GB989375A - Improvements in and relating to resinous compositions - Google Patents

Improvements in and relating to resinous compositions

Info

Publication number
GB989375A
GB989375A GB2420461A GB2420461A GB989375A GB 989375 A GB989375 A GB 989375A GB 2420461 A GB2420461 A GB 2420461A GB 2420461 A GB2420461 A GB 2420461A GB 989375 A GB989375 A GB 989375A
Authority
GB
United Kingdom
Prior art keywords
epoxy
polyvinyl chloride
boron trifluoride
vinylidene
chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2420461A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL24222D priority Critical patent/NL24222C/xx
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Priority to GB1020464A priority patent/GB1037974A/en
Publication of GB989375A publication Critical patent/GB989375A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/145—Compounds containing one epoxy group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/681—Metal alcoholates, phenolates or carboxylates
    • C08G59/682—Alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/72—Complexes of boron halides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)

Abstract

A curable composition comprises a monomeric polyepoxide with at least two cyclohexene oxide groups, a vinylidene polymer and a boron trifluoride-amine complex or an alkyl titanate in which the alkyl group has 1-4 carbon atoms. The compositions may be dissolved in organic liquids or dispersed as organosols or plastisols, useful for coating. Other polyepoxides, and monomeric monoepoxides may be incorporated with the polyepoxide of the invention. Lists of suitable polyepoxides, vinylidene polymers, catalysts and optional conventional additives, e.g. plasticizers, stabilizers, solvents, pigments, fillers are given in the Specification. Examples illustrate compositions containing various combinations of the following ingredients. Polyepoxides.-3,4 - epoxy - 6 - methyl cyclohexylmethyl - 3,4 - epoxy - 6 - methylcyclohexanecarboxylate; bis - (3,4 - epoxy - 6-cyclohexylmethyl) adipate; 3,4 - epoxycyclohexylmethyl 6 - methyl - 3,4 - epoxycyclohexylmethyl ether. Vinylidene polymers. - Polyvinyl chloride; mixed polyvinyl chloride and vinyl chloride-vinylidene chloride copolymer; vinyl chloride, vinyl acetate, vinyl alcohol copolymer; polyacrylonitrile; polystyrene; mixed polyvinyl chloride and a copolymer of ethylene with ethyl acrylate; mixed polyvinyl chloride and polyethylene. Catalysts. - Boron trifluoride - piperidine; boron trifluoride-ethylamine; tetraisopropyl titanate. Examples 25-32 illustrate the use of di-2-ethylhexyl adipate as a plasticizer, Example 32 the use for preparing an organosol of a thinner consisting of xylene, diisobutylketone and a naphtha solvent known as Apcothinner. Example 33 uses a mixture of methyl isobutyl ketone and toluene as a solvent. Specifications 735,974, 768,157, U.S.A. Specifications 2,745,847, 2,750,395, 2,794,030, 2,863,881, 2,874,167 and 2,884,408 are referred to.ALSO:Compositions containing a compound having at least two cyclohexane oxide groups, a vinylidene polymer and a boron trifluoride-amine complex or a lower alkyl titanate curing catalyst are used for coating. In Example 32, an organosol containing polyvinyl chloride, 3,4-epoxy-6-methylcyclohexylmethyl-3, 4-epoxy-6-methylcyclohexanecarboxylate, boron trifluoride-piperidine, di-2-ethylhexyl adipate, xylene, diisobutylketone and a naphtha solvent known as "Apcothinner" (Registered Trade Mark) was sprayed on steel panels having zinc phosphate surface treatment, air-dried and baked. In Example 33, films were cast on glass and on zinc phosphate-treated steel from a solution containing bis(3,4-epoxy-6-methylcyclohexylmethyl) adipate, a copolymer of vinyl chloride, vinyl acetate and vinyl alcohol, boron-trifluoride-piperidine, methyl isobutyl ketone and toluene. The films were air-dried and baked. Specifications 735,974 and 768,157 are referred to.
GB2420461A 1960-07-14 1961-07-05 Improvements in and relating to resinous compositions Expired GB989375A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
NL24222D NL24222C (en) 1961-07-05
GB1020464A GB1037974A (en) 1961-07-05 1961-07-05 Improvements in or relating to transistors

