GB980388A - N-substituted derivatives of aminoalkylsiloxanes - Google Patents
N-substituted derivatives of aminoalkylsiloxanesInfo
- Publication number
- GB980388A GB980388A GB5599/62A GB559962A GB980388A GB 980388 A GB980388 A GB 980388A GB 5599/62 A GB5599/62 A GB 5599/62A GB 559962 A GB559962 A GB 559962A GB 980388 A GB980388 A GB 980388A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- siloxane
- atoms
- hydrocarbon radical
- monovalent hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004215 Carbon black (E152) Substances 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 4
- 239000004927 clay Substances 0.000 abstract 3
- 239000006185 dispersion Substances 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 125000000816 ethylene group Chemical class [H]C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 239000008394 flocculating agent Substances 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- -1 siloxanes Chemical class 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- 230000000536 complexating effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229910001447 ferric ion Inorganic materials 0.000 abstract 1
- 230000003311 flocculating effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 150000002924 oxiranes Chemical class 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
Abstract
A siloxane having units of the formula <FORM:0980388/C1/1> wherein R1 is a monovalent hydrocarbon radical, Z is an ethylene or a hydrocarbon-substituted ethylene group, HO is interconnected to N through 2 C atoms, a is 0 or 1, n is an integer of from 3 to 15, b is 0, 1 or 2, R is H, a monovalent hydrocarbon radical or a unit of the formula <FORM:0980388/C1/2> and the N atom is separated from Si by at least 3 C atoms of each CnH2n group (see Division C3), is used as a flocculating agent for aqueous dispersions of clay. Comparative tests given in Example (5) show the superiority of the siloxane of Example (1) over other aminoalkylorganosilicon compounds in flocculating aqueous dispersions of clay.ALSO:A siloxane comprising units of the formula <FORM:0980388/C3/1> wherein R1 is a monovalent hydrocarbon radical, Z is an ethylene or a hydrocarbon-substituted ethylene group, HO is interconnected to N through 2 C atoms, a is 0 or 1, n is an integer of from 3 to 15, b is 0, 1 or 2, R is H, a monovalent hydrocarbon radical or a unit of the formula <FORM:0980388/C3/2> and the N atom is separated from Si by at least 3 C atoms of each Cn\H2n group, can be made by reacting a siloxane comprising aminoalkylsiloxane units of the formula <FORM:0980388/C3/3> with a mono-epoxide, preferably in the presence of a lower aliphatic alcohol or water as catalyst. Suitable epoxides are olefin oxides, epoxy alcohols and glycidyl ethers and esters, examples of which are given. The siloxanes may be co-polymerized with conventional siloxanes containing Si-bonded saturated or unsaturated hydrocarbon radicals. In a typical example (1) ethylene oxide was passed into an ethanol solution of a liquid delta aminobutylmethylsiloxane -dimethylsiloxane copolymer to yield an oil of the formula <FORM:0980388/C3/4> wherein Me=methyl; the cyclic tetramers <FORM:0980388/C3/5> were similarly prepared in Examples (2) and (3) respectively. Uses: As flocculating agents for aqueous dispersions of clay; and as complexing or co-ordinating agents for removing metal ions, particularly cupric and ferric ions, from aqueous solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5599/62A GB980388A (en) | 1962-02-14 | 1962-02-14 | N-substituted derivatives of aminoalkylsiloxanes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5599/62A GB980388A (en) | 1962-02-14 | 1962-02-14 | N-substituted derivatives of aminoalkylsiloxanes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB980388A true GB980388A (en) | 1965-01-13 |
Family
ID=9799123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5599/62A Expired GB980388A (en) | 1962-02-14 | 1962-02-14 | N-substituted derivatives of aminoalkylsiloxanes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB980388A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2144725A (en) * | 1983-08-04 | 1985-03-13 | Dow Corning | Dewatering of mineral slurries |
| EP0335407A2 (en) * | 1988-03-31 | 1989-10-04 | Union Carbide Corporation | Polyolefin compositions containing polyorganosiloxanes and the use thereof in the production of film material |
-
1962
- 1962-02-14 GB GB5599/62A patent/GB980388A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2144725A (en) * | 1983-08-04 | 1985-03-13 | Dow Corning | Dewatering of mineral slurries |
| EP0335407A2 (en) * | 1988-03-31 | 1989-10-04 | Union Carbide Corporation | Polyolefin compositions containing polyorganosiloxanes and the use thereof in the production of film material |
| EP0335407A3 (en) * | 1988-03-31 | 1991-03-27 | Union Carbide Corporation | Polyolefin compositions containing polyorganosiloxanes and the use thereof in the production of film material |
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