiler (012B) of the Combined Cycle Unit (A.6.1), The Air Duct (032), the Exhaust Gases (A.1.4) of the Chimney (A.1.5) of the Power Plant (A.5.1), for the First Drying (A.2.4) of the Biomass (A.2.2) and (A.2.1 ), the Depression Fan (033), the Cooling Tower (A.1.8A), the reduction of the Biomass moisture (A.2.2) and (A.2.1) below 30-35%, as a preparation for the Second Drying System (A.3.1), which takes place in Subsystem (A.E.1.3A), Biomass (A.2.2) and (A.2.1), the First Drying System (A.2.4), Milling-Pelletization and Storage in Biomass Silos (A.2.3), the Second Drying Stage (A.3.1) in Chambers (001AAA) and Subchambers (002AAA) of the Biomass Drying and Preheating Subsystem (A.E.1.3A) (A.2.2) and (A.2.1), the Subsystems of the Biomass Feeding Belts (037) of the Collector-Silo (003AA) ) and the Loading Arms (035A) as well as the Double Inlet Flaps (039A) of the Loading-Unloading Systems (A.7.1), per pair of Chamber (001AAA) and Subchamber (002AAA), with full automation of the internal continuous Biomass loading process (A.2.2) and (A.2.1) in the Subchambers (002AAA) of the Subsystem (A.E.1.3A) respectively, in contrast to our previous Application with OBI Number 20190100159, where the loading of Biomass (A.2.2) and (A.2.1) and its transfer and introduction to the corresponding Subchambers (002) of the System (A.3) is done with the discontinuous process and use of the repeal of Wagons (003), The Biomass Drying - Preheating Subsystem (A.E.1.3A) (A.2.2) and (A.2.1), then Subsystem (A.E.1.3A) or Drying - Preheating Subunit (A.4.1AA), Which is characterized by the Drying in the Second Stage (A.3.1), the Hot Exhaust Gases (A.1.4) from the entrance of the Chimney (A.1.5) of the Boiler (012) of the Steam Unit (A.5.1), the Cooling Tower (A.1.8Aa, the overall improvement of the efficiency of the System (A.E.1) on average indicatively more than 10%, in contrast to the efficiency of electricity generation from conventional pyrolysis-coalization, which is correspondingly lower than Power Generation System (A.E.1), otherwise as described in Claims 1 and 2, Pressurized Biomass One-Pass Pyrolysis-Carbonization Unit (A.4.10) and (A.4.1A), above, The Subsystem (A.E.1.4a) Pyrolysis-Carbonization of Biomass Under Pressure, then Subsystem (A.E.1.4a) or Pyrolysis-Carbonization Subunit (A.4.1AB), which is characterized by the fact that it consists of a Pyrolysis-Carbonization Subunit (A.4.1A), the Ground or Pelletized Dry Woody or Fine-grained Biomass (A.2.2A) and (A.2.1A), the Coal Pyrolysis Chambers (001AA) and Subchambers (002AA) and the Cooling-Heat Exchange Chambers (001AAB) and Subchambers (002AAB), The significant advantages for the entire Biomass Pyrolysis-Carbonization process (A.2.2) and (A.2.1), as described in detail above in Claim 1 and 2 and the Additional Advantages as also in Claim 1 and 2 Pyrolysis-Carbonization Subunit ( A.4.1O) and (A.4.1A) of Biomass Under Pressure, One Pass, Otherwise as in Claims 1 to 4 above, The Subsystem (A.E.1.5A) of the Modified Steam Electric Power Generation Unit (A.5.1), which is characterized by the fact that the Modified Units (A.5.1) will now operate with Pure or Mixed Combustion of Volatile Biomass (009) and Coal (009A), where in a first conversion of the Coal Power Plant into a Power Plant (A. 5.1) in principle for Mixed Combustion, indicatively with 1/3 Coal (009A) and 2/3 Volatile Biomass (009), the cost of conversion of the Coal Steam Electric Power Generation Unit to a Power Generation Unit (A.5.1), while with the produced