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US4274660A 1960-07-14 1960-07-14

Publications (1)

Publication Number Publication Date
GB989375A true GB989375A (en) 1965-04-14

Family

ID=21923527

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2420461A Expired GB989375A (en) 1960-07-14 1961-07-05 Improvements in and relating to resinous compositions

Country Status (4)

Country Link
AT (1) AT243516B (en)
CH (1) CH405709A (en)
GB (1) GB989375A (en)
NL (1) NL266665A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2197327A (en) * 1986-11-12 1988-05-18 Tohoku Dotetsu Kk Durable epoxy resin paint composition
WO2014181787A1 (en) * 2013-05-10 2014-11-13 株式会社ダイセル Curable epoxy resin composition and cured product thereof, diolefin compound and production method therefor, and production method for diepoxy compound
WO2019192847A1 (en) * 2018-04-04 2019-10-10 Huntsman Advanced Materials Licensing (Switzerland) Gmbh Accelerator composition for the cure of epoxy resins with aromatic amines
RU2780092C2 (en) * 2018-04-04 2022-09-19 Хантсман Эдванст Матириалз Лайсенсинг (Свитзеленд) Гмбх Composition of accelerator of curing epoxy resins with aromatic amines

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5690827A (en) * 1979-12-26 1981-07-23 Toshiba Corp Heat-resistant resin composition

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2197327A (en) * 1986-11-12 1988-05-18 Tohoku Dotetsu Kk Durable epoxy resin paint composition
DE3738193A1 (en) * 1986-11-12 1988-05-26 Tohoku Dotetsu Kk PERMANENT EPOXY RESIN PAINT COMPOSITION
GB2197327B (en) * 1986-11-12 1990-10-03 Tohoku Doutetsu Kk Durable epoxy resin paint composition
WO2014181787A1 (en) * 2013-05-10 2014-11-13 株式会社ダイセル Curable epoxy resin composition and cured product thereof, diolefin compound and production method therefor, and production method for diepoxy compound
CN105452322A (en) * 2013-05-10 2016-03-30 株式会社大赛璐 Curable epoxy resin composition and cured product thereof, diolefin compound and production method therefor, and production method for diepoxy compound
JPWO2014181787A1 (en) * 2013-05-10 2017-02-23 株式会社ダイセル Curable epoxy resin composition and cured product thereof, diolefin compound and method for producing the same, and method for producing diepoxy compound
WO2019192847A1 (en) * 2018-04-04 2019-10-10 Huntsman Advanced Materials Licensing (Switzerland) Gmbh Accelerator composition for the cure of epoxy resins with aromatic amines
CN111936545A (en) * 2018-04-04 2020-11-13 亨斯迈先进材料许可(瑞士)有限公司 Accelerator composition for curing epoxy resins with aromatic amines
JP2021520430A (en) * 2018-04-04 2021-08-19 ハンツマン・アドヴァンスト・マテリアルズ・ライセンシング・（スイッツランド）・ゲーエムベーハー Accelerator composition for curing epoxy resin with aromatic amines
RU2780092C2 (en) * 2018-04-04 2022-09-19 Хантсман Эдванст Матириалз Лайсенсинг (Свитзеленд) Гмбх Composition of accelerator of curing epoxy resins with aromatic amines
CN111936545B (en) * 2018-04-04 2023-07-14 亨斯迈先进材料许可(瑞士)有限公司 Accelerator composition for curing epoxy resins with aromatic amines

Also Published As

Publication number Publication date
CH405709A (en) 1966-01-15
NL266665A (en)
AT243516B (en) 1965-11-10

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