GB997303A - Alkylation process - Google Patents

Alkylation process

Info

Publication number
GB997303A
GB997303A GB24680/64A GB2468064A GB997303A GB 997303 A GB997303 A GB 997303A GB 24680/64 A GB24680/64 A GB 24680/64A GB 2468064 A GB2468064 A GB 2468064A GB 997303 A GB997303 A GB 997303A
Authority
GB
United Kingdom
Prior art keywords
ethene
reaction
olefin
mono
cyclic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24680/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB997303A publication Critical patent/GB997303A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/68—Catalytic processes with halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Aromatic hydrocarbons are alkylated by reaction with a mono-olefin of at least 3 carbon atoms in the presence as catalyst of an alkyl aluminium dichloride. The aromatic hydrocarbon may be mono- or poly-cyclic and may contain alkyl or alkylene substituents. The olefin may be cyclic or acyclic with terminal or internal unsaturation. Reaction is effected at -10 DEG to 120 DEG C. and 0.1-50 atm. in the presence of 0.0001-0.1 mol. of catalyst per mol. of aromatic hydrocarbon in the absence of oxygen. A solvent may be present. Ethene does not react and the process may be used to remove olefin contaminants from ethene. Preferably, ethene is absent when the reaction is initiated.
GB24680/64A 1963-06-17 1964-06-15 Alkylation process Expired GB997303A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US288537A US3277196A (en) 1963-06-17 1963-06-17 Alkylation process

Publications (1)

Publication Number Publication Date
GB997303A true GB997303A (en) 1965-07-07

Family

ID=23107559

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24680/64A Expired GB997303A (en) 1963-06-17 1964-06-15 Alkylation process

Country Status (3)

Country Link
US (1) US3277196A (en)
DE (1) DE1468978A1 (en)
GB (1) GB997303A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3381049A (en) * 1965-02-18 1968-04-30 Gulf Oil Corp Preparation of a low acid wash color cumene
US3875249A (en) * 1971-03-10 1975-04-01 Ethyl Corp Preparation of haloalkyl aromatic hydrocarbons
US4255343A (en) * 1979-08-13 1981-03-10 E. I. Du Pont De Nemours And Company Preparation of 2-T-alkylanthracene
CA2015191A1 (en) * 1989-04-25 1990-10-25 Kazuhiro Yamauchi Process for production of sec-butylbenzene

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2271956A (en) * 1939-09-27 1942-02-03 Robert F Ruthruff Preparation of alkyl aluminum halides
US2388428A (en) * 1943-03-31 1945-11-06 Universal Oil Prod Co Catalysis of organic reactions

Also Published As

Publication number Publication date
US3277196A (en) 1966-10-04
DE1468978A1 (en) 1969-02-06

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