Pyrolytic Active Carbon (008A) and (008B), ensures net Negative Carbon Dioxide Emissions, while Pure Combustion more than doubles the Negative Carbon Dioxide Emissions, while in Pure Combustion exclusively of Volatile Biomass (009), Carbon Dioxide emissions are zeroed out, increasing Negative Carbon Dioxide Emissions due to the production of Pyrolytic Activated Carbon (008A) and (008B), while at the same time the operation of the Chimney is reduced or completely abolished (A.1.5) of the Steam Power Plant (A.5.1), with the modified Cooling Tower (A.1.8A), where the Desulphurization and Desulfurization Systems, the Coal Mills, the Ash and Gypsum Removal Systems from Desulphurization and the Desulphurization, Denitrification Waste Purification Systems and other waste retained by the Pyrolytic Activated Carbon Filter (008A) and (008B), The Subsystem (A.E.1.7A) for Transport and Storage of Pyrolytic Activated Carbon (008A) and (008B), which is characterized by indicatively promoting it in enrichment and activation units of Pyrolytic Activated Carbon (008A) and (008B) with chemical or organic fertilizers and then promoting it for permanent storage as a Soil Improver in Georgia, in contrast to the current level of the technique, where no negative Carbon Dioxide Emissions are foreseen, Otherwise as in Claims 1, 2, 3, 4 and 5 above, 7. A Power Generation System (A.E.2) as a Unit Combination (A.5.1) with a Pyrolysis Unit (A.4.1E) under 20-40Bar Pressure of a Cleaning Diode, then Power Generation System (A.E.2), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.2.1E) Biomass Storage and Pre-Drying (A.2.0), (A.E. 2.2E) Preparation and First Drying of Biomass (A.2.0), (A.E.2.3E) Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E.2.4E) Pyrolysis- Carbonization of Biomass Under 20-40Bar Pressure, (A.E.2.5E) of the Steam Power Plant (A.5.1) and (A.E.2.7E) Transport and Storage of the produced Pyrolytic Activated Carbon (008A) and (008B) , which are characterized by the fact that they consist of each of the following Components as described below, namely: Where Subsystems (A.E.2.1E), (A.E.2.2E), (A.E.2.5E) and (A.E.2.7E) are characterized by being the same as Subsystems (A.E. E.1.1A), (A.E.1.2A), (A.E.1.5A) and (A.E.1.7Where they are claimed above in the System (A.E.1), The Biomass Drying - Preheating Subsystem (A.E.2.3E) (A.2.2) and (A.2.1), then Subsystem (A.E.2.3E) or Drying - Preheating Subunit (A.4.1EA), which is the same as the Subsystem (A.E.1.3A) above, but characterized by the fact that instead of the pair with Fixed Chambers and Subchambers (001AAA) and (002AAA) respectively, it consists of the pair with Fixed Chambers (001AEA) in conjunction with the Rotating Subchambers (002AEA), otherwise as in the Subsystem (A.E.1.3A) and the Pressurized Pyrolysis-Carbonization Unit (A.4.1E) in Claim 1, 2 and 5 above, The Biomass Pyrolysis-Carbonization Subsystem (A.E.2.4E) under 20-40Bar Pressure, then Subsystem (A.E.2.4E) or Pyrolysis-Carbonization Subunit (A.4.1EB), which is the same as the Subsystem (A.E.1.4A) above, however, is characterized by the fact that instead of the pairs with Fixed Chambers and Subchambers (001AAA)-(002AAA), (001AA)-(002AA) and (001AAB)-(002AAB) respectively, consists of the pairs with Fixed Chambers (001AEA), (001AE) and (001AEB) coupled with the Rotating Subchambers (002AEA), (002AE) and (002AEB) respectively, otherwise as in the Subsystem (A.E.1.4A ) and in the Pyrolysis-Carbonation Unit (A.4.1E) Under Pressure in Claims 3 and 6 