GB970969A - Dicarboxylic acids and their esters and a process for the preparation thereof - Google Patents
Dicarboxylic acids and their esters and a process for the preparation thereofInfo
- Publication number
- GB970969A GB970969A GB3230863A GB3230863A GB970969A GB 970969 A GB970969 A GB 970969A GB 3230863 A GB3230863 A GB 3230863A GB 3230863 A GB3230863 A GB 3230863A GB 970969 A GB970969 A GB 970969A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- aryl
- formula
- halo
- naoh
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C3/00—Vessels not under pressure
- F17C3/02—Vessels not under pressure with provision for thermal insulation
- F17C3/08—Vessels not under pressure with provision for thermal insulation by vacuum spaces, e.g. Dewar flask
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
- C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
- C07C59/66—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
- C07C59/68—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
- C07C65/24—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups polycyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds of formula <FORM:0970969/C1/1> wherein R1 and R2 are H, alkyl or aryl and R3 is alkyl or aryl, or both R2 and R3 may be part of a carbocyclic ring; Ar has the formula <FORM:0970969/C1/2> wherein the substituents R4 - - - R7 and R10 - - - R13 are H, halogen, alkyl or aryl, R8 and R9 are H, alkyl or aryl. Compounds of the first formula, wherein R1 is H, R2 and R3 are as above defined and Ar is arylene, are made by reacting a dihydroxy-arene with NaOH or KOH and a halo-alcohol containing the structural unit >C(OH)CX3, X being Cl, Br or I and neutralizing the product; a ketone plus a halo-form may be used as an alternative to the halo-alcohol. The examples describe the reaction of chloroform, NaOH and 2,2-bis(4-hydroxyphenyl) propane to give 2,2-bis [4-carboxy-1-methyl-ethoxy)phenyl] propane and the conversion of this dicarboxylic acid to its dimethyl ester.ALSO:Polyesters may be prepared by reacting with glycol a compound of formula <FORM:0970969/C3/1> wherein R1 is H or lower alkyl e.g. methyl, R3 is alkyl or aryl and R2, R8 and R9 are H, alkyl or aryl, or R2 and R3 are part of a carboxylic ring; the benzene rings in the formula may be substituted with halogen, alkyl or aryl groups.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3230863A GB970969A (en) | 1963-08-15 | 1963-08-15 | Dicarboxylic acids and their esters and a process for the preparation thereof |
FR985151A FR1404919A (en) | 1963-08-15 | 1964-08-13 | Dicarboxylic acids and their esters and process for their preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3230863A GB970969A (en) | 1963-08-15 | 1963-08-15 | Dicarboxylic acids and their esters and a process for the preparation thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
GB970969A true GB970969A (en) | 1964-09-23 |
Family
ID=10336579
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3230863A Expired GB970969A (en) | 1963-08-15 | 1963-08-15 | Dicarboxylic acids and their esters and a process for the preparation thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB970969A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2042333A1 (en) * | 1969-04-16 | 1971-02-12 | Sumitomo Chemical Co | |
EP0122204A1 (en) * | 1983-04-13 | 1984-10-17 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Containers having improved gas barrier properties |
EP0217267A2 (en) * | 1985-09-27 | 1987-04-08 | General Electric Company | Bis(dialkyl aromatic ether anhydride) and polymers obtained therefrom |
EP0295106A2 (en) * | 1987-06-10 | 1988-12-14 | Canon Kabushiki Kaisha | Optically active polymer and liquid crystal composition containig same |
WO2004113266A1 (en) * | 2003-06-20 | 2004-12-29 | Sigma-Tau Industrie Farmaceutiche Riunite S.P.A. | Derivatives of phenylalkyl and phenoxyalkyl acids for the treatment of the hyperglycaemia and hypertriglyceridaemia and type 2 diabetes and process for preparing them |
-
1963
- 1963-08-15 GB GB3230863A patent/GB970969A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2042333A1 (en) * | 1969-04-16 | 1971-02-12 | Sumitomo Chemical Co | |
EP0122204A1 (en) * | 1983-04-13 | 1984-10-17 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Containers having improved gas barrier properties |
WO1984004100A1 (en) * | 1983-04-13 | 1984-10-25 | Eastman Kodak Co | Polyesters having improved gas barrier properties and containers made therefrom |
JPS60501060A (en) * | 1983-04-13 | 1985-07-11 | イ−ストマン・コダック・カンパニ− | Polyester with improved gas barrier properties and containers made from it |
EP0217267A2 (en) * | 1985-09-27 | 1987-04-08 | General Electric Company | Bis(dialkyl aromatic ether anhydride) and polymers obtained therefrom |
EP0217267A3 (en) * | 1985-09-27 | 1988-03-23 | General Electric Company | Bis(dialkyl aromatic ether anhydride) and polymers obtained therefrom |
EP0295106A2 (en) * | 1987-06-10 | 1988-12-14 | Canon Kabushiki Kaisha | Optically active polymer and liquid crystal composition containig same |
EP0295106A3 (en) * | 1987-06-10 | 1989-03-15 | Canon Kabushiki Kaisha | Optically active polymer and liquid crystal composition containig same |
US4892675A (en) * | 1987-06-10 | 1990-01-09 | Canon Kabushiki Kaisha | Optically active polymer and liquid crystal composition containing same |
WO2004113266A1 (en) * | 2003-06-20 | 2004-12-29 | Sigma-Tau Industrie Farmaceutiche Riunite S.P.A. | Derivatives of phenylalkyl and phenoxyalkyl acids for the treatment of the hyperglycaemia and hypertriglyceridaemia and type 2 diabetes and process for preparing them |
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