GR1007392B - Μεθοδος παρασκευης νανο-οξαλικου πυριτικου πηκτωματος με εφαρμογες στα δομικα υλικα - Google Patents

Μεθοδος παρασκευης νανο-οξαλικου πυριτικου πηκτωματος με εφαρμογες στα δομικα υλικα

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Publication number
GR1007392B
GR1007392B GR20100100656A GR20100100656A GR1007392B GR 1007392 B GR1007392 B GR 1007392B GR 20100100656 A GR20100100656 A GR 20100100656A GR 20100100656 A GR20100100656 A GR 20100100656A GR 1007392 B GR1007392 B GR 1007392B
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GR
Greece
Prior art keywords
nano
oxalate
silicate
silicate gel
materials
Prior art date
Application number
GR20100100656A
Other languages
English (en)
Inventor
Παγωνα Βασιλειου Μαραβελακη
Αναστασια Μιχαηλ Βεργανελακη
Ιωαννης Λαμπρου Καρατασιος
Βασιλης Ιωαννη Κυλικογλου
Original Assignee
Παγωνα Βασιλειου Μαραβελακη
Αναστασια Μιχαηλ Βεργανελακη
Ιωαννης Λαμπρου Καρατασιος
Βασιλης Ιωαννη Κυλικογλου
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Παγωνα Βασιλειου Μαραβελακη, Αναστασια Μιχαηλ Βεργανελακη, Ιωαννης Λαμπρου Καρατασιος, Βασιλης Ιωαννη Κυλικογλου filed Critical Παγωνα Βασιλειου Μαραβελακη
Priority to GR20100100656A priority Critical patent/GR1007392B/el
Publication of GR1007392B publication Critical patent/GR1007392B/el

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/04—Carboxylic acids; Salts, anhydrides or esters thereof
    • C04B24/06—Carboxylic acids; Salts, anhydrides or esters thereof containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
    • C04B41/4535—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied as a solution, emulsion, dispersion or suspension
    • C04B41/4537—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied as a solution, emulsion, dispersion or suspension by the sol-gel process
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5089—Silica sols, alkyl, ammonium or alkali metal silicate cements
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/2092—Resistance against biological degradation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/23—Acid resistance, e.g. against acid air or rain
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54—Substitutes for natural stone, artistic materials or the like
    • C04B2111/547—Imitating ancient compositions, e.g. mediaeval mortars; Compositions specially designed for restauration of ancient buildings or building elements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72—Repairing or restoring existing buildings or building materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

Σύνθεση και χαρακτηρισμός ενός Νανο-Οξαλικού Πυριτικού πηκτώματος με δυνατότητα χρήσης του ως υλικό στερέωσης και επιφανειακής προστασίας των σύγχρονων, παραδοσιακών και αρχαιολογικών ανόργανων πορωδών δομικών υλικών (φυσικοί λίθοι, κονιάματα, επιχρίσματα), τα οποία έχουν υποστεί διάβρωση λόγω φυσικοχημικών ή και βιολογικών παραγόντων. Σύνθεση αρχικά του μονοένυδρου νανο-οξαλικού ασβεστίου, μετέπειτα ανάμειξή του με τετρααιθοξυσιλάνιο σε αιθυλική αλκοόλη παρουσία μικρής ποσότητας τασιενεργού ουσίας n-οκτυλαμίνης, υδρόλυση και πολυμερισμός του λύματος (Νανο-Οξαλικό Πυριτικό κολλοειδές αιώρημα) για δημιουργία ενός Νανο-Οξαλικού Πυριτικού πηκτώματος παρουσία υγρασίας περιβάλλοντος που δεν παρουσιάζει ρωγμές. Η σύνθεση της παρούσας εφεύρεσης διαφοροποιείται έναντι πολλών εμπορικών διαθέσιμων στερεωτικών, ως προς α) τις πρώτες ύλες, β) τη διαδικασία σύνθεσής της γ) την επίδρασή της στο περιβάλλον και την υγεία των ανθρώπων, δ) το κόστος παρασκευής της, ε) τις φυσικοχημικές και μηχανικές της ιδιότητες. Η αποτίμηση του υλικού Νανο-Οξαλικού Πυριτικού πηκτώματος γίνεται μετά την κατεργασία πορωδών λίθων με το Νανο-Οξαλικό Πυριτικό κολλοειδές αιώρημα και την ολοκλήρωση του πολυμερισμού του. Εμπλουτίζεται με την εφεύρεση αυτή το επιστημονικό πεδίο της συντήρησης και αποκατάστασης μνημείων, ενώ το συγκεκριμένο Νανο-Οξαλικό Πυριτικό πήκτωμα μπορεί να εφαρμοστεί και σε σύγχρονα δομικά υλικά, οπότε με την συμβατή δομή του με αυτά συμβάλλει στην αειφορία της κατασκευής.
GR20100100656A 2010-11-12 2010-11-12 Μεθοδος παρασκευης νανο-οξαλικου πυριτικου πηκτωματος με εφαρμογες στα δομικα υλικα GR1007392B (el)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GR20100100656A GR1007392B (el) 2010-11-12 2010-11-12 Μεθοδος παρασκευης νανο-οξαλικου πυριτικου πηκτωματος με εφαρμογες στα δομικα υλικα

