GB998097A - Composite body comprising a porous layer of a hydrogenation catalyst - Google Patents
Composite body comprising a porous layer of a hydrogenation catalystInfo
- Publication number
- GB998097A GB998097A GB11957/62A GB1195762A GB998097A GB 998097 A GB998097 A GB 998097A GB 11957/62 A GB11957/62 A GB 11957/62A GB 1195762 A GB1195762 A GB 1195762A GB 998097 A GB998097 A GB 998097A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tube
- hydrogen
- raney
- alloy
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 3
- 239000002131 composite material Substances 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 10
- 229910052739 hydrogen Inorganic materials 0.000 abstract 10
- 239000001257 hydrogen Substances 0.000 abstract 10
- 229910045601 alloy Inorganic materials 0.000 abstract 8
- 239000000956 alloy Substances 0.000 abstract 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 229910001316 Ag alloy Inorganic materials 0.000 abstract 5
- 229910001252 Pd alloy Inorganic materials 0.000 abstract 4
- 239000010949 copper Substances 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- 229910052802 copper Inorganic materials 0.000 abstract 3
- 229910052805 deuterium Inorganic materials 0.000 abstract 3
- 239000011888 foil Substances 0.000 abstract 3
- 239000008246 gaseous mixture Substances 0.000 abstract 3
- 229910052742 iron Inorganic materials 0.000 abstract 3
- 229910052684 Cerium Inorganic materials 0.000 abstract 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 abstract 2
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052776 Thorium Inorganic materials 0.000 abstract 2
- 239000002585 base Substances 0.000 abstract 2
- 239000012458 free base Substances 0.000 abstract 2
- 150000004678 hydrides Chemical class 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- 239000004065 semiconductor Substances 0.000 abstract 2
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- MOFOBJHOKRNACT-UHFFFAOYSA-N nickel silver Chemical compound [Ni].[Ag] MOFOBJHOKRNACT-UHFFFAOYSA-N 0.000 abstract 1
- 239000010956 nickel silver Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0221—Group 4 or 5 metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02231—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/508—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by selective and reversible uptake by an appropriate medium, i.e. the uptake being based on physical or chemical sorption phenomena or on reversible chemical reactions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B4/00—Hydrogen isotopes; Inorganic compounds thereof prepared by isotope exchange, e.g. NH3 + D2 → NH2D + HD
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/94—Non-porous diffusion electrodes, e.g. palladium membranes, ion exchange membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Abstract
<PICT:0998097/C1/1> <PICT:0998097/C1/2> <PICT:0998097/C1/3> Hydrogen is purified, or hydrogen and deuterium are separated, by use of a composite body comprising a compact pore-free base of a metal or alloy permeable to hydrogen in contact with a porous layer of a hydrogenation catalyst other than a hydride of Ti, Zr, Th, Ce or U. Suitable catalysts include e.g. finely divided Pt, Ni, Co, Fe, Cu and alloys thereof, and certain semi-conductor materials, e.g. N-type Si. Preferred metals for the base include Pd and its alloys, e.g. T with Ag; Ta and its alloys, e.g. with W; and Ti. In specific examples:-(1) a hydrogen electrode (Fig. 3) for a fuel cell has an open-ended nickel-silver tube 1 to one end of which Pd foil 2 is soldered. In the tube is placed a layer 3 of Raney Ni, and a weight or wire mesh is pressed thereon to assure intimate contact between layer 3 and foil 2. The electrode is immersed in 6N NaOH solution 6. The counter-electrode is an iron sheet. Instead of Raney Ni, Raney Fe, Co or Cu may be used. Alternatively, (2) a Raney copper layer may be used with a Pd/Ag alloy foil, and this electrode may also be used to prepare pure H2. (3) A 1:1 H2/D2 gaseous mixture is fed into a Pd/Ag alloy tube 9 (Fig. 4) containing a powdered Raney Co liner which causes the H2 to be readily absorbed by tube 9, from which the H2 is removed either electrolytically or by reduced pressure at the outer wall of the tube which may also be coated with Raney Co. A D2-enriched mixture emerges from the end of the tube. The systems of Fig. 4 may be used in known cascading or counter-current arrangements. (4) Pure H2 may be obtained by feeding at 14 (Fig. 5) a