GB990617A - Process for the selective hydrogenation of hydrocarbon mixtures - Google Patents

Process for the selective hydrogenation of hydrocarbon mixtures

Info

Publication number
GB990617A
GB990617A GB51200/63A GB5120063A GB990617A GB 990617 A GB990617 A GB 990617A GB 51200/63 A GB51200/63 A GB 51200/63A GB 5120063 A GB5120063 A GB 5120063A GB 990617 A GB990617 A GB 990617A
Authority
GB
United Kingdom
Prior art keywords
catalyst
copper
silver
hydrogenation
preferred
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB51200/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB990617A publication Critical patent/GB990617A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Abstract

Hydrocarbon mixtures containing compounds having more than one olefinic bond and/or at least one acetylenic bond, but substantially free from acetylene, are selectively hydrogenated to mono-olefins in the presence of a catalyst comprising at least one metal of Group Ib, i.e. copper, silver and gold, supported on an inert carrier. The process may be applied to hydrocarbon mixtures boiling below 216 DEG C., suitably those obtained by cracking processes, and these include full boiling range gasolines, narrow fractions thereof, and substantially pure butadiene and isoprene. The Group Ib metal may constitute 1-15% by weight of the total catalyst; silver and/or copper supported on silica gel is preferred. A preferred catalyst is made by impregnating the support with copper and/or silver complexed with a water-soluble nitrogen base, particularly ammonia or ethylene diamine, and calcining. Hydrogenation may be effected at 35-345 DEG C., at 1-50 atmospheres, and in the vapour, liquid or mixed phase, liquid being preferred as the hydrogenation is exothermic, and at a L.H.S.V. of 0.5-300 kg. olefine and/or acetylene per kg. catalyst; the hydrogenating gas, which contains at least 60% H2 by volume, may be the gas obtained in the catalytic reforming of gasoline fractions. Examples describe the selective hydrogenation of isoprene (2-methylbutadiene-1,3) to isoamylene.
GB51200/63A 1962-12-31 1963-12-30 Process for the selective hydrogenation of hydrocarbon mixtures Expired GB990617A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US248215A US3215750A (en) 1962-12-31 1962-12-31 Hydrogenation process for converting polyolefins or acetylenes to monoolefins

Publications (1)

Publication Number Publication Date
GB990617A true GB990617A (en) 1965-04-28

Family

ID=22938160

Family Applications (1)

Application Number Title Priority Date Filing Date
GB51200/63A Expired GB990617A (en) 1962-12-31 1963-12-30 Process for the selective hydrogenation of hydrocarbon mixtures

Country Status (5)

Country Link
US (1) US3215750A (en)
BE (1) BE641950A (en)
FR (1) FR1378632A (en)
GB (1) GB990617A (en)
NL (1) NL302682A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3439060A (en) * 1966-06-21 1969-04-15 Goodyear Tire & Rubber Selective removal of cyclopentadiene from a mixture containing at least one other hydrocarbon
US3492366A (en) * 1967-03-17 1970-01-27 Goodyear Tire & Rubber Removal of trace amounts of cyclopentadiene from isoprene by fluidbed adsorbent

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3542667A (en) * 1968-03-21 1970-11-24 Foster Wheeler Corp Process for the production of aromatic and olefinic hydrocarbons
US4173529A (en) * 1978-05-30 1979-11-06 The Lummus Company Hydrotreating of pyrolysis gasoline
US5281753A (en) * 1992-04-21 1994-01-25 Engelhard Corporation Process for the selective hydrogenation and isomerization of hydrocarbons
CA2867506C (en) 2012-03-27 2020-08-18 Dow Technology Investments Llc Method of making a manganese containing supported silver catalyst intermediate
TWI772322B (en) 2016-09-02 2022-08-01 美商陶氏科技投資有限公司 Process for preparing an epoxidation catalyst
FR3061195B1 (en) * 2016-12-22 2019-06-28 IFP Energies Nouvelles SELECTIVE HYDROGENATION PROCESS USING A PREPARED NICKEL CATALYST USING AN ADDITIVE COMPRISING AMINO ACID, AMIDE FUNCTION OR AN AMINO ACID
SG11202005995SA (en) 2017-12-28 2020-07-29 Dow Technology Investments Llc Process for preparing an epoxidation catalyst
CN114029069A (en) * 2021-11-17 2022-02-11 内蒙古鄂尔多斯电力冶金集团股份有限公司 Ionic liquid modified gold-copper acetylene hydrochlorination catalyst and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2802889A (en) * 1954-06-01 1957-08-13 Dow Chemical Co Selective hydrogenation of acetylene in ethylene and catalyst therefor
US3076858A (en) * 1958-06-16 1963-02-05 Dow Chemical Co Selective hydrogenation in the presence of copper catalysts
GB899653A (en) * 1958-07-25 1962-06-27 British Petroleum Co Improvements relating to the hydrogenation of gasolines

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3439060A (en) * 1966-06-21 1969-04-15 Goodyear Tire & Rubber Selective removal of cyclopentadiene from a mixture containing at least one other hydrocarbon
US3492366A (en) * 1967-03-17 1970-01-27 Goodyear Tire & Rubber Removal of trace amounts of cyclopentadiene from isoprene by fluidbed adsorbent

Also Published As

Publication number Publication date
FR1378632A (en) 1964-11-13
NL302682A (en) 1900-01-01
US3215750A (en) 1965-11-02
BE641950A (en) 1964-06-30

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