GB998830A - Decorating compositions and method of decorating therewith - Google Patents
Decorating compositions and method of decorating therewithInfo
- Publication number
- GB998830A GB998830A GB4673763A GB4673763A GB998830A GB 998830 A GB998830 A GB 998830A GB 4673763 A GB4673763 A GB 4673763A GB 4673763 A GB4673763 A GB 4673763A GB 998830 A GB998830 A GB 998830A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- silver
- mercaptan
- stirring
- mercaptans
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Structural Engineering (AREA)
- Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Chemically Coating (AREA)
Abstract
Silver mercaptides are prepared by the reaction between a silver salt or oxide and a mercaptan. The term mercaptan includes tertiary alkyl mercaptans containing 7 or more carbon atoms in the tertiary alkyl radical, primary and secondary alkyl mercaptans and other mercaptans which may be aliphatic, alicyclic, heterocyclic, aryl, alkaryl, aralkyl or terpenyl, and other compounds named in a list, e.g. p-chlorophenyl and 2-hydroxyethyl mercaptans, thioglycolic acid and esters thereof, and isooctyl 3mercaptopropionate. The mercaptides may be made by stirring an aqueous solution of a silver salt with a mercaptan. In Example 1, to a mixture of 8 mole tertiary nonyl mercaptan, chloroform, 4 mole Na2CO3, and water, was added 8.4 mole AgNO3 with stirring during 20 minutes. After stirring the mixture was allowed to settle. The chloroform layer was washed with water, filtered, stirred with activated charcoal, and filtered. The filtrate was kept for 4 hrs. in an open dish on a steam bath, with occasional stirring. A deep ruby, moderately viscous oil resulted. In Example 2, 2-naphthalenethiol, AgNo3 and sodium acetate were used.ALSO:A metallic coating is formed by use of a decorating composition comprising a silver mercaptide, a flux and a vehicle. The composition may be applied to an article and fired to a metallic film, lustre colour or stain. The mercaptide may be aliphatic, alicyclic, heterocyclic, aryl, alkaryl, aralkyl or terpenyl, and is preferably tertiary alkyl, e.g. with 7-30 carbon atoms per molecule. A long list of suitable mercaptides is given. The flux may be a salt or resinate of Rh, Ir, Bi, Cr, Pb, Cd, Sn, Cu, Co, Sb or U. The salt may be, e.g., borate, nitrate, silicate. The vehicle may be a mixture of essential oil, terpenes, resins, methyl ethyl ketone, cyclohexanone, ethyl acetate, amyl acetate, "Cellosolve" (Registered Trade Mark), butanol, nitrobenzene, toluene, xylene, petroleum ether, chloroform, carbon tetrachloride, Assyrian asphalt, balsams, or artificial resins, or may be lacquer or wax. The composition may also contain Au, Pt and/or Pd, e.g. as sulphoresinates, organic complexes or powder; Ag powder, amorphous, flakes or spherules, may also be employed. The composition may contain, e.g., 0.1-40.0% or more of silver. The composition may be applied by brushing, spraying, stippling, stamping, printing, or decalcomania transfer. The material may be fired at 250-900 DEG C. by kiln, flash, lehr or infra-red firing. Substrates include laminated artificial resins, glass, glass-ceramic, ceramic, quartz, mica, alumina, aluminium, stainless steel. Specific compositions and method of use are disclosed in the examples. Specification 926,979 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US24042762A | 1962-11-27 | 1962-11-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB998830A true GB998830A (en) | 1965-07-21 |
Family
ID=22906476
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4673763A Expired GB998830A (en) | 1962-11-27 | 1963-11-26 | Decorating compositions and method of decorating therewith |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1286867B (en) |
GB (1) | GB998830A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4262040A (en) * | 1978-08-30 | 1981-04-14 | Engelhard Minerals & Chemicals Corporation | Decoration for ceramics having the appearance of gold |
GB2231884A (en) * | 1989-04-27 | 1990-11-28 | Amp Akzo J V Inc | Heat decomposable fluid compositions containing organogold and organosilver compounds |
US5059242A (en) * | 1990-04-27 | 1991-10-22 | Firmstone Michael G | Seed layer compositions containing organogold and organosilver compounds |
GB2253635A (en) * | 1991-01-25 | 1992-09-16 | Amp Akzo Corp | Heat decomposable compositions containing organogold compound and glass forming resinate |
GB2253636A (en) * | 1991-01-25 | 1992-09-16 | Amp Akzo Corp | Heat decomposable compositions containing organogold compound and resin binder |
-
1963
- 1963-11-26 GB GB4673763A patent/GB998830A/en not_active Expired
- 1963-11-27 DE DE1963E0025934 patent/DE1286867B/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4262040A (en) * | 1978-08-30 | 1981-04-14 | Engelhard Minerals & Chemicals Corporation | Decoration for ceramics having the appearance of gold |
GB2231884A (en) * | 1989-04-27 | 1990-11-28 | Amp Akzo J V Inc | Heat decomposable fluid compositions containing organogold and organosilver compounds |
US5059242A (en) * | 1990-04-27 | 1991-10-22 | Firmstone Michael G | Seed layer compositions containing organogold and organosilver compounds |
GB2253635A (en) * | 1991-01-25 | 1992-09-16 | Amp Akzo Corp | Heat decomposable compositions containing organogold compound and glass forming resinate |
GB2253636A (en) * | 1991-01-25 | 1992-09-16 | Amp Akzo Corp | Heat decomposable compositions containing organogold compound and resin binder |
Also Published As
Publication number | Publication date |
---|---|
DE1286867B (en) | 1969-01-09 |
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