GB969237A - A method of preparing unipositional alkylated monohydric and polyhydric phenols - Google Patents

A method of preparing unipositional alkylated monohydric and polyhydric phenols

Info

Publication number
GB969237A
GB969237A GB2735661A GB2735661A GB969237A GB 969237 A GB969237 A GB 969237A GB 2735661 A GB2735661 A GB 2735661A GB 2735661 A GB2735661 A GB 2735661A GB 969237 A GB969237 A GB 969237A
Authority
GB
United Kingdom
Prior art keywords
unipositional
preparing
polyhydric phenols
alkylated monohydric
alkylated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2735661A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIRI GASPARIC
MILAN MORAK
Original Assignee
JIRI GASPARIC
MILAN MORAK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIRI GASPARIC, MILAN MORAK filed Critical JIRI GASPARIC
Publication of GB969237A publication Critical patent/GB969237A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/48Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by exchange of hydrocarbon groups, which may be substituted, from the same of other compounds, e.g. transalkylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08Ion-exchange resins
    • B01J31/10Ion-exchange resins sulfonated
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52Isomerisation reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Unipositional akylated phenols are obtained by isomerising a mixture of alkylated phenols by heating at 150-170 DEG C. in presence of a cationic resin such as sulphonated styrene-divinyl benzene copolymer. The examples describe the preparation of pt-butyphenol and 4-t-butylcatechol. U.S.A. Specifications 2,514,419, 2,516,152, 2,584,103 2,684,389 and U.S.S.R. Specification 109,978 are referred to.
GB2735661A 1960-07-30 1961-07-28 A method of preparing unipositional alkylated monohydric and polyhydric phenols Expired GB969237A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CS479260 1960-07-30

Publications (1)

Publication Number Publication Date
GB969237A true GB969237A (en) 1964-09-09

Family

ID=5391462

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2735661A Expired GB969237A (en) 1960-07-30 1961-07-28 A method of preparing unipositional alkylated monohydric and polyhydric phenols

Country Status (1)

Country Link
GB (1) GB969237A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6486339B2 (en) 1999-02-02 2002-11-26 Akzo Nobel Nv Phosphorylated product made by heating alkylated phenol in presence of solid acid catalyst

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6486339B2 (en) 1999-02-02 2002-11-26 Akzo Nobel Nv Phosphorylated product made by heating alkylated phenol in presence of solid acid catalyst
US6784325B2 (en) 1999-02-02 2004-08-31 Akzo Nobel N.V. Isomerization of alkyl phenol with a solid acid catalyst

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