GB997044A - Proces for the upgrading of a bis-triazinylamino stilbene derivative - Google Patents
Proces for the upgrading of a bis-triazinylamino stilbene derivativeInfo
- Publication number
- GB997044A GB997044A GB25067/63A GB2506763A GB997044A GB 997044 A GB997044 A GB 997044A GB 25067/63 A GB25067/63 A GB 25067/63A GB 2506763 A GB2506763 A GB 2506763A GB 997044 A GB997044 A GB 997044A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compounds
- general formula
- cation
- product
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RWFZHFYWPYSEOZ-UHFFFAOYSA-N 1,2-diphenyl-N,N'-bis(triazin-4-yl)ethene-1,2-diamine Chemical class N1=NN=C(C=C1)NC(=C(C1=CC=CC=C1)NC1=NN=NC=C1)C1=CC=CC=C1 RWFZHFYWPYSEOZ-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 150000001768 cations Chemical class 0.000 abstract 3
- 239000000047 product Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 239000012736 aqueous medium Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- QIJIUJYANDSEKG-UHFFFAOYSA-O 2,4,4-trimethylpentan-2-ylazanium Chemical compound CC(C)(C)CC(C)(C)[NH3+] QIJIUJYANDSEKG-UHFFFAOYSA-O 0.000 abstract 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 238000005282 brightening Methods 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 239000002453 shampoo Substances 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- -1 tri-n-propylammonium ion Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention comprises compounds of the general formula <FORM:0997044/C2/1> in the b -form (as described below), wherein Y is a sodium, calcium, ammonium, tert-octylammonium, di-n-propylammonium or tri-n-propylammonium ion. Compounds of the above general formula wherein Y is any cation, such as a cation of an alkali or alkaline earth metal or an ammonium cation derived from ammonia or a primary, secondary or tertiary amine, are obtained in the b -form by subjecting a compound of the above general formula in the conventional, a -form, in a closed vessel to a temperature between 100 DEG and 200 DEG C. and a pressure between 5 and 225 p.s.i.g. in the presence of an alkaline material, in aqueous medium. The treatment may be conducted in the presence, as additive, of a polyalcohol, hydroxyether or amine. The a -form of the above compounds is the product obtained when the compounds are prepared by conventional procedures, whilst the b -form is the product resulting from the above heat-pressure treatment and has a crystalline form which is distinct from that of the a -form. The a -form of the above compounds in which Y is sodium may be prepared by first reacting 2 mols. of cyanuric chloride with a mol. of 4,41-diaminostilbene-2,21-disulphonic acid, then reacting the condensation product with 4 mols. of aniline and finally neutralizing the reaction product with sodium hydroxide. Examples are given.ALSO:Soap, detergents and rug and upholstery shampoos may contain, as optical brightening agents, compounds of the general formula <FORM:0997044/C4-C5/1> wherein Y is cation, the compounds being in the b -form. The b -form is the product obtained when compounds of the above general formula in the conventional, a -form, are subjected in a closed vessel to a temperature between 100 DEG and 200 DEG C. and a pressure between 5 and 225 p.s.i.g. in the presence of an alkaline material, in aqueous medium (see Division C2).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20509262A | 1962-06-25 | 1962-06-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB997044A true GB997044A (en) | 1965-06-30 |
Family
ID=22760766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25067/63A Expired GB997044A (en) | 1962-06-25 | 1963-06-24 | Proces for the upgrading of a bis-triazinylamino stilbene derivative |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH424794A (en) |
| DK (1) | DK104938C (en) |
| ES (1) | ES289318A1 (en) |
| GB (1) | GB997044A (en) |
| NL (1) | NL141193B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4474577A (en) * | 1983-10-26 | 1984-10-02 | Mobay Chemical Corporation | Modified acid dyestuff |
| US4549980A (en) * | 1983-10-11 | 1985-10-29 | Mobay Chemical Corporation | White modification of a bis-triazinyl amino stilbene optical brightener and a process for making the same |
| US6080208A (en) * | 1996-05-23 | 2000-06-27 | Ciba Specialty Chemicals Corporation | Stilbene compounds and their use |
-
1963
- 1963-06-20 CH CH761063A patent/CH424794A/en unknown
- 1963-06-24 ES ES289318A patent/ES289318A1/en not_active Expired
- 1963-06-24 GB GB25067/63A patent/GB997044A/en not_active Expired
- 1963-06-24 DK DK301263AA patent/DK104938C/en active
- 1963-06-24 NL NL63294488A patent/NL141193B/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4549980A (en) * | 1983-10-11 | 1985-10-29 | Mobay Chemical Corporation | White modification of a bis-triazinyl amino stilbene optical brightener and a process for making the same |
| US4474577A (en) * | 1983-10-26 | 1984-10-02 | Mobay Chemical Corporation | Modified acid dyestuff |
| US6080208A (en) * | 1996-05-23 | 2000-06-27 | Ciba Specialty Chemicals Corporation | Stilbene compounds and their use |
Also Published As
| Publication number | Publication date |
|---|---|
| CH424794A (en) | 1966-11-30 |
| ES289318A1 (en) | 1963-11-16 |
| NL141193B (en) | 1974-02-15 |
| DK104938C (en) | 1966-07-25 |
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