GB993586A - Preparation of alkyl aromatic hydrocarbons - Google Patents

Preparation of alkyl aromatic hydrocarbons

Info

Publication number
GB993586A
GB993586A GB22601/63A GB2260163A GB993586A GB 993586 A GB993586 A GB 993586A GB 22601/63 A GB22601/63 A GB 22601/63A GB 2260163 A GB2260163 A GB 2260163A GB 993586 A GB993586 A GB 993586A
Authority
GB
United Kingdom
Prior art keywords
alkyl
aromatic
benzenoid
compound
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22601/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunoco Inc
Original Assignee
Sun Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sun Oil Co filed Critical Sun Oil Co
Publication of GB993586A publication Critical patent/GB993586A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/72—Addition to a non-aromatic carbon atom of hydrocarbons containing a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

Alkyl aromatic hydrocarbons are made by telomerizing ethylene on a "benzenoid" hydrocarbon at 50-80 DEG C. in the presence of a catalyst prepared by combining a non-aromatic tertiary amine with a compound of formula LiR in which R is alkyl, cycloalkyl, phenyl, alkylphenyl, phenylalkyl or alkenyl radical containing 1-30 C. Benzenoid is defined as a compound having at least one benzene nucleous which may be substituted and/or which may be fused to an alicyclic ring. Specified benzenoid hydrocarbons are xylenes, ethylbenzene, n-propylbenzene, i-propylbenzene, trimethylbenzenes, n-, sec.- and tert.-butylbenzenes, tetrahydronaphthalene and cyclohexylbenzene. If the starting aromatic contains a saturated hydrocarbon group having a hydrogen atom attached to the a -C atom, reaction will take place in the a -position by telomerization. If there are two a -hydrogens only one site is reactive in practice. When there is no a -hydrogen reaction occurs at the aromatic nucleus and growth therefrom ensues. Examples are given which describe the synthesis of C3-C17 alkyl aromatics.ALSO:A catalyst is prepared by combining a non-aromatic tertiary amine with a compound of formula NiR in which R is a hydrocarbon radical having 1-30 C selected from alkyl, cycloalkyl, phenyl, alkylphenyl or alkenyl radical. Additionally the catalyst may contain sodium alkyls. Preferred tertiary amines are triethylene diamine, 1:4-ethylenepiperidine, and tri-lower aliphatic amines.
GB22601/63A 1962-06-15 1963-06-06 Preparation of alkyl aromatic hydrocarbons Expired GB993586A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US20267862A 1962-06-15 1962-06-15

Publications (1)

Publication Number Publication Date
GB993586A true GB993586A (en) 1965-05-26

Family

ID=22750834

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22601/63A Expired GB993586A (en) 1962-06-15 1963-06-06 Preparation of alkyl aromatic hydrocarbons

Country Status (5)

Country Link
CA (1) CA935187A (en)
DE (1) DE1468652A1 (en)
GB (1) GB993586A (en)
LU (1) LU43901A1 (en)
NL (1) NL144571B (en)

Also Published As

Publication number Publication date
DE1468652A1 (en) 1969-01-16
LU43901A1 (en) 1963-08-14
CA935187A (en) 1973-10-09
NL144571B (en) 1975-01-15

Similar Documents

Publication Publication Date Title
GB1034491A (en) Antiozonants
SE7514518L (en) AZOLYL- (1) -METHANES AND SALTS THEREOF FOR USE AS MEDICINES AND PRODUCTS FOR THEIR PREPARATION
KR950700121A (en) COORDINATION CATALYST SYSTEM
GB993586A (en) Preparation of alkyl aromatic hydrocarbons
GB1184534A (en) Platinum Complexes of Organo Amino Phosphines
ES438595A1 (en) Prostaglandins and method for preparing same
EP0686632A4 (en) Benzothiazine derivative
KR890011932A (en) Polymerization Inhibition Composition for Vinyl Aromatic Compound
ES2008067T3 (en) PROSTACICLINE ANALOGS (PGI2).
ES426285A1 (en) Process for preparing alkyllation catalyst adjuvant solution
GB1108406A (en) Preparation of cyclododecatriene
ES427905A1 (en) Process for bulk dyeing high molecular organic compounds
GB1074687A (en) Organic peroxides
GB1101594A (en) Novel monomeric episulphides
ES457731A1 (en) D-homosteroids
GB957610A (en) Improvements in or relating to catalytic alkylation
GB1025576A (en) Estratriene amino-ethers
ES436647A1 (en) Cyclohexenyl compounds
Axen et al. 2, 2-Difluoro-PGF 2 analogs
GB1058403A (en) Improvements in or relating to novel 4-aza-thiaxanthene derivatives
ES2039626T3 (en) CATALYSTS FOR THE PREPARATION OF SATURATED ELASTOMERIC OLEPHINIC COPOLYMERS AND TERPOLYMERS.
GB986875A (en) The manufacture of halogeno-alkylidene tricyclic compounds and the conversion thereof
GB1286817A (en) Organosilicon compounds
GB969195A (en) New quaternary ammonium compounds and methods for the preparation thereof
DE2960787D1 (en) Process for preparing alpha, beta-dihalogeno-alkyl isocyanates