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Application Number Priority Date Filing Date Title
GR20100100656A GR1007392B (el) 2010-11-12 2010-11-12 Μεθοδος παρασκευης νανο-οξαλικου πυριτικου πηκτωματος με εφαρμογες στα δομικα υλικα

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GR1007392B true GR1007392B (el) 2011-09-08

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GR20100100656A GR1007392B (el) 2010-11-12 2010-11-12 Μεθοδος παρασκευης νανο-οξαλικου πυριτικου πηκτωματος με εφαρμογες στα δομικα υλικα

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103288359A (zh) * 2013-04-03 2013-09-11 中国科学院合肥物质科学研究院 氧化物微纳米结构有序多孔阵列的氧等离子体辐照制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1921054A1 (en) * 2005-07-30 2008-05-14 Universidad de Cádiz Method of strengthening stone and other construction materials

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1921054A1 (en) * 2005-07-30 2008-05-14 Universidad de Cádiz Method of strengthening stone and other construction materials

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
CARMEN SALAZAR-HERNÁNDEZ ET AL: "TEOS-colloidal silica-PDMS-OH hybrid formulation used for stone consolidation", APPLIED ORGANOMETALLIC CHEMISTRY, vol. 24, no. 6, 13 April 2010 (2010-04-13), pages 481 - 486, XP055002696, ISSN: 0268-2605, DOI: 10.1002/aoc.1646 *
DOHERTY ET AL: "Efficiency and resistance of the artificial oxalate protection treatment on marble against chemical weathering", APPLIED SURFACE SCIENCE, ELSEVIER, AMSTERDAM, NL, vol. 253, no. 10, 20 February 2007 (2007-02-20), pages 4477 - 4484, XP005894814, ISSN: 0169-4332, DOI: DOI:10.1016/J.APSUSC.2006.09.056 *
LIU ET AL: "A crude protective film on historic stones and its artificial preparation through biomimetic synthesis", APPLIED SURFACE SCIENCE, ELSEVIER, AMSTERDAM, NL, vol. 253, no. 5, 29 November 2006 (2006-11-29), pages 2625 - 2632, XP005782923, ISSN: 0169-4332, DOI: DOI:10.1016/J.APSUSC.2006.05.032 *
LIU ET AL: "Syntheses of a novel nanomaterial for conservation of historic stones inspired by nature", MATERIALS LETTERS, NORTH HOLLAND PUBLISHING COMPANY. AMSTERDAM, NL, vol. 61, no. 28, 12 October 2007 (2007-10-12), pages 4976 - 4979, XP022284112, ISSN: 0167-577X, DOI: DOI:10.1016/J.MATLET.2007.03.104 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103288359A (zh) * 2013-04-03 2013-09-11 中国科学院合肥物质科学研究院 氧化物微纳米结构有序多孔阵列的氧等离子体辐照制备方法

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