GB989401A - Catalytic oxidation of olefins - Google Patents
Catalytic oxidation of olefinsInfo
- Publication number
- GB989401A GB989401A GB10353/63A GB1035363A GB989401A GB 989401 A GB989401 A GB 989401A GB 10353/63 A GB10353/63 A GB 10353/63A GB 1035363 A GB1035363 A GB 1035363A GB 989401 A GB989401 A GB 989401A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- oxygen
- tellurium
- oxidation
- molybdenum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title 1
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052714 tellurium Inorganic materials 0.000 abstract 3
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000011733 molybdenum Substances 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 150000002696 manganese Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- FXADMRZICBQPQY-UHFFFAOYSA-N orthotelluric acid Chemical compound O[Te](O)(O)(O)(O)O FXADMRZICBQPQY-UHFFFAOYSA-N 0.000 abstract 1
- 239000008188 pellet Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- XHGGEBRKUWZHEK-UHFFFAOYSA-L tellurate Chemical compound [O-][Te]([O-])(=O)=O XHGGEBRKUWZHEK-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE642164D BE642164A (enrdf_load_stackoverflow) | 1963-03-15 | ||
NL302701D NL302701A (enrdf_load_stackoverflow) | 1963-03-15 | ||
GB10353/63A GB989401A (en) | 1963-03-15 | 1963-03-15 | Catalytic oxidation of olefins |
US333754A US3345406A (en) | 1963-03-15 | 1963-12-26 | Catalytic oxidation of olefins |
FR959590A FR1380883A (fr) | 1963-03-15 | 1964-01-07 | Oxydation catalytique d'oléfines |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB10353/63A GB989401A (en) | 1963-03-15 | 1963-03-15 | Catalytic oxidation of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB989401A true GB989401A (en) | 1965-04-14 |
Family
ID=9966287
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10353/63A Expired GB989401A (en) | 1963-03-15 | 1963-03-15 | Catalytic oxidation of olefins |
Country Status (4)
Country | Link |
---|---|
US (1) | US3345406A (enrdf_load_stackoverflow) |
BE (1) | BE642164A (enrdf_load_stackoverflow) |
GB (1) | GB989401A (enrdf_load_stackoverflow) |
NL (1) | NL302701A (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5330688B1 (enrdf_load_stackoverflow) * | 1970-11-18 | 1978-08-29 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1425301A (fr) * | 1964-09-15 | 1966-01-24 | Aquitaine Petrole | Catalyseur perfectionné pour l'oxydation d'hydrocarbures |
NL135123C (enrdf_load_stackoverflow) * | 1964-10-06 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2653138A (en) * | 1950-12-07 | 1953-09-22 | Socony Vacuum Oil Co Inc | Tellurium catalysts |
CA627938A (en) * | 1952-10-09 | 1961-09-26 | J. Hadley David | Preparation of unsaturated organic nitriles |
US3065264A (en) * | 1958-12-24 | 1962-11-20 | Du Pont | Vapor phase oxidation of propylene acrylic acid |
NL248487A (enrdf_load_stackoverflow) * | 1959-02-17 |
-
0
- BE BE642164D patent/BE642164A/xx unknown
- NL NL302701D patent/NL302701A/xx unknown
-
1963
- 1963-03-15 GB GB10353/63A patent/GB989401A/en not_active Expired
- 1963-12-26 US US333754A patent/US3345406A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5330688B1 (enrdf_load_stackoverflow) * | 1970-11-18 | 1978-08-29 |
Also Published As
Publication number | Publication date |
---|---|
BE642164A (enrdf_load_stackoverflow) | |
NL302701A (enrdf_load_stackoverflow) | |
US3345406A (en) | 1967-10-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4863891A (en) | Catalyst for the manufacture of acrylonitrile and methacrylonitrile | |
US4066704A (en) | Catalytic oxidation | |
GB878802A (en) | Production of unsaturated aliphatic aldehydes and the corresponding acids | |
US4767878A (en) | Process for the manufacture of acrylonitrile and methacrylonitrile | |
GB821999A (en) | Process for the catalytic oxidation of olefins | |
US4182907A (en) | Process for the oxidation of olefins to aldehydes and acids | |
US3567773A (en) | Production of unsaturated aliphatic acids | |
GB1481039A (en) | Process for preparing unsaturated carboxylic acids and catalyst for use therein | |
US3454630A (en) | Process for the oxidation of olefins to aldehydes and acids | |
US4176234A (en) | Process for the oxidation of olefins to aldehydes and acids | |
US4415482A (en) | Oxidation and ammoxidation catalyst | |
US3574729A (en) | Production of unsaturated aliphatic acids | |
JPS5827255B2 (ja) | 不飽和脂肪酸の製造方法 | |
US3644509A (en) | Oxidation of unsaturated aldehydes to the corresponding acids | |
US3992419A (en) | Method of preparing maleic anhydride and catalysts utilized therefor | |
US3240806A (en) | Process for producing a mixture of unsaturated aliphatic acids and aldehydes | |
US3358020A (en) | Catalytic process for the production of unsaturated aliphatic carboxylic acids | |
US3879453A (en) | Process for producing methacrolein and methacrylic acid | |
US3576764A (en) | Catalyst for the oxidation of olefins to unsaturated aldehydes and acids | |
US3702868A (en) | Process for the preparation of acetic acid by catalytic oxidation of olefines in gaseous phase | |
GB989401A (en) | Catalytic oxidation of olefins | |
US4256914A (en) | Catalytic oxidation of methacrolein | |
GB1115116A (en) | Improvements in the production of unsaturated aliphatic monocarboxylic acids | |
US3408392A (en) | Preparation of alpha, beta-unsaturated carboxylic acids with a molybdenumantimony-vanadium-oxygen ternary catalyst | |
ES452643A1 (es) | Un procedimiento para la preparacion de acido acrilico o a- cido metacrilico. |