gaseous mixture containing hydrogen into 13 which contains Pd/Ag alloy tube 11 closed at one end lined inside and outside with Cu powder layer 12. The gas in 13 is at about 20 atmospheres and in 11 is at 1 atmosphere. H2 is selectively adsorbed and dissolved in 11 and 12 and pure H2 will emerge from the tube while the remainder of the mixture leaves at 15. Blades 16 cause a turbulence in the inflowing mixture so that all the H2 is brought in contact with the tube. Specification 956,292 is referred to.ALSO:A hydrogen electrode comprises a compact pore-free base of a metal or alloy permeable to hydrogen in contact with a porous layer of a hydrogenation catalyst other than a hydride of Ti, Zr, Th, Ce, or U. Suitable catalysts include, e.g., Pt, Ni, Co, Fe, Cu, and alloys thereof, and certain semi-conductor materials, e.g. n-type Si. Preferred metals for the base include Pd and its alloys, e.g. with Ag; Ta and its alloys, e.g. with W ; and Ti. In specific examples, (1) a 1:1 hydrogen-deuterium gaseous mixture is fed into a Pd/Ag alloy tube 9, Fig. 4, containing a powdered Raney Co liner which causes the hydrogen to be readily absorbed by tube 9 from which the hydrogen is removed electrolytically while a deuterium-enriched mixture emerges from the tube; and (2) pure hydrogen is produced by electrolysis of 6N caustic soda solution using a cathode comprising a tube of Pd-Ag alloy or Pd closed at one end and packed with Pd black. Specification 956,292 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEW29722A DE1148981B (en) | 1961-03-29 | 1961-03-29 | Device for the chemical activation of gaseous hydrogen using pore-free metal membranes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB998097A true GB998097A (en) | 1965-07-14 |
Family
ID=7599304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11957/62A Expired GB998097A (en) | 1961-03-29 | 1962-03-28 | Composite body comprising a porous layer of a hydrogenation catalyst |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE615742A (en) |
CH (1) | CH415567A (en) |
DE (1) | DE1148981B (en) |
GB (1) | GB998097A (en) |
NL (1) | NL276463A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006031875A1 (en) * | 2004-09-14 | 2006-03-23 | Honda Motor Co., Ltd. | Fuel cells and methods for generating electricity |
US7955491B2 (en) | 2004-09-14 | 2011-06-07 | Honda Motor Co., Ltd. | Methods, devices, and infrastructure systems for separating, removing, compressing, and generating hydrogen |
CN108771944A (en) * | 2018-08-01 | 2018-11-09 | 北京无线电计量测试研究所 | A kind of nickel purifier and Hydrogen Atom Frequency Standard |
CN110173960A (en) * | 2019-06-28 | 2019-08-27 | 正和集团股份有限公司 | A kind of recycle device and technique of hydrogen-rich gas |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111099706A (en) * | 2019-12-12 | 2020-05-05 | 贵州振华电子信息产业技术研究有限公司 | Method for recycling tantalum in acid-containing waste liquid |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1059990B (en) * | 1958-01-17 | 1959-06-25 | Ruhrchemie Ag | Catalyst sieve electrode for the electrochemical conversion of active gases in fuel elements |
DE1091990B (en) * | 1958-02-24 | 1960-11-03 | Universal Oil Prod Co | Method and device for separating hydrogen from gas mixtures |
-
0
- NL NL276463D patent/NL276463A/xx unknown
-
1961
- 1961-03-29 DE DEW29722A patent/DE1148981B/en active Pending
-
1962
- 1962-02-15 CH CH183062A patent/CH415567A/en unknown
- 1962-03-28 GB GB11957/62A patent/GB998097A/en not_active Expired
- 1962-03-29 BE BE615742A patent/BE615742A/en unknown
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006031875A1 (en) * | 2004-09-14 | 2006-03-23 | Honda Motor Co., Ltd. | Fuel cells and methods for generating electricity |
US7955491B2 (en) | 2004-09-14 | 2011-06-07 | Honda Motor Co., Ltd. | Methods, devices, and infrastructure systems for separating, removing, compressing, and generating hydrogen |
CN108771944A (en) * | 2018-08-01 | 2018-11-09 | 北京无线电计量测试研究所 | A kind of nickel purifier and Hydrogen Atom Frequency Standard |
CN108771944B (en) * | 2018-08-01 | 2024-03-19 | 北京无线电计量测试研究所 | Nickel purifier and hydrogen atom frequency scale |
CN110173960A (en) * | 2019-06-28 | 2019-08-27 | 正和集团股份有限公司 | A kind of recycle device and technique of hydrogen-rich gas |
Also Published As
Publication number | Publication date |
---|---|
DE1148981B (en) | 1963-05-22 |
CH415567A (en) | 1966-06-30 |
NL276463A (en) | 1900-01-01 |
BE615742A (en) | 1962-07-16 |
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