above, Otherwise as in Claims 1, 2, 3 and 6 above, 8. An Electrolysis System (A.E.3) as a Combination of Unit (A.6.1) or (A.6.1') with a Pyrolysis-Carbonation Unit (A.4.1A) or (A.4.1E) Under Pressure, One Pass cleaning, then Power Generation System (A.E.3), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.3.1A,E) Biomass Storage and Pre-Drying (A.2.0), (A. E.3.2A,E) Preparation and First Drying of Biomass (A.2.0), (A.E.3.3A,E) Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E .3.4A,E) Pyrolysis-Carbonization of Biomass Under 20-40Bar Pressure, (A.E.3.6A,E) of the Single or Combined Cycle Unit (A.6.1) or (A.6.1'), (A.E .3.7A,E) Transport and Storage of the produced Pyrolytic Activated Carbon (008A) and (008B), which are characterized by the fact that they consist of the following Components as follows, namely: Where Subsystems (A.E.3.1A,E), (A.E.3.2A,E), (A.E.3.3A,E), and (A.E.3.7AE), are characterized by that they are the same as Subsystems (A.E.1.1A), (A.E.1.2A), (A.E.1.3A) and (A.E.1.7A) and (A.E.1.1e) , (A.E.1.2e), (A.E.1.3e) and (A.E.1.7e) above in System (A.E.1) and (A.E.2), The Subsystem (A.E.3.4A E) Pyrolysis-Carbonization of Biomass Under Pressure 20-40Bar, then Subsystem (A.E.3.4A E) or Pyrolysis-Carbonization Subunit (A.4.1AA) or (A.4.1 EB), is characterized by being the same as Subsystems (A.E.1.4A) and (A.E.2.4E) above, i.e. each as an innovative Pyrolysis-Carbonization Subunit (A.4.1AB) or (A. 4.1EB) Under Pressure, indicatively 20-40Bar, for the production of pure Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), characterized by the fact that the Superheated Exhaust Gases (014) for Pyrolysis-Carbonization in the Subchambers (002AA) and (002AE) are taken from the exit of the Gas Turbine (A.6.1A) and after Pyrolysis-Carbonization are forwarded to the Waste Gas Boiler (012B) of the Combined Cycle Unit (A.6.1), otherwise as claimed in Subsystem (A.E.1.4A) and (A.E.2.4E) above, The Subsystem (A.E.3.6AE) ) of the Simple or Combined Cycle Unit (A.6.1) or (A.6.1') hereinafter Subsystem (A.E.3.6AE), is characterized by the fact that it consists of a combination of a Modified Single or Combined Cycle Power Generation Unit (A.6.1') or (A.6.1) with Pure or Mixed Combustion of Volatile Biomass (009) with Fossil Fuels, indicative of PV (009B) and an innovative Pyrolysis-Carbonation Subunit (A.4.1 A) or (A.4.1E) Under Pressure, indicatively 20-40Bar, for the production of pure Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), in which case the multiple advantages arise both for the whole process of Pyrolysis-Carbonization of Biomass (A.2.2) and (A.2.1) as well as Power Generation, as claimed in the Detailed Description in Claims 1, 2, 3 and 5, 6 and 7 above, Otherwise as in Claims 1, 2, 3, 6 and 7 above, 9. An Electroprecipitation System (A.E.4) Combining a Unit (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonization Unit (A.4.1H) Under a Pressure of 20-40Bar of a Cleaning Diode then Power Generation System (A.E.4), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.4.1H) Biomass Storage and Pre-Drying (A.2.0), (A.E. 4.2H) Preparation and First Drying of Biomass (A.2.0), (A.E.4.3H) Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E.4.4H) Pyrolysis- Carbonization of Biomass Under Pressure 20-40Bar, (A.E.4.5H) of the Power Generation Unit (A.5.1) or (A.6.1) or A.6.1'), (A.E.4.7H) Transport and Storage of of produced Pyrolytic Activated Carbon (008A) and (008B), which are characterized by being composed of the following Components as