GB966776A - Refractory compacts and their manufacture - Google Patents
Refractory compacts and their manufactureInfo
- Publication number
- GB966776A GB966776A GB45795/61A GB4579561A GB966776A GB 966776 A GB966776 A GB 966776A GB 45795/61 A GB45795/61 A GB 45795/61A GB 4579561 A GB4579561 A GB 4579561A GB 966776 A GB966776 A GB 966776A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pressure
- minutes
- raised
- temperature
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/58085—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicides
- C04B35/58092—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicides based on refractory metal silicides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Powder Metallurgy (AREA)
- Lubricants (AREA)
Abstract
<PICT:0966776/C1/1> Powdered compositions consisting essentially of 20-53% Si, 40-65% Mo, 1-19% N, and 5-20% ZrO2, ZnO or Cr2O3 are used to manufacture shaped objects by heating under pressure until a substantially homogeneous sintering and alloying occurs and allowing the so-formed object to cool to room temperature. Starting materials specified are silicon nitride, molybdenum disilicide and elemental molybdenum. Up to 5% of inert diluents, e.g. Al, Mn, Ca, Mg, Cu and Ni may be present as elements or oxides. As described, these starting materials as powders are milled in the presence of benzene (water and 1-5% NaOH are also mentioned), dried and screened. Pre-ground dry ZrO2 is then added and the whole blended to give a mixture having a particle size predominantly of 1-3 micron. Acceptable products are formed where the particle size is up to 75 microns of which 75% are less than 5 microns. Die nibs for hot metal extrusion are manufactured by placing the composition at 16 (Fig. 2), in a bore 9 in a cylindrical graphite mould 10 having a base plate 11 through which a core piece 12 extends, tamping with plunger 17 and placing the assembly in a hydraulic press. 1000 p.s.i. is applied at room temperature and the temperature raised to 1200 DEG C. in 8 minutes thereupon the pressure is raised to 2000 p.s.i. and heating continued to 1600 DEG C. in 5 minutes. The pressure is again raised to 3000 p.s.i., the composition "soaked" for 30 minutes when the temperature is raised to 1650 DEG C. in 1 minute and the pressure to 4000 p.s.i. After 5 minutes the pressure and temperature are discontinued. The shaped objects have high lubricity and toughness and when used in die nibs for extruding metals, no lubricant is required. The composition may be first partly reacted and alloyed, pulverized and then re-sintered to form the desired compact. Specifications 924,414, 966,774 and 966,775 are referred to.ALSO:<PICT:0966776/C6-C7/1> Powdered compositions consisting essentially of 20-53% Si, 40-65% Mo, 1-19% N, and 5-20% ZrO2, ZnO or Cr2O3 are used to manufacture shaped objects by heating under pressure until a substantially homogeneous sintering an alloying occurs and allowing the so formed object to cool to room temperature. Starting materials specified are silicon nitride, molybdenum disilicide and elemental molybdenum. Up to 5% of inert diluents, e.g. Al, Mn, Cr, Mg, Cu and Ni may be present as elements or oxides. As described, these starting materials as powders are milled in the presence of benzene (water and 1-5% NaOH are also mentioned), dried and screened. Pre-ground dry ZrO2 is then added and the whole blended to give a mixture having a particle size predominantly of 1-3 microns. Acceptable products are formed where the particle size is up to 75 microns of which 75% are less than 5 microns. Die nibs for hot metal extrusion are manufactured by placing the composition at 16, Fig. 2, in a bore 9 in a cylindrical graphite mould 10 having a base plate 11 through which a core piece 12 extends, tamping with plunger 17 and placing the assembly in a hydraulic press. 1000 p.s.i. is applied at room temperature and the temperature raised to 1200 DEG C. in 8 minutes thereupon the pressure is raised to 2000 p.s.i. and heating continued to 1600 DEG C. in 5 minutes. The pressure is again raised to 3000 p.s.i., the composition "soaked" for 30 minutes when the temperature is raised to 1650 DEG C. in 1 minute and the pressure to 4000 p.s.i. After 5 minutes the pressure and temperature are discontinued. The shaped objects have high lubricity and toughness and when used in die nibs for extruding metals no lubricant is required. The composition may be first partly reacted and alloyed, pulverized and then resintered to form the desired compact. Specifications 924,414, 966,774 and 966,775 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78088A US3110091A (en) | 1960-12-23 | 1960-12-23 | Refractory compact manufacture |
Publications (1)
Publication Number | Publication Date |
---|---|
GB966776A true GB966776A (en) | 1964-08-19 |
Family
ID=22141829
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB45795/61A Expired GB966776A (en) | 1960-12-23 | 1961-12-21 | Refractory compacts and their manufacture |
Country Status (2)
Country | Link |
---|---|
US (1) | US3110091A (en) |
GB (1) | GB966776A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1450562A (en) * | 1964-06-01 | 1966-08-26 | Du Pont | Refractory dispersions and their preparation process |
US6863862B2 (en) * | 2002-09-04 | 2005-03-08 | Philip Morris Usa Inc. | Methods for modifying oxygen content of atomized intermetallic aluminide powders and for forming articles from the modified powders |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2866259A (en) * | 1956-02-20 | 1958-12-30 | Du Pont | Powder metallurgy compositions of molybdenum, iron and silicon, shaped objects thereof, and their preparation |
US2982619A (en) * | 1957-04-12 | 1961-05-02 | Roger A Long | Metallic compounds for use in hightemperature applications |
US2878113A (en) * | 1958-04-17 | 1959-03-17 | Du Pont | Fe-si-ti composition or product and process of preparing same |
-
1960
- 1960-12-23 US US78088A patent/US3110091A/en not_active Expired - Lifetime
-
1961
- 1961-12-21 GB GB45795/61A patent/GB966776A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
US3110091A (en) | 1963-11-12 |
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