described below, namely: Where Subsystems (A.E.4.1H), (A.E.4.2H), (A.E.4.3H) and (A.E.4.7H) are characterized by being the same as Subsystems (A .E.1.1A), (A.E.1.2A), (A.E.1.3A) and (A.E.1.7A) and (A.E.1.1E), (A.E.1.2E ), (A.E.1.3E) and (A.E.1.7E) above in System (A.E.1) and (A.E.2), The Biomass Pyrolysis-Carbonization Subsystem (A.E.4.4H) under 20-40Bar Pressure, then Subsystem (A.E.3.4H) or Pyrolysis-Carbonization Unit (A.4.1H), which is characterized by the fact that is the same as the Pyrolysis-Carbonization Unit (A.4.1H) in Claim 4 above, The Subsystem (A.E.4.5H) of the Power Generation Unit (A.5.1) or (A.6.1) or A.6.1'), hereafter Subsystem (A.E.4.5H), is characterized by the fact that it consists of a combination of a Modified Power Generation Unit (A.5.1) or (A.6.1') or (A.6.1) as in Subsystems (A.E.1.5A) and (A.E.3.5E) and an innovative Pyrolysis Unit- Carbonization (A.4.1H) Under Pressure, indicatively 20-40Bar, for the production of Clean Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) and (008B), which results in multiple advantages both for the entire Pyrolysis process - Carbonization of Biomass (A.2.2) and (A.2.1) as well as Power Generation, as analyzed in the Detailed Description in Claims 1, 2, 3, 4, 6, 7 and 8 above, Otherwise as in Claims 1, 2, 3, 4, 6, 7 and 8 above, 10. A Power Generation System (A.E.5) Combining a Unit (A.5.1) or (A.6.1) or A.6.1') with a Pyrolysis-Carbonization Unit (A.4.1'O) or (A.4.1A) or (A.4.1E) or (A.4.1H) Atmospheric Pressure, then Power Generation System (A.E.5), which is characterized by the fact that it consists of the following Subsystems, namely: (A.E.5.1) Biomass Storage and Pre-Drying (A.2.0), (A.E.5.2 ') Preparation and First Drying of Biomass (A.2.0), (A.E.5.3') Drying - Preheating of Biomass (A.2.2) and (A.2.1), (A.E.5.4') Pyrolysis-Carbonization with the Pyrolysis-Carbonation Units (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) Atmospheric Pressure, (A.E.5.5') of the Power Generation Unit (A .5.1) or (A.6.1) or A.6.1'), (A.E.5.7) Transport and Storage of the produced Pyrolytic Activated Carbon (008A) and (008B), which are characterized by the fact that they consist of the following Components Parts as described below, namely: Where Subsystems (A.E.5.1'), (A.E.5.2'), (A.E.5.3') and (A.E.5.7'), are characterized by being the same as Subsystems (A .E.1.1A), (A.E.1.2A), (A.E.1.3A) and (A.E.1.7A) claimed above in the System (A.E.1), The Subsystem (A.E.5.4') with Pyrolysis-Carbonation Units (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) Atmospheric Pressure, then Subsystem (A.E.5.4') or Pyrolysis-Carbonization Unit (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1Ε), characterized by being same as the Atmospheric Pressure Coking Units (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) in Claim 5 above, The Subsystem (A.E.5.5') of the Power Generation Units (A.5.1) or (A.6.1) or A.6.1'), hereafter Subsystem (A.E.4.5'), is characterized by the fact that it consists of a combination of a Modified Power Generation Unit (A.5.1) or (A.6.1') or (A.6.1) as in Subsystems (A.E.1. 5A) and (A.E.3.6A) and an innovative Pyrolysis Unit - Carbonization (A.4.1'0) or (A.4.1A) or (A.4.1E) or (A.4.1H) Atmospheric Pressure, for the production of pure Volatile Biomass (009) and Pyrolytic Activated Carbon (008A) ) and (008B), in which case the need arises for a Double or Triple or Multiple Purification of Volatile Biomass as in Claim 4 above, Otherwise as in Claims 1, 2, 5, 6, 7, 8 and 9 above,